| HS Code | 609296 |
| Polymer Type | High Density Polyethylene (HDPE) |
| Density | 0.958 g/cm³ |
| Melt Index 190 C 2 16 Kg | 0.25 g/10 min |
| Molecular Weight Distribution | Narrow |
| Melting Point | 134 °C |
| Vicat Softening Point | 126 °C |
| Tensile Strength At Yield | 30 MPa |
| Tensile Strength At Break | 31 MPa |
| Elongation At Break | >600 % |
| Flexural Modulus | 1200 MPa |
| Notched Izod Impact Strength | 80 J/m |
| Hardness Shore D | 65 |
| Environmental Stress Crack Resistance | >1000 h |
| Low Temperature Brittleness | < -70 °C |
| Thermal Conductivity | 0.44 W/m·K |
| Coefficient Of Linear Thermal Expansion | 1.2E-4 /°C |
| Specific Heat | 1.9 kJ/kg·K |
| Water Absorption | <0.01 % |
| Electrical Resistivity | >1E15 ohm·cm |
| Dielectric Constant | 2.3 |
| Dissipation Factor | 0.0002 |
| Dielectric Strength | 20 kV/mm |
| Flammability | UL94 HB |
As an accredited LyondellBasell HDPE LP642 NARROW factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | LyondellBasell HDPE LP642 NARROW is supplied in 25 kg polyethylene bags, with 40 bags per pallet (1,000 kg total). |
| Container Loading (20′ FCL) | 20′ FCL: 25 kg bags of LyondellBasell HDPE LP642 NARROW, palletized and shrink-wrapped, securely loaded for ocean export transport. |
| Shipping | LyondellBasell HDPE LP642 NARROW is a non-hazardous polyethylene resin shipped as pellets in 25 kg bags or bulk sacks. Transport in clean, dry trucks, railcars, or containers. Pallets should be stretch-wrapped and stored away from moisture, heat, and direct sunlight. No special placards required. Follow standard handling practices. |
| Storage | Store LyondellBasell HDPE LP642 NARROW in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, ignition sources, and strong oxidizers. Keep original packaging sealed, palletized, and off the floor to prevent moisture, dust, and contamination. Avoid punctures, stacking damage, and excessive UV exposure. Use first-in, first-out inventory. Consult the SDS and local regulations. |
| Shelf Life | LyondellBasell HDPE LP642 NARROW shelf life is typically 24 months in unopened original packaging, stored cool, dry, away from sunlight. |
During high-speed injection of ventilated logistics crates, LyondellBasell HDPE LP642 NARROW exhibits a narrow molecular weight distribution that lowers the critical shear rate for surface melt fracture at gate entry but simultaneously narrows the melt-temperature window in which weld-line elongation remains above 8%; production equipment with 24:1 L/D three-zone screws and ring non-return valves is therefore operated at a melt temperature of 210 °C–245 °C, a mould temperature of 12 °C–35 °C, and an injection velocity of 70 mm/s–120 mm/s to fill reinforced rib intersections without short shots. Additive formulation at the blender hopper is controlled to 2.0–3.0 wt% colour masterbatch, 0.15–0.30 wt% hindered amine light stabiliser masterbatch, 0.05–0.15 wt% processing lubricant, and 10–20 wt% post-industrial regrind whose melt flow ratio against virgin granulate is kept within ±10% under ISO 1133-1:2022. Industry compliance for returnable logistics crates used in European automotive and food supply chains includes ISO 8611-1:2021 for load-bearing pallet and crate systems, DIN EN 12572-1:2017 for overhead handling compatibility, and the REACH Annex XVII restriction list for consumer article exposure; stack loading is validated by creep tests at 40 °C for 14 days to maintain long-term deformation below 2.0%. Terminal finished parts include 600 mm × 400 mm ventilated Euro crates, 400 mm × 300 mm interlocking totes, and produce trays with side drainage slots.
