| HS Code | 634214 |
| Material Type | UHMW-PE |
| Density | 0.93 g/cm3 |
| Tensile Strength At Yield | 19 MPa |
| Tensile Modulus | 750 MPa |
| Elongation At Break | >300% |
| Shore D Hardness | 62 |
| Ball Indentation Hardness | 35 MPa |
| Charpy Notched Impact Strength | No break |
| Coefficient Of Friction | 0.10-0.20 |
| Water Absorption | <0.01% |
| Thermal Conductivity | 0.41 W/mK |
| Coefficient Of Linear Thermal Expansion | 150 x10^-6 /K |
| Melting Point | 135 °C |
| Maximum Continuous Service Temperature | 80 °C |
| Heat Deflection Temperature At 1 8 Mpa | 42 °C |
| Flammability | UL 94 HB |
| Volume Resistivity | >10^14 ohm-cm |
| Dielectric Strength | 45 kV/mm |
| Molecular Weight | 4.5 million g/mol |
| Color | Natural, Black, Green, Blue |
As an accredited Mitsubishi Chemical Advanced Materials UHMW-PE TIVAR factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Mitsubishi Chemical Advanced Materials UHMW-PE TIVAR is packaged as protective-wrapped sheets on pallets, with 10 sheets per pallet. |
| Container Loading (20′ FCL) | 20′ FCL container loaded with Mitsubishi Chemical Advanced Materials UHMW-PE TIVAR sheets or rods, palletized, braced, and secured for export. |
| Shipping | Mitsubishi Chemical Advanced Materials UHMW-PE TIVAR ships as a non-hazardous solid polymer in sheets, rods, or profiles. No DOT/IMDG/IATA hazardous classification is required. Pack in standard crates or pallets, protect from UV, moisture, and contamination, and transport at ambient temperature. Follow supplier documentation and local regulations. |
| Storage | Store TIVAR UHMW-PE in a cool, dry, well-ventilated area away from direct sunlight, heat, ignition sources, and strong oxidizing agents. Keep in original packaging or clean covered racks to prevent dust, oils, and contamination. Avoid excessive loads, sharp impacts, and deformation. Store flat or supported to prevent warping. Maintain moderate temperatures; do not store near flames or high heat. |
| Shelf Life | Mitsubishi Chemical's UHMW-PE TIVAR has indefinite shelf life if stored in original packaging away from sunlight, heat, and moisture. |
The replacement of acetal and copolyester wear components in high-speed beverage filling lines is driven by the coefficient of friction of Mitsubishi Chemical Advanced Materials TIVAR 1000 UHMW-PE against polished stainless steel, which is reported in the range of 0.10–0.20 when measured according to ASTM D1894. The formulation addition ratio for this sector is normally 100 wt% virgin TIVAR 1000; no plasticizer, filler, external lubricant, or anti-block additive is compounded into the stock shape because each of those modifications depresses the notched impact energy and creates a microenvironment for cleaning-chemical uptake. Where converters use closed-loop regrind from uncontaminated off-cuts, the addition is limited to ≤15 wt%, and only in compression-moulded blanks that are not designated for food-contact use; lot traceability must extend back to the original resin certificate because reprocessed material is not automatically covered by the food-contact declaration. Downstream production begins with stress-relieved extruded sheet or ram-extruded profiles, typically cut on gantry CNC routers with polished carbide tools at spindle speeds adjusted to avoid melt smearing; waterjet cutting is not preferred for thick sections because moisture entrapment in kerf walls can affect post-machining dimensional stability. Thermal expansion of UHMW-PE is in the order of 1.3–2.0×10-4 K-1, so machined guide rails require slotted holes and shoulder washers; press-fitting bottle gripper inserts into metal carriers without clearance causes buckling at hot-water washdown cycles up to 80 °C, and continuous service above this boundary reduces allowable bearing pressure. Compliance is anchored to FDA 21 CFR 177.1520 for olefin polymers intended for repeated food contact and to Regulation (EU) No 10/2011 with overall migration limits; converters must confirm the specific TIVAR grade against the lot-specific certificate because the food-contact status is grade-dependent, not family-wide. Terminal finished product types include star wheels, feed screws, deadplates, neck guides, bottle grippers, and chain guide profiles used in carbonated soft drinks, beer, dairy, and edible oil filling lines; published data for dry sliding wear in carbonated soft drink filling machines is limited to equipment-specific validation trials rather than a single universal PV limit.
