| HS Code | 750421 |
| Product Name | LyondellBasell HDPE M5370PX |
| Polymer Type | High Density Polyethylene (HDPE) |
| Density | 0.953 g/cm³ |
| Melt Flow Rate 190 C 2 16 Kg | 0.35 g/10 min |
| Melt Flow Rate 190 C 21 6 Kg | 25 g/10 min |
| Tensile Modulus | 1100 MPa |
| Tensile Stress At Yield | 27 MPa |
| Tensile Strain At Yield | 9% |
| Tensile Stress At Break | 30 MPa |
| Tensile Strain At Break | >600% |
| Charpy Notched Impact Strength 23 C | 15 kJ/m² |
| Charpy Notched Impact Strength 30 C | 5 kJ/m² |
| Shore D Hardness | 63 |
| Vicat Softening Temperature | 125°C |
| Escr 10 Igepal F50 | 1000 h |
| Melting Temperature | 130°C |
As an accredited LyondellBasell HDPE M5370PX factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | LyondellBasell HDPE M5370PX is supplied in 25 kg polyethylene bags and 1,000 kg bulk bags for industrial handling. |
| Container Loading (20′ FCL) | 20′ FCL container loading for LyondellBasell HDPE M5370PX: palletized 25 kg bags, stretch-wrapped, floor-loaded, dry container, approximately 24–25 MT net. |
| Shipping | LyondellBasell HDPE M5370PX ships as a non-hazardous high-density polyethylene resin, typically in 25 kg bags, bulk bags, or bulk truck/rail hopper cars. Keep packaging dry and closed, away from heat, sunlight, and moisture. No special DOT, IMDG, or IATA hazard markings required. Consult SDS for safe handling. |
| Storage | Store LyondellBasell HDPE M5370PX in a cool, dry, well-ventilated area, away from direct sunlight, heat, flames, and strong oxidizers. Keep in original sealed packaging, palletized and off the floor, to prevent moisture and contamination. Avoid prolonged UV exposure. Maintain moderate temperatures and good housekeeping; pellets may create slipping hazards. Store separately from incompatible materials. Follow supplier SDS and local regulations. |
| Shelf Life | Typically two years when stored in original, unopened packaging under cool, dry conditions, protected from direct sunlight and moisture. |
For thin-wall dairy and deli packaging, LyondellBasell HDPE M5370PX is normally charged directly to the injection press feed throat. Pre-drying is rarely required in cold-weather transport or dry warehouse storage; when pellet surface moisture is suspected after extended outdoor storage at relative humidity above 60%, drying at 80°C for 2 h in a desiccant hopper dryer stabilises screw feeding. On accumulator-assisted hydraulic injection machines of 200–350 t clamp force, a barrel profile of 180°C, 200°C, 210°C, 215°C and nozzle 200°C yields a homogeneous melt. The grade belongs to the high-flow HDPE injection moulding class, with melt flow rate commonly reported in the 30–40 g/10 min band under ISO 1133-1 and density near 0.953 g/cm³ under ISO 1183-1. These values permit wall-thickness reductions to 0.38–0.50 mm in stack moulds, provided injection speed reaches 150–250 mm/s and hydraulic pressure at the screw tip remains between 1,200 bar and 1,400 bar. For opaque dairy tubs, PE-based white masterbatch is metered at 2.0–4.0 wt%; concentrate levels above 5.0 wt% can increase melt elasticity and produce valve-gate blush. Terminal articles include yoghurt cups, margarine tubs and delicatessen containers. Food-contact compliance depends on the finished article, not the resin alone; the base polymer is positioned for evaluation under FDA 21 CFR 177.1520(c)(2.1) and EU Regulation (EU) No 10/2011, with overall migration limits of 10 mg/dm² measured according to EN 1186-1. Regrind levels should be held at or below 30% by weight for dairy containers because higher post-industrial recycled content shifts low-temperature impact performance and narrows the melt-temperature window.