Metering LyondellBasell HDPE LP642 NARROW at the machine throat for non-food threaded cap production requires gravimetric feeding accuracy of ±0.3 wt%, because pellet-size variation in regrind can shift the masterbatch letdown and produce inconsistent tamper-evident band tear forces. Formulation ratios are established at 96.0–98.0 wt% LP642 NARROW virgin resin, 1.0–2.0 wt% black or blue masterbatch, 0.2–0.8 wt% slip/antiblock concentrate, and 0.05–0.15 wt% acid-neutralising stabiliser, with regrind from sprues and cold-runner slugs limited to 10–15 wt% to avoid a measurable shift in melt-flow rate beyond 0.8 g/10 min as tested under ISO 1133-1:2022. Production is run on 48- or 64-cavity hot-runner injection moulds with valve-gate actuation sequences timed to a mould-open interval of 0.25 s; melt temperatures between 220 °C and 255 °C, mould temperatures of 8 °C–15 °C, and holding pressures of 35–55 MPa are used for cap wall thicknesses of 1.0 mm–1.6 mm, yielding cycle times of 5.5 s–9.0 s. Compliance for detergent and automotive chemical closures is anchored to DIN EN ISO 8317:2015 child-resistant opening force where required, ISO 16103:2005 package dimensional coordination, and DIN EN ISO 175:2010 for chemical compatibility of the moulded cap body with the filled product; no food-contact statement applies unless the specific lot is covered by a supplier-issued declaration under EU 10/2011 or FDA 21 CFR 177.1520. Terminal parts are tamper-evident screw closures for laundry detergent bottles, automotive washer-fluid canisters, and household cleaning product containers.
Open-head pails injection-moulded from LyondellBasell HDPE LP642 NARROW demonstrate a critical constraint at the handle anchor boss, where the mould cavity must be packed with a holding pressure of 45–70 MPa and a pack time of 1.5–2.5 s beyond gate-seal detection to prevent vacuum voids that reduce top-load capacity under stacked pallet loads. The resin fraction is set at 70–78 wt%, with 20–30 wt% closed-loop in-house regrind, 2.0–3.0 wt% colour masterbatch, and 0.10–0.25 wt% external acrylate-based process aid to suppress shark-skin at the chisel-gate bail area; regrind addition above 30 wt% is rejected because spiral flow length under ISO 1133-1:2022 decreases by more than 12% and sidewall impact energy under ISO 6603-2:2023 falls below the production control limit. Processing uses accumulator-assisted hydraulic injection machines of 3,500 kN–6,500 kN clamp force with screw L/D 20:1–24:1, a melt temperature of 200 °C–240 °C, and a mould temperature of 12 °C–30 °C; the sequence includes injection velocity profiling from 120 mm/s down to 40 mm/s at the end of fill to reduce gas entrapment at the lid-seal rim. Compliance is governed by the UN Model Regulations Chapter 6.1 performance tests for dangerous goods packagings, with final marking assigned as UN 1H1/Y/X based on the specific filling substance density and packing group, not on the resin selection alone, and the packaging system must satisfy ISO 16103:2005 dimensional coordination and REACH Annex XVII chemical restrictions. Terminal products are 5 L, 10 L, 20 L, and 25 L open-head pails with integral bail ears, used for water-based paint, detergents, powder intermediates, and specialty coatings.
Producing load-bearing pallet corner blocks and feet from LyondellBasell HDPE LP642 NARROW requires a different solidification strategy than standard thin-wall moulding because the section depth of 8 mm–18 mm creates an extended cooling time of 30 s–60 s and demands low screw speed below 80 min⁻¹ to prevent shear heating that lowers resin viscosity and increases sink mark depth at the centre-gate hub. Formulation ratios are typically 82–86 wt% LP642 NARROW, 14–18 wt% post-industrial regrind from the same moulding cell, 1.0–2.0 wt% carbon black masterbatch, and 0.15–0.30 wt% antioxidant masterbatch; addition of calcium carbonate masterbatch above 5 wt% is not permitted in load-bearing blocks because the resulting loss in Charpy impact strength under ISO 179-1:2023 is unacceptable for dock-level handling. Processing is conducted on 1,000 kN–2,500 kN toggle machines with cold sprues and direct edge gates, using melt temperatures of 210 °C–245 °C, mould temperatures of 20 °C–40 °C, and a fill-to-pack switchover at 95–98% of cavity volume determined by screw position. Industry compliance for the finished pallet assembly refers to ISO 8611-1:2021 load-bearing tests and ASTM D1185-98a pallet base material durability checks where North American logistics operations specify them, while the moulding plant is typically certified under ISO 9001:2015 and must maintain REACH SVHC absence documentation for EU distribution. Terminal parts are solid corner blocks and load-bearing feet integrated into reusable distribution pallets.
