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LyondellBasell Hiloy SAN 249

    • Product Name: LyondellBasell Hiloy SAN 249
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    VTB
    Specifications
    HS Code 167478
    Density 1.08 g/cm³
    Melt Flow Rate 4.0 g/10 min
    Tensile Strength At Yield 72 MPa
    Tensile Elongation At Yield 2.5%
    Flexural Modulus 3.5 GPa
    Flexural Strength 110 MPa
    Notched Izod Impact Strength 2.0 kJ/m²
    Deflection Temperature Under Load At 1 8 Mpa 95°C
    Vicat Softening Temperature 108°C
    Rockwell Hardness M83
    Light Transmission 88%
    Haze 2%
    Refractive Index 1.57
    Water Absorption 0.2%
    Mold Shrinkage 0.4-0.7%
    Ul94 Flame Rating HB

    As an accredited LyondellBasell Hiloy SAN 249 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing LyondellBasell Hiloy SAN 249 is supplied in 25 kg moisture-resistant bags, palletized for safe industrial handling and storage.
    Container Loading (20′ FCL) 20′ FCL container loading of LyondellBasell Hiloy SAN 249: palletized, dry, securely stowed and braced for safe ocean transport.
    Shipping LyondellBasell Hiloy SAN 249 is typically shipped as thermoplastic resin pellets in 25 kg moisture-barrier bags, octabins, or bulk containers/trucks. Protect from moisture, contamination, heat, and direct sunlight. It is generally not regulated for transport; verify current SDS and local shipping regulations.
    Storage Store LyondellBasell Hiloy SAN 249 in a cool, dry, well-ventilated area away from direct sunlight, heat, flames, and strong oxidizers. Keep original containers sealed and palletized, protecting contents from moisture, dust, and physical damage. Avoid excessive stacking, prevent static buildup, and follow the supplier’s SDS and local regulations for safe handling and storage.
    Shelf Life Store in a cool, dry, well-ventilated area; typical shelf life is two years from date of manufacture in unopened original packaging.
    Application of LyondellBasell Hiloy SAN 249

    On a 1,300 kN hydraulic injection press running a 4-cavity HVAC louver mold with 1.2 mm nominal wall sections, the 20 wt% short-glass reinforcement in LyondellBasell Hiloy SAN 249 reduces linear mold shrinkage to 0.2–0.4% when checked according to ISO 294-4:2018, but only when the mold temperature is held at 50 °C to 65 °C and packing pressure is maintained at 55 MPa to 70 MPa for 4 s to 6 s after fill. Batch audits over 24 h on a 40 mm three-zone screw with 20:1 L/D have shown that progressive screw wear above 0.15 mm radial clearance increases fiber length attrition, and the resulting drop in notched Charpy impact under ISO 179-1/1eA:2006 appears as micro-cracking around louver rib bases after repeated actuation on a ventilation load rig. This failure mode is controlled by measuring melt cushion at 3–5 mm and by replacing the screw and barrel when chrome plating in the feed section becomes visibly degraded.

    For this segment, compliance is anchored to ISO 3795:1989 and FMVSS 302 for horizontal burn rate; VOC and fogging are screened against VDA 278:2011, with desorption GC-MS aromatics sums held below 100 µg/g for laminar-flow dashboard air outlet parts. Floor feeding is arranged on gravimetric blenders with 90 wt% virgin material, 10 wt% in-plant regrind limited to sprues and runners from the same grade, 1.5 wt% to 2.0 wt% black or interior-color masterbatch, and 0.5 wt% processing stabilizer masterbatch when reclaim residence history exceeds 2 h in hot-air drying. Drying uses a desiccant dryer with -40 °C dew point at 80 °C for 4 h; target residual moisture before plastication is <0.02 wt%. Melt temperature measured at the nozzle is held at 230 °C to 245 °C for louvers and 245 °C to 255 °C for high-gloss instrument cluster shrouds; residence time above 5 min at 255 °C is avoided because the SAN matrix begins to release cyclic and linear oligomers that deposit on mold vents and increase cleaning frequency. Terminal products include HVAC vent louver vanes, center stack air deflectors, instrument cluster hoods, and steering column upper shrouds.

    What Limits Dimensional Stability in Appliance Control Housings Molded from 20% Glass-Reinforced SAN?

