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LyondellBasell HDPE L5485

    • Product Name: LyondellBasell HDPE L5485
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 516845
    Density 0.955 g/cm3
    Melt Mass Flow Rate 0.35 g/10 min (190°C/2.16 kg)
    Tensile Strength At Yield 27.6 MPa
    Tensile Strength At Break 24.1 MPa
    Elongation At Break 600%
    Flexural Modulus 1310 MPa
    Notched Izod Impact Strength 53.4 J/m
    Vicat Softening Temperature 126°C
    Melting Temperature 132°C
    Brittleness Temperature -76°C
    Environmental Stress Crack Resistance >1000 h (F50, 100% Igepal)
    Shore D Hardness 66

    As an accredited LyondellBasell HDPE L5485 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing LyondellBasell HDPE L5485 is packaged in 25 kg polyethylene bags or 1,000 kg bulk bags for transport and storage.
    Container Loading (20′ FCL) 20′ FCL loading of LyondellBasell L5485 HDPE: 25 kg bags on pallets, stretch-wrapped, secured in container for safe ocean transport.
    Shipping LyondellBasell HDPE L5485 is typically shipped as non-hazardous polyethylene pellets in 25 kg bags, jumbo bags, or bulk trucks/railcars. Keep packaging sealed and dry, away from heat, sunlight, and ignition sources. Not classified as dangerous goods; follow local transport regulations and avoid contamination.
    Storage Store LyondellBasell HDPE L5485 in a cool, dry, well-ventilated area in closed original containers. Protect from direct sunlight, moisture, dust, and contaminants. Keep away from heat, sparks, flames, and strong oxidizers. Avoid prolonged UV exposure. Store at ambient temperature, preferably below 50°C. Use first-in, first-out rotation, clean handling, and keep containers sealed and pallets off the floor.
    Shelf Life Store dry, cool, well-ventilated, away from sunlight; LyondellBasell HDPE L5485 has a recommended shelf life of 12 months from delivery.
    Application of LyondellBasell HDPE L5485

    In direct food-contact rigid packaging, LyondellBasell HDPE L5485 is specified on the basis of a nominal density of 0.954 g/cm³ (ASTM D1505) and a melt flow rate of 5.2 g/10 min at 190 °C/2.16 kg (ASTM D1238-23a). Compliance under FDA 21 CFR 177.1520(c) 3.2 covers olefin polymers used with aqueous, acidic, and fatty foods. Under Regulation (EU) No 10/2011 Annex I, the overall migration limit is 10 mg/dm², while specific migration limits for additives remain controlling. The following matrix consolidates the compliance boundary before formulation and processing parameters are introduced.

    United States21 CFR 177.1520(c) 3.2High-density olefin polymers for aqueous, acidic, and fatty food-contact use
    European UnionRegulation (EU) No 10/2011 Annex IOverall migration limit 10 mg/dm²; specific migration limits for positive-list additives
    European UnionRegulation (EC) No 2023/2006Good manufacturing practice for food-contact materials
    United States21 CFR 178.3297Colorants for polymers used in food-contact applications

    Formulation addition levels within the food-contact boundary are set by carrier resin compatibility and additive migration behavior. FDA-compliant color concentrate is introduced at 0.5–1.5 wt% for tub wall thicknesses below 1.0 mm and at 1.0–2.0 wt% for pail sidewalls above 1.8 mm. A slip and antiblock masterbatch containing 10 wt% erucamide is dosed at 0.2–0.5 wt%, yielding an active erucamide level of 0.02–0.05 wt% in the final melt. Active erucamide above 0.08 wt% lowers lid seal friction below assembly torque requirements and promotes core plate-out on extended production runs. Post-industrial regrind from the same food-contact compound may be reintroduced up to 30 wt% when the melt flow rate shift measured by ASTM D1238-23a remains within 0.5 g/10 min of virgin lots.