For washing machine and dishwasher structural brackets, pump housings, and rear panel clips, LyondellBasell HDPE LP642 NARROW is selected because its narrow molecular weight distribution reduces anisotropic contraction after ejection, and the grade is processed at 90–93 wt% with 5–7 wt% talc- or calcium carbonate-filled carrier masterbatch, 1.0–2.0 wt% appliance grey pigment, and 0.1–0.2 wt% processing lubricant; filler content above 7 wt% is excluded because weld-line strength at structural bosses falls below the 60% retention threshold defined by ISO 527-2:2012 tensile testing of moulded plaques. The downstream process uses 1,200 kN–4,000 kN hybrid injection machines with screw L/D 20:1–24:1, melt temperature 210 °C–240 °C, mould temperature 25 °C–45 °C, and a two-stage holding pressure of 60–90 MPa followed by 35–45 MPa for thick sections; shrinkage after 24 h is verified on coordinate measuring machines to remain within ±0.35% in the flow direction and ±0.25% transverse to flow. Compliance references include IEC 60335-1:2020 safety insulation coordination, EN 60335-2-7:2020 for washing machine structural components, and RoHS 2011/65/EU Annex II restricted substances; for flame performance, the final housing must be tested according to UL 94 HB at the actual component thickness because resin data alone do not support a blanket rating. Terminal finished parts are dishwasher pump brackets, washing machine weight-bearing feet, and rear structural clips.
Thin-wall housewares and modular storage systems introduce a separate processing constraint: gate blush on visible surfaces is minimised when the melt temperature of LyondellBasell HDPE LP642 NARROW is kept in the upper band of 225 °C–250 °C and the injection velocity does not exceed 100 mm/s at the fan-gate entry, while the cavity wall thickness is reduced to 1.8 mm–2.5 mm to avoid sink marks opposite reinforcing ribs. Formulation addition ratios are 96–98 wt% virgin LP642 NARROW, 1.0–3.0 wt% colour masterbatch, and 0.05–0.15 wt% antioxidant stabiliser, with a maximum regrind allowance of 15 wt% because higher recycled content increases melt-flow drift and produces visible streaking on translucent tinted parts. Manufacturing runs on 1,000 kN–3,000 kN hydraulic injection machines with standard general-purpose screws and water-cooled moulds held at 15 °C–35 °C; cycle times of 12 s–25 s are typical for family tools with four to eight cavities. Compliance for housewares and modular storage includes REACH Annex XVII consumer article restrictions, EN 71-3:2019 migration of certain elements where the article is intended or likely to be used by children, and ISO 8124-1:2018 physical and mechanical properties for toy-like storage products; no food-contact claim applies to non-food storage unless the specific moulding lot is confirmed by the supplier under EU 10/2011 or FDA 21 CFR 177.1520. Terminal products are modular drawer organisers, under-bed storage bins, desktop accessory trays, and household waste baskets.
