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LyondellBasell HDPE L5840AS

    • Product Name: LyondellBasell HDPE L5840AS
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 882936
    Density 0.958 g/cm3
    Melt Flow Rate 0.35 g/10 min (190°C/2.16 kg)
    Tensile Strength At Yield 26 MPa
    Tensile Strength At Break 33 MPa
    Elongation At Yield 9%
    Elongation At Break 600%
    Flexural Modulus 1200 MPa
    Notched Charpy Impact Strength At 23 C 10 kJ/m2
    Vicat Softening Point 128 °C
    Brittleness Temperature -70 °C
    Hardness Shore D 65
    Environmental Stress Crack Resistance >1000 h
    Melting Point 133 °C
    Water Absorption 0.01%

    As an accredited LyondellBasell HDPE L5840AS factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing LyondellBasell HDPE L5840AS is supplied in 25 kg polyethylene bags and 1,000 kg bulk bags for industrial use.
    Container Loading (20′ FCL) A 20-foot FCL container loaded with LyondellBasell HDPE L5840AS high-density polyethylene resin, securely palletized for ocean transport.
    Shipping LyondellBasell HDPE L5840AS is a non-hazardous high-density polyethylene resin, not regulated for transport under DOT/IMDG/IATA. It is shipped palletized in 25 kg PE bags or bulk boxes, stretch-wrapped, in clean, dry, covered containers. Avoid moisture, sunlight, heat, and contamination. Follow local rules and SDS.
    Storage Store LyondellBasell HDPE L5840AS in original, sealed containers in a cool, dry, well-ventilated area, away from direct sunlight, heat, sparks, flames, and strong oxidizers. Keep closed to prevent moisture, dust, and contamination. Avoid prolonged UV exposure; use first-in, first-out. Maintain good housekeeping to prevent pellet/dust accumulation. Ensure pallets are stable and protected from physical damage. Follow manufacturer’s SDS and local regulations.
    Shelf Life Shelf life is typically 24 months from production when stored in unopened original packaging, dry, cool, and away from direct sunlight.
    Application of LyondellBasell HDPE L5840AS

    Industrial crate and returnable logistics container production based on LyondellBasell HDPE L5840AS operates inside a narrow interaction between melt flow stability and the antistatic package incorporated in the pellet. On a reciprocating screw injection unit with a screw L/D of 20:1 and a compression ratio of 2.0:1–2.5:1, the barrel profile is normally set at 210 °C, 220 °C, 230 °C, and 240 °C across four zones, while the mold coolant supply is maintained between 10 °C and 20 °C through a central chiller circuit. These conditions prevent post-mold crystallization from producing sink marks on rib-to-wall intersections and maintain the ejection force low enough for automated takeout robots on cycle times of 18–35 s for crate sidewall thicknesses of 2.0–4.5 mm. The formulation is ordinarily 97–100 wt% L5840AS; when a polyolefin color masterbatch is required, it is metered gravimetrically at the machine throat at 1.0–3.0 wt%, and closed-loop post-industrial regrind is capped at 20 wt% because higher regrind fractions increase melt flow drift and reduce notched impact strength measured under ISO 179-1:2010. For food-transport crates intended for bread, vegetables, or dairy collection, compliance is documented under EU Regulation 10/2011 and FDA 21 CFR 177.1520 for olefin polymers; for non-food returnable logistics crates, material documentation is maintained under REACH 1907/2006 Article 33 and, where electrical or electronic components are inserted, under RoHS 2011/65/EU. Terminal products in this segment include stackable vegetable crates, bakery trays, distribution totes, and automotive parts bins. Production-scale failure modes observed on multi-cavity crate tools include gas tracks at the gate land when injection velocity exceeds 250 mm/s, and part-to-part weight variation above 0.8% when check-ring wear is not detected by cushion control.

