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LyondellBasell HDPE L5040TC

    • Product Name: LyondellBasell HDPE L5040TC
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 311052
    Density 0.954 g/cm³
    Melt Flow Rate 190 C 2 16 Kg 0.4 g/10 min
    Melt Flow Rate 190 C 21 6 Kg 10 g/10 min
    Tensile Modulus 1200 MPa
    Tensile Stress At Yield 27 MPa
    Tensile Strain At Yield 9%
    Tensile Stress At Break 30 MPa
    Tensile Strain At Break >600%
    Charpy Notched Impact Strength 23 C 25 kJ/m²
    Charpy Notched Impact Strength 30 C 8 kJ/m²
    Ball Indentation Hardness 50 MPa
    Vicat Softening Temperature A 50 128°C
    Heat Deflection Temperature B 75°C
    Thermal Conductivity 0.4 W/(m·K)
    Coefficient Of Linear Thermal Expansion 1.5E-4 1/K
    Water Absorption <0.01%
    Dielectric Constant 1 Mhz 2.3
    Volume Resistivity >10^15 Ω·cm
    Environmental Stress Cracking Resistance >1000 h
    Oxidation Induction Time >20 min
    Carbon Black Content 2.25%
    Melting Temperature 130°C
    Crystallization Temperature 115°C
    Bulk Density 0.55 g/cm³
    Moisture Content <0.02%

    As an accredited LyondellBasell HDPE L5040TC factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing LyondellBasell HDPE L5040TC is supplied in 25 kg polyethylene bags, typically 55 bags per 1,375 kg pallet.
    Container Loading (20′ FCL) Full 20-foot FCL container loaded with LyondellBasell HDPE L5040TC resin bags, palletized, shrink-wrapped, and secured for ocean transport.
    Shipping LyondellBasell HDPE L5040TC is shipped as non-hazardous polyethylene resin pellets in 25 kg bags, 1,000 kg bulk bags, or bulk trucks/railcars. Standard dry-van, covered truck, or rail hopper transport is suitable. Keep packaging dry, clean, and away from heat, moisture, and contamination. No hazardous-materials placards required. Follow the manufacturer’s SDS and local regulations.
    Storage Store LyondellBasell HDPE L5040TC in a cool, dry, well-ventilated warehouse, preferably on pallets, away from direct sunlight, heat, sparks, flames, and incompatible materials. Keep original packaging closed to prevent moisture, dust, and contamination. Follow first-in, first-out rotation. Avoid prolonged UV exposure and excessive stacking. No special temperature control is normally required.
    Shelf Life LyondellBasell HDPE L5040TC typically has a two-year shelf life when stored unopened in dry, cool, ventilated conditions away from direct sunlight.
    Application of LyondellBasell HDPE L5040TC

    LyondellBasell HDPE L5040TC enters downstream conversion with a melt flow rate of 0.40 g/10 min at 190 °C under 2.16 kg load as determined by ISO 1133-1 and a density of 0.954 g/cm³ as determined by ISO 1183-1. With melt flow below 1.0 g/10 min, the grade is specified in extrusion-dominant operations where parison melt strength, environmental stress crack resistance, and slow crack growth resistance control service life under chemical or mechanical load. Drying is not required when surface moisture remains below 0.05 wt%; at warehouse relative humidity above 60%, pre-drying in a desiccant hopper at 70 °C for 2 h is imposed before extrusion. The useful melt-temperature range is 185 °C to 205 °C in most downstream equipment, but the upper and lower limits shift with screw speed, backpressure, and regrind loading. The application segments below are separated by tooling, qualification test, and failure mode rather than by generic end-use labelling.

    Extrusion Blow Moulding of UN-Rated Free-Standing Jerricans and Tight-Head Drums

    On production-scale accumulator blow moulding lines, the grade is run with grooved-feed extruders of 80 mm to 120 mm screw diameter and 24:1 to 30:1 L/D ratio. Barrel zone settings are staged from 170 °C in the feed section to 195 °C at the metering zone, with the head assembly held at 190 °C to 200 °C; melt temperature measured by an immersion probe should not exceed 205 °C. The diverging-mandrel radial die is set to a die gap of 0.8 mm to 1.5 mm for a 20 L to 30 L shot size, producing a parison swell of 55% to 85% under typical shot weights of 1.2 kg to 2.1 kg. Mould cooling temperature is maintained at 10 °C to 20 °C, with blow pressure of 0.6 MPa to 0.8 MPa. The pinch-off zone requires a tool compression land of 0.4 mm to 0.6 mm; below 0.4 mm, the weld line fails the UN 6.1.6 leakproofness test, while above 0.6 mm, excessive flash disrupts the top-load plane and reduces ISO 12048 top-load capacity by 8% to 12%. Finished containers for packaging group II chemicals are qualified by UN 6.1.5.3 drop impact at 1.2 m at -18 °C and by UN 6.1.6 internal pressure held for 30 min. ESCR screening uses ASTM D1693 Condition A with Igepal CO-630 at 100% concentration and 50 °C. A known production bottleneck appears at the tail pinch-off when regrind level exceeds 20 wt% because the recycled fraction raises the melt viscosity locally and reduces weld line interdiffusion; internal pressure resistance of a 220 L tight-head drum can fall below the UN 6.1.6 requirement if the head temperature is not reduced by 3 °C to 5 °C after regrind addition.

