| HS Code | 992399 |
As an accredited Mitsubishi Chemical Advanced Materials UHMW-PE ESD / TIVAR factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Mitsubishi Chemical Advanced Materials UHMW-PE ESD/TIVAR packaging: one wooden pallet of shrink-wrapped sheets or rods, strapped and labeled. |
| Container Loading (20′ FCL) | 20′ FCL container loading of Mitsubishi Chemical Advanced Materials UHMW-PE ESD/TIVAR, palletized, braced, evenly distributed for safe transport. |
| Shipping | Mitsubishi Chemical Advanced Materials UHMW-PE ESD/TIVAR ships as non-hazardous, solid polymer sheets or rods. It is not regulated for DOT, IMDG, IATA, or ADR transport. Package in clean, protective wrapping; keep dry and away from heat, UV, and contamination. Secure loads during standard freight to prevent damage. |
| Storage | Store Mitsubishi Chemical Advanced Materials UHMW-PE ESD / TIVAR in a cool, dry, well-ventilated area away from direct sunlight, heat, flames, and strong oxidizers. Keep in original packaging, supported flat to prevent warping. Protect from UV, moisture, dust, oils, and reactive chemicals. Maintain normal humidity and avoid static-generating conditions. |
| Shelf Life | Indefinite shelf life if stored in original packaging, dry, cool, away from UV/heat; material remains stable, no specific expiration. |
In 300-mm front-end wafer logistics, contact surfaces for wafer combs, separators, and FOUP-related transfer nests are machined from TIVAR ESD because a surface resistivity that exceeds 109 Ω under ASTM D257-14 is not permitted by common ESD-protected-area procedures following ANSI/ESD S20.20-2021 and IEC 61340-5-1:2016; the same components must also avoid hard-particle generation above ISO 14644-1 Class 5 limits during wafer contact. The fabrication route is not a compounding or masterbatch dilution process. TIVAR ESD semi-finished sheet or rod is machined at 100% of the finished contact surface; unfilled UHMW-PE, acetal, or PEEK is not blended into the wafer-contact surface because any non-static-dissipative layer would create a charge-decay discontinuity measurable with a 100 V surface resistance probe per ANSI/ESD STM11.11-2021. Replaceable inserts are fitted into 6061-T6 aluminum carrier plates with mechanical keying rather than adhesive bonding; when an insert is replaced, the full contact area remains TIVAR ESD, not a diluted or laminated hybrid.
Stock shape conversion takes place on CNC machining centers with vacuum workholding and polished high-positive-rake carbide inserts. Chips are evacuated with dry compressed air; water-soluble coolants are avoided unless followed by deionized-water rinsing because residual cutting-fluid films can lower measured surface resistivity during qualification but later dry to leave a weak boundary layer that alters static decay. After machining, parts are deburred, cleaned in multi-stage ultrasonic baths with 18 MΩ·cm deionized water, dried in filtered air, and double-bagged in ESD-protective packaging. Incoming lots are verified at 10 V and 100 V test voltages per ANSI/ESD STM11.11-2021; parts that fail to fall within 106–109 Ω at both voltages are rejected before cleanroom entry. Finished component types include 300-mm wafer combs with pitch grooves, edge-gripping transfer arms, cassette guide rails, separator plates for wet bench handling, and FOUP load-port guide pads. Continuous service above 80°C or direct contact with strong oxidizing acids is outside the qualified service range; wet-bench immersion below 40°C in dilute acid is typical, but any chemical exposure must be re-qualified because the conductive modifier can be extracted by certain solvents, and published data for specific immersion cocktails in semiconductor cleaning baths is limited.
The dominant failure in manual PCB workholding is not bulk mechanical wear but localized charge retention in blind holes and snap-fit features after high-cycle placement. Unmodified UHMW-PE nests can tribocharge to several kilovolts when boards slide in and out at 20% RH; TIVAR ESD is used as 100% of the board-contact surface in modular nest plates, with no unfilled UHMW-PE or acetal upper layer. Compliance is based on IEC 61340-5-1:2016 and ANSI/ESD S20.20-2021, with periodic verification by point-to-point resistance per ANSI/ESD STM11.11-2021 and ESD-event detection on a charged-plate monitor during sliding-board trials. JEDEC JESD625-B is applied at contract assemblers for handling of ESDS devices on the line. The replacement ratio is governed by contact surface, not by total tool mass: TIVAR ESD inserts are specified at a minimum thickness of 6 mm and cover the full board outline; supporting aluminum or stainless steel frames are isolated from board contact.