    Because L5840AS is supplied with an antistatic package, dust attraction on molded crates is reduced without post-mold dipping in an external antistatic solution. The surface effect is generally sufficient for closed-loop returnable handling, but it is not a substitute for conductive carbon black compounds where surface resistivity below 109 Ω is required by the application. At relative humidity above 60%, moisture condensation on pellet surfaces can create splay in thick-walled sections; pre-drying at 80 °C for 2 h is applied only when splay is detected, because HDPE does not require routine drying. Crate molds with textured sidewalls should use draft angles of at least 2° per side; smooth-wall molds may operate at 1° with forced ejection. The use of silicone-based external mold release is not recommended because it transfers to the molded surface and interferes with inkjet date coding and label adhesion.

    Does Hot-Runner Gate Geometry Restrict Closure Torque Retention in L5840AS?

    Closure manufacturing with L5840AS is concentrated in high-cavitation tools where gate diameter, valve pin timing, hold pressure, and cooling time interact to determine skirt ovality, tamper-evident band hinge integrity, and removal torque after shipment. In a 48-cavity hot-runner tool with sequential valve gates, the melt entering the cap disk is held at 230–250 °C with an injection speed of 180–320 mm/s; hold pressure is typically 55–75 MPa for a cap skirt thickness of 1.2–1.8 mm. Lower hold pressure produces sink marks on the gate-side surface; higher hold pressure increases hot-runner gate stress and can cause gate stringing during valve pin retraction. The formulation uses 96–99 wt% L5840AS with 1.0–2.5 wt% color masterbatch and, where opening torque must be reduced, 0.5–1.0 wt% slip/anti-block masterbatch. The masterbatch carrier must be a certified HDPE or LLDPE carrier to avoid phase separation in the cap wall; any polypropylene-based masterbatch carrier above 1 wt% can generate visible flow marks and should be avoided. For food-contact carbonated soft drink, bottled water, dairy, and edible oil closures, the compound must meet FDA 21 CFR 177.1520 and EU Regulation 10/2011, with converter documentation maintained under Regulation EC 2023/2006 good manufacturing practice. Migration testing is conducted under EN 1186-1 with simulant selection controlled by food type; overall migration must remain below 10 mg/dm² under the intended contact time and temperature.

    The slip additive migration from the cap wall to the surface proceeds by diffusion in the semicrystalline HDPE matrix. At mold temperature below 15 °C, rapid cooling reduces surface migration and can increase opening torque during the first 48 h after molding; at mold temperature above 30 °C, cycle time lengthens and the cap skirt can develop radial warpage that prevents reliable application torque. Production-scale experience on closure lines shows that short shots appear when injection velocity drops below 200 mm/s on a 1.2 mm skirt, while jetting can occur above 320 mm/s if the gate land is shorter than 0.5 mm. Post-mold cooling is performed in stacks or bulk hoppers at 20–30 °C; closure torque testing is carried out after 24 h conditioning at 23 °C and 50% RH because polyolefin properties evolve during crystallization. Terminal products include tamper-evident caps for still water, carbonated soft drinks, dairy beverages, and edible oil bottles. The gate diameter is typically 0.6–0.9 mm for non-venting hot-runner tips, and the nozzle tip should be thermally isolated from the cold mold steel by a clearance of 0.1 mm to prevent gate freeze-off during cavity change operations.

    Closure molding variableControl window for L5840ASMeasurement instrument or reference
    Barrel zone 1–4210/220/230/240 °CImmersion pyrometer check at screw recovery
    Mold coolant supply15–30 °CCentral chiller and flow meter
    Injection speed180–320 mm/sMachine linear speed transducer
    Hold pressure55–75 MPaHydraulic pressure transducer with cushion control
    Hot-runner valve pin delay0.2–0.5 sSequence timer synchronized to injection profile
    Cycle time3.2–6.0 sRobotic takeout and mold safe signal

