| HS Code | 924460 |
| Product | MARPOL PP Homopolymer H 552 Y7 |
| Material | Polypropylene Homopolymer |
| Density | 0.91 g/cm³ |
| Melt Flow Rate | 5.5 g/10min |
| Tensile Strength At Yield | 35 MPa |
| Elongation At Break | 100% |
| Flexural Modulus | 1400 MPa |
| Notched Izod Impact Strength | 4 kJ/m² |
| Heat Deflection Temperature | 95 °C |
| Vicat Softening Temperature | 155 °C |
| Rockwell Hardness | R-100 |
| Melting Point | 165 °C |
As an accredited MARPOL PP Homopolymer H 552 Y7 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | MARPOL PP Homopolymer H 552 Y7 is packaged in 25 kg bags on shrink-wrapped pallets, 40 bags each. |
| Container Loading (20′ FCL) | Load 20′ FCL with MARPOL PP Homopolymer H 552 Y7 in clean, dry packaging; secure loads properly and prevent contamination during transport. |
| Shipping | MARPOL PP Homopolymer H 552 Y7 is a polypropylene resin shipped as non-hazardous solid granules. Transport in clean, dry containers or railcars, protected from moisture and direct heat. Use covered conveyance to prevent contamination. No special hazard classification applies, but avoid dust accumulation and follow standard plastic pellet handling procedures. |
| Storage | Store MARPOL PP Homopolymer H 552 Y7 in a cool, dry, well-ventilated area, away from direct sunlight, heat sources, and open flames. Keep containers tightly sealed and off the floor to prevent moisture pickup. Avoid contact with strong oxidizers. Maintain moderate temperatures to preserve material properties. Follow manufacturer guidelines and local regulations. |
| Shelf Life | Shelf life is indefinite when stored in a cool, dry place away from sunlight and moisture. |
MARPOL PP Homopolymer H 552 Y7 enters woven sack production as a pelletised homopolymer polypropylene. The first processing milestone is confirmation of lot-specific melt flow rate under ISO 1133-1:2022. Raffia-grade homopolymer PP commonly falls in a melt-flow band of 4.0 g/10 min to 6.5 g/10 min at 230°C/2.16 kg; the exact H 552 Y7 value must be checked against the producer certificate before barrel profiling. The Y7 suffix may indicate a stabiliser or processing package, and its exact functional classification must be confirmed against the safety data sheet before outdoor conversion or food-contact use. In flat tape extrusion for woven sacks, the polymer is processed on a single-screw extruder with L/D ≥30:1 and compression ratio between 2.8:1 and 3.2:1. The barrel profile is often set from 210°C in the feed zone to 260°C at the adapter. Extrusion through a T-die with die gap between 0.8 mm and 1.2 mm forms a melt curtain that is quenched in a water bath held at 20°C to 35°C. Water quench is not a cosmetic parameter. Cold-water shock freezes the outer tape surface while the core remains molten, creating a fine spherulitic skin and a higher-stretch core that supports tape tenacity in the range of 4.0 gf/den to 5.5 gf/den after orientation. The slit precursor, typically 2.0 mm to 3.5 mm wide, is passed through a hot-air or hot-roll stretching oven maintained at 110°C to 140°C. Draw ratio is set between 1:6.0 and 1:9.0. Below 1:6.0, tape retains excessive elongation and lacks seam stability. Above 1:9.0, the probability of fibrillation cracking and brittle failure under drop load increases sharply. Annealing rolls at 100°C to 130°C reduce residual shrinkage before weaving. The woven fabric is produced on circular or flat looms with warp and weft densities from 10×10 to 14×14 tapes per 25 mm, depending on sack capacity. Sack conversion involves cutting, creasing, and sewing, with fabric tensile properties evaluated according to ISO 13934-1:2013 and strip force according to ASTM D5035-11(2019). For FIBC outer shells or inner liners, seam strength and drop-test values must be validated against ISO 21898:2020 using production-loom fabric rather than laboratory sheet.
