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Mitsubishi Chemical Advanced Materials UHMW-PE SUPERPLUS

    • Product Name: Mitsubishi Chemical Advanced Materials UHMW-PE SUPERPLUS
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 871229
    Material UHMW-PE (Ultra-High Molecular Weight Polyethylene)
    Color Green
    Density 0.94 g/cm³
    Water Absorption 0.01 %
    Tensile Strength At Yield 17 MPa
    Elongation At Break 300 %
    Tensile Modulus 700 MPa
    Hardness Shore D 62
    Notched Impact Strength No break
    Coefficient Of Friction 0.10
    Abrasion Resistance 90 mm³ (DIN 53516)
    Melting Point 135 °C
    Maximum Continuous Service Temperature 80 °C
    Thermal Conductivity 0.42 W/(m·K)
    Coefficient Of Linear Thermal Expansion 2.0 x 10^-4 /°C
    Volume Resistivity >10^14 Ω·cm
    Dielectric Strength 45 kV/mm
    Chemical Resistance Resistant to most acids, alkalis, and solvents

    As an accredited Mitsubishi Chemical Advanced Materials UHMW-PE SUPERPLUS factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Mitsubishi Chemical Advanced Materials UHMW-PE SUPERPLUS ships as one sheet per pallet, wrapped in film, edge-protected, banded, and labeled.
    Container Loading (20′ FCL) 20′ FCL container loaded with Mitsubishi Chemical Advanced Materials UHMW-PE SUPERPLUS, palletized and secured to prevent shifting during transport.
    Shipping Mitsubishi Chemical Advanced Materials UHMW-PE SUPERPLUS is shipped as a non-hazardous, non-regulated solid polymer. Use clean, dry, sealed packaging on pallets or in crates. No UN number, hazard class, or packing group required. Protect from UV, moisture, contamination, and impact; transport at ambient temperature. Follow applicable local and carrier rules.
    Storage Store Mitsubishi Chemical Advanced Materials UHMW-PE SUPERPLUS in a cool, dry, well-ventilated area away from direct sunlight, heat, flames, and strong oxidizers. Keep it in original packaging, protected from UV and contamination. Avoid excessive stacking or loading that may deform stock shapes. No special ventilation is normally required; follow local regulations and supplier guidance. Always store away from sharp objects.
    Shelf Life Mitsubishi Chemical Advanced Materials UHMW-PE SUPERPLUS: indefinite shelf life when stored dry, away from sunlight, heat, moisture; no expiration specified.
    Application of Mitsubishi Chemical Advanced Materials UHMW-PE SUPERPLUS

    In high-volume poultry and red-meat processing lines, Mitsubishi Chemical Advanced Materials UHMW-PE Superplus sheet stock is machined into guide rails, chain wear strips, and cutting-table inserts because the base resin meets the olefin polymer requirements of FDA 21 CFR 177.1520 and falls below the 10 mg/dm² overall migration limit under the aqueous, acidic, and low-alcohol food simulants of EU Regulation No 10/2011. Stress-relieved plate is used instead of as-extruded skinned sections because residual stress in thicker stock produces localised dimensional drift during alternating washdown and refrigerated cycles. A 1 000 mm rail subjected to a 30 K temperature swing from a chilled processing room to hot-water sanitation changes length by approximately 5.4 mm to 6.0 mm based on a published coefficient of linear thermal expansion of 1.8 × 10⁻⁴ K⁻¹ to 2.0 × 10⁻⁴ K⁻¹; therefore installation holes are slotted and bolted connections are not clamped rigidly across the full flange width. ISO 62 water absorption after 24 h immersion is typically below 0.01% by mass, so the dimension change originates almost wholly from thermal gradient rather than moisture uptake. Peracetic acid solutions of 1 000 ppm to 2 000 ppm and sodium hypochlorite solutions up to 10% are routinely used without embrittlement, but continuous exposure to oxidative sanitisers at surface temperatures above 80°C is not recommended because creep modulus falls and retained machining stress can relax into flatness errors exceeding 0.3 mm per 1 000 mm. On actual processing lines, machining uses cutting speeds of 120 m/min to 180 m/min, positive rake angles of 5° to 10°, and through-tool air cooling rather than soluble-oil flood coolant to avoid swarf clogging and surface waviness that can harbour biofilm.