    Thin-wall food packaging tools running L5840AS are specified when wall stock falls between 0.45 mm and 0.90 mm and demolding must occur without vacuum-break deformation on the rim. In an accumulator-assisted injection unit with injection velocities above 250 mm/s, the material fills a 4- or 8-cavity mold at a barrel temperature of 220–240 °C; the mold is held at 10–15 °C to establish a frozen skin quickly enough to prevent penetration of the rim. Cycle time for a 0.6 mm sidewall cup is determined by cooling time at 2.8–5.0 s, while hold pressure is 40–60 MPa; above 60 MPa, core deflection becomes visible as sidewall thickness variation. The formulation uses 92–97 wt% L5840AS for white or translucent applications, with 3–5 wt% TiO₂-based white masterbatch, 0.5–1.0 wt% processing aid if jetting occurs, and up to 25 wt% in-house regrind that is generated and reused under the same food-contact quality agreement. For non-food thin-wall containers, regrind can reach 35 wt% if melt flow is monitored against ISO 1133-1:2022 and the melt flow rate does not drift more than 0.5 g/10 min from the incoming virgin material.

    EU Regulation 10/2011 requires overall migration below 10 mg/dm² under the intended contact time and temperature; U.S. submissions cite FDA 21 CFR 177.1520 for olefin polymers. The processing plant must maintain lot-level control of regrind contamination because PVC or PET tramp material at 0.1 wt% forms incompatible melt phases and weakens the sidewall. Production-scale equipment behavior in thin-wall tools shows that short shots occur when injection velocity drops below 220 mm/s on a 0.50 mm wall, and rim flash appears when vent depth exceeds 0.02 mm or when cavity pressure exceeds 60 MPa. Mold release pressure increases when demolding draft is below 0.5° per side; air ejection through a porous steel core or poppet valve is preferred over mechanical stripping to avoid rim cracks. Terminal products include yogurt cups, margarine tubs, ice cream containers, and single-serve portion cups with fill-and-seal lidding. The major in-cavity defect is cosmetic flow mark at the sidewall opposite the gate; this is controlled by raising the mold temperature locally to 20 °C only at the gate insert, while the rest of the cavity remains at 10 °C to protect cycle time.

    When Snap-Fit Undercut Release and Surface Scuffing Limit Household Storage Bin Output

    Household storage bin production with L5840AS commonly uses cam-action or hydraulic lifters to release snap-fit undercuts; tooling should incorporate a minimum 0.5 mm clearance for the snap feature during mold opening, otherwise ejection increases sidewall scuffing at cycle speeds above 8 shots/min. The melt temperature for these bins sits at 210–230 °C, with mold temperature 15–25 °C, and the shot size is normally 200–800 g. The formulation is 97–100 wt% L5840AS; a polyolefin color masterbatch is added at 1–4 wt%, and post-industrial regrind is capped at 25 wt% to avoid impact loss measured under ISO 179-1:2010. The product must comply with REACH 1907/2006 Article 33 for SVHC communication and, when intended for child-accessible storage, the manufacturer should apply the physical and mechanical testing concepts of EN 71-1 only for toy function, not for general household storage. Terminal output includes stackable storage totes, drawer organizers, shelf bins, and modular wardrobe components. At relative humidity above 60%, surface moisture can produce splay on large flat surfaces; pre-drying at 80 °C for 2 h is applied only when splay is observed, because HDPE does not require routine drying.

    Silicone-based external mold release is not recommended because it transfers to the molded surface and interferes with label adhesion and hot-stamping. The main production bottleneck is not fill pressure but ejection speed: snap-fit undercuts with sharp corners of 0.2 mm radius concentrate stress during demolding, producing microcracks that are not visible until side flexure occurs during use. This failure mode is reduced by designing the undercut with a 0.5 mm radius and by timing the lifter actuation at 0.2–0.5 s after mold opening, rather than simultaneously with platen retraction. Published data for L5840AS under high-speed household tooling with multiple undercuts is limited; validation on the actual tool is required when cycle time is below 10 s.

