Lyondellbasell Icorene 3545 Red 4104 Polyethylene Linear Low Density

LyondellBasell Icorene 3545 RED 4104 Polyethylene, Linear Low Density

    • Product Name: LyondellBasell Icorene 3545 RED 4104 Polyethylene, Linear Low Density
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 575640
    Product Name LyondellBasell Icorene 3545 RED 4104 Polyethylene, Linear Low Density
    Polymer Type Linear Low Density Polyethylene (LLDPE)
    Color Red
    Form Powder
    Processing Method Rotational Molding
    Density 0.935 g/cm³
    Melt Index 4.5 g/10 min (190°C/2.16 kg)
    Tensile Strength At Yield 13.8 MPa
    Tensile Strength At Break 17.2 MPa
    Elongation At Break 700%
    Flexural Modulus 552 MPa
    Hardness Shore D 55
    Vicat Softening Point 118°C
    Brittleness Temperature < -60°C
    Environmental Stress Crack Resistance > 1000 hr
    Uv Stabilizer Yes

    As an accredited LyondellBasell Icorene 3545 RED 4104 Polyethylene, Linear Low Density factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing LyondellBasell Icorene 3545 RED 4104 Polyethylene, Linear Low Density is supplied in 25 kg moisture-resistant bags, 40 bags per shrink-wrapped pallet.
    Container Loading (20′ FCL) 20′ FCL container loading for LyondellBasell Icorene 3545 RED 4104 Polyethylene, Linear Low Density; palletized 25 kg bags, properly secured.
    Shipping LyondellBasell Icorene 3545 RED 4104 Polyethylene, Linear Low Density is not classified as dangerous goods for transport. It is shipped as a non-hazardous solid polymer in bags, boxes, or bulk containers. No UN number, hazard class, packing group, or marine pollutant designation applies. Store dry, away from ignition sources.
    Storage Store in a cool, dry, well-ventilated area in closed original packaging. Keep off the floor on pallets, away from direct sunlight, heat, flames, ignition sources, and strong oxidizers. Protect from moisture, dust, and contamination. Avoid excessive stacking or bag damage. Use first-in, first-out rotation and follow the manufacturer’s SDS and local regulations.
    Shelf Life Typically 24 months from manufacture when stored in original packaging, cool, dry, away from direct sunlight and heat.
    Application of LyondellBasell Icorene 3545 RED 4104 Polyethylene, Linear Low Density

    Manufacture of cylindrical and rectangular storage tanks from LyondellBasell Icorene 3545 RED 4104 begins by charging the pre-pigmented powder directly from the original packaging. The material is a linear low density polyethylene with nominal density of 0.935 g/cm³ and melt flow rate of 3.5 g/10 min at 190°C/2.16 kg under ISO 1133-1:2022; the RED 4104 designation indicates that the colourant is incorporated at resin production stage rather than as a separate drum-tumbled masterbatch. Industry compliance for static storage vessels in agricultural and light industrial service is anchored to ASTM D1998-21 for upright polyethylene tanks; where the moulded body is used as an intermediate bulk container for regulated liquids, qualification proceeds under UN type 31H1 within the applicable dangerous goods transport regime. The formulation addition ratio for the shell layer is 100% virgin Icorene 3545 RED 4104; clean, non-crosslinked spatter and trimmed flash can be returned to the charge at 15–25% by shot mass, but additions above 25% are not recommended where low-temperature Charpy impact retention is specified to ISO 179-1/1eA because particle packing and antioxidant depletion in the recycled fraction shift impact response. The downstream production line for a 5,000 L vertical tank uses a shuttle-type rotational moulding machine with a major-to-minor arm ratio of 4:1; oven set point is 280–300°C, and peak internal air temperature is maintained at 210–225°C for 18–24 min depending on target wall thickness of 4–6 mm. The red pigment raises radiant heat uptake relative to natural LLDPE; peak internal air temperature overshoot above 235°C produces surface oxidation and reduces environmental stress-crack resistance when the tank subsequently holds ethoxylated surfactant formulations. When powder is stored in unheated warehouses at relative humidity above 60%, surface moisture can generate pinholes; the powder is therefore conditioned with dry air at 40°C until powder temperature exceeds dew point by at least 5°C before charging. Terminal product types include vertical static tanks from 500 L to 10,000 L, bunded pallet tanks, horizontal transport tanks, and rotationally moulded agitation sumps.