    Standard / regulationTest conditionRelevance to washdown food contact components
    FDA 21 CFR 177.1520Olefin polymers for direct food contactBase-resin conformity for cutting rails and wear strips
    EU Regulation No 10/2011Overall migration limit, 10 mg/dm²Compliance metric for dairy/meat washdown liquids
    ISO 6224 h immersion at 23°CConfirms water absorption below 0.01% by mass
    ASTM D638-14Type I specimen, 5 mm/min test speedTensile yield and elongation used to qualify plate batch before machining

    What clearance margins prevent pasteuriser line star wheels from seizing?

    Star wheels and timing screws machined from UHMW-PE Superplus are centred on servo drives and keyed shafts in carbonated beverage and hot-filled juice lines. Peripheral speed at the star wheel root diameter is generally 0.4 m/s to 1.2 m/s, and bottle contact pressure is kept below 0.1 MPa, which is below the dry sliding pressure-velocity boundary of unfilled UHMW-PE at comparable speeds; clearance rather than wear governs reliability. A 500 mm diameter star wheel installed at 20°C and raised to a pasteuriser tunnel temperature of 70°C increases diameter by 4.5 mm to 5.0 mm. Pocket clearances specified at ambient temperature are therefore opened by the calculated diametral growth; otherwise the bottle transfer point binds and breaks bottles. Production-line maintenance records show binding events concentrate where heat is asymmetric, such as single-side tunnel discharge. The surface coefficient of friction against PET is approximately 0.12 to 0.20 dry, but condensation can reduce it below 0.10, which imposes a lower backpressure limit and can allow bottle slip through timing screws. Polygon shafts rather than single-key joints are specified because round keyways create sharp notches that reduce impact toughness; if a keyway is unavoidable, the keyseat root radius is kept above 0.5 mm and the motor torque limiter is set to avoid shear after 40°C soak. Adhesive attachment of star wheel segments is not permitted because the polymer’s low surface energy prevents reliable bonding; crevice-free mechanical attachment with countersunk stainless fasteners and flanged bushings is used instead. Hot-filled juice lines running at 85°C for intermittent periods require the star wheel pockets to be machined oversized by an additional 0.3 mm per 100 mm of radius. If the wheel is exposed to alkaline cleaning chemicals above 70°C for more than 2 h per shift, stress relaxation occurs at the clamping zone; therefore clamping force is checked with a digital torque wrench and retightening is scheduled after the first 72 h of operation.

    Bulk material handling installations in iron-ore, coal, and copper processing use UHMW-PE Superplus as sacrificial chute liners, hopper liners, and apron feeder side wear plates. The selection depends on the coefficient of friction against wet fines being lower than carbon steel by a factor of 2 to 3, which reduces hang-up in bins; the material is not an impact pad for severe angular-particle impingement. In transfer chutes where particle velocity exceeds 4 m/s and impact angle exceeds 45° from horizontal, ceramic-backed rubber or chromium carbide plate is placed at the point of first contact, while UHMW-PE is installed on sliding zones downstream. Liner thickness is commonly 25 mm to 50 mm for abrasion zones and 50 mm to 100 mm where occasional impact occurs; published data for this specific configuration is limited, so full-scale wear trials determine replacement frequency. Installation uses stud-welded stainless pins with countersunk holes and slotted polymer apertures to allow thermal movement. A 2 000 mm liner cycled between -30°C and +35°C changes length by 23 mm to 26 mm, which is larger than the motion absorbed by typical bolted joints, so staggered slot lengths must be designed from a fixed central point rather than from a single edge. Bolting through round holes near the edge causes stress cracking within months of service. Natural Superplus is used where wet material provides charge dissipation; antistatic or carbon-loaded grades are specified only where conveyed material carries an explosive dust hazard. For coal handling where an explosive dust hazard is identified, a carbon-filled UHMW-PE grade is used because natural grades exhibit surface resistivity above 10¹² Ω.

