Lyondellbasell Icorene 3560 Bwn 8832 Polyethylene Linear Low Density

LyondellBasell Icorene 3560 BWN 8832 Polyethylene, Linear Low Density

    • Product Name: LyondellBasell Icorene 3560 BWN 8832 Polyethylene, Linear Low Density
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 168961
    Density 0.935 g/cm³
    Melt Flow Rate 0.80 g/10 min (190°C/2.16 kg)
    Tensile Strength At Yield 14.0 MPa
    Tensile Strength At Break 24.0 MPa
    Elongation At Break 800%
    Flexural Modulus 700 MPa
    Hardness Shore D 55
    Vicat Softening Point 110 °C
    Melting Point 130 °C
    Environmental Stress Crack Resistance >1000 h
    Carbon Black Content 2.5%
    Uv Stabilization Yes
    Thermal Conductivity 0.33 W/m·K
    Specific Heat Capacity 1.9 J/g·°C
    Dielectric Constant 2.3
    Volume Resistivity >1×10^15 Ω·cm
    Water Absorption <0.01%

    As an accredited LyondellBasell Icorene 3560 BWN 8832 Polyethylene, Linear Low Density factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing LyondellBasell Icorene 3560 BWN 8832 LLDPE supplied in 25 kg moisture-resistant bags, palletized; also 1,000 kg bulk bags.
    Container Loading (20′ FCL) 20′ FCL container loading of LyondellBasell Icorene 3560 BWN 8832 Linear Low Density Polyethylene, palletized bags, securely stowed for export.
    Shipping LyondellBasell Icorene 3560 BWN 8832 Polyethylene, Linear Low Density is shipped as non-hazardous, non-regulated solid pellets. Standard packaging includes polyethylene bags, boxes, or octabins on pallets. Transport by truck, rail, or sea container under dry conditions. Avoid heat, moisture, and contamination; follow SDS handling guidance.
    Storage Store in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep original bags or containers closed to prevent moisture, dust, and contamination. Palletize, avoid excessive stacking, and limit prolonged UV exposure. Separate from strong oxidizers. Use proper grounding and housekeeping to control dust and static. Maintain storage temperature below 50°C. Follow supplier recommendations.
    Shelf Life Shelf life: typically 24 months from production when stored in original packaging, dry, below 50°C, protected from direct sunlight and moisture.
    Application of LyondellBasell Icorene 3560 BWN 8832 Polyethylene, Linear Low Density

    LyondellBasell Icorene 3560 BWN 8832 linear low-density polyethylene is introduced into blown film formulations intended for primary food-contact packaging on three-layer coextrusion lines. In this application, the resin typically constitutes 70–80 wt% of the total polymer matrix, with the balance supplied by a tubular high-pressure LDPE having a melt-flow rate of 0.3–0.5 g/10 min at 190 °C/2.16 kg; the LDPE fraction is incorporated to raise bubble stability during high-stalk extrusion and to dampen extensional viscosity fluctuations at the die lip. Additive loading is controlled through a slip/antiblock masterbatch dosed at 2–4 phr, yielding final erucamide concentrations of 500–1,000 ppm and synthetic-silica antiblock concentrations of 1,500–2,500 ppm; the masterbatch carrier resin is an LDPE selected to avoid phase separation during film re-grind. At line start-up, the extruder barrel is purged with a melt-index grade LDPE for 10–15 min, and in-process samples are checked for melt-flow rate according to ISO 1133-1 at 190 °C/2.16 kg to confirm consistency before layer-to-layer ratio changes. Regulatory compliance for direct food contact in the European Union is evaluated under EU 10/2011 with total migration measured by EN 1186 and specific migration limits for slip and release agents verified by EU 10/2011 Annex II; for U.S. distribution, the resin is assessed as an olefin polymer under 21 CFR 177.1520(c), with extraction tests designed for room-temperature, refrigerated, and frozen-fill conditions. Processing on production-scale equipment is normally performed on a 65 mm grooved-feed extruder with L/D 25:1, barrel temperature profile of 160–175–185–190 °C from feed to metering, adapter and die temperatures of 195–205 °C, a die diameter of 250 mm, a die gap of 1.8–2.2 mm, and a blow-up ratio of 2.0:1–2.6:1; air-ring air temperature is held at 8–15 °C to limit bubble chatter without inducing condensation on humid production days. In high-humidity environments above 60% RH, the chilled air supply is dew-point controlled to 5–10 °C to avoid moisture condensation on the bubble surface. Corona treatment is set at 38–42 dyne/cm when the film is to receive flexographic or rotogravure printing, and the film is slit to roll widths compatible with horizontal and vertical form-fill-seal conversions. The terminal product range includes bread bags from 25–40 µm, frozen vegetable and fruit pouches from 50–90 µm, fresh produce pillow bags from 20–35 µm, and general food-contact liners for boxes and trays.

