| HS Code | 126374 |
| Material | Polypropylene Random Copolymer |
| Melt Flow Rate | 7.0 g/10 min (230°C, 2.16 kg) |
| Density | 0.90 g/cm³ |
| Tensile Strength At Yield | 31 MPa |
| Elongation At Yield | 12% |
| Flexural Modulus | 1150 MPa |
| Notched Izod Impact | 50 J/m (23°C) |
| Melting Point | 150°C |
| Vicat Softening Point | 130°C |
| Heat Deflection Temperature | 85°C at 0.46 MPa |
| Haze | 0.5% |
| Gloss | 100 |
As an accredited MARLEX PP RB707CF factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | MARLEX PP RB707CF polypropylene resin is supplied in 25 kg bags, packaged on pallets and wrapped for safe transport. |
| Container Loading (20′ FCL) | 20′ FCL container loading of MARLEX PP RB707CF: polypropylene resin packed in heat-sealed bags, palletized, secured, and containerized for safe transit. |
| Shipping | MARLEX PP RB707CF is a polypropylene resin, generally non-hazardous and non-regulated for transport. Ship in clean, dry, lined containers or bags to prevent contamination and moisture ingress. Avoid direct sunlight, high heat, and rough handling. Standard dry van or container is suitable; no dangerous goods documentation required. |
| Storage | Store MARLEX PP RB707CF in a cool, dry, well-ventilated area away from direct sunlight, heat sources, open flames, and strong oxidizers. Keep containers tightly sealed to prevent moisture contamination and dust accumulation. Avoid prolonged exposure to temperatures above 40°C. Follow standard industrial hygiene practices; no special hazardous storage requirements apply. |
| Shelf Life | Shelf life is indefinite when stored in original sealed packaging in a cool, dry area, protected from sunlight and heat. |
MARLEX PP RB707CF is evaluated in converter-scale applications where contact clarity, hinge endurance, and low residual stress in thin sections define the boundary between acceptable and rejected parts. The first processing track is thin-wall injection molding for direct food contact. In this track, melt temperature at the nozzle is the primary variable governing haze retention in 0.4–0.8 mm wall sections. When nozzle temperature drifts above 250 °C, low-molecular-weight fractions migrate to the flow front and deposit on polished cavity surfaces, producing gate-area haze that cannot be corrected by holding pressure alone. Processors running 12–16-cavity hot-runner tools commonly set the manifold temperature 5–10 °C below the nozzle temperature to reduce residence-time degradation. Mold temperature is maintained at 10–25 °C to fix aspect clarity before spherulite growth reorganizes the surface layer. Cycle-time criticality is observed below 0.6 mm nominal wall, where fill time must remain under 0.35 s per cavity to prevent short shots. Screw L/D ratios from 20:1 to 24:1 are adequate if compression ratios are kept in the 2.2:1–2.8:1 range because higher compression raises shear heating and shifts the effective melt viscosity. Clamp force on thin-wall tools of this type is typically specified at 3.0–5.0 kN/cm² of projected cavity area; lower clamp force on multi-cavity tools produces flash at the parting line because the required injection velocity is high. Pre-drying is not required when storage relative humidity is below 60%; above this threshold, surface moisture sorption can produce splay in thick sections and is addressed by drying at 80 °C for 2 h. Melt flow rate is determined by ISO 1133-1:2022 at 230 °C under 2.16 kg; converter-run values for MARLEX PP RB707CF must be verified against the batch certificate because grade-specific published data for this configuration is limited.
Raw-material ratios in this segment are typically limited to color masterbatch at 1.5–3.0 wt%, slip/antiblock masterbatch at 0.5–1.5 wt%, and nucleating masterbatch only when downstream converters require haze below 8% measured by ASTM D1003-21. Overloading nucleator beyond the supplier maximum shifts the impact behavior nonlinearly, with falling-weight impact values measured by ASTM D5420-21 decreasing by more than 25% at 0 °C in some polypropylene random copolymer systems. Direct food contact compliance is verified under FDA 21 CFR 177.1520 for olefin polymers and under EU Regulation (EU) No 10/2011 with overall migration below 10 mg/dm² using 3 wt% acetic acid and 20 vol% ethanol simulants. Terminal products include dairy tubs, deli containers, microwaveable bowls, and clear hinged lunch boxes.