    Clarifier chain sliders fail by creep before chemical attack

    Rectangular primary and secondary clarifiers use UHMW-PE Superplus wear pads, chain slippers, and sprocket idlers submerged in water containing 2 000 mg/L to 8 000 mg/L suspended solids and intermittent chlorine residuals from 0.5 mg/L to 5 mg/L. The failure mode is not chemical attack; it is creep. When a stainless chain link bears on a polymer slider at 20°C, continuous bearing stress should not exceed 3.5 MPa if replacement intervals are to remain above 5 years; published data for this specific configuration is limited, so site trials on rectangular collector mechanisms monitored thickness loss with ultrasonic gauging. The polymer’s 24 h water absorption under ISO 62 is below 0.01% by mass, but hydrogen peroxide or hypochlorite shock dosing at 10% to 15% during offline cleaning oxidises the surface layer, raising surface roughness from Ra 0.8 µm to Ra 1.6 µm after repeated cycles. Surface roughness above Ra 1.6 µm increases chain vibration and accelerates fatigue wear on the stainless pin. Strong mineral acids above 30% concentration, especially warm nitric acid, are not recommended for continuous immersion because oxidative degradation reduces near-surface molecular weight. Sprocket hubs are machined with a clearance fit of 0.15 mm to 0.25 mm on the shaft and clamped with split hubs; press fits are avoided because creep under load allows stress relaxation and eventual loosening.

    Wet-end paper machine dewatering elements and synthetic wire drag control

    Forming board tops, suction box covers, and foil blades machined from UHMW-PE Superplus are installed on paper machine wet-end structures where the synthetic forming fabric runs at 600 m/min to 1 200 m/min. The polymer is selected because its sliding surface against polyester forming fabric develops a water-lubricated friction level of approximately 0.05 to 0.10, reducing wire drag and drive energy compared with ceramic-to-fabric contacts. The critical machining specification is flatness, not surface hardness. Suction box covers are stress-relieved before rough machining, then finish-machined with a vacuum slot pattern and checked on a granite surface plate; flatness deviation is held to 0.08 mm per 1 000 mm because a wavy cover generates uneven vacuum levels across the sheet. Vacuum levels in low-vacuum boxes typically range from 10 kPa to 60 kPa. Because the wet-end temperature can rise from 20°C at installation to 60°C during operation, a 4 000 mm suction box cover changes length by 28.8 mm to 32.0 mm; mounting bolt holes are slotted and the covers are pinned at the centre to prevent walking. Natural UHMW-PE foil blades are not used in high-load applications above 80°C sustained temperature, where creep would cause contact-line distortion. Surface finish is specified as Ra 0.4 µm to Ra 0.8 µm on the fabric side; rougher surfaces abrade the fabric, while polished surfaces below Ra 0.2 µm can create stick-slip.

    When chloride-containing de-icing salts and seawater immersion govern bearing pad replacement intervals

    Port infrastructure and movable bridge machinery use UHMW-PE Superplus bearing pads, guide blocks, and sliding surfaces between steel interfaces where seawater or chloride-containing de-icing runoff excludes conventional bronze and nylon parts. Seawater immersion does not hydrolyse the polymer, and the low water absorption under ISO 62 means thickness does not swell sufficiently to close designed clearances. The operational boundary is compression set under long-duration static load. For a pad stressed to 10 MPa at 20°C under intermittent wave loading, creep accumulates faster than short-term ISO 815 compression set data would predict because wetting and drying cycles allow locked-in compression set to accumulate. Dock fender faces are therefore not machined to flat plates with direct bolt contact; they are backed with elastomeric cushions or spring washers that absorb 0.2 mm to 0.5 mm of polymer thickness loss before metallic contact occurs. At low tide the polymer transitions from submerged to atmospheric exposure; UV surface oxidation is limited unless the pad is directly exposed to sunlight for years, but above-water applications specify a carbon-black-filled UHMW-PE grade instead of natural Superplus to limit chain scission. When chloride concentration exceeds 10 000 mg/L and the polymer is cathodically protected, no galvanic corrosion occurs because the material is an insulator, but local pH can rise above 12 around steel cathodes and long-term alkalinity exposure should be considered when selecting backup plates. Sliding pads in ship launch ways are regularly lubricated with seawater or steam; dry slide against steel generates interface temperatures above 70°C, which softens the polymer surface and increases wear rate. Launch operations therefore wet the contact interface continuously until the hull is fully afloat.

