| HS Code | 788941 |
| Density | 0.95 g/cm³ |
| Water Absorption | <0.01% |
| Tensile Strength At Yield | 28 MPa |
| Tensile Strength At Break | 33 MPa |
| Elongation At Break | >600% |
| Tensile Modulus | 1100 MPa |
| Flexural Modulus | 1200 MPa |
| Shore D Hardness | 65 |
| Charpy Notched Impact Strength | 15 kJ/m² |
| Coefficient Of Friction | 0.25 |
| Thermal Conductivity | 0.40 W/(m·K) |
| Coefficient Of Linear Thermal Expansion | 150 µm/(m·°C) |
| Maximum Service Temperature | 80 °C |
| Melting Point | 130 °C |
| Volume Resistivity | >10^15 Ω·cm |
| Dielectric Strength | 45 kV/mm |
| Dielectric Constant | 2.3 |
| Flammability | HB |
As an accredited Mitsubishi Chemical Advanced Materials HDPE LSG factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Mitsubishi Chemical Advanced Materials HDPE LSG is supplied in 25 kg polyethylene bags, palletized and stretch-wrapped for industrial shipping. |
| Container Loading (20′ FCL) | 20′ FCL dry container loaded with Mitsubishi Chemical Advanced Materials HDPE LSG, palletized bags, securely stowed and braced for shipment. |
| Shipping | Mitsubishi Chemical Advanced Materials HDPE LSG is generally shipped as a non-hazardous solid thermoplastic in sealed bags, cartons, or palletized loads. It requires no special DOT, IMDG, or IATA hazardous-materials classification. During transport, keep it clean, dry, and away from direct sunlight, excessive heat, and ignition sources. |
| Storage | Store Mitsubishi Chemical Advanced Materials HDPE LSG in a cool, dry, well-ventilated area away from direct sunlight, heat, flames, and strong oxidizers. Keep in original, labeled, closed containers or packaging to prevent contamination, moisture, and UV degradation. Avoid excessive stacking or mechanical damage. Maintain clean handling conditions; no special temperature control is typically required. |
| Shelf Life | Mitsubishi Chemical Advanced Materials HDPE LSG: no specific shelf life; store in original packaging, dry, clean, away from direct sunlight and heat. |
| Application segment | Standard or code | Test or clause | Purpose |
|---|---|---|---|
| Wastewater weir plate | DVS 2207-1, ISO 527-2:2012 | Butt fusion weld tensile retention | Weld seam quality |
| Chlorine dioxide launder | ASTM D543-21 | Chemical immersion | Oxidant compatibility |
| Marine fender liner | ASTM G155-21, ISO 62:2008 | Xenon arc weathering, water absorption | Outdoor durability |
| Outdoor electrical housing | IEC 60529:2013, UL 746C | Ingress protection, outdoor suitability | Enclosure integrity |
| Food-processing surface | FDA 21 CFR 177.1520(c), EU 10/2011 | Overall migration limit 10 mg/dm² | Food-contact compliance |
| Grain silo liner | ASTM D257-24 | Surface resistivity | Static accumulation control |
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Mitsubishi Chemical Advanced Materials HDPE LSG is a light-stabilized high-density polyethylene stock shape grade, generally supplied as extruded sheet, rod, and welded profile sections under the Polystone® G LSG designation. The base resin belongs to the PE-HD class with a density tested to ISO 1183-1 in the range of 0.95 g/cm³ to 0.96 g/cm³. The LSG designation identifies the light-stabilization package rather than a change in base resin chemistry; black LSG grades typically use carbon black with hindered amine stabilizers, while natural or coloured variants may use hindered amine light stabilizer systems. Published batch values differ from generic PE-HD literature data because stock shape conversion, pigment type, and sheet thickness modify crystallinity, orientation, and additive consumption.