In bulk solids handling, chute liners fabricated from TIVAR 1000 are installed in coal, cement, and grain transfer points because the material’s low surface energy reduces build-up and its abrasion resistance extends liner life relative to structural steel in dry sliding contact, as characterised by laboratory tests such as ASTM G65. The formulation addition ratio is 100 wt% UHMW-PE without filler; the use of recycled polymer from post-consumer streams is excluded from this application because molecular weight reduction leads to early fracture at bolt holes and joint edges. Downstream production consists of waterjet or CNC router cutting from 10–50 mm sheet, followed by through-bolting with slotted holes that accommodate the thermal expansion coefficient of 1.3–2.0×10-4 K-1; hot gas extrusion welding with UHMW-PE rod is used only at butt joints where material movement can be absorbed by the welded bead. Compliance for bulk solids handling is governed by REACH and RoHS; mining-specific static discharge requirements require site-specific assessment because unmodified UHMW-PE is an insulator and can generate surface charges. Terminal products include silo liners, hopper cones, chute liners, chain guides, dump truck bed liners, railcar liner panels, and screw conveyor trough liners. Published data for abrasive wear in high-velocity coal transfer is limited to site-specific testing; laboratory abrasion tests do not fully represent impact impingement conditions.
Sludge scraper flights in municipal and industrial wastewater clarifiers operate in a continuous water-saturated environment where hygroscopic dimensional change and grit abrasion dictate replacement intervals. In this sector, the formulation addition ratio is 100 wt% virgin TIVAR 1000; no hygroscopic filler is permitted because filler-matrix interfaces would increase water absorption and create sites for biological fouling. Water absorption after 24 h immersion is reported below 0.01% according to ISO 62, which allows machined wear shoes to maintain width tolerances even when clarifiers are drained and refilled. Downstream processing involves CNC milling of blocks into scraper shoes, chain guide rails, and sprocket idler bushings; tooling must use positive rake geometry and compressed air cooling because UHMW-PE has a low thermal conductivity of approximately 0.40 W/m·K, and heat accumulation at the cut surface causes local expansion and dimensional overshoot. Installation uses stainless steel fasteners with shoulder washers and enlarged holes; welding is generally avoided in sludge contact zones because weld beads become stress concentrators under alternating bending loads. Compliance requirements are REACH and RoHS, with additional site-specific wastewater authority approvals where the component contacts potable water or chemically conditioned sludge. Terminal finished products include rectangular scraper shoes, chain sliding guides, sprocket bushings, torque arm bearing pads, and overflow weir slide plates. Published data for sludge-specific abrasive wear is limited; equipment owners typically evaluate via annual flight chain wear measurements rather than accelerated laboratory bench tests.
To resist hydrolysis, galvanic corrosion, and stress cracking in aggressive aqueous chemical metering systems, components are machined from TIVAR 1000 stock shapes. The formulation addition ratio is 100 wt% TIVAR 1000; no plasticizer or foreign polymer phase is included because plasticizer migration would change clearance gaps in close-running pump wear rings and valve seats. Chemical resistance is assessed under ISO 175 by immersion in the specific media, temperature, and concentration expected in service; general resistance charts must not be used as the sole qualification basis for oxidizing acids or biocides at the upper service temperature. Downstream production uses compression-moulded or ram-extruded blanks machined on CNC lathes; a tolerance of ±0.05 mm on valve seat outer diameters is achievable when machining is followed by a 24 h normalization rest at 23 °C before final inspection. Because adhesive bonding is ineffective on low-surface-energy UHMW-PE, inserts are retained by mechanical interference or flanged geometries, not by epoxy joints. The compliance framework is REACH, RoHS, and, for EU machinery, the applicable clauses of 2006/42/EC only insofar as the polymer part contributes to safety functions. Terminal finished products include diaphragm pump valve seats, centrifugal pump wear rings, sliding vanes, seal gland bushings, and metering pump slide pads. Published data for this specific configuration is limited in high-concentration hydrochloric acid above 40 °C, so plant qualification should include immersion testing under actual concentration and temperature.