    Processing on reciprocating-screw injection molding machines with screw L/D of 20:1 to 24:1 and compression ratio of 2.2:1 to 2.5:1 uses rear-zone temperatures of 180 °C, center zones of 195–205 °C, front zones of 210–220 °C, and nozzle settings of 200–220 °C. Mold temperature is held at 10–30 °C with turbulent cooling channels to limit warpage in thin-walled tubs. Hold pressure below 45 MPa on thick pail bosses creates visible sink marks, while melt temperatures above 230 °C increase odor generation and yellowing in fatty-food pails. Injection velocity is set at 80–120 mm/s for flow lengths up to 150 mm at wall thickness 0.6 mm to prevent short shots on high-speed multi-cavity lines cycling above 12 shots/min. Terminal products include 1–5 L sauce and dairy pails, 150–500 mL snap-lid tubs, deli container bodies, and tamper-evident lid systems used in chilled distribution.

    What Conditions Govern Multi-Cavity Closure Molding for Non-Carbonated Beverage Systems?

    Closure skirts produced from HDPE L5485 are typically molded in 38 mm and 43 mm tamper-evident configurations for non-carbonated dairy, juice, and spoonable dressing systems. The compliance framework is FDA 21 CFR 177.1520(c) 3.2 and Regulation (EU) No 10/2011, supplemented by Regulation (EC) No 1935/2004 for overall food-contact safety. ISO 8317:2015 applies only when the closure is marketed as child-resistant; for standard beverage closures it does not govern. Supplier declarations of compliance must cover the slip additive, color concentrate, and any processing aid introduced in the mold.

    Slip addition in closure molding is controlled within a narrow band. A 10 wt% erucamide masterbatch is dosed at 0.2–0.5 wt%, equivalent to 0.02–0.05 wt% active erucamide. At active erucamide above 0.08 wt%, removal torque on 38 mm skirts falls below 1.0 N·m, and the migrated slip film on core surfaces causes ejection friction and tamper-band deformation. Color concentrate is introduced at 0.4–1.2 wt%. Formulations that omit slip entirely produce removal torque above 3.5 N·m and stress-whitening at the tamper band. This grade is not recommended for carbonated soft-drink closures because top-load and pressure-retaining sealing requirements are outside the specification envelope of the material.

    Production-scale closure tools with 32 to 64 cavities require valve-gated hot runners or direct-gated cold runners with melt temperature held at 204–215 °C. Mold temperature is set at 8–15 °C to reduce cycle time to 5–8 s for closures weighing 2.0–3.5 g. Injection pressure at transfer is 70–90 MPa, hold pressure 40–60 MPa, and injection velocity 80–120 mm/s. Velocity reductions below 40 mm/s during filling of the tamper-band hinge cause short shots and inconsistent band elongation. If melt temperature exceeds 220 °C, longitudinal molecular orientation in the hinge region is reduced and the tamper-evident band fails during capping. Terminal products include 38 mm dairy cap shells, 43 mm sauce and dressing caps, overcaps for dry food canisters, dispensing flip-top caps, and measuring cup closures for liquid household chemicals.

    When an open-top industrial pail is certified for dangerous goods transport, the resin must demonstrate sufficient environmental stress crack resistance after passing UN 3H2 performance tests, including stack loading at 40 °C for 28 days and drop impact after conditioning. The compliance chain includes UN Model Regulations Chapter 6.1, ADR/RID Chapter 6.1, and IMDG Code Chapter 6.1 for open-top plastic jerricans. A packaging group II test program is frequently referenced for chemical fillings up to 1.5 kg/L relative density.

    Formulation for industrial pails differs from food-grade pail molding because external weathering and chemical exposure dominate. UV-stabilized color masterbatch is added at 0.6–1.2 wt%, carbon black masterbatch at 2.0–2.5 wt% for outdoor or abrasive chemical service, and antioxidant masterbatch at 0.2–0.5 wt%. Slip additives are omitted or held below 0.1 wt% because lid engagement and gasket sealing under stack load are more critical than surface slip. Post-industrial regrind is limited to 25 wt%; higher regrind levels introduce label adhesive, oil contamination, and low-molecular-weight fractions that produce pinholing near pail handles.