For initial engineering design, PE-HD extrusion grades of this class generally fall within the following normalized ranges: tensile yield stress 22 MPa to 27 MPa under ISO 527-2, flexural modulus 800 MPa to 1100 MPa under ISO 178, Charpy notched impact strength 6 kJ/m² to 12 kJ/m² under ISO 179-1/1eA, Shore D hardness 60 to 65 under ISO 868, Vicat softening temperature 75 °C to 82 °C under ISO 306/B50, melt flow rate under ISO 1133-1 (190 °C, 2.16 kg) generally 0.2 g/10 min to 1.0 g/10 min, and coefficient of linear thermal expansion 150 × 10-6 K-1 to 200 × 10-6 K-1 under ISO 11359-2. Water absorption after 24 h immersion under ISO 62 is generally below 0.01 wt%. These ranges are not an MCAM batch certificate; they are selection reference points that must be replaced by supplied test reports before load-bearing design.
Unstabilized high-density polyethylene undergoes photodegradation through Norrish Type I and Type II chain scission when exposed to UV-A and UV-B radiation between 290 nm and 400 nm. The reaction pathway consumes tertiary hydrogens on the polymer backbone, generates carbonyl and hydroperoxide intermediates, and produces a rapid loss of elongation at break. In unstabilized PE-HD, tensile elongation at break can fall below 50% of the original value after 12 to 24 months of outdoor exposure in temperate climates, while in high-solar-radiation environments the same threshold may be reached in 6 to 9 months. The LSG stabilization package retards this path by absorbing incident UV and quenching radical intermediates; carbon black loadings in comparable PE-HD weathering grades commonly fall in the 2 wt% to 3 wt% range, and hindered amine light stabilizers are often added at 0.1 wt% to 0.5 wt%. Exact MCAM formulation is proprietary.
Service temperature interacts with UV stabilization. At continuous surface temperatures above 60 °C to 70 °C, oxidative induction time decreases and the UV stabilizer package is consumed faster than at ambient-temperature weathering. For applications combining outdoor exposure with process heat, such as uninsulated chemical dosing lines or solar-heated tank covers, the user should request accelerated weathering data according to ISO 4892-2 or ISO 4892-3 and evaluate the change in tensile elongation at break, not colour change alone. Published data for this specific configuration is limited in the absence of the manufacturer's weathering certificate; surrogate data from natural or carbon-black PE-HD cannot be transferred directly to fabricated parts because weld seams and machined edges expose fresh surface area with different additive distribution.
The recommended melt zone for PE-HD sheet welding is normally 190 °C to 230 °C, with the upper limit constrained by autoxidation and bubble formation. A hot-gas or extrusion welding process should keep the weld zone above the crystalline melting temperature but below 240 °C for no longer than required to achieve root fusion. Thermal degradation at the weld root can be detected by a reduction in notched impact strength below the unwelded sheet baseline or by carbonyl index increases measured by infrared spectroscopy. Because black LSG sheet absorbs infrared heat faster than white PE-HD, the welding feed rate and gas temperature require adjustment; otherwise, surface scorching occurs before the root has reached fusion temperature. On production-scale hot-gas welding lines with 3 mm to 4 mm round PE-HD rod, the gas temperature is typically set 20 °C to 40 °C higher than the melt zone because the rod and plate consume heat through the work surface, but the exact setting depends on air flow and nozzle geometry.
For black LSG sheet below 4 mm thickness, the hot-gas welding parameter window narrows to approximately ±5 °C on nozzle outlet temperature because the carbon black absorbs infrared heat more rapidly than natural PE-HD. At the lower bound, incomplete root fusion reduces weld factor; at the upper bound, surface oxidation and microvoids appear as a dull, rough bead. This narrow window makes procedure qualification on production-scale lines essential, and some fabricators add a ceramic heat shield to reduce local surface radiation. Weld surfaces must be scraped no more than 15 min to 30 min before welding to remove oxidized material; oily contamination is removed with an alcohol wipe and dry air. Pre-drying of HDPE LSG sheet is not normally required for hot-gas or extrusion welding if the stock has been stored at standard room humidity; when chilled below the dew point, surface condensation must be removed by air wiping or room-temperature equilibration before welding.