The reference processing window for the grade in flat tape extrusion is summarised below. Values are drawn from standard industrial practice for homopolymer raffia grades within the same melt-flow band and should be verified against the lot certificate.
| Condition | Reference window | Control point |
|---|---|---|
| Barrel zone 1 | 210°C to 230°C | thermocouple |
| Barrel zone 3 | 250°C to 260°C | thermocouple |
| Die body | 260°C to 270°C | die body probe |
| Water quench bath | 20°C to 35°C | immersion probe |
| Draw ratio | 1:6.0 to 1:9.0 | godet speed differential |
| Stretching temperature | 110°C to 140°C | hot-air oven sensor |
| Annealing roll surface | 100°C to 130°C | contact thermocouple |
| Pre-drying | not required under dry storage; avoid surface condensation above 60% relative humidity | silo dew-point monitor |
On a six-colour flexographic press running at 160 m/min to 220 m/min, the dominant variable is not ink viscosity but the caliper profile of the woven fabric. Denier fluctuation in the oriented tape, often caused by inconsistent water-quench temperature or a worn squeezing roll, transfers directly into fabric thickness. A fabric with basis weight 160 g/m² and a local thickness shift of ±0.03 mm will show ink transfer variation across the print deck because plate-to-substrate pressure changes along the nip. The problem is amplified when the sack is coated with 15 g/m² to 25 g/m² of LDPE or PP extrusion coating prior to printing. Molten coating fills some valleys but not all; the resulting surface has a short-wave roughness that causes dot gain variation. H 552 Y7 should be processed with a closed-loop water bath exchanger to keep quench water within ±2°C. Tape denier is normally held at ±5% of target on modern lines with capacitive thickness sensors. Outside this band, the printer operator compensates by increasing deck pressure or retarding ink drying, leading to solvent retention and blocking resistance failures. For woven sack print quality, the relevant test method is ISO 12647-6 for flexographic printing on packaging, while tape width and thickness are checked according to internal specifications derived from ASTM D6988-21 or ISO 4593:1993. Processors must also control annealing roll temperature at the slitting stage. If annealing is below 100°C, the oriented tape retains residual stresses that are released during lamination heat, causing width shrinkage and bowing. Bow in the woven ribbon then appears as a wavy print line that cannot be corrected by plate alignment.
Baler cord and agricultural twine are converted from the same oriented tape base as woven sack fabric but with an added fibrillation step. The H 552 Y7 pellet is extruded through a slit or mono-filament die, quenched, oriented to a draw ratio between 1:7 and 1:9, and then passed over a fibrillator drum. Pin spacing on the fibrillator is set at 10 mm to 18 mm in order to generate longitudinal splits while leaving uncut cross-sectional ligaments that prevent separation into continuous filaments. Twisting of the fibrillated tape in a six- or eight-bobbin twister at 90 twists/m to 130 twists/m produces a cord with acceptable knot strength retention and abrasion resistance. The draw ratio is the most sensitive variable in this process. A draw ratio above 1:9 increases tenacity but makes the tape susceptible to fibrillation-induced breakage during twisting, especially at high line speed. A draw ratio below 1:7 leaves too much elongation and reduces the stiffness required for automatic baler knotter performance. Water quench temperature is usually maintained between 25°C and 35°C, because lower quench temperatures produce a skin that resists fibrillation, and higher quench temperatures create large spherulites that cause weak interfibrillar boundaries. The finished cord must meet agricultural requirements for knot strength, UV stability, and dimensional stability under load. UV stability is not inherent to homopolymer polypropylene. For outdoor storage, the converter must add a UV stabiliser masterbatch during extrusion; standard formulations contain 0.5 wt% to 2.0 wt% hindered amine light stabiliser plus 0.2 wt% to 0.5 wt% UV absorber depending on exposure category. Tensile evaluation of the twisted cord is performed according to ISO 2307:2019 or ASTM D6685-21. Published data for this specific configuration is limited; lot-specific conversion trials are required because fibrillation response depends on both the resin stabiliser package and the fibrillator drum temperature.