    On production lines using 1,200–1,500 t clamp force machines, open-top pails of 20 L shot weight 1.2–2.5 kg are molded with barrel rear-zone temperature 180 °C, mid-zone 195–205 °C, front-zone 210–220 °C, and nozzle 220 °C. Mold temperature is held at 10–25 °C, hold pressure at 50–70 MPa, injection pressure at 90–110 MPa, and cooling time at 20–35 s. If surface moisture is present on regrind stored at RH above 60%, a pre-drying step at 70 °C for 1–2 h is required to prevent splay on the pail sidewall. Screw speed is limited to 50–80 rpm to avoid excessive shear heating that raises melt temperature above 230 °C and creates yellowing near the sprue. Terminal products include 5 L, 10 L, 20 L, and 25 L open-top pails for water-based coatings, adhesives, inks, textile dyes, pool chemicals, and concentrated detergent intermediates.

    Returnable Crate and Logistics Container Molding with L5485 Under High-Regrind Supply Chains

    Returnable transport packaging exposes the material to both sub-zero impact and repeated sanitization cycles. The compliance baseline is REACH Regulation (EC) No 1907/2006 Annex XVII, RoHS Directive 2011/65/EU where electronic waste handling is involved, and the CONEG heavy-metal limit of 100 ppm total lead, mercury, cadmium, and hexavalent chromium for packaging. For direct food-contact bakery trays and dairy crates, FDA 21 CFR 177.1520(c) 3.2 and Regulation (EU) No 10/2011 apply.

    Color-coded crate production uses 0.5–2.0 wt% color concentrate, 0.5–1.0 wt% HALS and UV stabilizer masterbatch, and 0.2–0.5 wt% antioxidant masterbatch. Regrind is introduced at 20–40 wt%, but the high-flow character of L5485 requires lot-specific melt flow rate comparison against virgin resin. If melt flow rate increases more than 0.8 g/10 min, impact strength in corner gussets falls below the threshold for drop impact at -20 °C. Foaming agents and gas-assisted molding are avoided because the melt strength of this grade is insufficient for uniform cell structure.

    Conventional injection molding for crates uses wall thicknesses of 2.5–4.0 mm, melt temperature 200–215 °C, mold temperature 15–25 °C, hold pressure 40–60 MPa, and cooling time 25–40 s. Sequential valve gating on hot runners controls weld lines around corner ribs; linear injection velocity is 60–100 mm/s. In high-cavity stack molds, clamp force requirements range from 8,000 kN to 12,000 kN. When regrind exceeds 40 wt%, the processing window narrows because reduced molecular weight lowers melt viscosity and promotes flash at the parting line. Quantitative drop-impact data for L5485 at 40 wt% regrind in thin-wall ventilation ribs are limited in public datasheets; processor qualification should therefore include notched Izod and multi-axial impact tests on production-representative plaques. Terminal products include nestable dairy crates, beverage distribution trays, collapsible pallet boxes, ventilated agricultural harvest crates, and bakery stacking trays for automated warehouse systems.

    When Child-Resistant Pharmaceutical Closures Are Molded with HDPE L5485 and Long Flow Paths

    Child-resistant pharmaceutical closures and dosing cups require additive selection that permits the closure to pass ISO 8317:2015 senior-adult and child-resistant panel tests while remaining compliant with FDA 21 CFR 177.1520 and USP <661.1> for plastic packaging systems used with oral dosage forms. The European pharmacopoeial framework for polyolefin packaging, including Ph. Eur. monograph 3.1.5, is applied where the closure is part of a drug product dossier.

    Color concentrate is limited to 0.2–0.8 wt% and must be PE-carrier based to avoid affecting torque retention. Slip additives are either omitted or added at 0.05–0.1 wt% final active concentration. Higher slip levels compromise child-resistant push-turn or squeeze-turn mechanisms by reducing the coefficient of friction below the design assumption. Organic peroxide processing aids and silicone-based additives are not introduced where they might alter USP <661.1> extractables.

    Closure tooling uses 16 to 48 cavities, valve-gated hot runners, and melt temperatures of 195–215 °C. Mold temperature is 10–20 °C. For a 1.5–2.5 g closure, injection velocity is set at 60–100 mm/s, hold pressure at 50–70 MPa, and cooling time at 6–10 s. Long flow paths across the child-resistant engagement teeth require packing pressure maintained for 2–3 s after velocity-to-pressure transfer. If packing is removed too early, the teeth shrink unevenly and removal torque falls outside the 1.5–3.0 N·m specification window after accelerated aging at 40 °C/75% RH for 6 months. Terminal products include 28 mm and 33 mm child-resistant caps for solid oral dose bottles, graduated dosing cups of 10–30 mL, and closure shells for pediatric liquid formulations.