    Chemical metering pump heads and rotary valve seats are machined from UHMW-PE Superplus for sodium hypochlorite, ferric chloride, alum, and dilute sulphuric acid service at ambient temperature. The polymer withstands continuous immersion in pH 2 to pH 12 solutions without measurable hydrolysis, but organic solvents and aromatic hydrocarbons soften the amorphous phase at elevated temperature; any elastomeric seal that releases plasticising oil is replaced because oil migration into the polymer can reduce dimensional stability. Sealing faces are not cut from extruded stock with a rough skin; they are flycut from compression-moulded plate to avoid porosity, then lapped flat to 0.005 mm per 25 mm before installation. Because the polymer has a low thermal conductivity of approximately 0.40 W/(m·K), frictional heat at sealing faces is not conducted away rapidly, so face pressure and rubbing speed are limited to keep interface temperature below 60°C. A DN 100 valve body at 40°C must allow for 0.36 mm to 0.40 mm diametral growth if ambient assembly was at 20°C; the valve seat may otherwise bind when returned to service after hot cleaning. Bolt preload is maintained with stainless Belleville washers because the polymer relaxes under sustained compressive strain. Published data for this specific configuration is limited, so lip seal squeeze is validated by pressure testing at 1.5 times rated body pressure rather than by numerical modelling alone. For sodium hypochlorite metering, the seat is exposed to off-gassing at the suction side; gas bubbles collapse at local pressure drops and can cause surface pitting if aerated stock is not degassed. The pump head is therefore operated with flooded suction rather than suction lift.

    Pharmaceutical tablet packaging machines replace metal timing screws and guide rails with UHMW-PE Superplus because the material can be machined to a burr-free finish and avoids metal-to-tablet impact marks. The polymer is not inherently sterile; it is cleaned with 70% isopropanol or hydrogen peroxide vapour at ambient temperature. The critical process risk is solvent interaction: repeated isopropanol wiping at 60°C can induce stress crazing at sharp corners, so machined components have radiused edges above 0.5 mm. Surface roughness is specified at Ra 0.4 µm or better on tablet contact faces because cleaning validation swabs show that surfaces above Ra 0.8 µm retain higher quaternary ammonium residues after rinsing. Dimensional tolerance on timing screw root diameter is held to ±0.05 mm because too tight a root causes tablet breakage and too loose a root causes feed gaps. The low coefficient of friction against gelatine capsules can be below 0.10, which under some high-speed sorting conditions reduces capsule orientation reliability; tapered pockets are therefore used instead of straight-walled pockets. Published data for this specific configuration is limited, so installation qualification uses high-speed camera verification at 300 to 600 units/min.

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    Certification & Compliance
    More Introduction

    Mitsubishi Chemical Advanced Materials UHMW-PE SUPERPLUS, supplied under the TIVAR® SUPERPLUS trade designation, is an ultra-high-molecular-weight polyethylene intended for machined wear components in conveyor, bottling, packaging, and food-machinery applications. The grade is supplied as compression-moulded sheet and ram-extruded rod in natural white and black; standard sheet thicknesses are typically in the range 10–100 mm and standard rod diameters 20–250 mm. The polymer is non-polar and hydrophobic, with water absorption below 0.1% when tested in accordance with ISO 62. Density is reported in manufacturer literature as 0.93–0.94 g/cm³ by ISO 1183-1. The material is selected for bottle-handling star wheels, guide rails, wear strips, idler sprockets, and screw auger flights where dry sliding against stainless steel or aluminium occurs at ambient to moderately elevated temperatures.

    How Does UHMW-PE SUPERPLUS Differ from Conventional TIVAR 1000 and Generic UHMW-PE?