    Pallet Molding Window, Regrind Fraction, and Racking Load Compliance

    Pallets molded from L5840AS are run on injection molding machines with clamp force 2000–4000 tonnes, shot weights of 10–30 kg, and multiple hot-runner valve gates operated sequentially. The barrel feed throat is set at 200–210 °C, middle zones at 220–240 °C, and the mold at 10–25 °C; hold pressure is 60–90 MPa at the gate to control sink marks around the runner boss. Cycle time for a 15 kg pallet is normally 60–120 s depending on wall section and cooling channel layout. The formulation uses 70–100 wt% L5840AS depending on recycled HDPE content; post-industrial or post-consumer recyclate can be incorporated at 0–30 wt%, with an antioxidant masterbatch added at 0.5–1.0 wt% and color masterbatch at 1–2 wt%. If recycled fraction exceeds 20 wt%, the compound must be evaluated for melt flow shift according to ISO 1133-1:2022 and for notched impact strength under ISO 179-1:2010. Published data for L5840AS compounded with more than 30 wt% post-consumer HDPE under full-pallet geometry is limited; validation on the actual tool is required before release for racking application.

    Industrial pallets are tested under ISO 8611-1:2021 for flat pallets; racking load deflection is measured after 24 h conditioning at 23 °C and 50% RH. Export pallets must comply with ISPM 15 for heat treatment if wood components are included; for plastic pallets, REACH 1907/2006 restrictions apply to recycled content. Food contact pallets require EU Regulation 10/2011 if direct contact with unwrapped food occurs, but many logistics pallets are not direct-contact. Terminal products include rackable export pallets, hygienic pooling pallets, and distribution center pallets with RFID-molded pockets. Sequential valve gating is used because melt fronts from multiple gates meet at the center of the pallet; if the melt front temperature drops below 210 °C, the weld line becomes visible as a hairline crack under 750 kg racking load. The valve gating sequence is programmed with a delay of 0.3–0.8 s between gates to direct air traps toward the perimeter vents; vent depth 0.01–0.03 mm prevents gas burn marks without flash. Post-molding shrinkage of 0.8–1.5% is compensated by tool dimensioning based on ISO 294-1:2017 specimen shrinkage measurements. The primary production bottleneck on high-tonnage machines is plasticating capacity; a screw L/D of 20:1–24:1 with a compression ratio of 2.0:1–2.5:1 is required to achieve uniform melt temperature across the whole shot, and recovery time must remain below the cooling time to avoid cycle extension.

    Post-mold warpage in pallet decks is controlled by matched mold cooling and by leaving the pallet in a cooling fixture for 2–5 min after demolding. If the pallet is ejected too early, the residual heat in the thick runner boss produces a localized sink depth above 0.3 mm, which is detectable under oblique light and can affect pallet flatness during automatic storage and retrieval. For freezer-rated logistics pallets, notched impact testing should be conducted at −20 °C under ISO 179-1:2010 because HDPE impact performance changes with temperature. The antistatic property of L5840AS reduces dust accumulation on pallet decks in dry warehouses, but it does not provide protection against electrostatic discharge where an explicit conductive path is required; for that application, a conductive HDPE compound with surface resistivity below 106 Ω must be selected instead.

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    Certification & Compliance
    More Introduction

    LyondellBasell HDPE L5840AS is a high-density polyethylene grade supplied in pellet form for rigid packaging, blow molding, profile extrusion, and technical parts. The grade identity is defined by the producer’s technical bulletin and lot-specific certificate of analysis; primary specification methods include ISO 1183-1 for density, ISO 1133-1 for melt mass-flow rate at 190 °C and 2.16 kg, ISO 527-2 for tensile yield stress and elongation at break, ISO 179-1/1eA for notched Charpy impact, ISO 306/A50 for Vicat softening temperature, ASTM D1693-B for environmental stress-crack resistance, and ISO 11357-6 for oxidation induction time. Carbon-black-containing lots, when supplied, are additionally tested under ISO 6964 for carbon black content and ISO 3451-1 for ash. No single nominal value should be substituted for the lot certificate, because stabilizer type, molecular weight distribution, and comonomer content are adjusted within the product specification window.

    In storage and material handling, condensation on cold pellets can produce feed fluctuations and melt pressure variation when the surrounding air exceeds 60% relative humidity or when pellets are transferred from outdoor silos into a heated processing hall. Production-scale lines address this with hopper heaters and, when needed, predrying at 80 °C for 2 h to 4 h in desiccant dryers. Residence time above 220 °C is avoided because oxidative degradation raises melt flow rate and lowers environmental stress-crack resistance, even when initial oxidation induction time on the certificate is acceptable.