In high-cavitation closure moulds, injection-phase cavity pressure is monitored through piezoelectric transducers placed behind the valve-gate insert. When pressure at the end of fill exceeds 350 bar, the required clamp force on a 350-t press may become marginal, producing mould breathing, flash at the tamper-band undercut and part-mass drift of ±0.02 g or greater across cavities. HDPE M5370PX is processed for beverage closures at melt temperatures of 210–230°C, mould temperatures of 8–15°C and cycle times of 4.2–6.0 s, with injection pressure at the screw commonly 800–1,200 bar. Valve-gate diameters should remain at 0.8–1.2 mm to avoid gate-stringing while retaining adequate shear heating. Because the grade is not a gas barrier, carbonated soft-drink closure programmes use HDPE M5370PX as the shell, combined with EVA or PE/EVA induction liners or pre-formed gaskets; still-water and aseptic closures can be single-piece. Removal-torque stability after filling is evaluated according to ASTM D2063, seal integrity by vacuum bubble method under ASTM D3078, and bottle finish dimensions according to ISBT guidelines. Slip additive packages at 500–1,000 ppm erucamide reduce withdrawal torque, but high shear at the gate can exude slip agent and create cap-thread staining after 72 h ageing. Terminal parts include 28 mm and 30/25 mm tamper-evident beverage closures, dairy closures and hot-fill barrier shell applications where supported by closure liner technology.
| Standard or regulation | Scope | Relevant provision | Application boundary |
|---|---|---|---|
| FDA 21 CFR 177.1520 | Olefin polymers for food contact | Paragraph (c)(2.1) | Dairy cups, deli containers, closures |
| EU Regulation (EU) No 10/2011 | Plastic food contact materials | Annex I and II; overall migration 10 mg/dm² per EN 1186-1 | Food packaging in EU member states |
| ASTM D4976-12a | HDPE injection and extrusion materials | HDPE cell classification | Raw material specification for incoming resin |
| ISO 1133-1:2022 | Melt mass-flow rate | Method A, 190°C, 2.16 kg | Process capability monitoring |
| REACH 1907/2006/EC | Substances of very high concern | Article 33 communication; Annex XVII restrictions | Industrial and consumer packaging |
| ASTM D2063-09 | Closure torque retention | Application and removal torque measurement | Beverage and dairy closure functional release |
Threaded overcaps and dispenser collars for personal care and household chemical packaging are gated off-centre to move the gate vestige away from the top-load plane. HDPE M5370PX is processed here at melt temperature 190–210°C and mould temperature 10–15°C; the high melt flow reduces injection pressure to 600–900 bar in 16–32-cavity cold-runner tools. Gate diameter is typically 0.8–1.2 mm, and hold-pressure time is set by gate-seal determination rather than by total cycle time. The moulded collar is dimensionally stable enough for post-mould hot-stamp decoration or silk-screen registration, provided that mould shrinkage is measured according to ASTM D955-21 and matched to the decorator’s artwork film. Colour masterbatches with PE carriers are used at 1.0–3.0 wt%; additives that release volatile amines should be excluded from household-chemical overcaps because they can migrate into oxygen-sensitive formulations and alter cap torque. Stress-crack resistance is assessed with ASTM D1693 Condition A when the article is intended for bleach, surfactant or oxidiser exposure; thread roots and undercuts should be packed sufficiently to avoid moulded-in tensile stress, and no sharp transitions are permitted at the cap skirt junction. Terminal parts include overcap shells for deodorant sticks, hair-care jars, aerosol overcaps and detergent canister caps. In this application sector, weld-line strength is less sensitive than in beverage closures, but unequal filling in multi-cavity tools must be kept below 1.5% part-mass variation to maintain cap-to-bottle dimension fit.
Thin-wall pail moulds for water-based coatings, detergents and food ingredients use HDPE M5370PX to fill 1.0–1.2 mm sidewalls at flow-length-to-thickness ratios above 150:1. Injection machines are typically 450–650 t with melt temperature 180–210°C and mould temperature 10–20°C; holding pressure at cavity transducers is commonly 350–500 bar. Dropping sidewall thickness below 1.1 mm creates a top-load boundary: in stacked warehouse conditions, a filled 5-L pail at 40°C may fall below 450 N top-load capacity when tested per ISO 12048, so the rim geometry and lid undercut must be reinforced. Impact resistance is measured by drop testing per ISO 2248; for regulated chemical transport, drop height follows the packaging group and specific gravity logic of UN 6.1.5. The processing window is narrow at thin wall: injection speed should be 100–150 mm/s to balance flow length and gate appearance. The handle attachments and pail top ring are the most critical regions for cooling-time variation; differential shrinkage between the sidewall and ring increases distortion when demoulding before 8–10 s cooling. Published data for M5370PX in 1.0 mm stack-mould pail configurations is limited, so mould qualification should include short-shot series and top-load verification before production. Terminal parts include paint pails, detergent pails, re-closable ingredient pails and industrial tamper-evident containers.