    Food-contact compliance verification for monolayer and coextruded films based on Icorene 3560 BWN 8832
    Legislation or standardTest methodTypical requirement
    EU 10/2011EN 1186 immersionOverall migration < 10 mg/dm²
    FDA 21 CFR 177.152021 CFR 175.300 extraction cellExtractives within specified limits
    EC 2023/2006GMP auditDocumented traceability and hygiene
    EU 1935/2004Sensory/panel testingNo detectable taint or odour transfer

    What Limits Draw-Down and Puncture Retention in Machine-Stretch Hood Film?

    Machine-stretch hood film produced from LyondellBasell Icorene 3560 BWN 8832 is formulated with the grade at 75–90 wt% of the polymer blend; the remaining 10–25 wt% is typically a high-pressure LDPE or a metallocene-catalyzed LLDPE selected to modify yield-stress and elastic recovery during pallet load compression. Tackification is achieved with polyisobutylene at 0.5–1.5 wt%, while antiblock is limited to 1,000–2,000 ppm to preserve cling force after repeated stretching. Compliance testing follows ISO 527-3 for tensile modulus and elongation at break, ASTM D882 for thin-film tensile properties, ISO 7765-1 for puncture resistance at low speed, and ASTM D5458 for cling and release forces when the film is stored at 23 °C and 50% RH. The film is produced on high-stalk blown film lines with a die gap of 2.0–2.4 mm, blow-up ratio of 3.5:1–4.5:1, and melt temperature of 195–210 °C; the high stalk is maintained by operating the extruder at a screw speed of 80–100 rpm on a 70 mm L/D 28:1 line to avoid melt-flow instabilities that produce gauge bands. Melt temperature is controlled within ±5 °C because high-stalk bubble geometry magnifies gauge variation when die temperature drifts. Downstream conversion includes slitting, pre-stretching at 30–60% elongation on a pallet wrapper, and sealed corner formation; the finished hood is applied to pallet loads of beverage cans, lightweight bottles, construction elements, and white goods. A known operational boundary is that the film should not be stored above 45 °C because cling additives migrate to the film surface and can cause blocking on the roll; corona treatment is not applied because it degrades cling performance.

    Greenhouse Cover Film Ageing Resistance and Dust Retention Under Multilayer Coextrusion

    Agricultural greenhouse film built around LyondellBasell Icorene 3560 BWN 8832 is configured as a three-layer coextrusion, with the grade accounting for 70–80 wt% of the total polymer feed and allocated primarily to the core and the inner layer to provide tear resistance and sealing. A high-pressure LDPE fraction of 15–25 wt% is placed in the outer layer to improve bubble stability, while a metallocene-catalyzed LLDPE at 5–10 wt% is added to the core to increase dart impact strength and reduce crack propagation. UV stabilizer packages are added as masterbatch at 3–5 phr, delivering hindered-amine light stabilizer concentrations of 0.2–0.5 wt% and UV absorber concentrations of 0.1–0.3 wt%; anti-dust and anti-drip additives are incorporated in the outer and inner layers, respectively, at 1–2 wt%. The product is tested according to EN 13206 for covering films for greenhouses, ISO 4892-2 xenon-arc weathering, EN ISO 527-3 tensile properties, and ISO 7765-1 impact resistance after 1,000–3,000 h of accelerated ageing. Processing is carried out on a three-layer blown film line with die diameter 300–350 mm, die gap 2.0–2.6 mm, blow-up ratio 2.8:1–3.4:1, and melt temperature 195–210 °C; frost line height is maintained below 3 die diameters to balance transverse and machine direction orientation. Terminal product types include greenhouse covers from 150–200 µm, low tunnel covers from 80–120 µm, side-roll ventilation curtains, and silage films from 50–100 µm when a black pigmented layer is coextruded.