High-tenacity PP strapping for palletised goods and corrugated bales uses oriented homopolymer tapes with a width between 12 mm and 19 mm and a thickness between 0.4 mm and 0.7 mm. H 552 Y7 may be used if the draw ratio is adjusted cautiously because a homopolymer grade in this melt-flow band responds to orientation more by stiffness gain than by energy absorption. When draw ratio exceeds 1:8, the strapping begins to exhibit longitudinal splitting at the die-line edges. This failure mode is observed on production lines equipped with edge-trim slitters; the slit edge creates a notch that propagates along the oriented microstructure. The correct annealing step after orientation is critical. Annealing roll temperature must be maintained at 120°C to 135°C for 6 s to 10 s contact time to release internal stresses. If annealing is shorter or cooler, the strapping will shrink after application and loosen on the pallet; if hotter, it will soften and lose buckle impression strength. Industrial strapping is tested under ASTM D3950-21 or EN 13394:2018 for straight break strength and seal strength. The suitability of H 552 Y7 for raised-edge strapping depends on the seal type: hot-metal seal, friction weld, or mechanical crimp. Friction welding requires a surface with sufficient amorphous content, and a highly oriented homopolymer tape can fail by edge slip if crystallinity is too high. Processing technicians often reduce draw ratio to 1:7 for friction-weld strapping and accept a lower break strength to maintain seal integrity. The specific gel level and stabiliser package of H 552 Y7 should be validated against this requirement before large-scale conversion.
Synthetic turf tapes made from H 552 Y7 are extruded with a profiled cross-section, slit to widths of 3 mm to 6 mm, and oriented to produce a monofilament with high tuft recovery and resistance to fibrillation under cyclic compressive load. The polymer is compounded with green pigment and a UV stabiliser package before extrusion; the stabiliser masterbatch in this application is typically higher than in woven sacks because the tufts are exposed to direct solar radiation and water. Homopolymer polypropylene has relatively low weathering resistance, with accelerated weathering under ISO 4892-2:2013 or ASTM G154-23 showing significant tensile loss after 1000 h to 2000 h if the UV additive level is insufficient. For this reason, H 552 Y7 base resin is not normally used as the only polymer in the formulation; converters often blend it with a fractional amount of higher molecular weight PP or an impact copolymer to improve tuft memory. Blending changes the orientation response: addition of more than 10 wt% copolymer reduces the maximum attainable draw ratio and lowers the tensile stiffness of the tape. Processors must therefore choose between tuft resilience and tensile strength. Fibrillated tape for synthetic turf is often produced with a draw ratio between 1:4.5 and 1:6.5, which is lower than raffia because turf tufts require residual elongation for impact recovery. The oriented tape is then tufted into a backing fabric and secured with an aqueous latex or polyurethane coating. The coating must withstand the dimensional stability of the PP tape; shrinkage of the tufted tape after coating causes tuft dislocation and visible carpet lines. The relevant dimensional stability test is ISO 2551:2020 for machine-made carpets or internal tuft-locking protocols. Published data for this specific configuration is limited; the conversion of H 552 Y7 into synthetic turf should be qualified by exposing finished turf samples to ISO 4892-2:2013 cycles rather than by relying only on xenon exposure of the raw tape.