Table 1 summarizes starting-point ranges drawn from polypropylene random copolymer processing literature; grade-specific published data for MARLEX PP RB707CF is limited.
| Process variable | Thin-wall food packaging | Medical device housings | Closures |
|---|---|---|---|
| Nozzle melt temperature | 215–250 °C | 210–240 °C | 220–250 °C |
| Mold temperature | 10–25 °C | 20–35 °C | 15–30 °C |
| Holding pressure | 50–70 bar | 45–65 bar | 55–75 bar |
| Back pressure | 5–10 bar | 4–8 bar | 6–12 bar |
| Injection velocity | 150–250 mm/s | 80–160 mm/s | 180–280 mm/s |
| Screw L/D ratio | 20:1–24:1 | 20:1–22:1 | 20:1–24:1 |
Gate blush on transparent medical device housings is not a cosmetic defect alone. It correlates with residual stress at the gate vestige, which is measured by birefringence under crossed polarizers. When a clarified random copolymer PP is injected at too high a velocity into a cold runner system, shear-induced nucleation raises the free-energy barrier for chain relaxation. The result is a visible halo extending 2–5 mm from the gate. In production of MARLEX PP RB707CF components, this defect is minimized by reducing injection velocity in the first 20–30% of stroke and by using a mold temperature of 25–35 °C. Hot-runner valve gates with open diameters below 0.8 mm produce excessive shear and should be avoided when wall thickness exceeds 1.2 mm. On multi-cavity medical tools, cavity-to-cavity fill imbalance above 5% measured by short-shot studies produces inconsistent residual stress and optical anisotropy; hot-runner balancing by adjustable valve-gate timing brings imbalance below 3% on stable production lines.
Medical device housings require material certification under ISO 10993-5:2009 for in vitro cytotoxicity and ISO 10993-10:2021 for skin sensitization after the intended sterilization exposure has been applied to representative parts. For non-implant, limited-contact devices, FDA 21 CFR 177.1520 and USP <661.1> are typical starting points. Ethylene oxide sterilization is preferred over autoclave for load-bearing components because random PP heat deflection temperature under 0.46 MPa load is generally below 90 °C measured by ASTM D648-18, Method A. Autoclave exposure at 121 °C for 15 min can induce dimensional change in thick bosses and snap-fit geometries. Additive ratios in medical housings are typically limited to 1.0–2.0 wt% of a cobalt-free color masterbatch and 0.1–0.5 wt% of an antistatic masterbatch to avoid surface exudation. Terminal products include transparent diagnostic instrument covers, specimen transfer containers, and sharps-disposal housings where clarity assists fill-line confirmation.
For closure systems molded from random copolymer PP, continuous service requires seal force retention under carbonation, top-load, and thermal cycling. Injection and compression molding both appear in this downstream segment; injection-molded continuous-thread closures dominate because of their ability to hold valve-gate vestige geometry below 0.2 mm protrusion, which is critical for induction-seal liner wetting. Removal torque drift across a 24 h aging period is often assigned to slip-agent migration from the polymer bulk to the sealing surface. The standard test method is ASTM D2063-12; values for non-child-resistant 28 mm PCO 1881 closures are typically specified by brand owners as 0.8–2.3 N·m removal torque and 0.5–1.5 N·m application torque. Torque retention above 80% after 48 h at 40 °C is a common acceptance threshold, although grade-specific published data for MARLEX PP RB707CF is limited. On 48-cavity hot-runner injection tools common for 28 mm closures, the valve-gate piston delay is set to hold the gate open for an additional 0.3–0.6 s after packing to minimize sink at the sealing plug.
