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LyondellBasell HDPE M4612

    • Product Name: LyondellBasell HDPE M4612
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 581907
    Density 0.952 g/cm³
    Melt Flow Rate 190 C 2 16 Kg 0.25 g/10 min
    Melt Flow Rate 190 C 5 Kg 1.2 g/10 min
    Tensile Modulus 1200 MPa
    Tensile Stress At Yield 28 MPa
    Tensile Strain At Yield 9%
    Tensile Strain At Break >600%
    Charpy Notched Impact Strength 23 C 15 kJ/m²
    Charpy Notched Impact Strength 30 C 5 kJ/m²
    Vicat Softening Temperature 75°C
    Heat Deflection Temperature 0 45 Mpa 70°C
    Shore D Hardness 62
    Environmental Stress Cracking Resistance 10 Igepal 1000 h
    Melting Temperature 132°C
    Water Absorption <0.01%
    Bulk Density 0.55 g/cm³
    Volume Resistivity >1E15 ohm·cm
    Dielectric Constant 1 Mhz 2.3

    As an accredited LyondellBasell HDPE M4612 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing LyondellBasell HDPE M4612 is supplied in 25 kg polyethylene bags, palletized for transport, or in bulk containers for industrial use.
    Container Loading (20′ FCL) 20′ FCL container loading of LyondellBasell HDPE M4612 high-density polyethylene resin, securely palletized for export shipment and efficient handling.
    Shipping LyondellBasell HDPE M4612 is a non-hazardous polyethylene resin, not regulated by DOT, IMDG, or IATA. It ships as pellets in 25 kg bags, 1,000 kg bulk bags, or bulk trucks/railcars. Keep packaging closed and dry, away from heat, sunlight, moisture, and contamination. Spilled pellets are slippery; clean promptly.
    Storage Store LyondellBasell HDPE M4612 indoors in a cool, dry, well-ventilated area, away from direct sunlight, heat, sparks, flames, and strong oxidizers. Keep original packaging closed, clean, and labeled to prevent moisture and contamination. Use stable stacks with first-in, first-out rotation. Protect from UV and excessive temperatures, and promptly clean up pellet spills.
    Shelf Life LyondellBasell HDPE M4612 has a shelf life of 2 years when stored in a cool, dry place in original packaging.
    Application of LyondellBasell HDPE M4612

    For thin-wall injection molded dairy portion cups and delicatessen containers, LyondellBasell HDPE M4612 enters the tool at a reported melt mass-flow rate of 12 g/10 min under ISO 1133-1:2022 conditions at 190 °C with 2.16 kg load, which permits short-shot boundaries to be pushed toward flow length-to-wall thickness ratios of 150:1 to 250:1 in tools with gate lands below 0.5 mm. Accumulator-assisted presses in the 2,500–5,000 kN clamp force range are operated with injection velocities exceeding 200 mm/s, transfer at cavity pressures of 60–80 MPa, and total cycle times of 4–9 s for wall thicknesses from 0.45 mm to 1.2 mm. Melt temperatures are held at 200–240 °C and mold temperatures at 8–15 °C to reduce post-ejection warping in flat rims and stacking ledges. Formulation practice for food-contact packaging uses HDPE M4612 at 96.0–98.9 wt%, colorant or titanium dioxide white masterbatch at 1.0–2.5 wt%, slip/antiblock masterbatch at 0.05–0.20 wt%, and antioxidant additive at 0.03–0.10 wt%. Pre-drying is generally unnecessary below 60% relative humidity; at higher ambient humidity, a 65 °C hopper dryer for 2 h suppresses splay in ribs and snap rims. The relevant food-contact compliance framework includes FDA 21 CFR 177.1520 for olefin polymers, EU Regulation (EU) No 10/2011 with an overall migration limit of 10 mg/dm², and 21 CFR 174.5 for good manufacturing practice. Terminal product forms include 125 mL portion cups, 250–500 mL delicatessen tubs, 500–1,000 mL salad bowls, and matching snap lids where the rim seal must retain dimensional stability within ±0.10 mm across a multi-cavity stack. Short-shot formation in the stacking ledge occurs when transfer position is delayed beyond 0.10 s after the flow front reaches the end of the cavity, and on 24–48 cavity tools, cavity-to-cavity fill imbalance above 5% by part weight produces measurable rim warping. Process audits on high-output lines therefore record cushion position, cushion stability, and peak cavity pressure per cavity rather than relying solely on machine barrel temperature readouts.

