Lyondellbasell Icorene 3545 Red 4338 Polyethylene Linear Low Density

LyondellBasell Icorene 3545 RED 4338 Polyethylene, Linear Low Density

    • Product Name: LyondellBasell Icorene 3545 RED 4338 Polyethylene, Linear Low Density
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    VTB
    Specifications
    HS Code 903009
    Density 0.935 g/cc
    Melt Flow Rate 3.5 g/10 min
    Tensile Strength At Yield 17.2 MPa
    Tensile Strength At Break 12.1 MPa
    Elongation At Break 800%
    Flexural Modulus 758 MPa
    Vicat Softening Point 105 °C
    Melting Point 125 °C
    Hardness Shore D 50
    Color Red
    Form Pellets
    Polymer Type Polyethylene, Linear Low Density (LLDPE)
    Processing Method Injection Molding

    As an accredited LyondellBasell Icorene 3545 RED 4338 Polyethylene, Linear Low Density factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing LyondellBasell Icorene 3545 RED 4338 Polyethylene, Linear Low Density supplied in 25 kg bags; 40 bags per pallet (1,000 kg).
    Container Loading (20′ FCL) LyondellBasell Icorene 3545 RED 4338 Polyethylene, Linear Low Density shipped in 20′ FCL containers, typically palletized in 25 kg bags.
    Shipping LyondellBasell Icorene 3545 RED 4338 Polyethylene, Linear Low Density, is a non-hazardous polymer resin. It is typically shipped in 25 kg polyethylene bags on pallets, stretch-wrapped, in dry covered containers or trucks at ambient temperature. Avoid moisture, heat, direct sunlight, and contamination. No UN hazard class required.
    Storage Store in a cool, dry, well-ventilated warehouse in original sealed containers, bags, octabins, or silos. Protect from direct sunlight, moisture, dust, and contaminants. Keep away from heat, sparks, open flames, and oxidizing agents. Maintain ambient temperature; avoid excessive heat. Keep containers closed when not in use. Use first-in, first-out rotation to prevent aging and contamination. Ensure good ventilation.
    Shelf Life Store cool and dry in unopened original packaging; typically use within 24 months from date of manufacture.
    Application of LyondellBasell Icorene 3545 RED 4338 Polyethylene, Linear Low Density

    Agricultural sprayer bodies processed by rotational moulding use Icorene 3545 RED 4338 as a directly pigmented powder. The powder is not dry-blended with a separate red masterbatch at the machine. Oven air temperature is normally set between 260 °C and 280 °C. Internal air temperature in the mould is brought to 195–210 °C for wall sections of 4–8 mm. The peak internal air temperature is held for 4–7 min on shuttle-type equipment and 8–12 min on carousel machines. Arm ratio of 4:1 is standard for bi-axial rotation. The red 4338 pigment package absorbs infrared energy differently from natural powder. The cycle should be transferred only after mapping the internal air temperature trace for the specific mold. Early demoulding produces microvoids and inner-wall pinholes. Overheating oxidises the inner surface and shifts the red shade toward a chalky appearance. Cooling begins with forced air for 8–15 min, followed by water mist to stabilise flat sidewall panels. Demoulding is generally done at 70–90 °C to limit warpage. Powder storage above 80 % relative humidity can introduce surface moisture; pre-drying at 60 °C for 2–4 h is used when surface pinholes appear in the first trial parts.

    Agricultural sprayer bodies and storage tanks are exposed to diluted urea ammonium nitrate, emulsifiable concentrates, and nonionic surfactants. The grade is linear low density polyethylene, which gives higher environmental stress crack resistance than most low density polyethylene grades. The red 4338 pigment package must still be tested with the actual formulation. The material is not a barrier for concentrated nitric acid, oleum, or strong oxidizers. Prolonged contact with xylene, toluene, or chlorinated solvents causes swelling and stress cracking. Formulations containing more than 5 % aromatic solvent require permeability testing under ASTM D543-21. Moulded-in inserts should have a minimum radius of 6 mm. Cut-outs and ports are post-drilled rather than moulded with sharp internal corners. Residual stress near drain ports can be reduced by increasing local wall thickness by 20–40 % above the general wall. The final part should be pressure-tested at 1.1 to 1.3 times the service head before shipment.

    What Controls Wall Thickness Uniformity in Rotomoulded Playground Impact Panels?