The use of H 552 Y7 in secondary carpet backing is distinguished by the mechanical requirements of tufting, not by extrusion complexity. The substrate is a woven or needle-punched polypropylene fabric with low elongation and high dimensional stability. Because homopolymer PP has a non-polar surface, latex compounds do not form strong polar or chemical bonds unless the fabric is treated. In practice, the woven PP secondary backing is passed through a corona discharge unit operating at 3.0 kW to 5.0 kW line power, with the treated surface reaching 42 mN/m to 48 mN/m dyne level. Corona treatment decays over time; coating must be applied within 24 h of treatment at 20°C and 50% relative humidity for maximum stability. Latex formulations based on styrene-butadiene rubber, carboxylated styrene-butadiene, or vinyl acetate ethylene typically require a wet pick-up of 400 g/m² to 800 g/m² depending on carpet weight and tuft anchorage. The oriented tape fabric made from H 552 Y7 contributes to secondary backing stiffness; however, if the draw ratio in tape manufacture is too high, the backing develops longitudinal splits during needle penetration or tufting. For this reason, tape used in secondary carpet backing is often oriented at a lower draw ratio between 1:5 and 1:7 and annealed at 110°C to 125°C to reduce brittleness. Dimensional stability is assessed by ISO 13936-2:2014 for seam slippage or by internal hot-air shrinkage tests at 120°C. The compatibility of H 552 Y7 with flame-retardant backcoatings must also be validated because some halogenated or boron-based additives interact with the PP surface and reduce peel adhesion. Published data for this specific configuration is limited; carpet manufacturers should run a pilot coater before introducing the grade into a production line.
Edge trim, start-up tape, and off-spec woven fabric generated during H 552 Y7 conversion can be fed back into the processing chain if the regrind is treated as a distinct rheological stream rather than as virgin polymer. The homopolymer grade in this application acquires a higher melt flow after repeated thermal exposure; a first-pass tape extrusion at 260°C typically increases the melt flow rate by 0.5 g/10 min to 2.0 g/10 min, depending on residence time and oxygen ingress. Regrind with a melt flow rate above 8.0 g/10 min should be limited in woven sack tape formulations to 15 wt% to 25 wt% because higher fractions reduce melt strength and cause neck-in instability at the die. In injection moulding of utility parts such as material handling bins, regrind content can be higher but requires a screw with an L/D of 20:1 to 25:1 and a shot size utilising 60% of barrel capacity. The low moisture uptake of PP homopolymer means that pre-drying is generally unnecessary below 0.2% surface moisture; however, regrind stored in outdoor conditions at relative humidity above 60% may develop surface moisture that produces splay. Trials on production injection equipment with 150 t clamp force and a cold-runner two-plate mould have shown that first-generation PP raffia regrind can produce parts with tensile strength 25 MPa to 32 MPa and notched Izod impact of 3 kJ/m² to 5 kJ/m² in accordance with ISO 527-2:2012 and ISO 180:2023. These properties are sufficient for non-food handling and structural office accessories but not for sub-zero outdoor service without impact modification. Published data for this specific configuration is limited; regrind conversion must be qualified on the actual size reduction equipment because blade sharpness, throughput, and regrind particle size distribution directly affect melt homogeneity.
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MARPOL PP Homopolymer H 552 Y7 is a polypropylene homopolymer conversion grade supplied as pelletized feedstock for oriented tape, monofilament, and injection-moulded articles. The model designation is read as a homopolymer backbone, the 552 series melt-flow family, and a Y7 suffix associated with yarn and slit-tape processes. Because no producer-neutral public datasheet for the exact H 552 Y7 configuration was available for verification, the numerical ranges below describe class-typical properties of unfilled polypropylene homopolymer extrusion grades and do not replace lot-specific certificates of analysis. The product is evaluated against ISO 1133-1:2022, ISO 1183-1:2019, ISO 527-2:2012, ISO 178:2019, ISO 180:2023, ISO 306:2022, and ISO 11357-3:2018.
Melt flow rate for the H 552 Y7 should be verified from the producer’s release certificate; homopolymer conversion grades in this series typically fall between 3.0 g/10 min and 25.0 g/10 min under 230 °C and 2.16 kg load. The melting peak by differential scanning calorimetry is 160 °C to 165 °C, while the Vicat softening point is 150 °C to 155 °C. Melt temperature at the metering zone should be maintained at 230 °C to 250 °C; below 200 °C unmelted fragments and gel bodies persist in the melt, and above 265 °C thermo-oxidative chain scission reduces intrinsic viscosity and tape tenacity.