    What Limits the Cavity Count in Closure Molding When HDPE M4612 Replaces Low-Flow HDPE?

    Closure production with HDPE M4612 shifts from flow-limited filling to gate-freeze and demolding constraints in 32–64 cavity hot-runner or cold-runner stack molds. The 12 g/10 min melt flow allows short injection times, but dimensional stability in the tamper-evident band and sidewall ovality become controlling variables. Nozzle temperatures are maintained at 220–245 °C, mold coolant at 10–20 °C, injection pressure at 70–100 MPa, holding pressure at 50–70 MPa, and residual screw cushion at 3–6 mm. Cycle times for closures with wall sections of 0.6–1.2 mm generally fall between 6 s and 12 s, with gate diameters below 1.0 mm and valve-gate opening delays below 0.05 s. Typical formulation addition ratios in this sector are closure color masterbatch at 0.5–2.0 wt%, antioxidant at 0.05–0.15 wt%, and acid scavenger or processing aid at 0.02–0.05 wt% when discoloration from reground edge trim is observed. Regulatory requirements for food and beverage closures include FDA 21 CFR 177.1520(c), EU Regulation (EU) No 10/2011, and CONEG Model Toxics in Packaging Legislation with a combined heavy metal limit of 100 ppm. Terminal products include 28 mm still beverage screw caps, 38 mm dairy closures, and 40–53 mm personal care snap-on caps; carbonated soft drink closures are not generally assigned without separate creep and torque retention testing because published seal performance data for this specific HDPE M4612 configuration under carbonation is limited. On production-scale lines, lid ovality exceeding 0.3 mm is commonly traced to uneven mold cooling, especially in thicker tamper-evident bands, rather than to insufficient injection pressure.

    Downstream segmentMelt temperatureMold temperatureInjection/hold pressureCycle range
    Thin-wall dairy containers200–240 °C8–15 °C60–120 MPa4–9 s
    Multi-cavity closures220–245 °C10–20 °C70–100 MPa6–12 s
    Industrial crates and trays210–250 °C12–25 °C70–110 MPa18–35 s
    Housewares and storage articles210–250 °C15–25 °C60–100 MPa15–35 s
    Outdoor garden accessories210–245 °C15–25 °C40–65 MPa20–40 s

    High-Cycle Industrial Crate and Tray Molding with Regrind Streams

    Industrial crate and tray production uses HDPE M4612 in thick-section parts where the high melt flow is balanced against impact strength retention after regrind incorporation. General-purpose injection molding machines with clamp forces between 5,000 kN and 12,000 kN are set to melt temperatures of 210–250 °C, mold temperatures of 12–25 °C, injection pressures of 70–110 MPa, and hold pressures of 45–70 MPa. Cooling time for wall sections from 2.5 mm to 4.5 mm ranges from 18 s to 35 s. Formulation practice in this non-food sector permits regrind at 20–40 wt% from sprues, runners, and rejected crates, with carbon black masterbatch at 2.0–3.0 wt% for UV protection in outdoor logistics, antioxidant at 0.10–0.25 wt% to stabilize regrind heat history, and UV or hindered amine light stabilizer masterbatch at 0.3–0.8 wt% where crates are exposed to direct sunlight. Compliance references include REACH Regulation (EC) No 1907/2006, RoHS Directive 2011/65/EU where electronic supply chain use is relevant, CONEG Model Toxics in Packaging Legislation at a combined heavy metal limit of 100 ppm, and ISO 11469 for polymer part marking. Terminal product classes include stackable logistics crates, pallet boxes, dunnage trays for automotive handling, and compartment trays used in distribution centers. Regrind streams with particle sizes above 8 mm or irregular fines below 1 mm can create nozzle feed instability, and melt viscosity drift above ±8% across recycled batches is an accepted control boundary on production lines that blend edge trim with virgin HDPE M4612.