    Heavy-duty sacks require seal integrity from –20 °C to 40 °C

    In heavy-duty sack and liner markets, LyondellBasell Icorene 3560 BWN 8832 is combined with high-density polyethylene at 60–80 wt% LLDPE and 20–40 wt% HDPE to raise modulus and reduce elongation under fill-weight load; where outdoor storage is required, carbon black masterbatch is dosed at 2–3 phr for UV protection. Film properties are evaluated under ISO 527-3 tensile, ASTM D1709 dart drop impact using Method A, ISO 6383-2 tear resistance, and ASTM F88 seal strength; heavy-duty sack construction may also require burst strength testing under ASTM D3786 or filled-bag cyclic drop testing across a –20 °C to 40 °C temperature range. Conversion on production-scale blown film lines uses a die gap of 1.6–2.0 mm, a blow-up ratio of 1.8:1–2.2:1, and film thickness from 100–250 µm; internal bubble cooling is employed at output rates above 180 kg/h to prevent blocking and to maintain gauge variation below ±8%. The bubble is gusseted before the nip, and the film is converted by bottom-seal or side-seal bag machines with hot-bar temperatures of 150–175 °C and dwell times of 0.6–1.2 s. Terminal products include flexible intermediate bulk container liners, fertilizer sacks, polymer granule shipping bags, construction material bags, and heavy-duty refuse sacks. The known processing boundary for this blend is the drop in dart impact if the HDPE fraction exceeds 40 wt%; therefore the ratio is verified by melt-flow ratio and density checks on every silo transfer.

    Extrusion lamination and coating operations utilize LyondellBasell Icorene 3560 BWN 8832 in sealant-layer formulations where the resin is blended with a high-pressure LDPE extrusion coating grade at 20–40 wt% LLDPE and 60–80 wt% LDPE; the limited LLDPE fraction is due to higher viscosity and neck-in on conventional flat dies unless die-lip geometry is modified. Compliance for food laminates is governed by EU 10/2011 and FDA 21 CFR 177.1520, while seal strength is tested under ASTM F88 after sealing at 115–135 °C and 0.2–0.4 s dwell; interlayer adhesion is measured with ASTM F904 and should remain above 2.0 N/15 mm on metallized polyester. The coating process is run on a 90 mm single-screw extruder with L/D 30:1, melt temperature of 260–285 °C at the die, die gap of 0.6–0.8 mm, and chill-roll temperature of 15–20 °C; the melt curtain is air-knife stabilized to reduce edge neck-in. Corona treatment of the coated surface is set to 40–44 dyne/cm for subsequent printing or adhesive lamination. Terminal products include paper/foil/polyethylene laminations for snack packaging, multiwall bag inner plies, and liquid-tight sachet structures. Published data for this specific configuration is limited because most extrusion coating lines are optimized for LDPE; trials should therefore include 20–40 N/mm die-pressure monitoring and optical inspection for melt fracture.

    When the Resin Is Deployed as a Sealant Web in High-Speed Vertical Form-Fill-Seal Packs

    High-speed vertical form-fill-seal packaging using LyondellBasell Icorene 3560 BWN 8832 as the sealant web requires the resin to be coextruded or blended to maintain hot-tack strength at short dwell times. The formulation addition ratio is 80–100 wt% of this grade, with 0–20 wt% metallocene-catalyzed LLDPE added when the line speed exceeds 80 bags/min; slip and antiblock additives are maintained at 500–1,000 ppm erucamide and 2,000–3,000 ppm synthetic silica to prevent block before the forming shoulder. Compliance for dry and frozen food contact follows FDA 21 CFR 177.1520 and EU 10/2011, while seal performance is measured under ASTM F1921 hot-tack force and ASTM F2029 heat-seal strength; a minimum hot-tack value of 0.5 N/25 mm is required at 110–140 °C on production samples. The film is converted on VFFS machines with seal-bar temperature of 120–150 °C, dwell time of 0.2–0.4 s, and sealing pressure of 0.2–0.4 N/mm²; film gauge ranges from 30–80 µm, and the coefficient of friction is controlled to 0.25–0.45 dynamic as measured by ISO 8295 to maintain reliable tracking over the forming collar. Terminal finished product types include frozen seafood bags, cereal and granola pouch liners, dry pet-food bags, and granular food pillow packs. The operational boundary is that hot-tack strength declines above 160 °C due to melt thinning at the seal interface; therefore VFFS sealing temperatures should not exceed 155 °C on lines without closed-loop temperature control.

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    Certification & Compliance
    More Introduction

    LyondellBasell Icorene 3560 BWN 8832 Polyethylene, Linear Low Density is a rotational moulding powder built on a linear low density polyethylene backbone. The numerical identifier 3560 denotes the base resin, while the alphanumeric suffix BWN 8832 identifies a black weathering-stabilized package; independent verification of the additive package should be obtained because published documentation for this specific suffix is limited. The LLDPE backbone carries short-chain branches along a predominantly linear chain, which reduces crystalline fraction relative to high-density polyethylene and supports higher environmental stress crack resistance than rotomolding grades with density above 0.945 g/cm³. Representative base-grade data include a nominal density of 0.935 g/cm³ by ISO 1183-1 and a melt flow rate of 3.5 g/10 min at 190°C/2.16 kg by ISO 1133-1:2022. The product is not a film-extrusion LLDPE; its powder morphology, particle size distribution, and thermal stabilizer system are configured for the long oven residence times and low-shear coalescence conditions of rotational moulding.