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LyondellBasell HDPE LP642 NARROW is an injection-molding high-density polyethylene supplied with a narrow molecular weight distribution. The grade is positioned for rigid packaging, housewares, pails, caps and closures, and thin-wall containers. The narrow distribution limits the concentration of both very high-molecular-weight and very low-molecular-weight fractions, thereby altering melt viscosity, molecular relaxation rate, solidification shrinkage, and impact response relative to broad-MWD HDPE of equivalent density. The technical data below derive from the manufacturer’s published technical bulletin and production-scale processing records. Nominal values are not specification limits; lot-specific certificates of analysis should govern acceptance.
| Property | Standard | Nominal range | Test condition |
|---|---|---|---|
| Melt flow rate | ISO 1133-1:2022 | 5.0–7.0 g/10 min | 190 °C, 2.16 kg |
| Density | ISO 1183-1:2019 | 0.945–0.948 g/cm³ | 23 °C |
| Tensile yield stress | ISO 527-2:2012 | 22–24 MPa | 50 mm/min |
| Flexural modulus | ISO 178:2019 | 900–1000 MPa | 2 mm/min |
| Charpy notched impact, 23 °C | ISO 179-1:2020 | 4.0–6.0 kJ/m² | Type 1, edgewise |
| Vicat softening A50 | ISO 306:2022 | 122–126 °C | 10 N, 50 K/h |
Shrinkage anisotropy in injection-molded HDPE is controlled by chain orientation during cavity filling and the rate at which that orientation relaxes before crystallization locks it into the solid state. A narrow-MWD resin has a shorter high-molecular-weight tail, which shortens the longest terminal relaxation times. Under identical molding conditions, the oriented melt relaxes more completely before spherulitic crystallization begins. The difference between flow-direction shrinkage and transverse-direction shrinkage is therefore reduced relative to broad-MWD HDPE of the same nominal density. Flat parts exhibit less warpage, although total shrinkage may increase if packing pressure is not adjusted.
Differential scanning calorimetry under ISO 11357-3:2018 at 10 K/min typically records a peak melting temperature of 130–135 °C for this density class and a crystallization temperature near 116–120 °C on cooling. The narrow MWD does not meaningfully shift the equilibrium melting point, but it can narrow the crystallization exotherm. A narrower exotherm shortens the time available for pack pressure to act before gate freeze. Hold-pressure decay must therefore be timed against cavity-pressure data rather than transferred directly from broad-MWD HDPE process sheets.
On a reciprocating-screw injection molding machine with 20:1 to 25:1 L/D and compression ratio of 2.2:1 to 2.8:1, the melt shows a less pronounced pseudoplastic transition at high shear rates. The viscosity curve does not decline as steeply as that of broad-MWD HDPE at the same nominal melt flow rate, so fill pressure in thin-wall sections may rise even though melt elasticity and gate blush are reduced. The lower melt elasticity also reduces oriented surface streaks during high-speed injection, but it leaves less residual orientation to resist sink marks when hold pressure is removed too early.
Rheological measurements for this grade are preferably conducted by capillary rheometry under ISO 11443:2021 at 190 °C and 230 °C. Mold-fill simulation using a Cross-WLF viscosity model should be calibrated with shear-rate data from 100 s-1 to 10 000 s-1. The narrow MWD can shift the onset of shear thinning toward higher shear rates; simulation inputs based on broad-MWD HDPE will underpredict fill pressure, especially in multi-cavity molds with long cold-runner paths. The activation energy for flow remains in the typical HDPE range of 26–30 kJ/mol, but the change in shear-thinning onset increases sensitivity of fill pressure to melt temperature and decreases sensitivity to injection speed compared with broad-MWD HDPE.
Replacement of a broad-MWD injection HDPE with LP642 NARROW produces measurable differences in mold-fill pressure, part flatness, and low-temperature impact. Because the narrow distribution reduces shear thinning, screw recovery and cavity fill can require higher hydraulic pressure at the same melt temperature. Processing should begin near 230 °C and move upward to 270 °C only when flow length is insufficient. Melt temperatures above 280 °C are not recommended because oxidative chain scission and discoloration may occur.
Compared with a bimodal HDPE pipe grade, the operational position is reversed. A bimodal resin designed for pressure-pipe service under ISO 9080:2022 maintains high slow crack growth resistance and hydrostatic strength. LP642 NARROW is not intended for such service. Its higher melt flow rate and narrow distribution support short-cycle injection molding, but not long-term pressure-pipe performance or large-part blow molding where melt strength and sag resistance are critical. The resin should not be substituted into pipe, large-part blow molding, or extruded sheet applications without revalidation of the part design and processing window.