    When the same grade is shifted into multi-cavity houseware production, tooling with edge gates, fan gates, or hot-tip bushings is run at melt temperatures of 210–250 °C, mold temperatures of 15–25 °C, injection speeds of 60–120 mm/s, and pack times of 4–10 s. Total cycle times for wall thicknesses from 1.5 mm to 3.5 mm fall between 15 s and 35 s. The formulation is typically HDPE M4612 at 96.0–99.3 wt%, color masterbatch at 0.5–3.0 wt%, antistatic masterbatch at 0.1–0.5 wt%, and external lubricant or process aid at 0.05–0.15 wt% to reduce drag marks on deep draw surfaces. Compliance obligations include REACH Regulation (EC) No 1907/2006, RoHS Directive 2011/65/EU for articles with electronic components or recycling obligations, and 16 CFR 1303 with a lead limit of 90 ppm in surface coatings when decorative paint or print is applied. Terminal products include storage boxes, garment hangers, drawer organizers, laundry baskets, and under-bed containers. Surface blemishes from moisture condensation occur when pellets are transferred from outdoor silos at temperatures below 10 °C into a melt at 220 °C; in high-humidity regions, a hopper dryer at 65 °C for 2 h is used before molding. Scratch resistance and gloss retention in this grade are not separately specified in the published data, so these properties require OEM testing under ISO 4586-1 or equivalent internal methods rather than assumption from density or melt index.

    Outdoor Garden Accessory Molding and UV-Associated Property Retention Limits

    Outdoor garden accessory production in HDPE M4612 demands a different stabilizer strategy because translucent or light-colored parts do not have carbon black opacity to suppress ultraviolet chain scission. Injection molding conditions for planters, garden trays, and outdoor storage components use melt temperatures of 210–245 °C, mold temperatures of 15–25 °C, hold pressures of 40–65 MPa, and cooling times of 20–40 s for wall thicknesses from 2.0 mm to 5.0 mm. The formulation includes hindered amine light stabilizer masterbatch at 0.3–0.8 wt%, UV absorber masterbatch at 0.1–0.5 wt%, carbon black masterbatch at 2.0–2.5 wt% for black exterior parts, and pigment masterbatch at 1.0–3.0 wt% for colored parts. Compliance testing follows ISO 4892-2:2021 for artificial weathering under xenon-arc exposure, with impact retention checked by ASTM D256-23 and flexural property shift checked by ISO 178. Terminal product classes include injection molded planters, nursery trays, garden tool handles, and small outdoor storage bins. Published data for long-term outdoor performance of this specific HDPE M4612 grade in non-black pigmentation is limited; stabilizer packages must be validated by accelerated weathering rather than extrapolated from unmodified HDPE formulations. Processing technicians observe that molded-in stress in thick bosses or corner radii accelerates surface crazing after 1,000 h of ISO 4892-2:2021 exposure, making gate placement and packing density more important than simply increasing UV additive load.

    Application fieldCore compliance referenceTest or limitTerminal product class
    Thin-wall food packagingFDA 21 CFR 177.1520; EU Regulation (EU) No 10/2011Overall migration 10 mg/dm²Dairy cups, deli tubs, salad bowls
    Closure moldingFDA 21 CFR 177.1520(c); CONEG Model ToxicsHeavy metal sum 100 ppmStill beverage caps, dairy closures
    Industrial crates and traysREACH Regulation (EC) No 1907/2006; ISO 11469Marking and SVHC declarationCrates, pallet boxes, dunnage trays
    Housewares and storage articlesRoHS Directive 2011/65/EU; 16 CFR 1303Lead in surface coating 90 ppmStorage boxes, hangers, organizers
    Outdoor garden accessoriesISO 4892-2:2021; ASTM D256-23Impact retention after xenon-arc exposurePlanners, nursery trays, outdoor bins

    When In-Mold Labeling or Post-Mold Surface Treatment Becomes the Critical Process Step

    In-mold label processing of HDPE M4612 involves tooling modifications and surface energy control that are not required in undecorated molding. Melt temperatures are held at 220–245 °C, mold temperatures at 10–20 °C, injection speeds at 80–150 mm/s, and additional cycle time from label insertion at 0.5–1.5 s. Formulation practice for decorated packaging includes color masterbatch at 1.0–3.0 wt%, antistatic masterbatch at 0.1–0.3 wt%, and print-receptive additive masterbatch at 0.5–2.0 wt% when post-mold ink adhesion is required. Surface energy of untreated HDPE M4612 typically sits below 32 mN/m, and corona or flame treatment to above 40 mN/m, with measurement per ISO 8296:2003, is required for solvent-free inks and high-speed pad printing. Compliance for IML food containers includes EU Regulation (EU) No 10/2011 and FDA 21 CFR 177.1520, while the label stock and adhesive layer must separately meet FDA 21 CFR 175.105 where applicable. Terminal product forms include IML dairy containers, decorated storage pails, and printed closures with high-wear graphics. Post-treatment surface energy decays over time, and corona output must be revalidated after 24 h to 48 h because return to below 36 mN/m causes ink delamination in stacked decorated parts. For IML tooling, electrostatic pinning of the label must be completed before the melt flow front reaches the label edge; positioning error above 0.3 mm produces visible label shift and seal-boundary print distortion.