Additive ratios in closure formulations are tight because excessive erucamide causes cap-to-neck slip at low removal angles. Slip-agent loading is commonly held between 500 ppm and 1000 ppm for carbonated beverage closures, while pigmented systems run at 1.0–3.0 wt% masterbatch. TPE liner overmolding uses a melt temperature of 180–200 °C for the liner material to prevent decomposition at the interface with the PP shell. Compliance for food-contact closures requires FDA 21 CFR 177.1520, EU Regulation (EU) No 10/2011, and China GB 4806.7-2016 where applicable. Terminal products include 28 mm PCO 1881 beverage closures, 30/25 mm dairy closures, and 38 mm snack-seal caps.
Housewares and refrigerated storage applications expose MARLEX PP RB707CF to repetitive lid flexing, low-temperature impact, and food acids. The critical processing boundary in this segment is the living hinge. For a polypropylene random copolymer with clarified morphology, hinge life is reduced when mold temperature at the hinge is kept below 15 °C because frozen-in orientation creates microcracks along the hinge line. A preferred mold temperature of 25–35 °C at the hinge, with hinge thickness of 0.25–0.50 mm and a radius of 0.3–0.6 mm, produces a more ductile orientation state. Flexural fatigue resistance is measured by repeated bending through 180° until failure; grade-specific published data for RB707CF is limited, but random copolymer PP systems commonly survive 10⁴–10⁶ cycles when hinge geometry is optimized. Core shift in rectangular storage boxes becomes measurable when flow length exceeds 150 mm; molders compensate with stepped mold temperature from 20 °C near the gate to 35 °C at the end of fill to hold wall thickness within ±0.08 mm.
Dishwasher exposure in polypropylene storage containers requires additives that resist extraction of clarifiers and antioxidants by alkaline detergents at 65–85 °C. Compliance for food storage includes EU Regulation (EU) No 10/2011 overall migration testing in 3 wt% acetic acid, 20 vol% ethanol, and vegetable oil simulants, with results below 10 mg/dm². Low-temperature impact in freezer storage is evaluated by drop testing filled containers at -20 °C; random PP grades exhibit lower impact energy than block copolymers, so wall sections below 0.8 mm require radiused corners to avoid brittle fracture. Terminal products include transparent refrigerator boxes, lunch box lids with integral hinges, spice jars, and utility bins.
Table 2 consolidates the compliance test matrix for direct food and limited pharmaceutical-contact applications.
| Standard/regulation | Scope | Test condition or limit |
|---|---|---|
| FDA 21 CFR 177.1520 | Olefin polymers for food contact | Extraction limits under actual use temperature and food simulant conditions |
| EU Regulation (EU) No 10/2011 | Plastic materials for food contact | Overall migration <10 mg/dm² in aqueous, acidic, and alcoholic simulants |
| China GB 4806.7-2016 | Food-contact plastic materials | Overall migration and heavy metal limits per Chinese national standard |
| USP <661.1> | Pharmaceutical packaging plastic components | Chemical safety and biological reactivity under USP monograph |
| ISO 10993-5:2009 | Biological evaluation, cytotoxicity | In vitro cytotoxicity of medical device components |
| ISO 10993-10:2021 | Biological evaluation, skin sensitization | Sensitization testing after intended sterilization |
| REACH Directive EC 1907/2006 | EU chemicals regulation | SVHC content and restrictions applicable to polymer and additives |
| RoHS 2011/65/EU | Electrical/electronic equipment restrictions | Heavy metals Pb, Hg, Cd, Cr(VI), PBB, PBDE below harmonized limits |
In automated pipette tip production from polypropylene random copolymer, the straightness specification governs rack fitment and liquid-handler alignment. Molded tips in 64- and 96-cavity tools are checked by video metrology; deviation from the theoretical axis must remain below 0.10 mm over 70 mm length for tips used on 96-channel liquid handlers. This requirement is met by maintaining balanced hot-runner manifold temperatures within ±2 °C and by delaying gate freeze for a holding-pressure window of 0.5–1.0 s beyond visual gate seal. If gate seal occurs too early, the rib neck shrinks asymmetrically and the tip body bows toward the colder cavity side. Cycle times below 6 s for 96-well PCR plates increase gate-stringing frequency, which is a downstream automation failure mode when plates are stacked by robotic grippers. Video metrology systems with 0.005 mm linear resolution are used for tip straightness; optical gaging with 0.02 mm depth-of-field limits is sufficient for full rack geometry but not for individual tip axis deviation.