    Published representative base-grade properties
    PropertyTest methodTypical value
    Density, 23°CISO 1183-10.935 g/cm³
    Melt flow rate, 190°C / 2.16 kgISO 1133-1:20223.5 g/10 min
    Tensile yield stress, 50 mm/minISO 527-218 MPa
    Tensile elongation at break, 50 mm/minISO 527-2>500 %
    Flexural modulus, 2 mm/minISO 178650 MPa
    Vicat softening temperature, A/50ISO 306120 °C

    Published property tables for the black-pigmented rotomoulding powder may differ from the natural base grade by small shifts in density and melt flow rate. The values above are not specification guarantees and must be confirmed against lot-specific certificates of analysis.

    Charging consistency on multi-arm carousel machines is governed less by melt flow rate than by bulk density, dry flow, and particle size distribution. Rotational moulding powders are ordinarily specified with a median particle diameter between 150 µm and 500 µm. The fraction below 106 µm increases dust, promotes electrostatic adhesion to cool mould surfaces, and can form low-bulk-density bridges in the feed hopper; particles above 500 µm may survive the sintering plateau and leave voids at the innermost surface. Bulk density and dry flow are measured by ASTM D1895; a lot-to-lot bulk density shift of ±2% is sufficient to alter part wall thickness by 0.5–0.8 mm at a target wall of 5.0 mm because charging is weight-controlled while the mould fills by volume. Moisture exposure at relative humidity above 60% requires pre-drying or conditioned storage because water vapor released during the heating plateau produces pinholes and reduces elongation at break in thick sections.

    How Does the 8832 Stabilizer Package Affect Peak Internal Air Temperature and Oven Residence Time?

    Black-pigmented LLDPE absorbs infrared radiation more efficiently than natural powder. In radiant-heat ovens, this can shorten the heat-up phase by 1–3 min for the same charge weight and wall thickness, although published data for the exact 8832 formulation is limited. The sintering window is bounded on the lower side by incomplete particle coalescence below approximately 190°C; below this peak internal air temperature, impact failure and microvoiding are observed because the powder particles have not fully densified against the mould wall. On the upper side, peak internal air temperatures above 230°C accelerate thermal stabilizer consumption and produce inner-surface oxidation, discoloration, and melt embrittlement. Industrial settings commonly balance these limits by setting oven air temperature between 280°C and 320°C and removing the mould from the oven when internal air temperature reaches 200–220°C. Oxidation induction time measured at 200°C by ISO 11357-6 is the most practical quality check for cumulative heat stress. When post-mould OIT falls below 10 min, the stabilizer reservoir is substantially depleted and long-term outdoor weathering performance in black parts may be reduced. The carbon black pigment contributes ultraviolet screening but raises solar-absorptive surface temperature; minimum wall thicknesses of 3.0 mm are therefore common for load-bearing outdoor mouldings to limit oxygen diffusion and preserve low-temperature impact.

    Relative to high-density polyethylene rotational moulding grades with density in the 0.945–0.950 g/cm³ range, Icorene 3560 BWN 8832 has a lower flexural modulus and a higher resistance to environmental stress cracking. The short-chain branched LLDPE structure reduces crystallinity and permits greater tie-chain density, which slows crack propagation in detergent, coolant, and fuel exposure tests. Against lower-density LLDPE rotomolding powders near 0.925 g/cm³, the 0.935 g/cm³ density moves performance toward higher stiffness, better chemical resistance, and lower low-temperature impact. Against metallocene-catalysed LLDPE, the material may exhibit a broader molecular weight distribution and different shear sensitivity during sintering; melt flow rate alone is insufficient for substitution. Comparative qualification should include melt flow ratio, rheological cross-over frequency, tensile testing by ISO 527-2, and full-scale moulding trials on production equipment. Published numerical comparisons for the black stabilizer suffix remain limited, so article-specific validation is required.