    PropertyTest methodFunctional relevanceControl basis
    DensityISO 1183-1Stiffness, barrier, shrinkageLot certificate
    Melt mass-flow rateISO 1133-1, 190 °C/2.16 kgMelt viscosity and molecular weight indicatorLot certificate
    Tensile yield stress and elongationISO 527-2Short-term deformation resistanceLot certificate
    Notched Charpy impactISO 179-1/1eADuctile-to-brittle responseLot certificate
    Vicat softening temperatureISO 306/A50Short-term thermal resistanceLot certificate
    Environmental stress-crack resistanceASTM D1693-B, 50 °C, 10% IgepalChemical contact and residual stress resistanceApplication specification
    Oxidation induction timeISO 11357-6Stabilizer package levelLot certificate
    Carbon black contentISO 6964UV weathering resistanceWhere carbon-black lot is supplied

    What processing rheology separates this grade from lower-molecular-weight HDPE?

    Melt mass-flow rate under ISO 1133-1 is an inverse indicator of average molecular weight. High-molecular-weight HDPE grades used in blow molding and large-part extrusion typically exhibit MFR values at 190 °C/2.16 kg in the range of 0.2 g/10 min to 0.8 g/10 min, while injection-molding grades often exceed 10 g/10 min. HDPE L5840AS is positioned in the low-flow segment of the portfolio; the exact value is stated on the lot certificate. The lower MFR corresponds to higher zero-shear viscosity and stronger parison sag resistance. Capillary rheometry at 190 °C shows pronounced shear thinning: a broad molecular weight distribution reduces apparent viscosity at the high shear rates generated in screw channels and die gaps, while high elongational viscosity stabilizes the parison wall between die exit and mold closure.

    On single-screw extruders with barrier screws of 24:1 to 33:1 L/D, the practical consequence is that head pressure and motor load are controlled by screw speed and temperature profile rather than by high melt flow. Melt temperature settings for this viscosity class are commonly profiled from 180 °C at the feed throat to 210 °C at the die head. Die temperatures above 220 °C accelerate surface oxidation and reduce melt strength. Die swell in high-molecular-weight HDPE can range from 30% to 60% depending on tooling, output, and shear history; the die gap must therefore be sized below the intended final wall thickness to compensate for swell and subsequent parison drawdown.

    Compared with lower-molecular-weight HDPE grades, HDPE L5840AS has shorter linear melt flow length in injection-style flows. It is not recommended for thin-wall injection molding below 1 mm nominal wall thickness without gate, runner, and pressure-drop analysis. Thick technical parts may be injection molded, but clamp force requirements increase with the higher melt viscosity. The distinction is between high-extensional-viscosity forming processes and high-shear injection filling: HDPE L5840AS is adapted to the former, not the latter, unless the application specification explicitly validates thin-wall performance.

    Large blow-molded containers for agrochemicals, detergents, and water-based formulations represent typical conversion routes for resins in this viscosity class. On shuttle blow molders with 40 mm to 90 mm extruder screw diameter and accumulator heads, parison programming compensates for gravitational drawdown. Wall thickness distribution is dominated by die gap profiling, pre-blow timing, and clamp speed. Mold temperatures between 10 °C and 25 °C are commonly used to stabilize part geometry. When mold surface temperature exceeds 25 °C, cycle time increases and post-ejection shrinkage becomes anisotropic. Pinch-off weld integrity is influenced by melt temperature, clamp tonnage, and tool wear; low melt temperature can produce incomplete squeeze-out at the pinch line, while overheated melt reduces the mechanical strength of the welded zone.

    Extruded sheet and thermoforming lines also process this grade where stiffness and chemical resistance dominate. Sheet lines with 75 mm to 150 mm single-screw extruders and gear pumps deliver melt at 190 °C to 210 °C; polished roll stacks are operated between 60 °C and 90 °C depending on sheet thickness and surface gloss. Thermoforming requires uniform sheet temperature; infrared heating systems target core surface temperatures near 160 °C to 180 °C. Local overheating above 200 °C can initiate oxidative surface defects and reduce finished-part impact properties.