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    Certification & Compliance
    More Introduction

    LyondellBasell HDPE M4612 is a high-density polyethylene resin positioned within the manufacturer’s injection-moulding portfolio for high-speed conversion of thin-wall packaging, closures, housewares, and rigid consumer goods. Published technical data identify a nominal density of 0.946 g/cm³ under ASTM D1505 and a nominal melt flow rate of 12 g/10 min at 190 °C/2.16 kg under ASTM D1238 or ISO 1133-1:2022. The resin is produced by low-pressure ethylene polymerisation and is supplied in pellet form. The density places the material near the lower limit of the HDPE range, which reduces stiffness relative to higher-density HDPE grades while retaining the processing advantages of a high-melt-flow, narrow-molecular-weight-distribution design. That combination makes the grade suitable for applications in which rapid cavity filling and short cycle times are more important than maximum load-bearing capacity or long-term environmental stress cracking resistance.

    Nominal Property Dataset From Published Technical Data

    The values below are representative datasheet values and are not lot-specific certificate-of-analysis data. Lot-to-lot variation should be verified against the current LyondellBasell technical data sheet and the certificate supplied with each shipment. Mechanical values depend on specimen preparation, cooling rate, and test speed; therefore, direct comparison with other resins should use the same specimen geometry and conditioning history.

    Property Test standard Representative value
    Nominal density ASTM D1505 / ISO 1183-1:2019 0.946 g/cm³
    Melt flow rate ASTM D1238 / ISO 1133-1:2022 12 g/10 min
    Tensile stress at yield ASTM D638-14 25 MPa
    Flexural modulus ASTM D790-17 1,000 MPa
    Shore D hardness ASTM D2240-15 64
    Vicat softening point ASTM D1525-17 125 °C

    Published data for notched Izod impact and full environmental stress cracking resistance under all reagent conditions are limited for this specific grade. Converters should not extrapolate a single ESCR value across designs with different moulded-in stress, wall thickness, or chemical exposure. Where ESCR is the controlling requirement, the part should be validated in the intended chemical at the intended service temperature.

    In high-speed thin-wall injection moulding of margarine tubs, dairy containers, snack pots, and overcaps, HDPE M4612 is processed on reciprocating-screw machines with screw L/D ratios from 20:1 to 24:1 and compression ratios from 2.5:1 to 3.0:1. The high melt flow rate reduces pressure loss in multicavity hot-runner systems, but the relatively fast crystallisation of the grade requires adequate gate diameter to prevent premature gate freeze before packing is complete. For wall sections below 1.0 mm, gate diameters below 0.8 mm commonly produce sink marks and dimensional drift because the gate solidifies before holding pressure can compensate for volumetric shrinkage. On production tools with 16 to 32 cavities, the cushion position should remain stable within 3 mm; larger cushion variability produces shot-to-shot melt-density variation and warpage.

    Where Does M4612 Differ From Bimodal HDPE Blow Moulding Grades?

    HDPE M4612 should not be used interchangeably with bimodal HDPE blow-moulding grades. A bimodal HDPE intended for extrusion blow moulding of bottles or industrial containers typically has a lower melt flow rate, often below 1 g/10 min, and a higher density, commonly near 0.955 g/cm³. Its broader molar mass distribution provides high melt strength, high ESCR, and high resistance to parison sag. Those characteristics are directly useful in blow moulding but create high pressure drop, slow cavity filling, and poor flow-length-to-thickness behaviour in thin-wall injection moulding. HDPE M4612 reverses that balance: it sacrifices some melt strength and ESCR to obtain a melt flow rate of 12 g/10 min and faster cycle potential in pressure-limited injection tools.

    The difference is also visible in failure mode. Bimodal blow-moulding grades resist slow crack growth under stress-cracking agents for extended durations, while HDPE M4612 is intended for short-term packaging and non-aggressive contents. In aggressive detergent or surfactant-containing applications, a blow-moulding HDPE with an ESCR failure time above 100 h under ASTM D1693 method B would normally be selected instead. The choice is not a general quality difference but a difference in molecular architecture, comonomer placement, and additive package.