| Application | Melt temperature range | Mould temperature range | Typical cycle time range | Key control variable |
|---|---|---|---|---|
| Dairy cups | 180–215°C | 8–12°C | 4–7 s | Injection speed |
| Beverage closures | 210–230°C | 8–15°C | 4.2–6.0 s | Valve-gate seal |
| Overcaps | 190–210°C | 10–15°C | 6–10 s | Part-mass spread |
| 5-L pails | 180–210°C | 10–20°C | 8–12 s | Top-load retention |
| Non-food crates | 190–220°C | 8–18°C | 18–35 s | PCR blend ratio |
| Housewares | 190–215°C | 8–15°C | 4–9 s | Shrinkage anisotropy |
Non-food crate, pallet and tote programmes frequently blend HDPE M5370PX with post-consumer HDPE or post-industrial regrind to maintain process consistency. Dry-blend additions of 15–30 wt% post-consumer HDPE are common; above 30 wt%, notched impact strength and melt-flow consistency decline unless the recycle fraction is compounded and screened. Tensile yield stress is measured according to ISO 527-2, flexural modulus according to ISO 178, and Charpy impact according to ISO 179-1. Polypropylene contamination above 3 wt% in the recycle stream causes visible delamination and should be rejected; unpigmented M5370PX natural pellets allow visual detection of carbonised wood or paper contamination. Screw configuration matters when dry-blend PCR is used: a barrier screw with 25:1 L/D and a mixing element reduces thermal stratification. Processing for crates uses melt temperature 190–220°C and mould temperature 8–18°C; holding pressure is set by weight-stabilisation curves rather than fixed values. The resulting parts are used for returnable logistics crates, automotive shipping trays, agricultural totes and material-handling boards. Because these are non-food uses, compliance shifts to the general chemical regulation of the article: REACH 1907/2006/EC Article 33 applies to SVHC communication, and Annex XVII restrictions govern specific substances. The operational boundary is that post-consumer HDPE from detergent or oil containers may carry absorbed hydrocarbons that volatilise during injection and cause plate-out on cavity surfaces, so ventilation and mould maintenance cycles are shortened.
With thin-wall housewares, moulders reduce wall thickness from 1.0 mm to 0.6 mm to cut resin mass by 35–40%; the grade’s melt flow rate permits the change, but cooling time does not scale linearly. For HDPE M5370PX at mould temperature 10–12°C, a 0.6 mm wall typically requires 4–6 s cooling, while a 1.0 mm wall may remain in the tool for 8–12 s; the relationship approximates a square-law dependence of cooling time on wall thickness. Dimensional stability is evaluated by ASTM D955-21; shrinkage in the flow direction is generally 1.2–2.0%, with cross-flow shrinkage 0.8–1.5%, and anisotropic shrinkage is the main cause of corner warpage in shallow rectangular drawers. Gate placement at the geometric centre creates radial shrinkage gradients; relocating the gate to a short side narrows differential shrinkage along the long axis. Processing should avoid mould temperatures below 8°C because surface gloss falls and sink marks become visible at rib intersections. Terminal products include storage bins, drawer organisers, low-warp trays and toolbox organisers. These products are not food-contact unless separately qualified, and they are normally evaluated for dimensional retention after repeated loading according to internal stacking tests rather than a single material property standard.
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LyondellBasell HDPE M5370PX is a high-density polyethylene grade supplied in pellet form for high-stalk blown film and sheet extrusion. The designation places the material within the high-molecular-weight copolymer segment of the supplier's HDPE portfolio, where elevated melt strength and controlled swelling are specified for thin-gauge structures. In conversion practice, the grade is referenced on grooved-feed extruders with a length-to-diameter ratio of at least 24:1 and on spiral mandrel dies that require stable bubble geometry at film thicknesses below 20 µm. Lot-level certificates of analysis issued under ISO 9001:2015 controlled operations include density, melt flow rate, and additive package composition.