    ParameterControl rangeReference method
    Nominal density0.935 g/cm³ISO 1183-1:2019
    Melt flow rate3.5 g/10 min at 190°C/2.16 kgISO 1133-1:2022
    Oven set point280–300°Cplant thermal profile
    Peak internal air temperature210–225°Cshielded thermocouple
    Rotation ratio4:1 major/minormachine calibration
    Cooling rate0.5–1.5°C/min to 90°Ccooling station profile
    Regrind addition15–25% by shot massin-house impact retention to ISO 179-1/1eA

    What happens to low-temperature impact retention in saltwater-loaded rotomoulded buoy shells?

    For marine navigation buoy shells, the outer wall is processed as a single-shot skin of 5–7 mm thickness and then filled with a two-component polyurethane foam core at 40–60 kg/m³ free-rise density. The formulation addition ratio is 90–100% virgin Icorene 3545 RED 4104; clean post-industrial regrind from the same red product may be included up to 10%, but higher regrind levels reduce UV-stabiliser concentration and can shift surface Delta E beyond 1.5 against the customer’s chromaticity reference. Industry compliance in this segment is set by project specification rather than a single marine product standard; acceptance criteria typically combine ISO 179-1/1eU Charpy impact at -30°C, minimum tensile elongation of 400% under ISO 527-2, and 500 h xenon-arc exposure under ASTM D2565 with colour difference determined to ASTM D2244. In production, the shell is rotationally moulded at an oven set point of 270–290°C and a peak internal air temperature of 215–230°C; the mould rotates at 8 rpm on the primary axis and 2 rpm on the secondary axis for a 4:1 ratio. After the shell cools to 45°C, the polyurethane foam is injected through a sealed bung; filling before the wall reaches 45°C collapses foam cells at the interface and can increase water absorption above the 1% by volume criterion commonly specified for closed-cell buoyancy foam. Terminal product types include navigation marker buoys, mooring buoys, floating fender shells, and modular pontoon floats.

    When a rotomoulded playground component must satisfy migration limits without post-moulding painting, the pre-coloured RED 4104 grade allows the moulding plant to eliminate solvent-borne topcoats and the associated volatile organic compound handling. Icorene 3545 RED 4104 is charged at 100% virgin for the outer play-contact surface; closed-loop regrind from the same red part can be included at 10–20% only after batch-level migration testing, because airborne contamination from other production lines or mixed-colour scrap can change elemental release values. The industry compliance framework for this segment includes EN 71-3:2019+A1:2021 for migration of certain elements, ASTM F963-23 for play components supplied into North America, and EN 1176-1:2017 for structural integrity of equipment installed in public playgrounds. The downstream production process uses a biaxial rotational moulding machine with an oven set point of 270–290°C, peak internal air temperature of 215–225°C, and wall thickness of 4–6 mm; aluminium moulds are preferred over cast-steel moulds to reduce surface defects that would require abrasive repair. Cooling is conducted in forced-air stations at 0.5–1.0°C/min until the part core temperature falls below 80°C, because rapid water mist cooling on red LLDPE can induce differential shrinkage and visible surface haze. Terminal product types include toddler slide canopies, climbing panels, activity panels, spring rider bodies, and modular play house shells.

    When high-visibility red is required on aggregate process bins

    Colour-coded dry bulk handling bins used in mineral processing and construction waste segregation are rotationally moulded from Icorene 3545 RED 4104 with a minimum virgin wall fraction of 85%; the remaining 15% is restricted to closed-loop regrind from the same colour and product family, because regrind from other shades shifts the final part outside the site safety colour tolerance and creates streak lines at weld unions. Industry compliance for these bins references ISO 8611-1:2019 where the bin body is integrated with a pallet base, and ASTM D638-14 tensile testing across the sidewall-to-lifting-lug weld line is used to confirm load-bearing integrity. The downstream production line for open-faced bins uses a rock-and-roll rotational moulding machine, while closed hoppers run on a biaxial machine; oven set point is 260–285°C, cycle time is 25–35 min, and wall thickness varies from 6 mm on the sidewall to 10 mm at the load-bearing rim. If a steel armature is inserted for forklift contact, the armature is preheated to 120°C before charging to reduce stress cracking around the insert. Terminal product types include 1,000–3,000 L aggregate hoppers, colour-coded waste segregation skips, and forklift-mounted process bins.