Where berthing loads combine low-angle abrasion with intermittent high-strain impact, UHMW-PE wear pads are specified as sacrificial surfaces between vessel hulls and fixed structures. The formulation addition ratio is 100 wt% UHMW-PE for natural marine wear pads; for black UV-stabilized marine grades, a compounder-specific UV masterbatch is added at a loading that is not public, but the producer’s lot certificate should identify the grade as UHMW-PE with an additive content below 5 wt%. A conditional processing boundary exists: unmodified TIVAR 1000 is not suitable for constant direct sunlight without carbon black or UV stabilizers because surface oxidation embrittles the outermost 0.5–1.0 mm layer over successive seasons, so converters should specify UV-stabilized grades for above-water fender contact faces. Downstream production involves CNC routing from 25–100 mm sheet, followed by chamfering of bolt holes and fitting with stainless steel or duplex steel fasteners; polyurethane pads are sometimes substituted for low-abrasion applications but fail earlier under high rubbing velocities against steel hulls. Compliance for marine infrastructure uses REACH, RoHS, and the applicable requirements of the EU Construction Products Regulation only when the fender pad is part of a CE-marked fender system; otherwise, material certification is based on manufacturer lot test certificates. Terminal finished products include dock fender pads, pile guide strips, offshore boat landing pads, conveyor wear strips on ship-to-shore unloaders, and hatch cover wear pads. Published data for wave-zone impact fatigue is limited; equipment designers generally calculate bearing pressure using the manufacturer’s tensile yield stress, which for TIVAR 1000 is reported above 17 MPa according to ISO 527-2.
In ISO Class 5–7 cleanrooms used for semiconductor front-end handling, static dissipative UHMW-PE components are machined from TIVAR CleanStat stock shapes because unmodified UHMW-PE can accumulate surface charge during low-humidity transport. The formulation addition ratio is not a simple virgin polymer condition: the static dissipative grade is a compounded UHMW-PE system with a conductive additive loading that yields a surface resistivity between 106 and 109 Ω when measured according to IEC 60093; the exact filler percentage is proprietary and grade-specific, but the compound remains UHMW-PE-based. Downstream production requires strict machining hygiene: cutting tools must be dedicated to antistat-modified UHMW-PE to avoid metallic or carbon contamination, and vacuum extraction at the spindle removes fines that would otherwise compromise cleanroom particle counts. Post-machining cleaning uses deionized water and IPA-approved wipes, not solvent immersion, because prolonged solvent exposure can extract low-molecular-weight conductive additive and shift surface resistivity. Compliance is framed by IEC 61340-5-1 for electrostatic control and by cleanroom materials qualification protocols such as outgassing and particle shedding limits; components intended for direct wafer contact require additional fab-specific testing because published data for TIVAR CleanStat in specific wafer-handling configurations is limited. Terminal finished products include wafer cassette guides, end-effector pads, conveyor wear strips, transport tray rails, and equipment access panels. The operational boundary is that static dissipative performance is surface-sensitive, so resurfacing by machining removes the modified layer and requires re-qualification of resistivity.
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Mitsubishi Chemical Advanced Materials supplies UHMW-PE TIVAR as a family of ultrahigh-molecular-weight polyethylene stock shapes and machined components. The base polymer is a linear polyethylene with molecular mass reported in industrial literature above 1 × 10⁶ g/mol, placing it within the ASTM D4020 category for UHMW-PE. Standard TIVAR 1000 is converted into compression-moulded sheet and ram-extruded rod; finished parts are produced by CNC milling, sawing, drilling, or butt welding. Published datasheets for unfilled TIVAR list density in the range 0.93–0.94 g/cm³ under ISO 1183-1, tensile yield stress near 17–22 MPa under ISO 527-2, Shore D hardness in the low 60s under ISO 868, and Charpy unnotched impact commonly reported as no break under ISO 179-1/1eU. Water absorption after 24 h is below 0.01% under ISO 62, which is lower than typical polyamide 6 and contributes to greater dimensional stability in wet service. Typical uses include chute liners, silo liners, wear strips, chain guides, star wheels, guide rails, and bearing blocks in solids-handling, packaging, and chemical process equipment.
The principal difference between TIVAR and ordinary high-density polyethylene is the absence of measurable melt flow at standard processing conditions. Under ISO 1133-1, HDPE is routinely measured at 190 °C/21.6 kg, whereas UHMW-PE produces no stable melt flow because of its exceptionally high molecular mass. This molecular characteristic translates directly into a different wear response. In dry sliding against polished steel, published coefficient-of-friction ranges for unfilled UHMW-PE are commonly reported at 0.10–0.20 under ASTM D1894, compared with HDPE values that generally sit higher and are more affected by surface roughness. The longer polymer chains in TIVAR reduce the rate of surface material removal in abrasion-dominated applications such as sand-laden slurry flow and particulate impact.