    Impact panels and slide sections moulded from RED 4338 must pass the EN 71 series despite the pigment being integrally dispersed. Wall thickness uniformity controls impact absorption. A section that drops below 3.5 mm in the high-impact zone can fail the drop test on a concrete substrate. Moulders use a 4:1 arm ratio and adjust the minor-axis speed to push powder into deep draw areas. The red pigment should not be added as a dry blend at the machine because pigment agglomerates reduce local impact strength. Ultrasonic wall thickness measurement is taken at a minimum of 12 points per panel before the part leaves the fixture. The outer mould surface is maintained without scratches; a scratch acts as a stress concentrator under impact and can reduce the energy absorbed before fracture.

    Standard or regulationTest methodRelevance
    EN 71-1:2014+A1:2018Mechanical and physical propertiesDrop, impact, and tip-over requirements for toys
    EN 71-2:2020FlammabilityBurn rate of accessible surfaces
    EN 71-3:2019+A1:2021Migration of certain elementsLimits for heavy metal release from pigmented surfaces
    ASTM F963-23Standard Consumer Safety Specification for Toy SafetyHeavy metals, impact, and sharp-edge requirements for US markets
    16 CFR 1303Ban of lead-containing paintLead content in surface coatings and substrates

    The migration kinetics of the red 4338 pigment in the polymer matrix must be assessed rather than treating the colour as a surface coating. Processing near 280 °C can decompose the pigment if the oven cycle is extended without adjusting internal air temperature. A melt index in the 4–5 g/10 min range under ISO 1133-1:2022 keeps the mould fill time short. Short fill time limits the thermal history seen by the pigment. For parts thinner than 4 mm, pigment loading cannot be raised above the formulation target without reducing low-temperature impact. Cold-climate playground equipment should be qualified with ISO 179-1:2010 at -20 °C. The red 4338 grade is not a replacement for a surface-applied warning colour when the standard requires a contrasting colour on the impact surface; the design engineer must confirm that the pigmented wall itself is accepted by the relevant notified body.

    In marine buoy applications, the moulding powder is selected for wall-section uniformity rather than for pigment loading alone. Foam-filled polyethylene buoys are produced in clamshell moulds with wall thicknesses from 5 mm to 12 mm. The red 4338 shell must withstand float impact from vessel contact and cyclic flexure at the mooring eye. Moulded-in stainless steel mooring inserts should be preheated to 60–80 °C before insertion. The boss forming the insert anchor is designed with a wall thickness at least 1.5 times the insert diameter. Mould surfaces are kept free of scratches because a surface defect in the outer wall becomes a crack initiation site under saltwater exposure. Ultraviolet resistance of the red pigment package is verified by ISO 4892-3:2016 cycle 1. For tropical or high-reflectance water conditions, ISO 4892-2:2013 gives a more severe screening method. The grade does not contain an antifouling additive; barnacle and algal attachment is a maintenance issue.

    Environmental stress crack resistance is a qualifying test for buoys. The selected condition is ASTM D1693-15B using 10 % Igepal CO-630 at 50 °C. Published data for the red 4338 configuration is limited; a moulded plaque from the production lot should be tested before the buoy design is approved. Cut edges around inserts should be sealed with a polyethylene-compatible sealant. This prevents saltwater wicking into the foam core and subsequent freeze-thaw damage. Threaded fasteners should be assembled with a torque below the value that produces stress whitening at the insert boss. Stress whitening indicates local yielding and will shorten service life in cyclic load. The wall thickness around the mooring eye should be increased by 30–50 % over the nominal shell wall. The parting line is located away from the mooring plane in the mould design to reduce failure risk.

    Secondary containment sumps under intermittent acid and solvent contact.

    Because secondary containment sumps may see pooled acids, alkalis, and solvent-contaminated water, the red 4338 pigmented grade must be tested against the actual chemical mixture. Standard polyethylene chemical resistance tables cannot fully describe mixed solvent effects. Chemical resistance testing is run under ASTM D543-21 at 23 °C and 60 °C for 7 days. Weight change, dimensional change, and tensile properties are measured before and after exposure. A retained tensile elongation at break of no less than 80 % of the unexposed value is a typical structural-integrity acceptance criterion set by the fabricator. The red 4338 pigment package may accelerate surface oxidation at the upper test temperature if the stabiliser system is depleted. Welded seams are made by extrusion welding using a rod of the same pigmented grade. Hot-air welding is not recommended because it produces lower short-term peel strength. Sump floors should have a slope of at least 1° to avoid ponding at wall intersections. Wall thickness near fluid connection points is increased by 25–50 % over the general wall.