    Housewares and Appliance Component Edge-Case Behavior

    Housewares and appliance interior parts formed from L5485 are governed by REACH Regulation (EC) No 1907/2006 Annex XVII and, for children’s storage items marketed as toys, EN 71-3 migration limits for specific elements; food-contact kitchenware falls under Regulation (EU) No 10/2011 and FDA 21 CFR 177.1520. Color concentrate is added at 0.5–1.5 wt%, antistatic masterbatch at 0.5–1.0 wt% for dust-sensitive appliance housings, and antioxidant masterbatch at 0.2–0.4 wt%. Production uses melt temperatures of 190–210 °C, mold temperatures of 15–25 °C, hold pressures of 35–55 MPa, and wall thicknesses of 1.2–2.5 mm; terminal products include storage bins, waste containers, refrigerator shelf brackets, detergent dispenser housings, and appliance kick plates.

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    Certification & Compliance
    More Introduction

    LyondellBasell HDPE L5485 is a high-molecular-weight high-density polyethylene grade classified within the extrusion blow molding segment. Published datasheet values place the nominal density at 0.956 g/cm³ when measured according to ISO 1183-1, with a melt mass-flow rate of 0.45 g/10 min under 190 °C and 2.16 kg load using ISO 1133-1. That low melt flow rate indicates a high average molecular weight and a melt viscosity that is oriented toward parison stability, melt strength, and slow crack growth resistance rather than high-speed injection mold filling. The resin is used on accumulator-head blow molding lines for automotive fuel tanks, 220 L drums, intermediate bulk container liners, and agricultural or industrial packaging in which environmental stress cracking is a principal service failure mode. The grade is supplied as pelletized product, and the values presented here are typical starting data rather than contractual specification limits; the current LyondellBasell technical data sheet and lot-specific certificate of analysis remain the controlling documents.

    The molecular architecture of HDPE L5485 is not fully described in all public summaries, but the grade occupies the high-molecular-weight HDPE category. Tensile data obtained under ISO 527-1/-2 at 50 mm/min typically indicate a tensile stress at yield near 25 MPa and a tensile modulus near 1300 MPa. These values reflect the moderate crystallinity associated with a density of 0.956 g/cm³ and place the material above linear-low-density polyethylene in stiffness while retaining greater strain capacity than highly crystalline injection molding HDPE homopolymers with densities above 0.960 g/cm³. At the nominal density, a two-phase density model using 0.855 g/cm³ for amorphous polyethylene and 1.000 g/cm³ for crystalline polyethylene gives a crystalline volume fraction near 0.70, which is consistent with the observed modulus and barrier behavior.

    Impact resistance is a central selection criterion for this product class. Typical Charpy notched impact values under ISO 179-1/1eA are reported near 22 kJ/m² at 23 °C and near 12 kJ/m² at -30 °C. These low-temperature values support cold-climate handling of large drums and fuel tank drop tests. Long-term stress crack resistance under ASTM D1693 Condition B, 10 % Igepal CO-630, 50 °C, typically exceeds 1000 h for the neat resin. This is the main differentiating factor against lower-molecular-weight HDPE blow molding grades that may fall below 100 h in the same test. Because ASTM D1693 data are subject to high scatter, structural parts in contact with surfactant solutions, fuels, or oxidizing formulations are frequently qualified using ISO 16770 or full-container stress cracking trials under end-use chemical and pressure conditions.

    When Does L5485 Replace a General-Purpose HDPE Blow Molding Resin?