Additive loading in laboratory consumables is kept leaner than in packaging: antistatic masterbatch at 0.2–0.6 wt%, no slip agents, no pigment unless required for OEM color coding, and no mold release that could interfere with polymerase chain reaction yield. Compliance for food-contact labware is verified under FDA 21 CFR 177.1520, for pharmaceutical packaging components under USP <661.1>, and for biological suitability by ISO 10993-5:2009 for in vitro cytotoxicity. Sterilization by gamma radiation at 25 kGy is commonly specified; random PP may yellow if the antioxidant package is insufficient, with color shift measured by ASTM D6290-19 for pellet or plaque yellowness change. Terminal products include pipette tips, microcentrifuge tubes, PCR tube strips, and cryovial bodies.
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Marlex PP RB707CF is a clarified polypropylene random copolymer supplied in pellet form by Chevron Phillips Chemical for extrusion blow moulding, injection stretch blow moulding preform production, and selected extrusion applications where low haze and controlled organoleptic performance are specified. The grade carries a nominal melt flow rate of 2.0 g/10 min when tested under ASTM D1238-23 at 230°C/2.16 kg and a density of 0.905 g/cm³ under ISO 1183-1:2019. The random copolymer structure incorporates ethylene comonomer at a level sufficient to suppress crystallinity relative to polypropylene homopolymer; differential scanning calorimetry under ISO 11357-3:2018 typically indicates a peak melting temperature of 131–135°C. Commercial applications are concentrated in extrusion blow moulded containers from 250 mL to 5 L for food contact, pharmaceutical, and personal care packaging where clarity, impact resistance, and low taste/odour transfer are specified. The product is not intended for sustained load-bearing structural parts; its processing window is narrow and must be validated on the intended conversion line.
In extrusion blow moulding, the practical melt-temperature window is 190–215°C from feed zone to die head. Below 190°C, the melt viscosity is too high, producing rough parison surfaces and increasing wall-thickness scatter to more than ±10% on oval or flat-sided containers measured by ultrasonic wall-thickness gauges after moulding. Above 215°C, two failure mechanisms become dominant. First, the low-melt-flow random copolymer loses parison hang strength; on a shuttle line with a 60 mm extruder diameter and 24:1 L/D barrier screw, a die-head temperature increase from 210°C to 225°C raised wall-thickness variation from ±10% to ±18% and shortened usable parison length by 30%. Second, the clarifier package begins to degrade, producing a yellow shift of ≥0.5 b* units under ASTM D6290 and a haze increase of 2–3% on 1 mm plaques after 15 min residence time. The processing window is therefore the central constraint in high-output operations; barrel zones should be profiled at 180°C/190°C/200°C/205°C/210°C with the head and die held at 210°C unless a different profile is validated by ASTM D1003 haze measurements and wall-thickness capability studies.
Extruder screw speed should be set to 45–70 rpm on a 60 mm barrier screw with 24:1 to 30:1 L/D and a compression ratio of 2.5:1 to 3.0:1. Above 70 rpm, shear heating may generate local melt temperatures 5–10°C above the barrel setpoint, which is sufficient to approach the clarifier degradation threshold. Die-head pressures of 20–35 MPa are typical for 60 mm extruders. Pressures below 18 MPa indicate insufficient backpressure, which can leave unmelts and reduce optical homogeneity. Pressures above 40 MPa increase shear heating and may push local melt temperature beyond the clarifier thermal limit even when barrel setpoints remain within range. Blow-up ratios between 2.5:1 and 3.5:1 are preferred; below 2.5:1, thicker walls cool slowly enough to permit spherulite growth and haze, while above 3.5:1, parison thinning reduces side-wall impact performance below the 60 J/m notched Izod baseline under ASTM D256-10. Mould temperatures of 10–25°C are recommended for cycle-time and haze control; chilled water at 10°C restricts spherulite growth, whereas mould temperatures above 30°C extend cycle time and increase haze.
