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Mitsubishi Chemical Advanced Materials UHMW-PE STERRA ESD

    • Product Name: Mitsubishi Chemical Advanced Materials UHMW-PE STERRA ESD
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 140881
    Material Type Ultra-high molecular weight polyethylene (UHMW-PE), electrostatic dissipative
    Color Blue
    Density 0.94 g/cm3
    Tensile Strength 19 MPa
    Tensile Modulus 750 MPa
    Elongation At Break >300%
    Notched Charpy Impact Strength >100 kJ/m2
    Shore D Hardness 62
    Coefficient Of Friction 0.20
    Water Absorption <0.01%
    Thermal Conductivity 0.41 W/mK
    Surface Resistivity 10^6 to 10^9 ohm/sq
    Volume Resistivity 10^6 to 10^9 ohm-cm
    Continuous Service Temperature -200 to 80 °C
    Melting Point 135 °C

    As an accredited Mitsubishi Chemical Advanced Materials UHMW-PE STERRA ESD factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing One Mitsubishi Chemical Advanced Materials UHMW-PE STERRA ESD sheet, 1220 × 2440 mm, protective-film wrapped on a wooden pallet.
    Container Loading (20′ FCL) 20′ FCL loaded with Mitsubishi Chemical Advanced Materials UHMW-PE STERRA ESD, securely palletized and braced to prevent movement during transit.
    Shipping Mitsubishi Chemical Advanced Materials UHMW-PE STERRA ESD is a non-hazardous, electrostatic-dissipative ultra-high-molecular-weight polyethylene solid. It is not regulated for transport by DOT, IATA, IMDG, or ADR. Ship in clean, dry packaging on pallets at ambient temperature, avoiding moisture, contamination, and direct sunlight. No special hazard labels required.
    Storage Mitsubishi Chemical Advanced Materials UHMW-PE STERRA ESD should be stored in a cool, dry, well-ventilated area, away from direct sunlight, heat, flames, and strong oxidizers. Keep in original packaging, protected from dust, moisture, oils, and contaminants. Support flat or vertically to prevent deformation. Avoid prolonged UV/high-temperature exposure, and maintain clean conditions to preserve electrostatic-dissipative properties. Use first-in, first-out.
    Shelf Life Shelf life is indefinite when stored in original packaging under cool, dry conditions, away from direct sunlight, heat, and contaminants.
    Application of Mitsubishi Chemical Advanced Materials UHMW-PE STERRA ESD
    In semiconductor front-end wafer transport, machined STERRA ESD stock-shape components replace ceramic, PEEK, or anodised aluminium carriers in wafer cassette support rails, transfer nest plates, and vacuum end-effector contact pads. The substitution is driven by simultaneous requirements under SEMI S2-0718 and ANSI/ESD S20.20-2021: surface resistance within the static-dissipative band of 1 × 10⁶ to 1 × 10⁹ Ω when measured per IEC 61340-2-3 at 50 ± 5% RH, particle shedding below detection limits of a 0.1 µm laser particle counter positioned 25 mm from the wear interface, and no metallic ion contamination that would trigger gate oxide integrity failures on 300 mm wafers. Stock-shape machining permits the production of end-effector pads with vacuum-channel