Production processing starts with CNC routing of TIVAR ESD sheet to flatness 0.15 mm/m; press-fit stainless steel threaded inserts are installed in reamed holes, because tapping UHMW-PE directly yields threads that creep under clamp loads above 10 MPa. Critical reference edges and locating pins are machined in the same setup to avoid stack-up error. After assembly to the carrier plate, each nest is subjected to a 100 V surface-resistance measurement at 40%–60% RH and after 24 h conditioning; nests that pass at 50% RH but fail at 12% RH are rejected for dry-room use. In production, a recurring failure mode is burr generation at the board-edge contact lip when cutting tools exceed 150 m/min surface speed with insufficient positive rake; the resulting micro-burrs charge under sliding and produce intermittent ESD events that are not detected by a simple surface-resistance meter but appear on a charged-plate monitor. Terminal product types include snap-in PCB support nests, selective soldering fixture plates where heat exposure remains below 80°C, automated optical inspection board carriers, test socket guide plates, and press-fit assembly fixtures. Boards with gold-edge contacts are handled by milled clearance slots to prevent electrolytic micro-corrosion from conductive carbon filler transfer; the same filled surface should not be used as a direct bearing surface against bare nickel-plated PCB edges without verification, because the carbon-modified material can leave a black contact mark. This is an approved ESD-safe contact material only when mechanically retained, not adhesively bonded with cyanoacrylate, because the low surface energy of polyethylene prevents reliable structural adhesion.
| Application segment | Primary compliance reference | Specified electrical range | Test method |
|---|---|---|---|
| Semiconductor wafer handling | ANSI/ESD S20.20-2021, SEMI E78-1106 | 106–109 Ω surface | ASTM D257-14, ANSI/ESD STM11.11-2021 |
| PCB nest tooling | IEC 61340-5-1:2016, JESD625-B | 106–109 Ω surface | ANSI/ESD STM11.11-2021 |
| Cleanroom robotic end-effectors | SEMI E78-1106, ISO 14644-14:2016 | 106–109 Ω, particle emission per ISO 14644-1 Class 4 | ASTM D257-14, ISO 14644-1 |
| Lithium-ion cell assembly | IEC 61340-5-1:2016, ANSI/ESD S20.20-2021 | decay from 1 kV to 100 V in <2 s | ANSI/ESD STM11.11-2021, IEC 61340-2-1:2015 |
| Flat panel display cassette guides | SEMI E78-1106, ISO 14644-1 | retained surface <100 V, surface 106–109 Ω | ANSI/ESD STM11.11-2021 |
| Powder-contact liners | IEC TS 60079-32-1:2013, ATEX Directive 2014/34/EU | surface <109 Ω, charge decay per IEC 61340-2-1:2015 | ASTM D257-14, IEC 61340-2-1:2015 |
At 2.5 m/s² robot acceleration, the contact pad in a 200-mm wafer handling robot enters a coupled particle and static risk regime. TIVAR ESD is used at 100% of the contact pad surface; a harder PEEK or ceramic substrate may serve as the structural body, but the wafer-contact area is not diluted by adhesive films or non-static-dissipative polyurethane coatings. Industry compliance references include SEMI E78-1106 for electrostatic compatibility of equipment, ISO 14644-14:2016 for particle emission from equipment, and ANSI/ESD S20.20-2021 for ESD-protected equipment. The replacement ratio in multi-layer end-effector construction is expressed as 100 mm² of TIVAR ESD per contact point for a 200-mm wafer, with no point-contact below 8 mm diameter. Larger pads reduce contact pressure but increase particle contact area; smaller pads concentrate load and can wear into a groove under robot acceleration.
Manufacturing the insert requires CNC micro-machining of TIVAR ESD sheet into low-profile pads with edge radii of at least 0.5 mm to avoid wafer edge scraping. The pads are undercut to receive a mechanical retaining lip in the aluminum end-effector; no adhesives are used for retention. Post-machining cleaning is the process bottleneck: ultrasonic cleaning with 18 MΩ·cm deionized water at 40 kHz for 10 min removes machining debris from the surface micro-valleys, but cleaning alone does not remove embedded particles produced by dull tools. Therefore, tool life is managed by replacing polished carbide inserts after 50 linear meters of machined UHMW-PE edge, or when burrs are visible at 20× magnification. In cleanroom operation, an observed failure mode is edge micro-fracture under high acceleration above 2.5 m/s²; the pad can create a low-amplitude vibration that appears as particle shedding from the wafer backside. Strict balance and pad thickness uniformity of ±0.03 mm across the end-effector are required to avoid this shedding. Terminal products include wafer edge-grip pads, reticle cassette contact buttons, glass substrate end-effector pads, pre-aligner nest inserts, and overhead transport gripper pads. Continuous service above 60°C or exposure to ozone from wafer cleaning processes is not recommended unless a grade-specific chemical compatibility review is performed.
Lithium-ion cell stacking fixtures under dry-room conditions below 1% RH require line-contact surfaces that discharge static without creating insulative wear debris. TIVAR ESD is substituted at 100% for any line-contact surface that touches bare cell tabs, separator edges, or pre-installed busbars. In this dry-room environment, static decay time must be below 2 s from 1 kV to 100 V per IEC 61340-2-1:2015, and surface resistance must remain within 106–109 Ω according to ANSI/ESD STM11.11-2021 at 100 V test voltage. Because the process environment combines low humidity with solvent vapors from electrolyte filling, any material replacement must also be assessed for dimensional stability and for the risk of conductive carbon particle transfer to cell insulation layers. TIVAR ESD is machined from compression-molded sheet; no additive masterbatch is introduced by the cell manufacturer, and the material is not blended with virgin UHMW-PE at the machining plant because a non-conductive skin would form after machining if the conductive filler distribution is disturbed by skiving.