    The substitution is justified primarily when containers fail by environmental stress cracking or low-temperature impact rather than by simple yield-strength overload. General-purpose HDPE blow molding grades with similar density but melt flow rates of 1.0 to 3.0 g/10 min usually process at lower head pressure and may permit shorter cycle times, but their lower average molecular weight reduces resistance to slow crack growth under hoop stress and aggressive fluids. HDPE L5485 is selected when UN design-type certification under the applicable UN Model Regulations, Chapter 6.1 for single packagings or Chapter 6.5 for intermediate bulk containers, is required. The grade is also selected when stacked drums must pass compression testing under ASTM D642 or drop testing under ASTM D2463, particularly at sub-ambient temperatures.

    Compared with injection molding HDPE grades having melt flow rates above 5 g/10 min, HDPE L5485 has substantially higher melt viscosity and lower cavity-filling ability. It is not appropriate for thin-wall injection molded containers with flow length-to-thickness ratios above 200:1, where filling pressure, shear heating, and orientation-induced warpage become limiting. The product is likewise not a film resin; the high melt viscosity and low melt flow rate reduce drawability on blown film lines, making it unsuitable for thin-gauge packaging film where HDPE grades with melt flow rates of 0.1 to 0.3 g/10 min are commonly used.

    Relative to HDPE pipe grades governed by ISO 9080 or ASTM D2837, HDPE L5485 is not designed for sustained internal pressure at continuous elevated temperatures. Its property set is optimized for intermittent mechanical loading, cold-temperature impact, and chemical contact at ambient or sub-ambient service conditions. In automotive fuel tank construction, the resin is typically used in multilayer coextruded structures with an EVOH or polyamide barrier layer and adhesive tie resins. The HDPE outer and inner layers provide structural integrity, pinch-off weld strength, and ESCR, while the barrier layer controls hydrocarbon permeation under evaporative emission standards such as 40 CFR Part 86 or Euro 6 procedures. The HDPE grade itself does not provide sufficient barrier for low-emission fuel systems without a coexisting barrier layer.

    Chemical resistance follows general high-density polyethylene behavior. The resin shows low water absorption below 0.01 % under ISO 62 at 24 h immersion. It resists many aqueous acids, alkalis, and polar organic solvents at ambient temperature, but compatibility with aromatic or chlorinated hydrocarbons and strongly oxidizing acids must be validated under EN ISO 175 immersion testing. Continuous exposure above 60 °C to concentrated nitric acid, halogens, or strong oxidizers is outside the recommended service envelope unless specific qualification data demonstrate otherwise. For food contact, the resin may be reviewed against FDA 21 CFR 177.1520 for olefin polymers and EU Regulation 10/2011 as amended, provided migration testing is completed on the finished article for the actual food type, contact time, and temperature.

    Rheological Boundaries, Accumulator-Head Machine Conditions, and Part Qualification

    The low melt flow rate of HDPE L5485 requires careful thermal management on production-scale accumulator-head machines. Typical extrusion blow molding operations use single-screw extruders with 25:1 to 30:1 L/D ratios, barrier screws, and grooved feed sections to control high back pressure. Melt temperature measured at the die is normally started between 195 °C and 220 °C, with an initial setpoint near 205 °C for 220 L drum tools. Mold temperature is usually held between 10 °C and 25 °C; higher mold temperatures improve surface gloss but reduce cycle rate by delaying parison pinching and demolding stability.

    At die temperatures below 190 °C, the elevated apparent viscosity at die shear rates of 100 to 1000 s⁻¹ can produce surface roughness, die-lip buildup, and irregular parison edges. Above 230 °C, residence-time-dependent thermo-oxidative chain scission becomes more significant, shifting the melt flow rate upward and reducing ESCR after repeated regrind use. For fuel tank and UN-certified drum applications, melt temperature uniformity is typically controlled within ±5 °C of setpoint at the accumulator head. Batch-to-batch viscosity variation from lot changes can require adjustment of screw speed and accumulator fill pressure; a prequalified lot-change procedure should include a melt flow rate check and a short ESCR confirmation on retained specimens.

    Parison sag is a measurable production bottleneck because high molecular weight increases melt strength but also increases extrusion pressure. Parison programmers with axial wall-thickness step resolution of ≤1 mm are standard on large drum lines. For 220 L tight-head drums, programmed wall thickness commonly ranges from 1.8 mm to 4.5 mm. Excessive thickness above 5.0 mm increases cycle time and material cost without proportional ESCR improvement. Clamp force settings for large tools typically range from 1800 kN to 2500 kN depending on flash area, mold design, and tool deflection. Inadequate clamp force at the parting line produces flash that reduces weld integrity and may prevent the finished container from passing UN drop or stacking tests.