    The principal reported difference is tribological. In clean, dry sliding against stainless steel with counterface roughness Ra 0.4–0.8 µm, TIVAR® SUPERPLUS is specified for a lower dynamic coefficient of friction and reduced wear volume than standard unfilled UHMW-PE. Manufacturer literature positions the grade for higher continuous speeds and higher cycle rates in bottling and packaging lines. Published comparative data for this exact configuration are limited; process engineers should request application-specific wear curves from the producer when replacing TIVAR® 1000.

    Unlike oil-filled UHMW-PE, TIVAR® SUPERPLUS does not rely on migratory lubricant additives that can alter food-contact status or leave surface residues. The grade is supplied as an unfilled olefin polymer covered under FDA 21 CFR 177.1520 and EU 10/2011 when the finished article meets the use conditions stated in the regulation. Low moisture absorption reduces dimensional swell in wet packaging environments compared with nylon and acetal; equilibrium water uptake remains below 0.1%, whereas polyamide 6 absorbs 2.5–3.0% at 23°C and 50% relative humidity by ISO 62.

    The representative values in table 1 are compiled from TIVAR® SUPERPLUS manufacturer data and are typical for the unfilled grade; lot-specific acceptance values should be taken from the current technical datasheet.

    PropertyTest methodTypical value
    DensityISO 1183-10.93–0.94 g/cm³
    Water absorptionISO 620.05–0.10%
    Tensile yield stressISO 527-220–23 MPa
    Tensile elongation at breakISO 527-2>200%
    Tensile modulusISO 527-2600–700 MPa
    Shore D hardnessISO 86860–65
    Charpy impact strengthISO 179-1/1eUNo break at 23°C
    Vicat softening temperatureISO 306/A5080–85°C
    Melting peak temperatureISO 11357-3133–138°C
    Dynamic coefficient of friction, dry, against polished stainless steelASTM G115 or manufacturer internal protocol0.08–0.15
    Long-term service temperatureManufacturer data−200 to +80°C
    Linear thermal expansion coefficientISO 11359-21.5–2.0 × 10⁻⁴ K⁻¹

    Machining of TIVAR® SUPERPLUS is performed on CNC routers, machining centres, and automatic lathes with carbide-tipped or polycrystalline diamond tooling. Because the material has a linear thermal expansion coefficient of 1.5–2.0 × 10⁻⁴ K⁻¹ and tends to stress-relax after stock removal, roughing cuts should leave 1.0–2.0 mm on critical surfaces for a final finishing pass at ambient temperature. Bearing clearances for rotating parts must be increased relative to metals: a 100 mm UHMW-PE ring heated from 20°C to 60°C expands by approximately 0.6–0.8 mm at the upper end of the thermal expansion range. High spindle speeds and aggressive chip loads can generate frictional heat at the cut surface, producing melt smear and dimensional drift; compressed-air cooling, sharp tooling, and clearance angles of 5–10° are used on production CNC lines to limit heat accumulation.

    Wear and Friction Data in Dry Sliding Against Stainless Steel Counterfaces

    Dry sliding wear of UHMW-PE against stainless steel is controlled by counterface roughness, contact pressure, sliding velocity, and frictional heating. For TIVAR® SUPERPLUS, the preferred stainless steel surface finish is Ra 0.4–0.8 µm with no sharp honing peaks; at Ra above 1.6 µm, abrasive ploughing removes polymer from the surface and wear volume increases nonlinearly. Under clean, dry conditions at ambient temperature, the dynamic coefficient of friction against polished stainless steel is reported in the range 0.08–0.15; at pressures above 0.5 MPa or velocities above 0.5 m/s, frictional heating becomes the limiting factor and the local surface temperature may approach the 80°C continuous-service threshold.

    Pressure-velocity limits for unfilled UHMW-PE in continuous dry operation against steel are commonly quoted as 0.07–0.14 MPa·m/s; published data for TIVAR® SUPERPLUS under application-specific speeds and counterface roughness are limited. The grade is therefore best validated on a representative test rig using the actual stainless steel finish and load schedule. Block-on-ring testing according to ASTM G77 or thrust-washer screening according to ASTM D3702 can be used to rank candidate materials, but the results should not be scaled directly to conveyor duty without accounting for frictional heat removal and debris clearance.