cross-sections of 1.5 mm × 2.0 mm and flatness tolerances of ±0.05 mm over a 200 mm length, provided the rough-machined blank is annealed at 100 °C for 4 h and slowly cooled at ≤10 °C/h to relieve internal stress introduced during compression moulding of the original sheet. The coefficient of linear thermal expansion for UHMW-PE in the range of 1.5 × 10⁻⁴ to 2.3 × 10⁻⁴ K⁻¹ remains a binding constraint: a temperature excursion of only 5 °C on a 300 mm long guide rail produces dimensional growth of 0.23 mm, which is unacceptable for cassette registration features requiring ±0.1 mm positional repeatability. CNC milling parameters recorded on production-scale vertical machining centres specify single-flute carbide end mills, spindle speeds of 8,000–12,000 min⁻¹, and feed rates of 0.05–0.10 mm/tooth to avoid melt smearing at the cut surface, which would degrade surface resistivity uniformity across the component. Machined parts are cleaned by ultrasonic immersion in deionised water followed by isopropanol wipe-down; silicone-based release agents or hydrocarbon-based cutting fluids are excluded because residual films alter the measured surface resistance by more than one order of magnitude and introduce uncontrolled organic contamination into the wafer environment.The electrical performance of STERRA ESD in semiconductor service is humidity-independent within the tested window, distinguishing carbon-based permanent dissipative networks from surfactant-laden anti-static grades that lose dissipative behaviour below 20% RH. Surface resistivity measurements on finished components conditioned at 12 ± 3% RH, 50 ± 5% RH, and 90 ± 5% RH for 168 h per IEC 61340-2-3 show no systematic drift outside instrument uncertainty of ±0.5 decade, as summarised in the following table. Charge decay from 1000 V to 100 V per IEC 61340-2-1 is consistently below 2.0 s across the same humidity envelope. Operational boundaries are explicit: continuous contact with wafer backside films at temperatures above 80 °C softens the bearing surface enough to induce plastic deformation under clamp forces exceeding 250 N; exposure to N-methylpyrrolidone or hot dimethyl sulfoxide (both present in specific stripping and cleaning chemistries) causes localised swelling that must be evaluated for each process integration. The components are not suitable for direct vacuum-chamber interior use where outgassing per ASTM E595 exceeds permitted total mass loss of 1.0% and collected volatile condensable material of 0.1%, because UHMW-PE is not a low-outgassing polymer for high-vacuum service. FOUP door guide plates, cassette indexing rails, and wafer sorter contact pads constitute the principal terminal components in this track.
    Conditioning environmentTest methodMeasured surface resistivity (Ω/sq)Charge decay 1000 V→100 V
    23 ± 1 °C, 12 ± 3% RH, 168 hIEC 61340-2-31 × 10⁶ – 1 × 10⁸< 2.0 s per IEC 61340-2-1
    23 ± 1 °C, 50 ± 5% RH, 168 hIEC 61340-2-31 × 10⁶ – 1 × 10⁸< 2.0 s per IEC 61340-2-1
    23 ± 1 °C, 90 ± 5% RH, 168 hIEC 61340-2-31 × 10⁶ – 1 × 10⁸< 2.0 s per IEC 61340-2-1