    Because appliance control panel frames and washing machine control housings require post-mold flatness within 0.3 mm over a 250 mm datum length, the practical limitation becomes anisotropic post-mold shrinkage caused by glass-fiber orientation around circular display apertures; this tolerance is measured after 48 h conditioning at 23 °C and 50% RH under ISO 291:2008. In a two-drop hot-runner tool with valve gates set 22 mm from the aperture edge, measured shrinkage parallel and perpendicular to flow differs by 0.15–0.25 percentage points, producing local concavity that exceeds the flatness zone. To reduce this, processing uses a sequential valve-gate program that opens the outer gates 0.8 s before the inner gates, melt temperature 240 °C at the nozzle, mold temperature 60 °C, and packing pressure 65 MPa to 75 MPa for 8 s until gate seal. Screw retraction distance is controlled within 2 mm to limit cushion instability and short-shot fluctuation during automatic start-up after alarms.

    Compliance for this segment is defined by IEC 60335-1:2010/AMD2:2016 for unattended appliance housings, IEC 60695-2-11:2021 glow-wire flammability, UL 94 HB thickness-rated data at 1.5 mm, RoHS Directive 2011/65/EU Annex II substance restrictions, and REACH (EC) No 1907/2006 SVHC candidate list screening. The dry-blend addition ratio on the floor is 88 wt% virgin Hiloy SAN 249, 10 wt% closed-loop regrind from rejected control frames, and 2 wt% appliance-grade masterbatch in a SAN carrier; regrind fraction above 15 wt% is not permitted because fiber length reduction shifts tensile modulus under ISO 527-2:2012 by more than 5% and reduces weld-line elongation to break below 1.0%. Finished articles include front control panel frames, display bezels, rotary selector brackets, and rear structural carriers for free-standing washing machines and dishwashers.

    Electrical Terminal Support and Enclosure Components: IEC 60695-2-11 Glow-Wire Performance and Processing Constraints

    In low-voltage electrical support parts, where the material is not current-carrying, the selection logic shifts from tracking resistance to dimensional stability for contact spacing and insert retention; creepage and clearance dimensions under IEC 60664-1:2020 are maintained through tooling, while material batch consistency is monitored with ISO 178:2019 flexural modulus and ISO 75-2:2013 heat deflection temperature at 1.82 MPa. DIN rail mount bases and relay socket housings molded from 20 wt% glass-reinforced SAN are processed on 800 kN to 1,200 kN injection presses with shut-off nozzles because low-shear flow at 240 °C to 250 °C can otherwise produce stringing during sprue break.

    StandardTestConditionAcceptance target
    IEC 60695-2-11:2021Glow-wire flammability650 °C, 1.5 mmNo ignition or flame ≤ 30 s
    IEC 60112:2009Tracking indexSolution AReported value used for creepage calculation
    ISO 178:2019Flexural modulus23 °C, 2 mm/minWithin ±5% of grade nominal
    IEC 60068-2-30:2005Damp heat cyclic25 °C/55 °C, 95% RHNo surface blistering after 2 cycles

    Feeding ratio for electrical support components is 92 wt% virgin material, 5 wt% black masterbatch, and 3 wt% reprocessed sprue/runner only; external post-industrial recyclate is excluded because inconsistent metal contamination can raise conductivity and interfere with IEC 60112 tracking measurements. Insert molding of brass terminal posts requires preheating inserts to 80 °C to 100 °C in an infrared tunnel; the mold cavity is fitted with pressure transducers to switch from velocity control to pressure control at 95% of fill, and perimeter vents are depth-relieved to 0.02 mm to avoid polymer staining at the vent land. Terminal products include DIN rail mount bases, relay socket housings, terminal block shells, and meter enclosure brackets.

    Insert-molded stand mixer gear housings with sintered bronze bearing seats expose the styrene-acrylonitrile matrix to localized hoop stresses during cooling because the linear thermal expansion coefficient of the metal insert is approximately 10 × 10⁻⁶ K⁻¹ lower than that of the filled polymer; on a 1,600 kN molding cell, the failure mode is not bulk fracture but micro-voiding at the insert interface when the mold is released below 60 °C. Post-mold thermal shock testing of assembled gear platforms under IEC 60335-1:2010/AMD2:2016 mechanical strength requirements has shown that preheating the bronze inserts to 90 °C before insertion and holding the mold at 65 °C during packing reduces void formation by the time the component reaches 23 °C ambient. Where sprue pulls and textured ejection surfaces must be combined, draft angles below 0.5° have produced multiple ejection failures on production cells unless an internal mold release masterbatch is added.