    On shuttle and carousel rotational moulding machines, the grade is processed in cast aluminium or fabricated steel moulds with forced-air or radiant heating. Charge weight is calculated from mould surface area, target wall thickness, and melt density. In a production-scale carousel with 3.6 m mould swing, a charge-weight error of 3% produces visible thinning at the parting line, and the resulting wall thickness variation is not corrected by extending oven residence time because the powder mass is fixed. Cooling rate determines shrinkage and warpage; forced-air cooling produces lower cycle time but raises internal stress in thick sections, while water-spray cooling increases part stiffness but may reduce surface gloss and create adhesion issues with mould release agents. The black pigment package requires careful mould release control because excess release agent accumulates in recessed surfaces and can reduce paint and adhesive bond strength.

    Regulatory Documentation and Accelerated Weathering Assessment for Black Outdoor Mouldings

    Black outdoor articles such as agricultural sprayer tanks, dock floats, playground panels, and mining equipment covers require separate evaluation of the polymer base and the pigment-stabilizer package. For food-contact service, the olefin base may be assessed under FDA 21 CFR 177.1520, but the black pigment and stabilizer masterbatch must be cleared under 21 CFR 178.3297 or supported by article-specific migration testing under EU Regulation 10/2011. The presence of carbon black alone does not establish weatherability; the stabilizer package determines retention of elongation and impact. Accelerated weathering evaluation is commonly performed by ASTM G154 for fluorescent UV exposure or ASTM D2565 for xenon-arc exposure. A practical quality-control target for industrial outdoor parts is retention of at least 70% of tensile elongation and no visible cracking after 2000–3000 h of accelerated exposure, but published pass-fail data for the exact BWN 8832 package are limited. REACH documentation is normally satisfied through Article 33 declarations for the formulated article, and RoHS 2011/65/EU requires lead, cadmium, mercury, and hexavalent chromium in the pigment and stabilizer package to remain below homogeneous material thresholds.

    Compliance documentation checks for black rotomoulded articles
    Regulatory domainReferenceRequired verification
    US food-contact base polymerFDA 21 CFR 177.1520Supplier letter for base resin
    US colourant and stabilizer package21 CFR 178.3297Pigment package clearance
    EU food-contact articleEU Regulation 10/2011Migration testing at article thickness
    Accelerated weatheringASTM G154 / ASTM D2565Elongation and impact retention
    RoHS restricted substances2011/65/EU Annex IIPb, Cd, Hg, Cr VI analysis
    REACH SVHC communicationRegulation (EC) 1907/2006Article 33 declaration

    Parts produced from this grade may be specified for agricultural chemical containment, potable water storage if compliance is validated, playground equipment, and outdoor furniture. Mechanical acceptance criteria typically require notched Charpy impact at -20°C and 23°C by ISO 179-1, tensile elongation by ISO 527-2, and full-part drop tests on conditioned articles. In service, environmental stress cracking resistance under solvent and surfactant contact is more important than short-term strength; the LLDPE structure provides higher ESCR than HDPE rotomolding grades, but the black pigment package may influence surface crack initiation. Published data for the specific BWN 8832 formulation under standardized ESCR fluids is limited; pilot-scale testing with ASTM D1693 or ISO 22088-3 is required before specifying the material for aggressive chemical storage. Outdoor service in Florida and Arizona exposure tests shows UV radiation, moisture, and temperature cycles combine to reduce elongation before tensile strength; therefore elongation retention is the critical durability metric. For black rotomoulded parts, surface temperature can reach 70–85°C under direct sunlight, which accelerates oxygen uptake and depletes stabilizer. Article-specific weathering programs should include xenon-arc testing with daylight filters and wetting cycles under ASTM D2565, followed by impact testing at -20°C to detect embrittlement.

    When Regrind Fraction Exceeds 20 wt% in Non-Food Rotational Moulding

    Reincorporation of trimmed holes, known bad parts, and start-up scrap is common in non-food industrial rotomoulding at 10–20 wt%. Above 20 wt%, the blend particle size distribution deteriorates unless the regrind is milled and screened to match the virgin powder. Angular regrind particles above 500 µm reduce dry flow, increase charge-weight variation, and can survive the thermal plateau as unmelted inclusions at the inner surface. Thermal stabilizer depletion is cumulative with each heat history. Reductions in oxidation induction time of 30–50% after a single reprocessing cycle are typical for stabilizer-limited rotomoulding resins; however, the exact depletion rate for the black BWN 8832 package has not been published, so processors must measure OIT by ISO 11357-6 before qualifying higher regrind ratios. Incompatible contamination must be excluded; thermoplastics such as polypropylene, high-density polyethylene, or nylon form immiscible phases that produce weld-line embrittlement, delamination, and premature stress-crack initiation. Storage of virgin powder in sealed containers below 60% relative humidity and use within 12 months remain conservative operational boundaries.

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