    What Limits Continuous-Slip Performance of ESD-Grade UHMW-PE on Stainless Steel Chain Tracks?

    For ISO 14644-1:2015 Class 5 cleanroom conveyor systems transporting wafer cassettes, reticles, or flat-panel display substrates, continuous-sliding guide rail inserts fabricated from STERRA ESD are specified where metal-to-metal contact would generate unacceptable particle counts and ceramic wear strips would transfer excessive vibration to the product. The dominant tribological constraint is the pressure-velocity limit: with a dynamic coefficient of friction against 304 stainless steel in the range of 0.10–0.14 (unlubricated, 23 °C, 50% RH, reciprocating pin-on-disc per ASTM G99), the safe continuous-service PV value for UHMW-PE in unlubricated sliding is approximately 0.08–0.15 MPa·m/s. Exceeding this PV threshold by operating a chain track at 0.5 m/s with a contact pressure above 0.30 MPa drives the surface temperature of the polymer beyond its continuous-use rating of 80 °C, producing localised melting, transfer film breakdown, and a discontinuous wear mechanism that increases volumetric wear rate by two orders of magnitude. Wear factors derived from block-on-ring testing per ASTM G77 for UHMW-PE sliding against Ra 0.4 µm stainless steel range from 1 × 10⁻¹⁰ to 5 × 10⁻¹⁰ in³·min/ft·lb·hr under the stated PV envelope; above the envelope, published data for this specific configuration is limited because the failure mode transitions from adhesive transfer to gross thermal softening.Design of conveyor rail cross-sections must accommodate the ESD requirement without relying on topical anti-static sprays that would be rejected under ANSI/ESD S20.20-2021 continuous-conformance audits. The dissipative property is volumetric, meaning machining away the skin does not remove a surface layer of conductivity, as occurs with some ionomer-coated anti-static grades. Mounting of rail inserts is executed with countersunk polyether ether ketone or 316L stainless screws torqued to 2.5–3.5 N·m; over-torquing crushes the UHMW-PE bore and introduces compressive set that distorts the running surface. Pre-drilling with a 90° included-angle drill and a feed of 0.08 mm/rev prevents heat-generated stress cracking at the hole periphery. Conveyor guides machined from STERRA ESD sheet in thicknesses of 10 mm, 15 mm, and 20 mm enter service in cleanroom fab interbay and intrabay transfer systems, vertical lift indexers, and load-port dock plates where ESD-safe sliding contact is required. The product is also specified for cassette buffer-station wear strips, where the component must survive 3 million cassette insert-extract cycles without generating visible debris detectable by a Class 5 surface particle scan of 0.3 µm threshold.Printed circuit board assembly lines processing charge-sensitive components with charge-device-model withstand voltages below 100 V require nest fixtures, press-fit support anvils, and selective solder pallet inserts that do not accumulate triboelectric charge during board handling. Machined STERRA ESD components fulfil this function where glass-epoxy fixtures would require additional grounding straps and where acetal anti-static grades lose conductivity after repeated IPA wipe-downs. Selective solder pallet inserts are machined to aperture tolerances of ±0.05 mm to register around through-hole component bodies while maintaining 0.5 mm minimum wall thickness between adjacent apertures; the thermal exposure in selective soldering, where molten solder at 260–280 °C is applied for 2–4 s per joint, remains within the short-term excursion capability of UHMW-PE when the insert is positioned at least 3 mm from the solder wave contact zone. Surface resistance of finished pallet inserts is verified per ANSI/ESD STM11.11 using a 2.27 kg probe with 100 V test voltage, falling between 1 × 10⁶ and 1 × 10⁹ Ω. The material is also specified for wave solder pallet frames outside the thermal core, PCB depaneling fixture jaws, and functional test station guide rails, where the non-scratching surface prevents damage to exposed copper traces during board slide-in. RoHS Directive 2011/65/EU and REACH Regulation (EC) 1907/2006 Article 33 declarations accompany the stock-shape documentation when requested.

    Lithium-Ion Cell Formation Tray Inserts and Electrolyte Contact Boundaries

    The migration of liquid electrolyte constituents into tooling polymers governs material selection for lithium-ion cell formation tray inserts and cell positioning nests. Standard electrolyte formulations based on LiPF₆ at 1.0–1.2 mol/L in carbonate solvent blends (ethylene carbonate:dimethyl carbonate:ethyl methyl carbonate in approximate 1:1:1 volumetric ratio) impose chemical resistance requirements that cross-linked elastomers and many engineering thermoplastics fail within 500 h of immersion at 45 °C. UHMW-PE, with its non-polar saturated hydrocarbon backbone, resists swelling in carbonate solvents; published immersion data for UHMW-PE in dimethyl carbonate at 45 °C for 28 days indicates mass uptake below 0.1%. The ESD variant adds a critical process safety function: formation trays that carry cells through charge-discharge cycling at 0.1C to 1C rates must not accumulate static charge that could arc to exposed cell tabs, where the minimum ignition energy of electrolyte vapour is below 0.2 mJ. Machined tray inserts locate prismatic cells with pocket tolerances of +0.10/−0.00 mm on the cell footprint; the low Coefficient of friction allows cell placement without marring aluminium laminate pouch films, while the compressive yield strength of approximately 17–20 MPa per ISO 527 prevents insert deformation under stack clamping loads of 150–250 N per cell in fixture designs with 4:1 mechanical advantage. Operational boundaries include incompatibility with electrolyte spillage that is not immediately wiped: although the polymer itself is chemically resistant, residual LiPF₆ hydrolyses in ambient air to hydrofluoric acid, which etches the conductive carbon network at the surface and degrades measured surface resistance by more than one decade after 72 h of continuous exposure. Production corrective action requires removal of electrolyte-contaminated inserts within 8 h, cleaning with anhydrous ethanol, and re-verification of surface resistance per IEC 61340-2-3 before return to service. The track is completed with cell ageing rack rails, module assembly fixture base plates, and end-of-line test nest components, all machined from stock sheet and rod.