    The dry-blend ratio for this segment is 86 wt% virgin Hiloy SAN 249, 8 wt% in-house regrind from gear housings with insertion failures, 4 wt% color masterbatch, and 2 wt% internal mold release masterbatch; regrind is limited to parts that have not undergone oil contamination in machining cells. Processing uses a 40 mm three-zone screw with 20:1 L/D and compression ratio 2.2:1; barrel zones are set to 210 °C, 230 °C, and 245 °C, nozzle at 250 °C, injection speed profiled from 60 mm/s in the insert region to 100 mm/s in the thin-wall rim to avoid insert displacement, hold pressure 70 MPa for 5 s, and cushion 3–5 mm. Compliance rests on REACH (EC) No 1907/2006 and RoHS Directive 2011/65/EU; no direct food-contact claim is supported unless migration testing under EU 10/2011 is completed on the finished colored article. Terminal product types include stand mixer lower gear housings, food processor bowl carrier rings, and small appliance motor mount flanges.

    When Structural Brackets Must Pass BIFMA X5.1-2017 Fatigue Cycles Without Creep Rupture

    When office chair armrest support brackets are loaded in cyclic cantilever bending under ANSI/BIFMA X5.1-2017 seating durability and structural strength protocols, the design constraint shifts from static tensile strength to creep rupture resistance at the gate weld line. Production-scale static load application on a 500 N test frame has shown that replacing a single central sprue gate with two side-edge gates changes fiber orientation from transverse to longitudinal along the primary stress direction, increasing load retention after 40,000 cycles by a measurable margin under the same BIFMA protocol. Rib thickness is limited to 60–70% of the nominal wall to avoid sink marks on visible light-gray surfaces. Formula addition for this segment is 90 wt% virgin material and 10 wt% in-plant reclaim, with 1.5 wt% UV-stabilized color masterbatch for exposed covers. Processing uses melt temperatures of 240 °C to 250 °C, mold temperatures of 55 °C to 65 °C, and screw back pressure 0.35 MPa to preserve glass-fiber length during plastication. Compliance includes ANSI/BIFMA X5.1-2017, ISO 4892-2:2013 method A cycle 1 for accelerated weathering of office furniture surfaces, and REACH (EC) No 1907/2006 SVHC screening. Terminal products are armrest support brackets, lumbar mechanical frames, and under-seat side covers. Published multi-run data for this exact viscosity grade under full-chair fatigue loading is limited; therefore homologation includes part-level cycle testing on finished assemblies before batch release.

    Chrome Adhesion in Sanitary Accessory Components Remains Dependent on Acid Etch Control

    For chrome-plated towel rail end caps and shower head brackets, the 20 wt% glass reinforcement in Hiloy SAN 249 creates a surface-etch sensitivity that is not present in unfilled ABS plating grades. The etch must remove 0.8 µm to 1.2 µm of surface polymer without exposing glass fibers longer than 15 µm, because protruding fibers act as local current density concentrators during copper deposition and produce pits visible after bright nickel. Plating line failures in production have been traced to mold release residuals exceeding 0.05 mg/dm², measured by gravimetric surface extraction before etch; dry air demolding is therefore preferred over external release sprays. Compounding ratio is 95 wt% virgin Hiloy SAN 249 with 5 wt% white or black masterbatch; regrind is excluded from visible plated surfaces because even 5 wt% regrind adds fiber fragments that alter surface topography after etch. Injection molding uses a mold temperature of 50 °C to 60 °C; high-gloss mold surfaces are polished to #600 grit diamond paste and vents are limited to 0.01 mm depth to minimize fiber bloom. Etching is performed in commercial chromic acid-sulfuric acid baths at 60 °C for 6 min to 8 min, followed by electroless nickel strike and standard Cu/Ni/Cr electroplating. Compliance is bounded by ASTM B571-18 for coating adhesion verification, ISO 9227:2022 neutral salt spray for corrosion resistance, REACH (EC) No 1907/2006, and RoHS Directive 2011/65/EU. Terminal products include towel rail end caps, shower head mounting brackets, soap dish frames, and lavatory faucet trim substrates for non-potable decorative application.

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    Certification & Compliance
    More Introduction

    LyondellBasell Hiloy SAN 249 is a styrene-acrylonitrile copolymer grade positioned in the Hiloy product range for injection-moulded technical components that require transparency, rigidity, dimensional stability and resistance to aliphatic hydrocarbons, fats and oils. The numerical suffix 249 identifies a specific commercial material within the Hiloy SAN series; it is not a direct substitute for another SAN grade unless melt volume-flow rate, tensile modulus, Vicat softening temperature and mould shrinkage are matched against the current manufacturer technical data sheet.