    Test methodConditionMeasured property
    ASTM D543-217 days, 23 °C / 60 °CWeight change, dimensional change, tensile retention
    ASTM D1693-15B10 % Igepal CO-630, 50 °CEnvironmental stress crack resistance
    ISO 22088-2:2006Constant tensile stress in surfactantCreep rupture under chemical load
    ISO 527-2:201223 °C, 50 mm/minTensile elongation at break

    The grade is not suitable for continuous immersion in methylene chloride, acetone, or methyl ethyl ketone; these solvents cause softening and gross swelling. For sumps containing diesel or hydraulic oil, the standard ASTM D543-21 exposure gives only a first-order indication; full-scale testing with the actual oil mixture and a 30-day contact period is required to expose slow plasticiser extraction. Moulded channels should have a minimum corner radius of 6 mm to reduce stress concentration at the transition from floor to sidewall. Joint flanges are moulded with a full-radius transition rather than a square shoulder. After welding, a spark test at 5–10 kV is applied to detect pinholes in the wall. The use of a red pigmented grade in a containment area does not avoid the need for external warning labels where the fluid itself is colourless.

    In food processing facilities, material handling bins and divider boards moulded from RED 4338 are used to segregate raw material flows. The red colour visually marks the raw side of a facility when a plant uses colour-coded zoning. Food-contact compliance is based on the base polyethylene; the pigment package must be authorised under FDA 21 CFR 177.1520(c) and EU 10/2011. The finished bin should be migration-tested as a whole article because red pigment concentrates can alter specific migration behaviour. The migration kinetics of the red pigment and processing stabilisers in the polymer matrix are assessed with food simulants A, B, D2, or E according to the intended food type. The part design avoids blind holes and sharp internal corners below 3 mm radius; these features trap organic matter. Cleaning with hot water at 82 °C and alkaline detergent is typical in high-sanitation lines.

    The grade withstands repeated industrial washdown cycles, but steam lances above 110 °C can cause local deformation. Bins are moulded with a bottom drain hole of at least 25 mm diameter to allow complete draining after cleaning. For stacking strength, the sidewall rib pattern is designed to prevent creep in warm room conditions. The resin supplier does not provide a stacking guarantee without part-specific testing. A rough top edge or parting-line flash is removed because it interferes with washdown hygiene. Mould release agent should be avoided on food-contact surfaces; if release is needed, a food-compatible semi-permanent grade is used and baked onto the mould surface before moulding. Post-mould annealing at 60 °C for 1–2 h may be used to relieve residual stress in large flat bin walls before first use.

    When red 4338 powder replaces natural powder in recreational watercraft hulls

    Kayak and dinghy hulls are often rotationally moulded from linear low density polyethylene. The density specification under ISO 1183-1:2022 is approximately 0.935 g/cm³, which provides a balance between impact ductility and panel stiffness. A 4:1 arm ratio gives uniform wall thickness over the long shallow draft. Hull wall thickness typically ranges from 4 mm to 8 mm; thicker sections at the keel are produced by adjusting the internal air temperature trace and by local mould insulation. The red 4338 pigment gives a UV-visible shell that does not require topcoat painting. Abrasion resistance of polyethylene is moderate; repeated beaching causes surface erosion, but the pigment is dispersed through the wall rather than applied as a surface layer.

    Low-temperature ductility is checked with ISO 179-1:2010 at -20 °C before a hull design is accepted for cold-water use. The mould parting line is located above the waterline where possible because a sharp parting line creates a crack point in cold impact. The red pigment absorbs infrared differently from natural powder; oven residence time is set by internal air temperature rather than by a fixed table. Moulders should map the first trial with a thermocouple and adjust the cycle until the peak internal air temperature reaches 195–210 °C without exceeding 220 °C for more than 5 min. For hulls with integrally moulded footrest slots, the slot radius is not less than 6 mm to reduce strain concentration. Threaded hatch inserts are preheated and installed after cooling to avoid a heat-sink defect. This specific red 4338 configuration has limited published data for long-term UV retention in high-altitude freshwater use; outdoor exposure programmes per ISO 4892-2:2013 are used as a screening tool before full commercial lots are committed.

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    Certification & Compliance
    More Introduction

    The LyondellBasell Icorene 3545 RED 4338 grade is a pre-coloured, UV-stabilized linear low density polyethylene powder supplied for rotational moulding of hollow, impact-resistant parts. Published material-data values situate its nominal density between 0.935 g/cm³ and 0.940 g/cm³ under ISO 1183-1, with a melt flow rate of 4.5 g/10 min to 5.0 g/10 min at 190 °C/2.16 kg measured by ISO 1133-1:2022. The linear low density polyethylene backbone is therefore differentiated from blown-film LLDPE by its higher melt flow rate and from conventional HDPE rotomoulding grades by its lower density and higher short-chain branching. The product is not an extrusion pellet resin; it is delivered as a free-flowing powder with particle-size distribution controlled for dry-flow and bubble dissolution inside rotating tools.