    FDA 21 CFR 177.1520 Status Dictates Hopper Liner Specification for Secondary Pharmaceutical Packaging

    Classification of STERRA ESD under FDA 21 CFR 177.1520 as an olefin polymer requires careful supply-chain verification because the carbon-based dissipative filler is not automatically covered by Paragraph (a)(1) compositional provisions. Published data for this specific configuration is limited; the stock-shape manufacturer should be consulted for a written 21 CFR 177.1520 statement specific to the ESD grade, and where food-contact compliance is mandated, the specification should require batch-level certification rather than reliance on generic polymer class compliance. The application focus in pharmaceutical secondary packaging is therefore restricted to components that do not contact the drug product directly: tablet press discharge chutes, bottle unscrambler guide rails, and cartoning machine wear strips where fine dust from tableting or powder filling operations creates a hybrid electrostatic-dust explosion hazard that the ATEX workplace directive 1999/92/EC and the equipment directive 2014/34/EU both address. In such dusty installations, the ESD grade must maintain surface resistance below 1 × 10⁹ Ω per IEC 61340-2-3 so that triboelectric charge generated by sliding contact with polyethylene terephthalate bottles or gelatin capsules decays faster than the charge accumulation rate of the process, typically 0.5–2 s per unit operation. Simultaneously, the component must not generate particulates above the pharmaceutical packaging area limit of 0.5 µm at 3,520 particles/m³ for ISO 14644-1 Class 5 enclosures, which precludes the use of graphite-filled grades that shed conductive filler into the product stream. Machined liners are installed with hot-plate or ultrasonic welding only where the manufacturer's processing guidance permits thermal joining below 180 °C; weld zones require post-weld surface resistance re-qualification because the melt-flow process can disrupt the conductive percolation network along the joint line, creating isolated insulative zones above 1 × 10¹¹ Ω that act as localised charge traps.Where flammable solvent vapours or combustible dust atmospheres are classified according to the ATEX Directive 2014/34/EU and IEC 60079 series, the specification of ESD-grade UHMW-PE for sliding bearings, guide rollers, and storage bin liners must address both surface resistivity and charge-transfer resistance as separate test parameters within IEC 60079-32-2:2015. The standard's technical requirement that surfaces in Group II explosive atmospheres present surface resistance between 1 × 10⁶ and 1 × 10⁹ Ω is a necessary but not sufficient condition; the charge-transfer resistance measured between the polymer surface and a defined hemispherical electrode must also remain below 1 × 10⁹ Ω to prevent brush discharges from isolated conductive islands that can ignite hydrogen-air atmospheres with minimum ignition energy of 0.017 mJ. UHMW-PE ESD grades based on dispersed carbon black networks are generally considered to provide continuous conductive pathways at filler loadings above the percolation threshold of approximately 0.5–2.0 vol%; however, the proprietary formulation of STERRA ESD is not disclosed, and the end-user must verify the IEC 60079-32-2 parameters on finished machined parts rather than relying on stock-shape datasheets that report only IEC 61340 surface resistivity. Sliding bearing service in solvent storage areas and drum refilling stations is bounded by the same PV limit of 0.08–0.15 MPa·m/s that governs cleanroom conveyor use, with continuous-use temperature restricted to 80 °C to avoid softening-induced seizure. The terminal component set includes tank farm roller guides, drum-handling slide plates, and valve actuator wear rings, all machined from STERRA ESD sheet or rod with final dimensions verified against the installation drawings of the classified zone. The following compliance matrix consolidates the governing requirements across the application segments.
    Application segmentGoverning standard/directiveClause or test designationParametric requirement
    Semiconductor wafer handlingANSI/ESD S20.20-2021Table 1: ESD Protected Area itemsSurface resistance 1 × 10⁶ – 1 × 10⁹ Ω
    Semiconductor wafer handlingSEMI S2-0718Section 16: ESD controlEPA-compliant grounding path
    Cleanroom conveyor systemsISO 14644-1:2015Classification Annex AISO Class 5 particulate threshold
    Cleanroom conveyor systemsASTM G77Block-on-ring wear testWear factor within 1 × 10⁻¹⁰ – 5 × 10⁻¹⁰ in³·min/ft·lb·hr
    PCB assembly fixturesANSI/ESD STM11.11Surface resistance of planar materials1 × 10⁶ – 1 × 10⁹ Ω
    Lithium-ion battery fixturesIEC 61340-5-1:2016Clause 5.3.2: ESD protected areaCharge decay < 2.0 s from 1000 V to 100 V
    Pharmaceutical packagingFDA 21 CFR 177.1520Paragraph (a)(1): olefin polymersGrade-specific compliance statement required
    ATEX environmentsIEC 60079-32-2:2015Surface resistance and charge-transfer testsBoth parameters < 1 × 10⁹ Ω
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    Certification & Compliance
    More Introduction