    The specification package for incoming inspection should include melt volume-flow rate to ISO 1133-1:2022, tensile stress and tensile modulus to ISO 527-2 or ASTM D638-14, flexural data to ISO 178, notched impact strength to ISO 179-1 or ISO 180, Vicat softening temperature to ISO 306, heat deflection temperature to ISO 75-2, density to ISO 1183, and light transmission to ISO 13468-1. Mould shrinkage is determined by ISO 294-4.

    Commercial SAN copolymers generally contain acrylonitrile in the range 24–28 wt%. The polar nitrile group raises the glass transition, melt viscosity and solvent resistance relative to polystyrene; most SAN grades exhibit a glass transition between 105 °C and 110 °C. Grade-specific comonomer content is usually not disclosed because it belongs to the formulation and is covered by the manufacturer’s product identity.

    Injection moulding of this product requires a desiccant dryer. Moisture content above 0.1% by weight produces silver streaks and splay. Drying at 80 °C for 2–4 h to a supply-air dew point of −30 °C or lower is the standard industrial procedure. Bags stored at relative humidity above 60% for longer than 24 h should be re-dried before entering the hopper.

    What melt-temperature boundaries prevent yellowing and dimensional instability?

    Melt temperature at the nozzle is normally started between 220 °C and 250 °C for unfilled SAN. At temperatures above 260 °C, residence time should not exceed 5 min; thermal degradation of the acrylonitrile segment causes yellowing and surface defects. If the shot size is less than 20% of the machine barrel capacity, the temperature profile should be reduced because the material remains at melt temperature for an extended period.

    Mould temperature is typically set from 40 °C to 70 °C. A colder mould shortens cycle time but increases residual stress and reduces weld-line strength in transparent parts. A hotter mould improves surface replication and reduces flow marks but increases cooling time and cycle length.

    On production-scale equipment, screw design affects melt quality more than the set temperature. A general-purpose screw with an L/D of 18–22 and a compression zone of 4–7 D is adequate for this rigid copolymer. A high-shear screw is unnecessary and can raise melt temperature beyond the set point, intensifying gate blush and yellowing at the sprue.

    For mould-filling simulation, the material card should be based on measured capillary rheometry data. A Cross-WLF viscosity model can be fitted to viscosity shear-rate data measured over 100–10,000 s⁻¹. If the datasheet does not include viscosity curves, the moulding team should request the data from the supplier; simulation with generic polystyrene viscosity data under-predicts pressure drop for SAN because the acrylonitrile comonomer strengthens intermolecular interactions.

    The class-level property differences that govern substitution against GPPS, ABS and PMMA

    Class-level comparative ranges for unfilled injection-moulding grades; the product datasheet for LyondellBasell Hiloy SAN 249 governs all design values.
    Property Test method SAN GPPS Transparent ABS PMMA
    Tensile yield stress ISO 527-2 60–75 MPa 45–55 MPa 35–50 MPa 60–75 MPa
    Tensile modulus ISO 527-2 3.2–3.8 GPa 3.0–3.4 GPa 2.0–2.4 GPa 3.0–3.6 GPa
    Notched Charpy impact strength ISO 179-1/1eA 2–3 kJ/m² 1.5–2.5 kJ/m² 10–20 kJ/m² 2–3 kJ/m²
    Vicat softening temperature ISO 306/B50 100–110 °C 90–100 °C 95–105 °C 100–112 °C
    Light transmittance ISO 13468-1 88–90% 88–90% 85–88% 90–92%
    Mould shrinkage ISO 294-4 0.4–0.7% 0.4–0.7% 0.5–0.8% 0.4–0.8%

    The tabulated ranges show the main engineering difference: SAN is stiffer and more heat-resistant than GPPS, but its notched impact strength is much lower than that of transparent ABS. This occurs because SAN is a single-phase glassy copolymer, while ABS contains an elastomeric polybutadiene phase that absorbs impact energy.

    For application areas in which the part is repeatedly struck or dropped, Hiloy SAN 249 is not a direct substitute for transparent ABS. When the part must resist contact with alcohols, aliphatic hydrocarbons, detergents or cosmetic oils, SAN may outperform ABS because the polar acrylonitrile group reduces solvent swelling and environmental stress-cracking.