    Below-ground cable pits and meter enclosures

    In below-ground utility enclosure production, the primary process variable is post-moulding shrinkage at the moulded-in rib intersections. Icorene 3545 RED 4104 is processed at 100% virgin for the load-bearing top cover, while the base may contain up to 15% clean regrind from the same red enclosure; the regrind addition is excluded from the cover because of the potential for reduced flexural stiffness in the trafficable surface. Industry compliance for this segment follows ANSI/SCTE 77-2017 tier load ratings where the product is specified for trafficked areas, and ISO 178 flexural modulus testing is used to verify rib stiffness after long-term ground load. The downstream production process uses a biaxial rotational moulding machine with a shot size of 15–30 kg, an oven set point of 280–300°C, and a wall thickness of 6–8 mm; after demoulding, the enclosure is placed on a flat cooling fixture for 24 h before lid machining to stabilise dimensions. The red pigmentation provides high visibility when covers are opened for maintenance of buried electrical infrastructure; however, the material is not suitable for continuous service above 50°C or direct contact with aromatic hydrocarbons. Published data for this specific coloured grade under ANSI/SCTE 77 tier testing is limited, so third-party qualification is required for each tooled geometry. Terminal product types include underground cable pits, irrigation valve boxes, meter enclosures, and trafficable equipment enclosures.

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    Certification & Compliance
    More Introduction

    LyondellBasell Icorene 3545 RED 4104 Polyethylene, Linear Low Density is a rotational-moulding powder based on a linear low-density ethylene copolymer. The grade is supplied as a free-flowing, red-pigmented powder in which the numeric suffix 4104 identifies a specific colour formulation rather than a natural resin parameter. For batch-specific properties, the supplier certificate of analysis should be consulted; the following values are typical of the product class and are not to be treated as specification limits.

    PropertyTypical valueTest method
    Density at 23 °C0.934–0.936 g/cm³ISO 1183-1:2019
    Melt flow rate at 190 °C / 2.16 kg4.5 g/10 minISO 1133-1:2022
    Tensile yield stress14–16 MPaISO 527-2:2012
    Elongation at break>800 %ISO 527-2:2012
    Flexural modulus, 1 % secant380–450 MPaISO 178:2019
    Vicat softening temperature, A50108–112 °CISO 306:2022
    Brittleness temperature< -70 °CASTM D746-20
    Environmental stress crack resistance, 100 % Igepal>500 hASTM D1693-21

    Does the 4.5 g/10 min melt flow rate constrain sintering kinetics or bubble dissolution?

    At a nominal melt flow rate of 4.5 g/10 min under ISO 1133-1:2022, this LLDPE lies near the upper flow limit for many rotational-moulding applications. The lower zero-shear viscosity accelerates particle coalescence at peak internal air temperature, but bubble dissolution does not scale linearly with melt flow rate. In thick sections above 6–8 mm, gas diffusion to the free surface becomes rate-limiting; therefore higher melt fluidity alone does not eliminate porosity. On carousel-type machines using cast-aluminium or steel tools in the 0.5–1.0 m³ range, peak internal air temperature is typically held between 200 °C and 210 °C for this density class. Extended exposure above 220 °C for more than 8 min can induce oxidative degradation and may shift the red chromophore toward lower chroma. Cooling rate must also be controlled: water-spray quench should not begin until the melt temperature has fallen below 100 °C, otherwise differential shrinkage and pigment crazing can develop at sharp mold radii. Published data for this specific RED 4104 configuration is limited, and process validation on the intended tool geometry is required.

    The powder is intended for single-layer and multi-layer hollow parts produced by rotational moulding. Particle-size distribution and dry-flow behaviour should be verified against ISO 4610:2001 or ASTM D1921-20. Free-flowing powders with a nominal 35-mesh (500 µm) top cut and a median particle size near 250 µm provide uniform wall thickness in thin ribs and threaded bosses. High-speed mechanical blending above 400 min⁻¹ can fracture LLDPE powder and increase fines below 125 µm, causing bridging in drop hoppers and pinholes at the inner mold surface. A low-intensity paddle mixer or direct use of the precompounded red powder is therefore preferred for multi-cavity tools with narrow filling channels.