    Mitsubishi Chemical Advanced Materials UHMW-PE STERRA ESD is an ultrahigh-molecular-weight polyethylene sheet and rod grade in which electrostatic dissipative behavior is generated within the polymer matrix rather than by a post-applied coating. The product is specified where uncontrolled triboelectric charging on guide rails, nests, vacuum wands, and conveyor components must remain below the control limits referenced in ANSI/ESD S20.20-2021 and IEC 61340-5-1. The base polymer retains the low-friction and abrasion resistance characteristic of UHMW-PE, while the dissipative additive system alters the electrical response from the insulative condition of unfilled UHMW-PE to a controlled dissipative band. Published data for every machined configuration is limited; lot-specific certificates should be requested for production qualification because additive dispersion and thermal history influence measured values.

    Unfilled UHMW-PE is a strong insulator, commonly exceeding 1 × 10¹² Ω/sq on dry surfaces. The STERRA ESD grade is formulated to place surface resistivity in the static-dissipative range, typically between 1 × 10⁶ Ω/sq and 1 × 10⁹ Ω/sq according to IEC 62631-3-2. That range avoids both the conductive region below 1 × 10⁴ Ω and the insulative region above 1 × 10⁹ Ω used in common ESD classification schemes. The electrical term “dissipative” is functionally significant: charge is removed at a slower rate than through a conductive carbon-black-filled polymer, reducing the risk of a rapid discharge into a sensitive device. The STERRA ESD designation therefore does not imply zero charge generation; it describes the resistance path through which generated charge migrates to grounded tooling.

    What Electrical Test Conditions Control the Reported Values?

    Surface resistivity measurements on this grade are strongly dependent on electrode geometry, relative humidity, and surface preparation. Values are typically reported after conditioning at 23 ± 2 °C and 50 ± 5 % RH for not less than 48 h. When measurements are taken at 12 ± 3 % RH under ANSI/ESD STM11.11, the measured surface resistance may shift toward the upper end of the dissipative range because the elimination of adsorbed moisture reduces surface conduction. Machining coolant residues, finger oils, and mold release can create electrically insulating skins, so test coupons should be cleaned with a residue-free solvent and reconditioned before measurement. The reported range is not a single-point guarantee; it is an envelope that accommodates positional variation across a pressed slab or extruded rod.

    The conduction mechanism is percolation-based. In the high-viscosity UHMW-PE matrix, the dissipative filler is dispersed as a network that is deliberately operated near the percolation threshold. Small shifts in local filler concentration produce measurable changes in surface resistivity because the current path is controlled by interparticle contact frequency. This is why the product is specified as a band rather than a narrow target. Overcompensation would push the material into the conductive range and create a low-resistance path that can discharge a component too quickly. Undercompensation would leave charge retention and allow surface voltage to build during repeated sliding contact. The balance is maintained through compounding controls and periodic electrical verification on finished parts.

    Thermal Expansion, Bearing Clearance, and Cleaning Limits

    The linear thermal expansion coefficient of UHMW-PE is in the range of 1.3 × 10⁻⁴ K⁻¹ to 1.8 × 10⁻⁴ K⁻¹ measured by ISO 11359-2. On a 100 mm machine-guide section, a temperature rise of 10 K can produce expansion of roughly 0.13 mm to 0.18 mm. Bearing retainers, guide rails, and locating fixtures must be designed with clearance that accounts for this movement, particularly in dry-running systems where frictional heat accumulates at localized contact points. The material is not recommended for continuous service above 80 °C in air under mechanical load because dimensional stability and creep resistance decline as the crystalline softening region is approached. Short-duration excursions above 80 °C may be tolerated in low-stress environments, but structural load-bearing parts require verification under the specific thermal profile.