Supplier documentation assigns a density of 0.950 g/cm³ determined under ISO 1183-1:2019 and a melt flow rate of 0.70 g/10 min at 190 °C with a 2.16 kg load per ISO 1133-1:2022. The high-load melt flow rate at 21.6 kg is reported as 21 g/10 min under the same method. These two values indicate a melt flow ratio of approximately 30, reflecting a molecular weight distribution broad enough to deliver shear thinning during extrusion and extensional viscosity during stalk drawing. Published data for the molecular weight distribution curve of M5370PX is limited, but the resin is not classified as an injection-moulding material. The density at the lower end of the HDPE range from 0.945 g/cm³ to 0.965 g/cm³ contributes to environmental stress-cracking resistance greater than that of higher-density film grades with reduced comonomer content.
On a high-stalk blown film line built around a 90 mm grooved-feed single-screw extruder with 24:1 L/D ratio and a 300 mm spiral mandrel die, the material is processed at barrel set temperatures from 190 °C to 225 °C, with adapter and die setpoints between 210 °C and 230 °C. Melt temperature is maintained in the range 200 °C to 230 °C. A die gap of 1.2 mm to 1.8 mm, a blow-up ratio of 3.5:1 to 5.0:1, and a frost-line height of 8 to 12 die diameters are used to orient the film and balance machine-direction and transverse-direction tear properties. On coextrusion structures, the grade is placed in the core or sub-skin layers to raise overall stiffness while polyolefin plastomer or sealant layers provide seal initiation below 110 °C. Extruder head pressure on a 75 mm line with a 200 mm die may reach 25 MPa to 35 MPa at screw speeds above 85 min⁻¹; output above 180 kg/h therefore requires a high-torque extruder or gear pump. Temperatures above 240 °C are not recommended because oxidative chain scission reduces melt strength and increases gel formation.
Batch-to-batch variation in melt flow rate is controlled within ±0.05 g/10 min for a supplier production campaign, but converters should monitor film gauge profiles because a density shift of ±0.002 g/cm³ can alter secant modulus by approximately 3 % and may require die gap adjustment. Field experience from multi-layer lines shows that pressure-limited output is the primary bottleneck when M5370PX occupies the core layer above 40 wt% of total structure. Process optimisation on high-stalk film lines uses dart impact by ISO 7765-1:2004 and Elmendorf tear by ASTM D1922-23 to detect anisotropic toughness. A machine-direction tear value below 10 N/mm is interpreted as an indication of overdraw, while a dart impact value below 150 g at 25 µm suggests insufficient transverse orientation or excessive melt temperature. These thresholds are not universal specification limits; they are line-specific control windows developed on production-scale high-stalk lines.
High-stalk film conversion is sensitive to extensional viscosity and cooling rate. The melt rheology of M5370PX produces a stable stalk height that is not maintained by conventional low-molecular-weight HDPE at the same die gap and output. Bubble oscillation is observed when the frost-line height is reduced below 6 die diameters or when the blow-up ratio is increased above 6:1; both conditions shift orientation and reduce machine-direction tear resistance. Use of a screen pack from 60 mesh to 120 mesh with a breaker plate open area above 50 % is specified to limit melt fracture and pressure fluctuation. Published elongational viscosity data for this specific grade is limited in the open supplier literature, but stable high-stalk operation indicates extensional hardening at the Hencky strains attained in commercial bubble drawing. A frost-line height below 6 die diameters at a blow-up ratio above 5.0:1 imposes transverse orientation that can reduce Elmendorf tear in the machine direction below 10 N/mm. Under the inverse setting, a blow-up ratio below 3.0:1 with a frost-line height above 14 die diameters can reduce dart impact because of excessive draw in the machine direction.
