| HS Code | 129186 |
| Density | 0.94 g/cm³ |
| Water Absorption | <0.01% |
| Tensile Strength At Break | 17 MPa |
| Elongation At Break | >300% |
| Tensile Modulus | 650 MPa |
| Charpy Notched Impact Strength | 100 kJ/m² |
| Shore D Hardness | 62 |
| Coefficient Of Friction | 0.20 |
| Thermal Conductivity | 0.42 W/(m·K) |
| Coefficient Of Linear Thermal Expansion | 2.0 × 10^-4 /°C |
| Specific Heat Capacity | 1.9 kJ/(kg·K) |
| Surface Resistivity | 10^6 to 10^9 ohm |
| Volume Resistivity | 10^6 to 10^9 ohm·cm |
| Maximum Continuous Service Temperature | 80°C |
| Minimum Service Temperature | -200°C |
| Flammability Rating | UL94 HB |
| Color | Black |
As an accredited Mitsubishi Chemical Advanced Materials UHMW-PE 88-2 ESD factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Mitsubishi Chemical Advanced Materials UHMW-PE 88-2 ESD: 1 piece per ESD-safe protective wrap in a labeled wooden shipping crate. |
| Container Loading (20′ FCL) | 20′ FCL container loaded with palletized Mitsubishi Chemical Advanced Materials UHMW-PE 88-2 ESD, secured, moisture-protected, evenly distributed, and regulatory compliant. |
| Shipping | Mitsubishi Chemical Advanced Materials UHMW-PE 88-2 ESD ships as non-hazardous, non-DG solid plastic stock shapes. Packaged on pallets, wrapped for dust/moisture protection. No special transport labeling required. Transport under ambient conditions; avoid prolonged sunlight, ignition sources, and excessive heat. Store clean and dry. |
| Storage | Store in a cool, dry, well-ventilated area. Keep away from direct sunlight, heat, flames, and oxidizing agents. Keep original packaging sealed to prevent contamination, moisture, and dust. Store flat/supported to prevent warping. Do not stack heavy loads. Use appropriate racks or pallets; avoid sharp objects, excessive stress, oils, and solvents. Maintain clean, antistatic conditions and rotate stock. Follow local regulations. |
| Shelf Life | No specified expiration; typically indefinite if stored cool, dry, protected from UV, moisture, and contamination in original packaging. |
Compression-moulded stock shapes of Mitsubishi Chemical Advanced Materials UHMW-PE 88-2 ESD are converted into wafer cassette combs, station transfer arms, end-effector pads, and storage stand components for 200 mm and 300 mm front-end tools. The static dissipative character is introduced by a pre-dispersed conductive filler in the UHMW-PE matrix; the fabricator does not adjust filler ratio or add external carbon masterbatch. Any local post-machining heat above 180 °C may degrade the conductive network at the surface, so machining strategies are selected to minimise frictional heating. Surface resistance is measured on finish-machined coupons using ASTM D257-14 with a 500 V DC megohmmeter and 2.27 kg concentric ring probes, with acceptance commonly falling inside the static dissipative window of 106–109 Ω/sq. End users in semiconductor fabs impose additional verification per IEC 61340-5-1 Annex B, adapting probes for solid machined components; values outside the ESD protected area control plan are rejected even if the material remains within the manufacturer-typical range. Machining is conducted on a five-axis CNC router fitted with polished carbide or polycrystalline diamond inserts, spindle speed 8 000–12 000 min−1, feed 0.3–0.6 mm/tooth, and compressed air chip evacuation at 0.6 MPa; liquid coolant is omitted to avoid ionic contamination of the dissipative filler and subsequent surface resistance instability. Flatness of 0.05 mm over a 300 mm span is achieved by roughing in two symmetrical passes followed by a finishing pass with 0.1–0.3 mm stock removal. The machined wafer guides are deburred with abrasive-filled nylon brushes, cleaned with isopropanol, and passed through an ionised air stream to remove residual dust before packaging in sealed polyethylene film. Continuous service temperature is limited to 40 °C for cantilevered transfer arms with span-to-thickness ratios above 12:1; at higher ratios and temperatures, creep deformation under wafer load may exceed slot alignment tolerance. Static decay acceptance from ±1000 V to ±100 V in <2 s is specified by the fab ESD control plan rather than guaranteed by the polymer supplier, and published data for this specific configuration is limited where the component includes mixed dielectric inserts.