    The designation RED 4338 indicates that the red pigment package is compounded into the resin at the producer level, eliminating the separate weighing and dry blending of colour concentrate at the moulding machine. Dry-blended pigment concentrates can segregate during storage or tumbling, producing colour streaks, variable opacity, and localized differences in UV stabilization. In this grade, the pigment and hindered amine light stabilizer system are dispersed into the polymer before delivery. The red pigment does not provide the same broadband light-blocking behaviour as a 2.0 wt% to 3.0 wt% carbon-black package; therefore, outdoor service life depends on the stabilizer formulation, part wall thickness, and geographic solar irradiance rather than on pigment opacity alone. Published accelerated weathering data for this exact configuration are limited, so long-term colour retention claims should be verified by ISO 4892-2:2013 xenon-arc testing on moulded parts of the intended section thickness.

    Why Does Rotational Moulding Require a Different Melt Flow and Particle Size Than Extrusion Compounding?

    Rotational moulding uses conduction heating through a metal mould shell and coalescence of polymer particles under low shear, not screw plasticization. A material intended for this process must therefore have a sufficiently high melt flow rate to form a continuous pinhole-free layer without the mechanical shear that an extruder provides. The 4.5 g/10 min to 5.0 g/10 min melt flow rate of Icorene 3545 RED 4338 is measurably higher than typical blown-film LLDPE grades, which often fall below 1.0 g/10 min under the same 190 °C/2.16 kg condition. In rotomoulding, higher flow improves particle fusion and shortens the time required to reach a smooth inner surface. At the same time, the linear low density architecture retains enough zero-shear melt strength to prevent sag or thinning on vertical mould surfaces during rotation.

    Particle geometry is equally process-critical. Rotomoulding powders are commonly controlled to a top size near 35 mesh (500 µm) with a specified proportion below 74 µm for fine-particle packing. Coarse particles increase the risk of pinholes and uneven wall thickness, while excessive fines can create dry-flow problems and dust during charging. Powder dry flow is measured by funnel methods related to ASTM D1895, although published dry-flow values for this specific grade may not be included in every material-data sheet. Moisture uptake above approximately 0.10 wt% can also impair dry flow and create bubbles during heating. If the powder is exposed to relative humidity above 60%, pre-drying at 70 °C to 80 °C for 2 h to 4 h is a conservative start point before charging the mould.

    The grade is intended for use on shuttle, carousel, and rock-and-roll machines. On conventional biaxial machines, the primary-to-secondary rotation ratio is typically set near 4:1, but the optimum depends on part geometry, mould offset, and oven air distribution. Aluminium moulds with 6 mm to 10 mm wall thickness provide better heat transfer than stainless steel tools, although cast aluminium surfaces may require periodic release-agent conditioning to prevent build-up of degraded pigment or oxidized polymer. Because the red pigment can alter the heat absorption characteristics of the moulded layer, the first production trials on a new tool should record mould surface temperature and internal air temperature continuously rather than relying only on oven dwell time.

    Oven Air Temperature, Internal Air Curves, and the Risk of Overcure in Pigmented LLDPE

    For linear low density polyethylene rotational moulding, the peak internal air temperature inside the mould is a more useful control parameter than oven air temperature alone. The target peak internal air temperature for this grade generally lies in the 200 °C to 220 °C range. Oven air setpoints between 260 °C and 300 °C are common start points, but the required dwell depends on part wall thickness, tool thermal mass, and oven airflow. If the internal air temperature is driven above 230 °C, the risk of antioxidant depletion, pigment degradation, and red colour shift increases, especially in thick sections where heat history is longer. Conversely, failure to reach approximately 200 °C can leave partially fused powder, visible pinholes, or low impact strength at the inner surface.