    When the 4104 red pigment is transferred through ungrounded stainless-steel conveying lines

    Electrostatic charging may alter powder flow and pigment distribution. The red-pigmented powder can accumulate surface charge during high-velocity pneumatic transfer, particularly at velocities above 20 m/s and relative humidity below 30 %. Grounding of transfer lines, hoppers, and mold surfaces is recommended to prevent segregation of the pigment fraction and to reduce dust adhesion. The effect is more pronounced with dry-blended colour systems than with fully compounded powders; users should determine from the supplier whether RED 4104 is melt-compounded into the polymer or supplied as a dry-blend. If the pigment is not fully compounded, low-intensity tumble blending for 10–15 min is usually sufficient to achieve visual uniformity, but extended blending can increase fines and static charge. Independent pigment migration data should be requested when the moulded article contacts fatty food simulants, because the red colour formulation may contain organic or inorganic pigments with migration behaviour different from the base LLDPE.

    Pigment dispersion and weathering retention in red 4104 rotational moulding powders

    The weathering performance of red-pigmented LLDPE depends on both the stabilizer package and the pigment chemistry. Inorganic red pigments generally provide better opacity and lower migration than soluble organic red pigments, but they can raise density and reduce low-temperature impact at high loading. The public datasheet for Icorene 3545 RED 4104 does not always disclose the full pigment composition; therefore exterior automotive or recreational parts should be qualified by accelerated weathering on moulded plaques under ISO 4892-2:2013 or ASTM D2565-23. Pigment agglomeration can occur if the powder is stored above 60 % relative humidity or below 5 °C, producing visible specks in thin-wall sections. Drying is not normally required for rotational moulding of LLDPE, but high humidity storage can introduce surface moisture that slows particle coalescence and increases bubble retention.

    Mechanical performance in the moulded article is governed by the balance between density, comonomer content, and molecular weight distribution. Compared with a conventional LDPE rotational-moulding powder of density 0.918–0.925 g/cm³, Icorene 3545 RED 4104 at 0.934–0.936 g/cm³ provides higher flexural modulus and improved stress crack resistance, while retaining sufficient low-temperature impact for agricultural tanks and automotive ducting. Compared with a high-density polyethylene rotomoulding grade of density above 0.940 g/cm³, the grade offers lower stiffness but substantially better resistance to brittle fracture at sub-zero temperatures. The medium melt flow rate also distinguishes it from lower-flow LLDPE grades of 2.5–3.5 g/10 min, which may require longer oven residence but can give lower bubble retention in very thick walls.

    Thermal degradation pathways in red-pigmented LLDPE during extended oven residence

    The oxidative degradation of linear low-density polyethylene is initiated at weak C–H bonds adjacent to branch points, forming hydroperoxides that decompose to alkoxy and hydroxyl radicals. The red pigment can act as either a radical scavenger or a pro-oxidant depending on the chromophore class, metal content, and particle surface treatment. Therefore, regrind recycling must be limited and monitored. A drop in oxidative induction time below 10 min at 210 °C under ISO 11357-6:2018 indicates that the stabilizer package is depleted and that recirculated powder will produce surface discolouration or internal porosity. In production, regrind levels above 20 wt% are generally not recommended without re-stabilization, because the moulded part may fail low-temperature impact tests such as ASTM D746-20 or ISO 974:2000. Users of red-pigmented powders should also avoid combining the material with amine-based antistatic additives, because amine chemistry can react with certain red organic pigments and cause premature colour shift.

    Grade classDensity rangeMelt flow rate at 190 °C / 2.16 kgTypical flexural modulusDifferentiating behaviour in rotational moulding
    Conventional LDPE0.918–0.925 g/cm³2.0–5.0 g/10 min200–350 MPaLower stiffness; easier processing; higher permeability
    Icorene 3545 RED 4104 LLDPE0.934–0.936 g/cm³4.5 g/10 min380–450 MPaHigher stiffness and ESCR; moderate bubble retention in thick sections
    HDPE rotomoulding0.940–0.955 g/cm³3.0–8.0 g/10 min700–1100 MPaHigher stiffness; lower low-temperature impact; greater warpage tendency

    Regulatory qualification for coloured LLDPE rotomoulding powders requires separate evaluation of the base olefin polymer and the pigment formulation. The base LLDPE may be covered by FDA 21 CFR 177.1520 and Commission Regulation (EU) No 10/2011, but the RED 4104 pigment must be independently assessed under 21 CFR 178.3297 or the applicable national colorant provisions. For food-contact articles, specific migration testing with fatty food simulant D1 or D2 under EN 1186-1:2002 is required when the contact ratio exceeds 1 dm²/kg. Users should not assume that clearance of the unpigmented base resin extends to the finished red article. For industrial applications, compliance with REACH and RoHS should be confirmed through the supplier’s regulatory data sheet, particularly because red pigments may contain trace metals that are restricted in electrical and electronic equipment.

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