Downstream conversion for battery tooling uses waterjet cutting of 12–25 mm sheet followed by CNC finish-machining on three-axis vertical mills. Waterjet cutting is preferred over band sawing for rough blanks because it does not create melted edge beads that retain charge. All holes for locating pins are reamed to H7 tolerance and fitted with stainless steel bushings if repeated insertion is required. Edge radii of 1.0 mm are applied to all separator-contact profiles. After machining, components are washed with isopropyl alcohol followed by deionized-water rinse and vacuum-dried at 40°C for 8 h to remove moisture absorbed during waterjet processing. A documented production issue is that waterjet-cut surfaces can have lower measured surface resistivity than machined surfaces because abrasive cutting exposes conductive carbon domains; after 72 h aging in a dry room, values stabilize. Parts that are measured immediately after cleaning are held at 25°C ± 3°C in the dry room for 72 h before final resistance acceptance to prevent false pass results. Terminal product types include cell stacking fixture plates, separator winding mandrel sleeves, formation tray guides, module locating pins, tray separator inserts, and end-plate alignment blocks. Process boundaries: TIVAR ESD is not placed in direct contact with laser-welding heat-affected zones, because local temperatures above 80°C will soften the surface and can trap weld spatter; weld-nest contact points that sit within 10 mm of a tab weld are made from ceramic or mineral-filled thermoset, with TIVAR ESD used only on the far-field alignment surface.
In Gen 8.5 and Gen 10.5 fabs, glass substrate cassettes impose two interacting constraints at the glass contact line: particle generation below ISO 14644-1 Class 3 limits and retained static charge below 100 V during automated storage and retrieval. TIVAR ESD guide strips are used at 100% of the contact surface in the cassette slot, replacing unfilled UHMW-PE strips that previously required costly ionizer coverage. The compliance basis is SEMI E78-1106 for electrostatic compatibility, ISO 14644-14:2016 for particle emission from equipment, and ANSI/ESD STM11.11-2021 for surface resistance. The addition ratio is not a resin mixture but a full-contact replacement: a cassette with 80 guide strips uses TIVAR ESD throughout the slot bottom and side rails; partial substitution is not permitted because alternating conductive and insulative strips creates differential charge decay along the substrate edge and can induce lateral drift during automated retrieval.
Processing of the guide strip is normally by profile extrusion or CNC machining from sheet, depending on slot geometry. Extruded profiles are annealed to reduce residual stress and cut to length with a 0.05 mm length tolerance; machined strips are produced with a single-pass finishing cut to avoid producing a smeared surface layer. A critical limitation is that TIVAR ESD is not suitable for continuous contact with hot glass above 60°C in buffer zones near annealing or sputter deposition equipment. Terminal products include cassette slot guide strips, anti-scratch wear pads for glass handling robots, alignment blocks for laminators, and edge supports in inspection stations.
If a powder-contact liner in electronics-grade ceramic transfer exceeds 109 Ω, triboelectric charge on funnel walls causes powder adhesion, bridging, or a propagating brush discharge that may violate IEC TS 60079-32-1:2013 if the powder atmosphere is classified as combustible dust. TIVAR ESD liners are installed as 100% replacement of stainless steel or unfilled UHMW-PE liners in rotary valve housings, screw conveyor troughs, and hopper interiors; the wear surface is not diluted with glass-filled polyamide or acetal because those materials have different wear rates and static decay behavior. Compliance for material contact is based on IEC TS 60079-32-1:2013, ATEX Directive 2014/34/EU for equipment intended for explosive atmospheres, and IEC 61340-5-1:2016 as a supplementary ESD control framework. Surface resistivity is measured per ASTM D257-14 and charge decay per IEC 61340-2-1:2015.
Liners are produced from 6–20 mm TIVAR ESD sheet by CNC routing or waterjet cutting, then mechanically fastened to the steel shell with countersunk fasteners that do not interrupt the flat wear surface. Hot-air welding or extrusion welding is used only on seams outside the powder flow path; UHMW-PE has a narrow melt processing window, and the ESD-modifier distribution can be disrupted by uncontrolled welding. In rotary valve service, liners are machined with a 0.1 mm clearance to the rotor; if clearance is below 0.05 mm, rubbing causes local heat, surface disruption, and static-resistivity drift. Published data for wear rate in this specific configuration is limited; each powder formulation should be trialed in a pilot rotary valve with the actual particle size distribution because the combined effect of abrasive filler particles and static-dissipative carbon domains on frictional heating is not predictable from sheet properties alone. Terminal products include hopper liners, screw conveyor trough liners, rotary valve end plates, discharge chute liners, dust-collector transition pads, and flexible screw conveyor wear strips. Operational boundary: continuous use with hot powder above 60°C or with strong oxidizers such as concentrated hydrogen peroxide is outside the qualified service range; for food or pharmaceutical contact, the specific TIVAR ESD grade must be verified against relevant migration and extractables requirements because not all static-dissipative UHMW-PE grades carry the same food-contact certifications.
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