    Processing Window, Screw Recovery, and Gate Freeze Requirements

    Cylinder set-up for HDPE M4612 commonly begins with a rear zone at 170 °C, centre zones from 180 °C to 230 °C, and a nozzle temperature near 220 °C. The actual melt temperature should be verified with a needle pyrometer because screw shear can raise melt temperature by 5 °C to 10 °C above the barrel setting. Mould temperatures between 15 °C and 40 °C provide sufficient crystallinity for ejection and dimensional stability. At mould temperatures below 15 °C, rapid quenching can increase post-mould shrinkage and produce sink marks; above 60 °C, cycle time increases without a proportionate gain in stiffness for most non-load-bearing thin-wall parts.

    Screw recovery should be completed within roughly 0.8 to 1.2 of the cooling timer to avoid extending the cycle. Backpressure above 10 bar can generate excessive shear heating, odour, and yellowing in high-throughput operations. Clamp force per cavity for thin-wall high-speed moulding is more reliably estimated from projected area and effective cavity pressure, typically 30 MPa to 50 MPa, than from nominal injection pressure alone. A tool with worn parting lines or insufficient clamp force may flash because the lower melt viscosity of HDPE M4612 permits flow into clearances that higher-viscosity grades do not enter.

    When Thin-Wall Tools Demand a Narrow Molecular Weight Distribution

    HDPE M4612 is selected when the limiting factor in production is pressure-limited filling rather than long-term load-bearing performance. The narrow molecular weight distribution reduces viscous energy dissipation relative to broader grades, which lowers peak injection pressure at identical fill speed and wall section. That benefit appears most clearly in thin-wall tools running high-speed injection, where the flow length can exceed 150 mm at wall sections below 1.2 mm. In such tools, injection speed should be raised before holding pressure is increased; excessive holding pressure compresses the melt after the gate freezes and may create overpacking at the gate with excessive shrinkage farther from the gate.

    Because the material is a low-pressure HDPE with a density of 0.946 g/cm³, parts are not optically clear. Abrupt changes in wall thickness create visible sink marks and internal voids. The use of generous radii at rib intersections and a wall-thickness variation below 15 % is recommended to maintain consistent filling and packing. Venting depths should not exceed 0.02 mm to avoid flash while permitting air escape. Published data for spiral-flow length of HDPE M4612 under specific tool geometries is limited; converters often establish machine-specific flow windows by spiral-flow moulding or by short-shot studies on the production tool.

    Moisture absorption by non-predried HDPE is usually low, but condensation from cold silo storage or high-humidity transfer lines can produce surface splay. When splay is observed, the resin should be predried in a desiccant dryer at 80 °C for 2 h. Predrying is not normally required for stable indoor storage below 60 % relative humidity. The grade is not recommended for combination with amine-based antistatic concentrates without prior validation, because amine additives can migrate to the mould surface and create plate-out, deposit formation, or odour in high-temperature processing.

    Regulatory compliance for food-contact use must be confirmed by the current manufacturer’s compliance statement. HDPE grades with a density within the high-density polyethylene range are generally evaluated under FDA 21 CFR 177.1520 for olefin polymers used in contact with food. European food-contact evaluation for plastics is conducted under Regulation (EU) No 10/2011, which includes an overall migration limit of 10 mg/dm² under the intended food-simulant conditions. The article must also be assessed under REACH Regulation (EC) No 1907/2006 and, for electrical or electronic applications, under RoHS Directive 2011/65/EU, with lead below 1,000 ppm and cadmium below 100 ppm by weight in homogeneous material.

    In closures and overcaps, HDPE M4612 provides dimensionally stable mouldings at cycle times below those of lower-melt-flow HDPE grades. However, the material is not a replacement for polypropylene in hinged closures that require repeated flexural endurance or in closures requiring high-temperature hot-fill resistance above 100 °C. Validation should include application torque, removal torque, liner adhesion, and seal integrity after drop testing. For screw caps, the thread geometry should be radiused rather than sharp because HDPE has lower notch sensitivity than polypropylene but lower modulus than glass-filled or nucleated polypropylene grades. Part weight should be monitored as a production control; a weight drift above 1 % can indicate changes in cushion, melt temperature, or check-ring wear that are not visible in a short-run quality check.

    The grade also differs from high-flow HDPE grades with higher density near 0.960 g/cm³. Those grades provide higher flexural modulus and lower creep, but they typically require higher injection pressure at equal melt flow rate and exhibit lower impact resistance in thin frozen-in layers. HDPE M4612 offers a lower stiffness but a wider flow window in rapid cycling tools. The final selection should be based on spiral-flow length, part stiffness, drop-impact performance, and chemical exposure, not on melt flow rate alone.

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