| Property | Test method | UHMW-PE TIVAR | HDPE |
|---|---|---|---|
| Density | ISO 1183-1 | 0.93–0.94 g/cm³ | 0.94–0.96 g/cm³ |
| Tensile yield stress | ISO 527-2 | 17–22 MPa | 22–30 MPa |
| Shore D hardness | ISO 868 | 62–66 | 58–64 |
| Dynamic coefficient of friction against polished steel, dry | ASTM D1894 | 0.10–0.20 | 0.15–0.30 |
| Water absorption after 24 h | ISO 62 | <0.01% | 0.01–0.02% |
The friction and wear advantage of TIVAR over HDPE is not uniform across all conditions. At high speeds and low loads, the difference between UHMW-PE and HDPE narrows, and polyoxymethylene or lubricated polyamide may outperform both. The TIVAR material is most differentiated in low-speed, high-load, wet, or abrasive environments where its low surface energy and high impact tolerance prevent fracture. In contrast, HDPE is more easily machined into thin sections but shows lower abrasion resistance in particulate conveying.
Because UHMW-PE does not undergo conventional melt processing, the conversion route for TIVAR components imposes design constraints on wall thickness and residual stress. Compression-moulded sheet and ram-extruded rod are produced at temperatures above the crystalline melting point, with industrial compression moulding commonly reported at platen temperatures near 180–220 °C and holding pressures in the low 5–10 MPa range. The low thermal conductivity of UHMW-PE, approximately 0.41 W/(m·K), extends heating and cooling cycles compared with HDPE or polyamide. Production-scale presses must therefore apply controlled cooling ramps to prevent internal voids, surface sinks, and warpage in thick sections. Ram extrusion of TIVAR rod is slower than continuous HDPE extrusion because the material must be intermittently pressed through the heated die rather than conveyed by screw rotation. These processing constraints explain why TIVAR is generally supplied as stock shapes and machined parts rather than as thin-wall injection-moulded profiles.
TIVAR is not a single formulation. Unfilled TIVAR 1000 is used for general wear and impact service. Specialty grades include TIVAR H.O.T. for elevated-temperature dry-running service, TIVAR ESD and TIVAR CleanStat for static-dissipative applications, TIVAR Clean for food-contact and pharmaceutical use, and filled variants for modified friction or wear response. Because filled and modified grades contain additives, their tensile strength, abrasion resistance, coefficient of friction, and compliance differ from standard TIVAR 1000. Published data for each specific grade should be obtained from the manufacturer technical datasheet; unfilled-grade values must not be applied to filled or static-dissipative formulations. For food-contact applications, unfilled natural UHMW-PE can be evaluated under FDA 21 CFR 177.1520 and EU Regulation 10/2011 when appropriate raw materials and good manufacturing practices are used. Specific migration testing depends on final article geometry, food simulant, and contact time. Static-dissipative grades are typically evaluated by surface resistivity under IEC 62631-3-2 or ANSI/ESD STM11.11. REACH and RoHS declarations must be confirmed with the manufacturer for each grade, particularly for black and filled variants containing conductive carbon or other functional additives.
If a loaded bushing or bearing housing requires high compressive yield strength above 40 MPa, standard UHMW-PE is generally not selected because unfilled polyamide 6 and polyoxymethylene provide higher tensile and flexural moduli. The upper continuous service temperature of standard TIVAR is commonly cited at 80 °C; short-term excursions above 90 °C reduce load-bearing capacity because the material softens. Sustained static load at elevated temperature should be evaluated under ISO 899-2 for creep. In high-PV dry-running bushings, polyoxymethylene and internally lubricated polyamide exhibit better dimensional stability and lower wear at high load, while TIVAR is preferred in wet, low-speed, high-abrasion environments where polyamides absorb water and polyoxymethylene may be more sensitive to abrasive wear. TIVAR should be avoided with strong oxidizing acids, and aromatic hydrocarbons can cause swelling. Chemical resistance data should be confirmed under ISO 175 for the specific chemical concentration and temperature.
In cement plants and grain handling terminals, TIVAR liners are installed in chutes, silo discharge cones, and belt conveyor skirtboards. The liners are typically supplied as compression-moulded sheets that are cut, drilled, and countersunk on site. Field installations require slotted holes or oversized clearance to accommodate thermal expansion because UHMW-PE has a higher coefficient of linear thermal expansion than the steel substrate. In abrasive transfer points, the liner is often specified in thicknesses above 10 mm to allow periodic resurfacing or replacement. The low friction surface reduces material hang-up in sticky or high-moisture bulk solids, but the supporting steel structure must provide continuous backing because UHMW-PE is not a structural material. Published data for specific chute configurations is limited; abrasion rate depends on particle velocity, impact angle, particle hardness, and liner thickness, so field trials are recommended before full-scale deployment.