For injection stretch blow moulding preforms, melt temperature should be 220–235°C and cold mould coolant should be held at 8–12°C to quench the clarified melt into a low-haze amorphous state. Preform wall thickness should remain below 4 mm; thicker preforms retain heat and develop core haze from slow cooling. Reheat blow temperatures of 90–110°C measured by infrared pyrometer on the preform surface are typical for this grade class. Machine clamp force in shuttle blow moulding is usually 50–150 kN for containers up to 2 L; larger containers with pinch-off seams above 250 mm may require 200–300 kN because weld-line integrity at the pinch-off is a function of clamp pressure and material melt strength.
Table 1 consolidates representative physical property values reported in producer technical literature for Marlex PP RB707CF. These values are not lot-specific specifications and should be compared against a certificate of analysis for the commercial lot in use.
| Property | Method | Typical value |
|---|---|---|
| Melt flow rate | ASTM D1238-23 (230°C, 2.16 kg) | 2.0 g/10 min |
| Density | ISO 1183-1:2019 | 0.905 g/cm³ |
| Tensile strength at yield | ASTM D638-14, Type IV, 50 mm/min | 30 MPa |
| Elongation at yield | ASTM D638-14, 50 mm/min | 12% |
| Flexural modulus, 1% secant | ASTM D790-17 | 1,090 MPa |
| Notched Izod impact, 23°C | ASTM D256-10 | 60 J/m |
| Haze, 1 mm plaque | ASTM D1003-13 | 4% |
| Gloss, 60° | ASTM D2457-13 | 90 GU |
| Vicat softening temperature, 10 N | ASTM D1525-17e1 | 131°C |
The notched Izod impact of 60 J/m at 23°C distinguishes RB707CF from homopolymer polypropylene grades commonly specified for blow moulding. Homopolymer grades with similar melt flow rate typically exhibit notched Izod values below 25 J/m but flexural modulus near 1,500 MPa under ASTM D790-17. The modulus sacrifice of approximately 20–25% is the trade-off for improved impact and lower haze. This trade-off should be quantified by drop testing finished containers using ASTM D2463-15 or ASTM D5276-19, because flexural modulus alone does not predict drop performance in thin-walled bottles with wall thickness below 1 mm. The grade is also less rigid than PET, with a density of 0.905 g/cm³ compared with 1.34 g/cm³ for PET, and is not a barrier resin; oxygen transmission rate of polypropylene at 1 mm thickness is approximately 1,000–2,000 cm³/(m²·24 h·0.1 MPa) at 23°C and 0% RH. RB707CF is therefore unsuitable for carbonated soft drink containers requiring CO₂ retention unless barrier treatment or multilayer structures are used.
Because RB707CF is used in taste-sensitive applications, the grade is supplied with a clarifier package that has lower thermal stability than unclarified homopolymer. Residence time in the extruder at 220°C should be limited to 10 min; repeated extrusion of regrind at more than 30 wt% is not recommended unless laboratory tests using ASTM D3960 for gel content and sensory panel methods for taste and odour confirm no detectable change. For pharmaceutical and food-contact applications, finished-article odour and taste should be evaluated under ASTM E2609 or equivalent sensory protocols; no raw resin can self-certify finished-article organoleptic performance. Pre-drying is not normally required for sealed pellet boxes. However, if silo storage exceeds 30 days at relative humidity above 60%, drying at 80°C for 2–4 h in a desiccant dryer with a -30°C dew point is required to prevent moisture-induced splay and surface streaks. Overdrying beyond 4 h is not beneficial and may increase static charge build-up in pellet conveying lines, causing feed-throat bridging.