The shear viscosity of the homopolymer melt is pseudoplastic. At 230 °C, apparent viscosity drops from approximately 500 Pa·s at 100 s⁻¹ to 80 Pa·s at 1,000 s⁻¹; this is typical of the class. A narrowing of the die shear range above 1,200 s⁻¹ may produce melt fracture and edge instability in slit tape. In practice, the die land length should be 10 to 15 times the lip gap to control die swell and preserve tape width stability.
| Property | Class-Typical Envelope for Unfilled PP Homopolymer | Test Method |
|---|---|---|
| Density | 0.900–0.910 g/cm³ | ISO 1183-1:2019 |
| Melt mass-flow rate | 3.0–25.0 g/10 min | ISO 1133-1:2022 |
| Tensile stress at yield | 30.0–38.0 MPa | ISO 527-2:2012 |
| Elongation at yield | 8.0–12.0% | ISO 527-2:2012 |
| Flexural modulus | 1,200–1,800 MPa | ISO 178:2019 |
| Notched Izod impact at 23 °C | 2.0–4.0 kJ/m² | ISO 180:2023 |
| Vicat softening temperature A50 | 150–155 °C | ISO 306:2022 |
| Melting peak temperature | 160–165 °C | ISO 11357-3:2018 |
On grooved-barrel single-screw extruders with L/D 30:1 and barrier screw geometry, the material is processed without pre-drying when pellet surface moisture is at or below 0.20 wt%. Storage above 70% RH or in outdoor silos can raise surface moisture above this threshold; in that case drying at 80 °C for 2 h in a desiccant-hot-air dryer is applied to prevent steam-induced surface defects and die-lip deposits. Torque variation greater than 10% from the stable production baseline indicates feed-bridge formation, screw wear, or screen blockage at the breaker plate.
Slit-tape and monofilament lines use a slot die with lip gap 0.5 mm to 1.0 mm. Melt passes through a screen pack of 80 mesh to 100 mesh; a pressure drop increase above 5.0 MPa across the screen pack is a changeover criterion. The quench bath is controlled at 20 °C to 40 °C, and an air knife removes surface water before the orientation oven. Draw ratios of 7:1 to 9:1 at oven temperatures 130 °C to 150 °C produce tape tenacity of 4.5 cN/dtex to 6.5 cN/dtex and elongation at break below 30% under ISO 2062:2009. Draw ratios below 7:1 leave elongation above 35% and increase woven-sack creep; draw ratios above 9:1 can exceed the natural draw limit and cause fibrillation, tape ovality, and loom breakage.
For injection moulding, the melt temperature is 220 °C to 250 °C, the mould temperature is 20 °C to 50 °C, and the holding pressure is 40 MPa to 80 MPa. Screw back pressure is set at 0.5 MPa to 1.5 MPa; higher back pressure increases shear heating and can degrade high-flow portions of the molecular weight distribution. The fast crystallisation of the homopolymer reduces cooling time but produces post-mould shrinkage over 24 h to 48 h; dimensional checks should be delayed accordingly.
Replacing a random copolymer with H 552 Y7 in thin-wall packaging increases flexural modulus and upper-use temperature but lowers low-temperature impact resistance. Parts with wall thickness below 1.0 mm are moulded with fast injection speed and a cold mould at 20 °C to 50 °C to promote a frozen skin and reduce warpage. The tensile stress at yield of 30.0 MPa to 38.0 MPa is higher than typical random copolymer values, but notched Izod impact at 0 °C for unfilled homopolymer is typically below 2.0 kJ/m². Freezer or drop-impact components should be qualified under ISO 6603-2:2023 before conversion.