Production-scale extrusion welding of PE-HD LSG sheet is routinely carried out with single-screw extruders in the 20 mm to 30 mm screw diameter range and L/D ratios of 20:1 to 25:1. The extruder barrel zones are set in the 190 °C to 230 °C range, and the screw speed is adjusted so that melt output reaches the weld groove without starving or overfeeding the root. Batch-to-batch variation in melt flow rate affects the weld bead profile, especially in black LSG stock where carbon black increases viscosity and may require a 5 °C to 10 °C increase in melt zone temperature relative to natural PE-HD sheet. These adjustments are line-specific and should be verified by weld qualification before structural work.
Machining of HDPE LSG stock shapes requires positive-rake cutting geometry and reduced clamping pressure to prevent stress whitening. The low modulus and high thermal expansion make tight machining tolerances below ±0.1 mm for dimensions above 300 mm difficult to hold on a conventional machining centre. HDPE LSG can be planed, turned, milled, and drilled; saw cuts should use coarse tooth geometry and low feed pressure to prevent chip melting at the cut face. Because the material is softer than PA or POM, workpieces can creep during clamping; vacuum fixturing or distributed clamping is preferred for thin sections. Residual stresses from extrusion can cause stress release after one-sided machining, so balanced stock removal from both faces is recommended for flatness-critical components.
Chemical compatibility of HDPE LSG follows the PE-HD chemical resistance profile, with useful resistance to dilute aqueous acids, alkalis, brines, and many polar solvents at ambient temperature. The product is generally unsuitable for strong oxidizing acids, chlorinated solvents, and low-molecular-weight aromatic hydrocarbons because these agents can swell, stress-crack, or oxidize polyethylene. Chemical resistance tables should be read with the design stress and temperature; a chemical that is compatible at 23 °C may attack PE-HD at 60 °C under constant tensile load. For outdoor chemical containment, the LSG grade's stabilizers must be considered as extractable components. If the tank contents are food-contact fluids or pharmaceutical media, migration data specific to the formulated LSG grade are required; generic PE-HD food-contact clearances do not automatically cover UV-stabilized or coloured variants. Regulators require end-use migration testing under Regulation (EU) 10/2011 and, for United States applications, compliance under FDA 21 CFR 177.1520 with the limitations on additive and colourant selection. Published data for this specific configuration is limited; the converter should request a conformity declaration and, where applicable, a support statement for the chosen colour and stabilizer package.
The replacement decision between HDPE LSG, UHMWPE, and PP-H is controlled by three load-dependent properties: notch sensitivity at low temperature, creep under continuous load, and abrasion mass loss under particulate sliding. HDPE LSG is generally selected where outdoor UV resistance and weldability are required, but the abrasion mass loss is higher than UHMWPE under the same sliding conditions. UHMWPE, with a molecular weight above 3 × 106 g/mol, has a dramatically higher resistance to sliding wear and impact, but its high melt viscosity makes hot-gas welding impractical and often limits fabrication to machining or compression forming. HDPE LSG can be welded using conventional hot-gas, extrusion, and butt-fusion procedures, which allows field repair of large chemical tanks and outdoor storage structures. Compared with PP-H, HDPE LSG retains higher impact strength at low temperature and better stress-cracking resistance in many aqueous detergent applications, but PP-H has a higher Vicat softening temperature, typically 90 °C to 95 °C, and may be preferred when repeated cleaning with hot process water above 80 °C is specified.
Compared with standard natural HDPE sheet, the LSG grade is not necessarily a higher molecular weight resin; the primary difference is the light-stabilization package. The molecular weight distribution and melt flow rate can be similar to standard PE-HD extrusion grades, but the stabilizer package changes oxidative induction time and long-term weathering response. Therefore, the LSG designation should not be interpreted as a higher abrasion or impact grade; for sliding wear and impact, UHMWPE remains the appropriate selection.