| Standard | Designation | Application boundary for 88-2 ESD machined components |
|---|---|---|
| IEC 61340-5-1 | ESD protected area control programme | Verifies surface resistance and grounding path after installation in semiconductor equipment |
| ASTM D257-14 | DC resistance or conductance of insulating materials | Baseline surface resistivity on machined coupons before release |
| RoHS 2011/65/EU | Restriction of hazardous substances | Required for semiconductor equipment modules placed on the EU market |
| REACH 1907/2006 | SVHC screening and article-level duties | Declaration for imported stock shapes and machined articles |
| SEMI E78-0318 | ESD hardware in semiconductor manufacturing | User-level validation of wafer-contact components in fabs |
Machining-induced residual stress is the primary limitation in back-end test socket frames and handler nests produced from 20 mm and 30 mm compression-moulded sheet. UHMW-PE exhibits a coefficient of linear thermal expansion of approximately 1.5–2.0 × 10−4 K−1 when measured by ISO 11359-2:1999; for a 400 mm socket frame, a 20 K thermal swing produces 1.2–1.6 mm length change if the part is unrestrained. This movement is not uniform across the sheet because the conductive filler and moulded-in stresses create anisotropic dimensional recovery. Vicat softening temperature is near 80 °C under ISO 306/A120, so stress-relief annealing is limited to 70–80 °C for 2 h per 25 mm wall thickness; higher annealing temperatures risk permanent distortion and surface oxidation of the carbon-filled matrix. Precision boring of socket pockets is performed on jig-boring machines at 800–1200 min−1 with single-lip carbide tooling, with hole tolerance H7 per ISO 286-2 achievable only when the sheet has been stress-relieved and rough-bored before final finish boring. The fill ratio of the grade is fixed by the manufacturer and is not user-adjustable; attempts to increase dissipation by adding graphite or metal powders to the machined surface invalidate lot traceability and may create hard particles that damage spring probes. Metal inserts installed by press-fit alone in socket guides may lose retention force over thermal cycling because the UHMW-PE matrix creeps; designers avoid interference fits above 0.5% strain and instead use mechanical fasteners or insert-moulded alternatives. After machining, socket frames are degreased with isopropanol and measured with a coordinate measuring machine at 20 ± 2 °C. Dimensional stable terminal parts require that machining be symmetrical across the sheet thickness; published data for this specific ESD grade under repeated reflow-like thermal cycles is limited, so end users must qualify socket frame geometry with their own thermal cycling protocol and surface resistance recheck per ASTM D257-14.
| Parameter | Lower boundary | Upper boundary | Failure mode above boundary |
|---|---|---|---|
| Spindle speed | 1500 min−1 | 12 000 min−1 | Melt adhesion and local loss of dissipative surface |
| Feed per tooth | 0.1 mm | 0.6 mm | Edge chipping and micro-fuzz formation |
| Annealing temperature | 70 °C | 80 °C | Permanent distortion near Vicat softening |
| Maximum continuous service | 40–60 °C | Creep deformation under load | |
In cleanroom conveyor applications, 88-2 ESD is machined into dry-running wear strips, side guide rails, and lane dividers for accumulation tables in semiconductor packaging and flat-panel display handling. The material exhibits a coefficient of friction against brushed stainless steel of approximately 0.15–0.25 when tested per ASTM D1894-14; the static dissipative carbon-black filler modifies the frictional signature only slightly compared with unfilled UHMW-PE, but particulate generation from abrasion is the controlling parameter in ISO 14644-1 Class 5 environments. Mounting holes are slotted because a 1000 mm long wear strip expands by 3.0–4.0 mm for a 20 K temperature rise, using a CLTE of 1.5–2.0 × 10−4 K−1 per ISO 11359-2:1999. Fasteners are tightened to 2 N·m maximum with 0.5 mm radial clearance around the screw shank, preventing buckling during washdown or thermal cycling. The rail profile is cut from extrusion or compression-moulded bar on a CNC gantry router with carbide-tipped compression bits at 10 000 min−1; edges are heat-smoothed at 120 °C to seal micro-fuzz. Particle release qualification is performed by the end user under ISO 14644-14:2016, as published data for particle emission from this specific carbon-filled ESD grade under accelerated dry sliding is limited. For dry-running bearings, sliding speed should remain below 0.1 m/s and contact pressure below 0.3 MPa to avoid excessive black wear particulates. After machining, parts are rinsed with deionised water and isopropanol, dried with ionised air, and bagged in a cleanroom-compatible polyethylene sleeve. The terminal product is an ESD-safe guide rail that prevents triboelectric charge accumulation on accumulated display panels while preserving cleanroom cleanliness classifications.