    Parameter Start-point range Measurement or instrumentation
    Peak internal air temperature 200 °C–220 °C thermocouple through mould vent
    Oven air setpoint 260 °C–300 °C oven air thermocouple
    Typical biaxial rotation ratio 4:1 machine speed setting
    Moisture limit before moulding <0.10 wt% Karl Fischer or loss-on-drying
    Cooling before demoulding forced air to 70 °C–80 °C infrared pyrometer

    Cooling after the oven cycle affects part shrinkage, warpage, and impact properties. Slow cooling raises crystallinity and can increase modulus while lowering low-temperature impact, whereas very rapid quenching can reduce warpage but may introduce uneven shrinkage between thick and thin sections. For red-pigmented LLDPE, forced-air cooling is typically started after the melt has coalesced and the internal air temperature is below the crystallization onset by about 10 °C to 15 °C. Demoulding while the part remains above 80 °C can increase distortion, particularly on large flat surfaces. The exact cooling curve should be established by differential scanning calorimetry of the moulded part at 10 K/min under ISO 11357-3 to identify crystallization peak temperature for that specific pigmented formulation.

    Compared with natural or unpigmented rotomoulding powder, the red pigment can increase the surface temperature of the powder layer during oven residence because the colour alters absorptivity in the visible and near-infrared regions. The effect is less pronounced than with carbon-black compounds, but it can still shorten the time required to reach peak internal air temperature in thin-walled parts. Production lines transferring from natural to red-pigmented material should therefore monitor the internal air curve and reduce oven dwell if the peak internal air temperature is reached earlier than expected. This is not a defect indicator; it is a process adjustment required to maintain equivalent cure state.

    When Red 4338 Replaces Dry-Blended Colour Concentrate in a Rotational Moulding Line

    In dry-blend opera­tions, a colour concentrate is added at 1 wt% to 3 wt% to natural powder and mixed by tumble blender. Batch-to-batch colour consistency then depends on blender load size, mixing time, concentrate particle size, and the handling of the blend during transfer to the mould. Icorene 3545 RED 4338 removes that variable by pre-dispersing the red pigment and stabilizer package into the polymer. For production-scale manufacturing, this can reduce the in-house quality-control burden because the incoming lot is already compounded to a controlled colour and additive level. The trade-off is reduced flexibility in changing colour intensity, since the pigment concentration is fixed by the resin supplier.

    The following nominal property ranges are useful for comparison with other rotomoulding grades of similar density. These values are based on publicly available material-data summaries and should be confirmed against the current technical data sheet before design finalization.

    Property Standard method Unit Nominal value or range
    Density ISO 1183-1 g/cm³ 0.935–0.940
    Melt flow rate 190 °C/2.16 kg ISO 1133-1:2022 g/10 min 4.5–5.0
    Tensile yield strength ISO 527-2:2012 MPa 16–18
    Tensile elongation at break ISO 527-2:2012 % ≥800
    Flexural modulus ISO 178:2019 MPa 550–650
    Environmental stress-crack resistance ASTM D1693-15 h >1000

    Against high-density polyethylene rotomoulding grades, Icorene 3545 RED 4338 shows lower flexural modulus but improved environmental stress-crack resistance because the short-chain branches reduce the tight lamellar packing that makes HDPE more notch-sensitive in aggressive environments. Against high-pressure low density polyethylene homopolymer of similar melt flow rate, the linear low density structure generally raises tensile yield strength and stiffness while retaining high elongation. Against film-grade LLDPE, the product has a higher melt flow rate and is supplied in powder form, whereas film resins are pelletized and often contain slip or antiblock packages that are not appropriate for rotational moulding. Against natural Icorene 3545 grade, the red variant provides pre-compounded colour and UV stabilization, but its thermal and rheological profile is otherwise intended to remain within the same processing window.

    The product is used in rotational moulding of outdoor parts such as tanks, protective covers, agricultural reservoirs, and structural housings where uniform red colour and resistance to environmental stress-cracking are required. It is also specified where a dry-blend colour concentrate would be difficult to control on the production floor. However, the exact application performance depends on mould wall thickness, part design, and the local service environment. Published data for this specific red configuration are limited for aggressive fuels, strongly oxidizing agricultural chemicals, or potable water contact; chemical compatibility testing should therefore be performed on moulded specimens under the intended service temperature and exposure duration.

    Storage and handling boundaries for the powder should be observed. The material should be kept in a dry, shaded area below 40 °C, and opened containers should be resealed to prevent moisture pickup. Avoid combining the powder with incompatible additive masterbatches containing copper-based thermal stabilizers or amine-reactive chemistries, because interactions with phenolic stabilizers and the red pigment can produce colour shift or premature stabilizer consumption. For regulatory compliance, the base olefin polymer may be assessed under 21 CFR 177.1520(c), but the red colourant must be cleared under appropriate colourant provisions such as 21 CFR 178.3297 before a direct food-contact claim is made. REACH SVHC disclosure and RoHS 2011/65/EU Annex II confirmation are batch-specific and should be requested from the supplier when the moulded part is exported into regulated jurisdictions.

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