    In wet or lubricated conditions, the coefficient of friction drops further and wear is often negligible, which is why bottle-handling applications use water-based lubrication to extend service life. However, water at 60–80°C can accelerate creep in highly loaded bearing surfaces; clamping loads in star wheels and guide rails should be distributed to keep compressive stress below 5 MPa at operational temperature.

    When Component Temperatures Approach the 80°C Continuous-Service Threshold

    The continuous-service temperature of TIVAR® SUPERPLUS is typically given as −200°C to +80°C. Above 80°C, yield strength and hardness decrease because the polymer approaches its Vicat softening range of 80–85°C under ISO 306/A50. In poorly cooled rotary components, frictional heating can produce local surface temperatures higher than the average ambient temperature; a thermal derating factor is therefore required when sliding velocity exceeds 0.3 m/s or contact pressure exceeds 0.25 MPa.

    Creep and dimensional stability limits should be evaluated at the maximum process temperature. Under a compressive stress of 10 MPa at 23°C, unfilled UHMW-PE exhibits time-dependent deformation; the creep modulus is approximately 400–600 MPa after 1000 h. At 60°C the creep modulus falls significantly, and continuous bearing stress should be limited to 1–2 MPa unless the component is supported by a metallic backing plate. Published data for this specific grade at process-specific temperatures are limited; creep testing according to ISO 899-2 or internal manufacturer protocols should be requested when the part operates above 40°C.

    For design documentation, the material is normally specified against ASTM D4020 for UHMW-PE moulding and extrusion materials and ISO 11542-1:2011 for designation and specification. The grade is not implantable; it is an industrial and food-machinery product. The compliance matrix in table 2 lists the principal chemical and food-contact requirements referenced in supplier declarations.

    RequirementStandard or regulationRelevant parameter
    Food-contact olefin polymersFDA 21 CFR 177.1520Extractives and end-use limitations
    EU plastic food-contact materialsEU 10/2011Overall migration ≤ 10 mg/dm²
    UHMW-PE specificationASTM D4020Density, tensile, impact, abrasion classification
    Chemical inventoryREACH EC 1907/2006SVHC < 0.1% w/w per producer declaration
    Restricted substances in electrical equipment2011/65/EU and (EU) 2015/863Pb, Hg, Cd, Cr(VI), PBB, PBDE, DEHP, BBP, DBP, DIBP below thresholds

    Extrusion, Compression Moulding, and Ram Extrusion Feedstock Controls

    UHMW-PE cannot be processed by conventional single-screw extrusion or injection moulding because its very high molecular weight—typically in the range 5–9 million g/mol—gives melt viscosities above 108 Pa·s at 190°C, preventing measurable melt flow by ASTM D1238. TIVAR® SUPERPLUS is therefore consolidated by compression moulding of powder or by ram extrusion into rod. Compression moulding is carried out at temperatures of 200–220°C and pressures of 3–5 MPa, followed by slow cooling to reduce internal stress and void formation.

    Ram extrusion uses a heated cylinder and reciprocating plunger with an L/D ratio of 10–20 on the heated section; the powder is compacted in a forming die and cooled under pressure. Incoming powder is controlled for bulk density, particle-size distribution, and residual moisture. Outgoing stock is tested for density, tensile yield stress, elongation at break, hardness, and fusion quality; immersion ultrasonic scanning at 2.25 MHz is used to detect voids and poor fusion zones. Lot-to-lot variation in wear-critical parts is reduced by matching sheet or rod from the same production batch for all mating components.

    In bottling and packaging lines, TIVAR® SUPERPLUS is machined into star wheels, infeed screws, and guide profiles where impact resistance at low temperatures and low friction against stainless steel are required. In food machinery, the grade is used for scraper blades and wear strips in humid washdown conditions; the water absorption below 0.1% prevents the swelling and dimensional changes observed in nylon components. In dry bulk handling, the material is specified for silo liners and hopper liners because its low surface energy reduces bridging and caking of hygroscopic powders. Design data for these applications should be verified against the current MCAM datasheet and the actual operating temperature, load, and cleaning-chemical exposure.

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