In structural and abrasion service, the coefficient of friction and surface hardness also differ. HDPE LSG has Shore D hardness in the 60 to 65 range; UHMWPE is typically 60 to 70 but deforms more readily under point load because of lower flexural modulus. HDPE LSG is a better candidate for fabricated tank shells and outdoor secondary containment because it is available in thick sheet and can be butt-welded with a defined weld factor. The weld factor for PE-HD in pressure-containing structural joints is commonly taken in the 0.6 to 0.8 range, depending on weld process and operator qualification; the value must be established by destructive weld tests, not assumed from raw-material yield stress. Continuous service temperature in air is generally limited to 60 °C under mechanical load, with short-term unloaded peaks below 95 °C; below -50 °C, impact strength decreases and dynamic loading should be avoided.
The table below compiles representative property ranges for initial material substitution screening. Because stock shape properties vary with conversion route and batch, the values are not acceptable as final design allowables.
| Property | Test method | HDPE LSG representative range | UHMWPE representative range | PP-H representative range |
|---|---|---|---|---|
| Density | ISO 1183-1 | 0.95–0.96 g/cm³ | 0.93–0.94 g/cm³ | 0.90–0.92 g/cm³ |
| Tensile yield stress | ISO 527-2 | 22–27 MPa | 17–22 MPa | 25–35 MPa |
| Flexural modulus | ISO 178 | 800–1100 MPa | 600–900 MPa | 1200–1500 MPa |
| Charpy notched impact strength | ISO 179-1/1eA | 6–12 kJ/m² | no break | 5–15 kJ/m² |
| Shore D hardness | ISO 868 | 60–65 | 60–70 | 68–74 |
| Vicat softening temperature B50 | ISO 306/B50 | 75–82 °C | 76–82 °C | 90–95 °C |
| Water absorption 24 h | ISO 62 | <0.01 wt% | <0.01 wt% | 0.01–0.03 wt% |
The second table lists compliance documentation that a converter or end user should obtain before specifying HDPE LSG in regulated sectors.
| Requirement | Reference | Applicability to HDPE LSG |
|---|---|---|
| United States food-contact olefin polymer clearance | FDA 21 CFR 177.1520 | Applies to the base polyethylene; UV stabilizers and pigments must be individually cleared or the final article must be tested for end use. |
| European plastic food-contact materials | Regulation (EU) 10/2011 Annex I | Requires migration testing under intended food simulants and temperature/time conditions; stock shape grade does not provide automatic compliance. |
| RoHS hazardous substance restrictions | Directive 2011/65/EU Annex II | HDPE LSG without flame-retardant additives typically complies; supplier declaration is required. |
| REACH SVHC communication | Regulation (EC) 1907/2006 Article 33 | Supplier must communicate if an SVHC exceeds 0.1 wt%; not expected for standard PE-HD stock shapes, but batch-specific confirmation is needed. |
| Weathering test method for outdoor qualification | ISO 4892-2 / ISO 4892-3 | Used to benchmark UV-stabilized LSG grades; acceptance criteria must be defined by the design authority. |
For rotational ventilation ducts and outdoor secondary containment, the HDPE LSG grade is frequently specified when the fabricated structure must remain outside for more than 5 years without painting. The light-stabilized black sheet reduces surface oxidation in high-UV sites, but the design must still account for the high coefficient of linear thermal expansion and low modulus. Expansion loops and slotted bolt holes are required when the expected temperature differential exceeds 40 °C. Because black sheet surface temperatures in direct sunlight can rise 25 °C to 35 °C above ambient, the thermal expansion calculation should use the upper surface temperature, not the ambient air temperature. Published data for this specific configuration is limited beyond the manufacturer's weathering and thermal-aging certificates, so outdoor installations should be validated with a trial panel exposed at the intended site orientation and latitude.