Additive compatibility must be controlled. Avoid melt blending with high levels of peroxide masterbatch because peroxide-induced chain scission will raise melt flow rate and reduce parison hang strength. If melt flow adjustment is required, blend with a controlled-rheology grade and track the shift using ISO 1133-1:2022 at 230°C/2.16 kg. For colouring, a polypropylene-compatible masterbatch of 2–4 wt% with carrier melt flow rate between 5–20 g/10 min can be used; at carrier levels above 4 wt%, the final MFR may shift above 2.5 g/10 min and alter parison hang strength. Periodic wipe-down of the die lip and mandrel is required during runs exceeding 8 h, particularly when running trim scrap at the upper regrind limit, because minor plate-out from the clarifier system can accumulate and create surface defects.
The 2.0 g/10 min melt flow rate places RB707CF in the high-melt-strength portion of the random copolymer portfolio. By contrast, injection-grade clarified random copolymers with MFR of 12 g/10 min yield shorter usable parison length and thinner side walls in extrusion blow moulding. Published data for direct grade-to-grade parison drawdown comparisons is limited; however, production-scale observations on accumulator-head machines indicate that a 2.0 g/10 min grade retains a usable parison length of approximately 1,200 mm before drawdown exceeds 15%, while a 12 g/10 min clarified random copolymer reaches similar drawdown at 600 mm under identical die diameter and temperature. This difference defines the product’s niche: RB707CF is appropriate for long-parison, multi-cavity or large-part extrusion blow moulding, whereas high-flow clarified grades are better suited to ISBM preform injection or thin-wall injection moulding where melt must fill long flow paths at low wall thickness.
Rheological characterisation under ISO 11443:2021 at 200°C and apparent shear rates from 100 s⁻¹ to 1,000 s⁻¹ is recommended to set die land dimensions, because single-point MFR does not capture shear-thinning behaviour. The die land length-to-gap ratio should be 10:1 to 15:1 to avoid melt fracture and maintain optical clarity. A Maddock mixing section with 0.25 mm clearance can improve homogenization but increases shear heating, so melt temperature should be verified with needle probes at the screw tip.
Table 2 summarises regulatory boundary conditions that apply to RB707CF in common packaging markets. The raw pellet status in Table 2 is not a substitute for finished-article compliance testing; conversion conditions, additives, colorants, and surface treatments may change the regulatory outcome.
| Regulation/Standard | Scope | RB707CF boundary condition |
|---|---|---|
| FDA 21 CFR 177.1520 | Olefin polymers for food-contact articles | Base resin is within scope when finished article meets extraction limits and conditions of use in the applicable paragraph. |
| Regulation (EU) No 10/2011 | Plastic food-contact materials | Finished article must meet overall migration limit 10 mg/dm² under migration testing; converter must validate complete formulation. |
| USP <661.1> | Pharmaceutical packaging materials | Physicochemical testing on finished container is required; raw resin certification does not replace finished-article testing. |
| REACH 1907/2006 | SVHC and Annex XVII restrictions | No SVHC intentionally added at >0.1% w/w in standard pellet form; verify with Safety Data Sheet. |
| RoHS 2011/65/EU | Heavy metals and brominated flame retardants | Not a typical application scope for packaging, but pellet would not be expected to exceed 100 mg/kg cadmium or 1,000 mg/kg lead. |
Because RB707CF is a polypropylene-based resin, its solvent compatibility differs from polycarbonate or PET. Solvents with solubility parameters close to polypropylene may swell the amorphous phase; compatibility should be tested according to ISO 175:2010 with the intended container contents at end-use temperature. For pharmaceutical packaging, USP <661.1> physicochemical testing on the finished container is mandatory. For food contact, the finished article must meet overall migration limit 10 mg/dm² under Regulation (EU) No 10/2011 as amended. For applications requiring steam sterilization at 121°C, RB707CF is not recommended without finished-part dimensional and haze verification because the Vicat softening temperature is 131°C under ASTM D1525-17e1; continuous exposure above 110°C can induce post-crystallization, gloss loss, and dimensional change. Published data for specific solvent compatibility and creep rupture of large containers produced from RB707CF is limited; design validation should include finished-article testing rather than reliance on raw resin data alone.