| Property | Test Standard | Typical Value |
|---|---|---|
| Density | ISO 1183-1:2019 | 0.950 g/cm³ |
| Melt flow rate 190 °C/2.16 kg | ISO 1133-1:2022 | 0.70 g/10 min |
| High-load melt flow rate 190 °C/21.6 kg | ISO 1133-1:2022 | 21 g/10 min |
| Tensile yield stress | ISO 527-2:2012 | 26 MPa |
| Tensile elongation at break | ISO 527-2:2012 | >600 % |
| Flexural modulus | ISO 178:2019 | 1100 MPa |
| Notched Charpy impact strength | ISO 179-1:2010 | 20 kJ/m² |
| Vicat softening temperature | ISO 306:2022 | 127 °C |
| Melting temperature | ISO 11357-3:2018 | 132 °C |
| Environmental stress-cracking resistance | ASTM D1693, Condition B | >50 h |
| Water-vapour transmission rate at 25 µm | ISO 15106-2:2015 | 3.5 g/(m²·day) |
Values are typical lot averages and do not constitute specification limits. The grade is stabilised for film extrusion; the consumer end-use package must be validated against the relevant migration and mechanical performance standards before commercial release.
For food-contact use, the unmodified grade is manufactured to permit compliance with FDA 21 CFR 177.1520(c)3.1a and EU Regulation 10/2011. Migration testing is performed according to EN 1186-1:2002 or equivalent in the final packaging configuration because processing aids, printing inks, and lamination layers influence the final exposure profile. The grade is not intended for medical implant use, and it is not listed under ISO 12162 pressure design values for potable water service. For pipe applications, a PE100-classified bimodal HDPE should be selected instead. REACH pre-registration and RoHS status are documented by the supplier for industrial packaging and film structures, but converters must verify the latest regulatory position with the supplier because additives and masterbatches can shift the final article classification.
Selection between M5370PX and a standard unimodal HDPE film grade becomes operationally significant when the target film is a detergent sack or industrial liner exposed to aqueous stress-cracking media at thicknesses below 15 µm. The comonomer distribution in M5370PX yields a higher environmental stress-cracking resistance than typical unimodal film grades with a melt flow rate above 1.0 g/10 min, while retaining the modulus of HDPE. Against LLDPE butene or hexene film grades, M5370PX is selected for higher modulus and lower water-vapour transmission, but it is not the first-choice resin where low-temperature puncture or seal-through-contamination performance is the controlling requirement. Against bimodal HDPE pipe grades, M5370PX does not possess the long-term hydrostatic strength classification required for pressure pipe; the two product classes are not interchangeable despite similar density.
| Material Category | Typical Density | Melt Flow Rate 190 °C/2.16 kg | Principal Conversion Mode | Trade-off Relative to M5370PX |
|---|---|---|---|---|
| M5370PX | 0.950 g/cm³ | 0.70 g/10 min | High-stalk blown film | Reference grade |
| Standard unimodal HDPE film | 0.952 g/cm³ | 1.0 g/10 min | Stalk or pocket blown film | Lower environmental stress-cracking resistance, lower melt strength, higher output |
| LLDPE butene | 0.920 g/cm³ | 1.0 g/10 min | Blown film | Higher dart impact and elongation, lower modulus, weaker vapour barrier |
| Bimodal HDPE pipe | 0.949 g/cm³ | 0.30 g/10 min | Pipe extrusion | Higher long-term hydrostatic strength, not film-verified |
The comparative position is determined primarily by end-use mechanical and barrier requirements, not solely by density or melt flow rate. M5370PX is specified where high-stalk bubble stability, HDPE stiffness, and moderate moisture barrier are specified. Standard unimodal film HDPE is used for very thin films at high output but shows lower environmental stress-cracking resistance. LLDPE grades are preferred for dart impact and seal performance, but they lack the modulus of HDPE. Bimodal pipe grades should not be substituted for film applications because their pellet lot design is not optimised for film surface quality and they are not supplied with film-grade stabilisation.
Published data for specific film structures based on M5370PX is limited in the openly available literature. The resin is not classified as UV-stabilised; if agricultural film or silage cover use is considered, carbon black or hindered-amine light stabiliser masterbatch must be added by the converter. Regrind levels are limited to 20 wt% of total feed unless lot-specific trials validate higher levels, because uncontrolled regrind addition increases gel count and reduces dart impact. Drying is not normally required for unopened pellet bags, but if condensation has occurred, a desiccant dryer set at 80 °C for 2 h reduces surface pitting and bubble defects.