    When ESCR and slow crack growth control shelf-life

    Chemical compatibility of HDPE L5840AS with aggressive or polar liquids is not inferred from density or MFR alone. Environmental stress-crack resistance is measured under ASTM D1693-B using 10% Igepal CO-630 at 50 °C; some specifications use 100% Igepal or notched constant tensile load procedures under ISO 16770. The test is probabilistic: failure time is reported as F50 and F20 values, and the same polymer lot can show different ranking when the stress state changes from molded-in residual stress to external tensile load. Slow crack growth in high-density polyethylene is governed by tie-molecule concentration, lamellar thickness distribution, and crystallinity; molecular architecture is therefore a more sensitive differentiator than MFR alone.

    Compared with conventional high-flow HDPE grades, HDPE L5840AS is selected where stress cracking induced by cap torque, internal pressure, or deflected sidewalls is a known failure mode. The grade is not a substitute for fluorinated containers or barrier-layer structures when aromatic hydrocarbons or strong oxidizing agents are present; high-density polyethylene has well-known permeation and swelling limits under ISO 175. Published data for this specific configuration is limited, so compatibility testing under the intended storage conditions is required.

    For mechanical design, short-term tensile yield stress and flexural modulus are associated with density. High-density polyethylene resins in the 0.950 g/cm³ to 0.960 g/cm³ class typically show tensile yield stresses from 22 MPa to 30 MPa under ISO 527-2 and flexural moduli from 900 MPa to 1400 MPa under ISO 178. These class ranges are not lot-specific product guarantees; the L5840AS certificate of analysis is authoritative. Notched Charpy impact energy under ISO 179-1/1eA at 23 °C is commonly above 10 kJ/m² for HDPE, but the value at -30 °C can fall sharply depending on molecular weight and thermal history. Vicat softening temperature under ISO 306/A50 typically lies near 120 °C to 130 °C for high-density polyethylene; continuous load-bearing service is not defined by Vicat alone.

    Compared with LDPE and linear low-density polyethylene, the higher crystalline fraction of HDPE L5840AS gives lower water vapor transmission under ISO 15106-1 and lower oxygen permeability under ISO 15105-1, at a trade-off of lower elongation at break and reduced low-temperature impact. The density increase from 0.920 g/cm³ to the 0.950 g/cm³ to 0.960 g/cm³ class also raises modulus and top-load capacity. These differences are not linear; they depend on cooling rate and orientation introduced during molding.

    Distinct from pipe-grade HDPE, HDPE L5840AS is not automatically classified as a PE100 material under ISO 12162. Pipe-grade design is based on long-term hydrostatic strength at 20 °C and 80 °C; blow-molding and sheet grades are designed for parison rheology, surface quality, and stress-crack resistance under short-term and intermittent loading. The stabilizer package may also differ: pipe grades generally contain higher levels of hindered phenolic and phosphite antioxidants for extended extrusion and field exposure, while blow-molding grades prioritize color, organoleptics, and ESCR control. Container producers must therefore avoid cross-specifying a pipe-grade HDPE as a direct substitute without verifying the full lot certificate.

    Regrind addition changes rheology and ESCR. In production, closed-loop regrind at 10% to 20% by weight is common, but each pass through the extruder shortens the stabilizer package and increases melt viscosity variability. Above 20% regrind, lot-specific OIT and Charpy impact can drift below the application specification; melt filtration through 60 mesh screens is used to remove carbonized gel particles. The maximum allowable regrind level must be validated on the target blow-molding or sheet line, not transferred from a different grade.

    For food-contact use, the grade must be covered by the supplier’s compliance statement under FDA 21 CFR 177.1520 and EU 10/2011; industrial non-food use is supported by REACH registration. RoHS compliance applies where electrical or electronic equipment components are molded. These compliance statements are grade- and lot-specific; they do not exempt the converter from migration testing under the final article’s conditions of use.

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