    Water absorption of the grade is below 0.01 % after 24 h immersion per ISO 62, so ambient humidity does not require pre-drying. Cleaning with reagent-grade isopropanol at 20–30 °C for short contact is generally acceptable for removing inorganic particulate. The material is not intended for continuous immersion in strong oxidizing acids at temperatures above 40 °C, nor for steam autoclaving above 121 °C because the combination of heat and pressure can produce permanent deformation. Halogenated solvents should be avoided during cleaning unless the exposure is short and followed by full evaporation under 23 °C forced air; retained solvent can temporarily alter surface resistivity measurements and may affect dimensional verification.

    If Carbon-Black-Filled Conductive UHMW-PE Is Under Consideration

    A key difference from carbon-black-filled conductive UHMW-PE is the resistance range. Conductive grades are frequently supplied with surface resistivity below 1 × 10⁴ Ω/sq to provide rapid charge transfer in highly charged processes. STERRA ESD is formulated in the dissipative range, so it does not behave as a metallic conductor. That distinction matters in semiconductor handling because a conductive polymer placed against a charged device can produce a fast energy transfer. The dissipative grade provides a slower discharge path and is typically selected when the process requires avoidance of both charge retention and low-resistance shorting. Mechanical properties of conductive UHMW-PE tend to diverge further from unfilled UHMW-PE as filler loading increases; the STERRA ESD system is positioned closer to the mechanical profile of unfilled UHMW-PE, though minor reductions in elongation and notch sensitivity should be expected and verified by the end user.

    Compared with unfilled UHMW-PE, the principal difference is electrical: unfilled UHMW-PE does not dissipate charge unless it is combined with external ionization, conductive coatings, or metallic contact points. The STERRA ESD grade allows the polymer part itself to participate in the grounded path. It is not a replacement for a certified ESD worksurface, and it does not remove the need for proper grounding of fixtures and machine frames. In continuous sliding applications on dry substrates, unfilled UHMW-PE can retain surface voltages well above 10 kV; the dissipative grade is intended to hold voltages below the process-specific limit, but the final value depends on sliding speed, contact pressure, and humidity.

    Property Variation Across Extruded Sheet and Machined Blanks

    The manufacturing route for UHMW-PE is not conventional screw injection molding. Sheet and rod are produced by compression molding or ram extrusion, with heating around the crystalline melting region and consolidation under pressure. The dissipative additive changes the melt viscosity and can widen the pressure variation seen on ram extruders relative to unfilled UHMW-PE. Machining requires high positive rake angles and polished flutes to avoid smearing; the polymer’s low thermal conductivity concentrates frictional heat at the tool edge, and dull tools can produce local surface melting that modifies resistivity. Stress-relief annealing after heavy machining is standard because residual stress around sharp internal corners can lead to delayed cracking. A gradual heating and cooling cycle below 80 °C is generally sufficient to reduce machining-induced stress without degrading the dissipative additive.

    PropertyTest methodRepresentative range
    DensityISO 1183-10.93–0.94 g/cm³
    Surface resistivityIEC 62631-3-21 × 10⁶–1 × 10⁹ Ω/sq
    Volume resistivityIEC 62631-3-11 × 10⁶–1 × 10⁹ Ω·cm
    Shore D hardnessISO 86861–65
    Tensile yield stressISO 527-2/1B16–18 MPa
    Elongation at breakISO 527-2/1B>150 %
    Water absorption, 24 hISO 62<0.01 %
    Linear thermal expansion coefficientISO 11359-21.3 × 10⁻⁴–1.8 × 10⁻⁴ K⁻¹

    For cleanroom guide-rail and fixture applications, the grade is machined into wafer combs, end effectors, separator plates, and transfer nests where standard unfilled UHMW-PE would retain charge. The dissipative material is used in combination with grounded tooling, and resistivity is verified on the finished machined part because tooling heat and surface roughness can shift the reading from the bulk slab value. In applications where particle contamination is a critical parameter, users should request outgassing and contact-cleaning data from the manufacturer for the specific machined configuration rather than relying on generic UHMW-PE cleanliness values.

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