    The following table summarizes typical physical and mechanical values reported for LyondellBasell HDPE L5485 under standard test methods. These values are not lot-specific specification limits and must be confirmed against the supplier’s current product datasheet for production qualification.

    Typical values reported for LyondellBasell HDPE L5485
    Property Test method Typical value Unit
    Density ISO 1183-1 0.956 g/cm³
    Melt mass-flow rate ISO 1133-1, 190 °C, 2.16 kg 0.45 g/10 min
    Tensile stress at yield ISO 527-1/-2 25 MPa
    Tensile strain at yield ISO 527-1/-2 8 %
    Tensile modulus ISO 527-1/-2 1300 MPa
    Charpy notched impact strength, 23 °C ISO 179-1/1eA 22 kJ/m²
    Charpy notched impact strength, -30 °C ISO 179-1/1eA 12 kJ/m²
    Environmental stress crack resistance ASTM D1693 Condition B, 10 % Igepal CO-630, 50 °C >1000 h
    Vicat softening temperature ISO 306 A/50 N 128 °C
    Water absorption, 24 h ISO 62 <0.01 %

    In production, the lower melt flow rate of HDPE L5485 means that screw speed, back pressure, and accumulator fill rate are typically reduced relative to settings used for a 3.0 g/10 min blow molding HDPE. Color or grade changeovers require extended purging because the high-molecular-weight melt retains pigment and regrind in accumulator head dead spots longer than low-viscosity grades. Repeated regrind use above 30 % by mass can shift the melt flow rate and reduce ESCR unless the regrind is dry, uncontaminated, and blended with sufficient virgin resin. Published data for the specific effect of multiple regrind cycles on HDPE L5485 is limited, so each processing plant should establish its own upper regrind limit by testing MFR under ISO 1133-1 and ESCR under ASTM D1693.

    The following starting parameters are used as a reference for accumulator-head extrusion blow molding of large parts from HDPE L5485. They must be adjusted to the actual machine, tool, and part design.

    Starting extrusion blow molding parameters for accumulator-head machines
    Parameter Starting range Unit Measurement method or equipment
    Melt temperature at die 195–220 °C Needle thermocouple at adapter or die entry
    Mold temperature 10–25 °C Mold temperature-control unit
    Blow air pressure 0.5–0.7 MPa Pressure gauge at blow pin
    Parison axial wall resolution ≤1 mm Parison programmer step size
    Screw L/D ratio 25:1–30:1 — Barrier screw with grooved feed section
    Melt temperature setpoint control ±5 °C Closed-loop heater bands and air-cooling zones

    In automotive fuel tank production, the useful comparison point is not merely the tensile property set but the parison behavior in a multilayer head. HDPE L5485 is selected for high melt strength and resistance to pinch-off weld cracking after drop impact. Pinch-off welds are formed under rapid compression of the parison, and contamination, mold release agents, or moisture on the tool surface reduce weld strength. Such defects are detected not by tensile bars but by full-tank impact tests, leak testing, and cyclic pressure testing under the applicable OEM specification. For 220 L drums carrying dangerous goods, resin qualification is only one input; the finished package must pass design-type testing for drop, stacking, leakproofness, and hydraulic pressure as specified in the applicable UN Model Regulations chapter for the package type.

    Unless the current regulatory datasheet states otherwise, HDPE L5485 is not promoted as a direct food-contact material without migration testing on the finished article. It is also not intended for continuous immersion in strong oxidizing acids at elevated temperature, nor for pressurized water piping where hydrostatic design stress under ISO 9080 is the controlling property. The use temperature range for structural parts is bounded at the low end by ductile-to-brittle transition behavior near -30 °C in notched impact testing and at the high end by Vicat softening near 128 °C under ISO 306. For safety-critical applications, end-use testing on the finished container or tank is mandatory because the resin alone cannot represent weld, wall-thickness, or design-dependent performance.

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