    Chemical resistance testing according to ISO 22088-3 or ASTM D543 indicates that SAN accepts aliphatic hydrocarbons, vegetable oils, alcohols and mild acids, but fails quickly in ketones, esters, chlorinated hydrocarbons, aromatic solvents and concentrated strong acids. This solvent profile defines the operational boundary: the material is suitable for hard transparent housings and cosmetic packaging, but not for fuel-system components or parts exposed to brake cleaner.

    When prolonged UV exposure is present, PMMA remains the lower-risk transparent material

    For external glazing or outdoor lenses, SAN can yellow and microcraze unless the specific grade is UV-stabilized. Published data for the stabilization package of this particular Hiloy SAN 249 grade is limited; therefore outdoor suitability should be confirmed by Xenon-arc ageing according to ISO 4892-2 on the finished part, with the acceptance criterion agreed before testing.

    Relative to PMMA, SAN typically gives lower optical clarity and lower scratch resistance but offers better melt flow in thin-wall sections and lower water absorption. The melt-viscosity difference is process-relevant: PMMA can require higher injection pressure and longer cooling time for the same wall thickness.

    In a direct comparison with transparent ABS, SAN generally has lower density, higher light transmission and better resistance to alcohol-based cleaners. Transparent ABS has higher notched impact strength and better low-temperature ductility. Material selection therefore often reduces to a single question: does the application require light transmission with chemical resistance, or impact survival at sub-zero temperatures?

    Weld lines and regrind ratios produce measurable property cliffs

    Weld-line strength in this type of material is low. In a multi-gate tool, weld lines may reduce local tensile strength by 30–50% compared with the bulk material. Design of optical housings should therefore avoid placing weld lines at screw bosses or snap-fit hooks unless destructive testing on moulded parts validates the design.

    Flow lines in transparent parts are caused by melt-front hesitation at thin ribs and ribs behind bosses. The remedy is not solely higher melt temperature; it requires local wall-thickness adjustments, gate relocation or gas counterpressure. Increasing melt temperature beyond 250 °C to remove flow lines usually degrades the surface and increases yellow index.

    Regrind addition in transparent parts should usually be limited to 0–10 wt% because granulation and re-drying raise yellow index and haze. For unstressed industrial components, regrind levels up to 20 wt% may be used after sieving fines below 2 mm. Glass-reinforced versions generate more brittle regrind and require lower maximum addition; published regrind data for this specific grade is limited.

    Hot-runner manifolds should be designed with externally heated channels and no dead spots. Internal heated torpedo systems can retain the melt at elevated temperature and produce yellow streaks in clear parts. Runner diameter below 6 mm may create excessive shear rates and degradation in medium-flow transparent grades.

    Vent depth for SAN is typically 0.02–0.04 mm; vents should be placed at the end of fill to prevent burn marks and short shots. Inadequate venting raises filling pressure and produces a visible burn mark at the last area to fill.

    Post-mould shrinkage is not complete at ejection; most additional shrinkage occurs within 24–48 h. Tight-tolerance parts should be measured after ageing at 23 °C and 50% RH for at least 24 h per ISO 291. If dimensions shift beyond tolerance, annealing at 10–20 °C below the Vicat softening point can relieve residual stress.

    Compliance, documentation and batch verification checks

    Compliance evidence and test responsibilities for the supplied resin and the finished article
    Requirement Standard or regulation Test responsibility
    REACH restriction and SVHC disclosure Regulation (EC) No 1907/2006 Resin supplier disclosure
    RoHS restricted substances in electrical and electronic equipment Directive 2011/65/EU Supplier declaration
    Food-contact migration of finished article EU Regulation (EC) No 10/2011 Converter or brand owner
    Cytotoxicity of medical device housing ISO 10993-5 Finished-device manufacturer
    Xenon-arc weathering for outdoor use ISO 4892-2 Brand owner or test laboratory

    Food-contact compliance is not established by the resin grade alone. The finished article must be tested under EU Regulation (EC) No 10/2011 for overall migration and specific migration of acrylonitrile; the applicable specific migration limit must be confirmed in the regulation or relevant national positive list. A resin supplier’s food-contact statement applies only to the resin as supplied, not to a pigmented or compounded article.

    For medical device housings, ISO 10993-5 and ISO 10993-10 testing is performed on the sterilised finished device. Biocompatibility depends on processing aids, colourants, surface texture and sterilisation method, so the resin producer cannot certify the final device.

    Incoming quality control should record melt volume-flow rate and density on each lot. A flow-rate deviation greater than ±10% from the established production target can change pressure drop and filling behaviour in thin-wall tools, especially in multi-cavity layouts with unbalanced runners.

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