Cell formation trays machined from 88-2 ESD hold prismatic lithium-ion cells under controlled stack pressure without accumulating triboelectric charge between cell tabs and the metal fixture frame. Volume resistivity measured by IEC 62631-3-1:2016 is normally within 106–109 Ω·m on conditioned test samples, but lot-specific values are reported on the manufacturer certificate. The operating ceiling in formation rooms is set at 60 °C; at 40–50 °C the compressive strength of UHMW-PE is significantly lower than at 23 °C when tested per ISO 604:2002, so fixture designers limit contact pressure to 4 MPa to keep permanent indentation below 0.05 mm after 500 formation cycles. The stock shape is stress-relieved before machining to remove moulded-in anisotropy. Roughing is performed with a vacuum-assisted end mill at 6000 min−1 and 0.2 mm finishing passes; through-holes are drilled with slow-helix single flute tools at 1500–2500 min−1 to avoid melt smear that would affect cell pocket accuracy. Electrolyte exposure to ethylene carbonate/dimethyl carbonate and LiPF₆ mixtures is a critical boundary; components that may see electrolyte splash are tested per ASTM D543-21 for dimensional change and surface resistance shift before deployment, and published data for this specific ESD grade in long-term immersion is limited. Finished formation trays are dried at 60 °C for 4 h and sealed in polyethylene bags; moisture uptake in the carbon-filled surface can shift low-humidity surface resistance readings. The terminal fixture is a cell formation tray requiring pocket location accuracy of ±0.1 mm over 600 mm, achieved by alternating light cuts and symmetrical material removal from both sides of the sheet.
Pharmaceutical tablet dedusters, dust hood liners, and secondary packaging lanes use 88-2 ESD where static charge on polymer surfaces causes powder adhesion and weight inaccuracies. The carbon-filled UHMW-PE is machined into guide plates and dust hood liners, but product-contact status must be confirmed in writing from the manufacturer for the exact stock shape and grade; the ESD grade is not automatically acceptable for direct oral-dosage contact under FDA 21 CFR 177.1520 or EU 10/2011. Where no positive compliance statement exists, components are limited to non-contact machine elements or are isolated from the product stream by stainless steel covers. Surface resistance is verified on each production lot per ASTM D257-14; readings above 1 × 1010 Ω are rejected under the site ESD control plan. Machining is carried out on sealed CNC routers with HEPA-filtered dust extraction, and spindle speeds are kept below 5000 min−1 to reduce fine carbon-black particles that could contaminate washrooms or packaging halls. Cleaning is restricted to purified water and isopropanol; no chlorinated solvents are used because extraction of conductive filler from the surface can create localised non-dissipative patches. Operating boundaries include continuous ambient temperature below 50 °C, no autoclave exposure, and no oxidising sterilants such as ozone or peracetic acid unless compatibility is determined by ASTM D543-21. The terminal product is an ESD-safe tablet guide plate that reduces powder sticking while maintaining dimensional stability under low-humidity conditions.
For PCB assembly fixtures that remain outside soldering ovens, 88-2 ESD is machined into selective soldering pallets, stencil wipe cradles, and press-fit jig bodies. The material must not be exposed to reflow radiant loading because continuous use temperature is below 90 °C; a 260 °C reflow zone produces irreversible deformation and oxidation of the carbon-filled surface. In selective soldering cells, the fixture is positioned away from the nozzle, and transient contact with hot tooling is restricted to 5 s at 180–220 °C. Thermal expansion over a 400 mm pallet between 20 °C and 60 °C is approximately 2.4–3.2 mm; slotted mounting holes with 1.0 mm radial clearance are used to avoid buckling. Surface resistance is checked after each 1000 production cycles; if readings exceed 1 × 109 Ω, the fixture is cleaned with isopropanol and retested, or replaced. Machining includes heat-edge sealing at 120 °C to close surface micro-fuzz, but local overheating above 180 °C may permanently damage the conductive network. Static decay is measured for lot acceptance by FTMS 101C Method 4046.1, with decay from 1000 V to 100 V required in <2 s at 12% RH and 23 °C when specified by the electronics assembler. The finished pallet provides a rigid ESD-safe work-holding surface for manual soldering and press-fit insertion, not for oven transport.