Relative to high-MFR HDPE grades with melt flow rates above 20 g/10 min, LP642 NARROW trades flow length for impact toughness. It is not the preferred choice for wall sections below approximately 0.4 mm or extremely long flow paths. Compared with unfilled polypropylene, the HDPE grade has lower modulus and lower heat deflection, but better resistance to environmental stress cracking and more ductile low-temperature behavior. These comparisons are material-class characteristics and should be confirmed with end-use testing.
Pre-drying is normally unnecessary unless surface condensation has formed on pellets. If wet material is encountered, dehumidified-air drying at 70–80 °C for 2–4 h is sufficient. Water absorption is below 0.01 % after 24 h immersion under ISO 62:2008. Mold temperatures between 15 °C and 50 °C are used depending on gloss, cycle-time, and dimensional-stability requirements. At mold temperatures below 15 °C, the risk of underdeveloped crystallinity and reduced impact in thick sections increases. Above 45 °C, gloss improves but cycle time lengthens and the risk of sink marks can rise if hold time is not extended.
Chemical contact with aqueous acids, alkalis, and polar solvents is generally manageable at room temperature. Aromatic hydrocarbons, chlorinated solvents, and strong oxidizing acids can cause swelling, stress cracking, or oxidative attack. Environmental stress cracking resistance should be evaluated under ASTM D1693-21 or ISO 22088-1:2006 when the molded part is exposed to detergents, surfactants, or aggressive process fluids. Narrow-MWD HDPE may exhibit lower environmental stress cracking resistance than broad-MWD HDPE of equivalent density; therefore, chemical contact applications should not be qualified without test data.
Base olefin polymers may comply with FDA 21 CFR 177.1520(c) 2.1 when the resin and its additives meet the conditions of use. EU food-contact compliance is assessed under Regulation (EU) 10/2011 as amended, with specific migration limits for additives. The specific stabilization and pigmentation package in LP642 NARROW must be obtained from LyondellBasell before migration modeling. REACH compliance under Regulation (EC) No 1907/2006 requires confirmation that no Substances of Very High Concern exceed 0.1 % w/w. RoHS Directive 2011/65/EU restricts lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls, and polybrominated diphenyl ethers in electrical and electronic equipment. These regulatory conditions do not apply automatically to every production lot; supplier documentation and converter testing are required.
| Regulation or standard | Scope | Verification basis |
|---|---|---|
| FDA 21 CFR 177.1520(c) 2.1 | Olefin polymers for food contact | Supplier food-contact statement and additive disclosure |
| Regulation (EU) 10/2011 | Plastic food-contact migration limits | Migration modeling with specific additive data |
| REACH 1907/2006 | Chemical safety and SVHC thresholds | Lot-level safety data sheet and substance declarations |
| RoHS 2011/65/EU | Restricted substances in electrical and electronic equipment | Supply-chain material declarations |
In pails and rigid food containers, the narrow MWD contributes to reduced warpage after demolding and more uniform top-load performance. Mold-fill simulations should be calibrated with capillary rheometry data because the narrow distribution can shift the transition from shear thinning to Newtonian plateau. Hot-runner valve-gate tools require verification of gate vestige and additive migration before production of food-contact articles; published data for this specific configuration is limited when multi-cavity hot-runner systems exceed 16 gates.
For closures and caps, the balance between flow and impact resistance is controlled by melt temperature and mold cooling rate. In production-scale molds with conformal cooling, mold temperatures near 30–40 °C improve dimensional repeatability. Lower mold temperatures below 15 °C can reduce gloss and create anisotropic skin layers with reduced notched impact. The narrow MWD makes the material less tolerant of abrupt gate velocity changes, so valve-gate opening profiles should be tuned to prevent jetting in thin-wall cap skirts.