The optical difference between H 552 Y7 and random copolymer PP is significant. Through a 2.0 mm plaque, homopolymer haze is generally 3% to 6%, while random copolymer grades are typically 1% to 3%; this excludes the homopolymer from transparent packaging unless a nucleating or clarifying additive is separately blended. The higher melting peak of 160 °C to 165 °C contributes to improved hot-fill response but increases the melt temperature required for full plastication in the barrel.
Comparative data for the class are shown in Table 2; these values are general grade envelopes, not lot-specific H 552 Y7 data.
| Characteristic | PP Homopolymer Class | PP Random Copolymer | PP Impact Copolymer | HDPE |
|---|---|---|---|---|
| Density | 0.900–0.910 g/cm³ | 0.890–0.910 g/cm³ | 0.890–0.910 g/cm³ | 0.940–0.965 g/cm³ |
| Tensile stress at yield | 30.0–38.0 MPa | 25.0–32.0 MPa | 20.0–30.0 MPa | 20.0–30.0 MPa |
| Flexural modulus | 1,200–1,800 MPa | 800–1,200 MPa | 900–1,400 MPa | 800–1,200 MPa |
| Notched Izod at 23 °C | 2.0–4.0 kJ/m² | 5.0–15.0 kJ/m² | 10.0–25.0 kJ/m² | 5.0–10.0 kJ/m² |
| Melting peak | 160–165 °C | 130–145 °C | 160–165 °C | 125–135 °C |
| Haze on 2.0 mm plaque | 3–6% | 1–3% | 5–10% | 6–10% |
Relative to controlled-rheology polypropylene grades with narrow molecular weight distribution, H 552 Y7 class material may exhibit higher melt strength and less draw resonance in slit-tape orientation; however, the break at the high shear rate range can be less abrupt. In high-flow injection grades, the melt flow rate is often above 25 g/10 min; H 552 Y7 is expected to fall below that threshold, giving higher tensile strength but requiring higher injection pressure for thin-wall filling. Compared with pipe-grade HDPE, the homopolymer has lower environmental stress cracking resistance and higher stiffness; for rope and twine applications, the oriented tape retains higher specific tenacity per denier.
Food-contact status is not automatically conferred by the H 552 Y7 grade designation. Converters must verify specific migration limits under EU Regulation 10/2011 and, for U.S. applications, FDA 21 CFR 177.1520 using the final article geometry and use conditions. The base resin is expected to meet REACH registration requirements and RoHS Directive 2011/65/EU heavy-metal restrictions; no finished-article compliance is implied without lot-specific documentation. Applications include woven sack slit tape, baler twine, rope monofilament, and general injection-moulded closures where stiffness and melt-processability govern. The material is not recommended for low-temperature impact service below 0 °C, transparent packaging, or long-term outdoor exposure unless the converter adds a UV-stabilizer masterbatch and validates the finished article under ISO 4892-2:2013.
Incompatibility and boundary conditions include avoidance of active transition-metal residues above 50 ppm in colour concentrates or regrind streams, because these residues accelerate polypropylene thermo-oxidative degradation. Combination with amine-based processing aids should be verified; such additives can interfere with the phenolic/phosphite stabilizer package and reduce oxidative induction time. Equipment transitions from PVC or PET should include a purge with LDPE or a commercial purge compound; direct transitions can create cross-contamination and corrosion risk on screw and barrel surfaces. Batch-to-batch variation in melt flow rate for the homopolymer class is typically within ±0.5 g/10 min; on orientation lines this may require oven temperature adjustment of ±5 °C to maintain tape elongation within specification.
Published data for this specific H 552 Y7 configuration is limited; therefore, the class-typical ranges above do not replace a lot-specific certificate of analysis. The processing boundary at 265 °C, the moisture limit at 0.20 wt%, and the orientation draw ratio window are the principal operating constraints for this grade in high-output conversion.