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Mitsubishi Chemical Advanced Materials UHMW-PE 88-2 ESD is a bulk-modified electrostatic-dissipative ultra-high-molecular-weight polyethylene supplied as machinable sheet and rod. Under ISO 1043-1:2011 the base polymer belongs to the PE-UHMW class; commercial grades of this type generally have weight-average molecular weights in the 3×106 to 6×106 g/mol range, although the manufacturer may not publish the exact value for this filled grade. The ESD suffix denotes a dispersed carbon-based conductive phase that lowers electrical resistance from the insulating range into the static-dissipative range. The product is not injection-mouldable in conventional screw machinery because the melt viscosity of PE-UHMW is too high; stock shapes are produced by compression moulding or ram extrusion and are converted into finished components by subtractive machining.
Surface resistivity is determined on finished parts or test plaques according to IEC 62631-3-2 or ASTM D257; typical ESD UHMW-PE compounds are specified in the 106–109 Ω/sq range. Volume resistivity is usually measured in accordance with IEC 62631-3-1 and falls between 106 Ω·cm and 109 Ω·cm. These values satisfy the static-dissipative limits referenced in ANSI/ESD S20.20 and IEC 61340-5-1 for protection of static-sensitive devices. Because the conductive filler is distributed through the bulk, the dissipative behavior remains after machining cuts into the stock shape. The percolation network can be affected by heavy polishing, solvent cleaning, or surface contamination; surface resistivity should be re-qualified on production-representative components at the specified measurement voltage and relative humidity.
The dissipative behavior of carbon-filled UHMW-PE is less humidity-dependent than that of antistatic grades made with migratory surfactants. Surfactant-based antistatic polyethylenes lose surface activity at low relative humidity because ionic mobility decreases as absorbed water is removed. A bulk carbon network does not require water to conduct; resistance values may increase slightly under dry-room conditions but generally remain within the dissipative range. This distinction is significant in dry rooms operating below 10% relative humidity, where surface-active antistatic additives may approach insulating values.
The unfilled PE-UHMW reference is an electrical insulator with surface resistivity above 1012 Ω/sq. The conductive additive in UHMW-PE 88-2 ESD reduces that resistance but can act as a flaw initiator, so notched impact strength may be lower than that of virgin UHMW-PE. Fracture studies on carbon-filled polyethylenes report reductions in Charpy impact energy of 10–30% depending on filler volume fraction; published data for this specific MCAM grade is limited, so comparative impact values should be taken from the current manufacturer datasheet. The low coefficient of friction of UHMW-PE is retained in many ESD grades: pin-on-disc values against polished steel are commonly between 0.10 and 0.15 under 0.1 MPa apparent pressure per ASTM G99. The filler also increases Shore D hardness from about 62 to 66 and can lower the specific wear rate in dry sliding because the carbon phase interrupts the large fibrillar transfer films that unfilled UHMW-PE forms.
The stiffness remains low in comparison with ESD acetal or PEEK. Tensile yield stress of ESD UHMW-PE compounds is generally 18–22 MPa under ISO 527-2:2012, while tensile elongation at break typically exceeds 200% for the unfilled base and may be slightly lower in filled ESD versions. The compressive modulus of UHMW-PE is approximately 0.7–1.0 GPa under ISO 604:2002, so heavily loaded guides and gears may require metal inserts or thicker cross-sections than acetal designs. Continuous service in air is generally limited to 80°C, with short-term excursions possible only at low load. Below −100°C the impact toughness of UHMW-PE remains comparatively high, although the conductive filler may introduce some notch sensitivity.
Machined components from UHMW-PE 88-2 ESD are used in wafer cassettes, guide rails, vacuum end-effectors, and lift pins where static charge accumulation would otherwise attract airborne particles or damage gate oxides. The material exhibits water absorption below 0.01% after 24 h immersion per ISO 62:2008, which prevents the dimensional instability associated with nylon or acetal in humid cleanroom air. The low hardness relative to silicon and quartz reduces contact-edge chipping during wafer transfers. The material is not suitable for high-temperature diffusion or etch process environments above 80°C, nor for plasma exposure where polyethylene would degrade and contaminate the chamber.
Chemical compatibility in wet-bench handling is limited to aqueous acid and alkaline solutions at ambient temperature. Polyethylene does not dissolve in common polar solvents, but the presence of conductive carbon can increase the measured mass change in oxidizing media because the filler surface may adsorb oxygen or oxidize. The base polymer is attacked by strong oxidizing acids such as concentrated nitric acid, hot sulfuric acid above 60°C, and free halogens. Isopropyl alcohol, ethanol, and deionized water are suitable wipe-down agents for finished parts; solvent exposure does not create the environmental stress cracking observed in polycarbonate or acrylic. Pre-drying is not required at relative humidity above 60% because moisture uptake is negligible, but condensate should be removed before dry-gas purge.
Metal components in semiconductor handling equipment have bulk resistivity below 10−5 Ω·cm and therefore behave as conductors, not static-dissipative materials. A direct metal-to-wafer contact can produce a rapid discharge and damage oxide layers. In contrast, UHMW-PE 88-2 ESD maintains resistivity in the 106–109 Ω range, allowing charge to bleed off over milliseconds to seconds rather than nanoseconds. This discharge-rate distinction is significant for sensitive devices and is one reason why carbon-filled polymer stock shapes are used for contact pads and vacuum nests.
| Property and test method | UHMW-PE 88-2 ESD class | Unfilled UHMW-PE | ESD acetal comparison |
|---|---|---|---|
| Density, ISO 1183-1:2019 | 0.93–0.95 g/cm³ | 0.93–0.94 g/cm³ | 1.40–1.42 g/cm³ |
| Tensile yield stress, ISO 527-2:2012 | 18–22 MPa | 18–22 MPa | 55–65 MPa |
| Elongation at break, ISO 527-2:2012 | >200% | >250% | 10–30% |
| Surface resistivity, ASTM D257 | 106–109 Ω/sq | >1012 Ω/sq | 106–109 Ω/sq |
| Shore D hardness, ISO 868 | 62–68 | 62–66 | 80–85 |
| Water absorption, 24 h, ISO 62 | <0.01% | <0.01% | 0.2–0.3% |
Representative published ranges for ESD UHMW-PE and comparison materials; verify current MCAM datasheet for specification minima and exact test conditions.
The material also differs from ESD PEEK in cost and upper use temperature. ESD PEEK grades can operate continuously above 250°C and provide higher strength, but are more expensive and more abrasive to tooling. UHMW-PE 88-2 ESD is generally selected where the process remains below 80°C and the highest property requirement is abrasion resistance and low moisture uptake. For high-cycle mechanical drives, the creep of UHMW-PE must be considered; published long-term creep data for this exact filled grade is limited. Designs should use the manufacturer’s creep modulus curves rather than short-term tensile data for press-fit joints or clamped connections.
UHMW-PE components machined from thick stock shapes contain residual stress from compression moulding or ram extrusion. If finish machining is performed without a roughing stage, the part can bow after removal from the fixture. A common fabrication sequence involves rough cutting with 2–3 mm remaining stock, then stress-relief annealing in air at 80–90°C for 1 h per 25 mm of thickness, followed by slow cooling and finish machining. Published data for this specific filled grade is limited, but the thermal stabilization step lowers the initial strain and improves flatness retention in service. The linear coefficient of thermal expansion for UHMW-PE is high, typically 1.3–2.0×10−4 K−1 per ISO 11359-2:1999, so a temperature change of 10°C on a 500 mm plate can produce more than 0.65 mm of length change if unconstrained.
On standard multi-axis machining centers, carbide-tipped or polycrystalline diamond tooling with high rake angles and low cutting speeds is preferred. Flood coolant is often omitted for cleanroom parts because the surface can entrain cutting fluid; dry machining with filtered air-jet chip removal avoids residue. The carbon additive increases tool wear relative to unfilled UHMW-PE but is far less abrasive than glass-fibre filled polymers. Burr formation is reduced by using sharp tools and low feed per tooth; secondary polishing of UHMW-PE surfaces should be minimized because smearing can degrade the electrostatics of the bulk filler network.
Within the Mitsubishi Chemical Advanced Materials UHMW-PE range, unfilled grades offer maximal impact toughness and may be supplied with food-contact documentation under FDA 21 CFR 177.1520. The ESD variant trades a portion of that toughness for static dissipative function. No food-contact claim is made for the carbon-filled ESD product unless a specific regulatory letter is provided for the exact stock-shape formulation. RoHS 2011/65/EU and REACH SVHC compliance documentation should be obtained from the manufacturer for the current production lot; bulk carbon-filled polyethylenes are typically within RoHS limits for lead, mercury, cadmium, hexavalent chromium, PBB, and PBDE, but component buyers must verify because global supply-chain formulations change.
In a wafer-handling application, a vacuum end-effector machined from this material is typically designed with contact pads having surface resistivity checked at 12% relative humidity and 23°C. The component is cleaned with isopropanol, mounted to an anodized aluminum frame with insulated fasteners, and subjected to a 100 V charge dissipation test on the assembled tool. The UHMW-PE body remains in the static-dissipative range after repeated wafer-contact cycles provided the surface has not been coated with silicone or heavy oils; such contaminants may form an insulating film and defeat the dissipation function.