    Thermoforming-grade sheet stock is produced on a single-screw vented extruder with 120 mm screw diameter and 33:1 L/D ratio, feeding a coat-hanger die with a final land length of 30 mm to 40 mm. Melt temperature at the die entry is controlled between 195 °C and 210 °C; the chrome-roll polish stack is set to 80 °C, 85 °C, and 90 °C on the bottom, middle, and top rolls respectively for sheet thicknesses of 2 mm to 5 mm. Draw ratio during thermoforming is kept below 2.5:1 for shallow trays and below 1.8:1 for deep automotive liners because wall-thickness variation measured by contact gauge should not exceed ±0.15 mm. Plug speed is restricted to 150 mm/s for high-crystalline sections; faster plug movement cools the sheet below the forming temperature and initiates microcracks at the plug contact. The sheet stock is evaluated by ISO 527-2 tensile testing at 50 mm/min, ISO 178 flexural modulus at 2 mm/min, and ISO 179/1eA Charpy impact at -20 °C. In agricultural service, lot-to-lot consistency in ESCR is tested by ISO 16770 full-notch creep tensile test in 2 wt% nonylphenol ethoxylate solution at 80 °C; a failure below 100 h is an automatic quarantine trigger on lines producing chemical contact trays. Regrind from skeletal web is limited to 15 wt% because higher loads depress the Charpy impact strength by more than 10% and increase sheet sag over the mould cavity by 2 mm at a forming temperature of 170 °C.

    What Limits Melt Temperature During Corrugated Drainage Pipe Extrusion?

    For corrugated drainage pipe of 100 mm to 300 mm internal diameter, the line is built around a single-screw extruder of 75 mm to 90 mm screw diameter and 30:1 L/D ratio, directly coupled to a corrugator with aluminium mould blocks travelling at 2 m/min to 6 m/min. The die head is set to a melt temperature of 185 °C to 195 °C; the upper boundary of 195 °C is set not by degradation but by the onset of melt fracture at the vacuum forming slot when the drawdown ratio exceeds 2.2:1. At melt temperatures above 195 °C, the pipe wall between corrugation peaks thins below 0.6 mm, and the drop-weight impact resistance measured by ISO 3127 at -20 °C becomes batch-sensitive. The corrugator vacuum is controlled at -25 kPa to -35 kPa, with water spray cooling at 15 °C to 25 °C. A typical line setup uses a heated calibration collar at the pipe end to control inner diameter to ±1.0 mm, while the haul-off feeds a perforated pipe coiler for drainage applications. Structured-wall pipe is tested under ISO 9969 for ring stiffness, but for buried drainage the more relevant qualification is EN 13476-3, where a ring stiffness of 4 kN/m² to 8 kN/m² is common for agricultural and civil drainage. ESCR acceptance testing uses ISO 16770 at 4 MPa and 80 °C. Processors running 20 wt% post-industrial regrind can maintain ISO 16770 failure time above 500 h only if regrind is dried to 0.03 wt% moisture and melt temperature is lowered by 3 °C; otherwise corrugation tip cracking appears within the first 200 h of constant tensile load.

    When HDPE L5040TC Is Melt-Spun into High-Tenacity Monofilament and Industrial Strapping Tape

    Although not the highest-output melt spinning grade, the resin's melt strength and slow crack growth resistance are relevant for monofilament used in sewage sludge dewatering belts and for heavy-duty strapping where creep under constant load is the primary failure mode. The extruder is a 90 mm single-screw unit with 30:1 L/D ratio and a gear pump to stabilize spinneret pressure at 8 MPa to 12 MPa; barrel temperatures are staged from 200 °C to 220 °C. Monofilament dies are 0.5 mm to 2.0 mm in diameter, followed by a water quench tank at 30 °C to 45 °C and a first godet speed of 10 m/min to 15 m/min. Orientation takes place across hot-air ovens at 115 °C to 130 °C, with total draw ratios of 7:1 to 10:1; final relaxation of 3% to 6% between the last two godets controls hot-air shrinkage at 100 °C for 15 min below 3% when tested to ASTM D2259. For strapping tape of 10 mm to 25 mm width and 0.5 mm to 1.2 mm thickness, the lower draw ratio of 6:1 to 8:1 is preferred because edge fibrillation increases above 8:1; tensile strength and elongation are assessed by ASTM D3950, with oriented HDPE strapping values in the range of 150 MPa to 250 MPa. Published data for this specific L5040TC configuration in monofilament is limited, so line qualification relies on comparative ISO 2062 tenacity and ISO 899-1 creep rupture tests under 10% to 30% of breaking load rather than supplier-derived minimum values. A recurring processing fault is draw resonance between the first and second godet sets when the hot-air oven temperature differs by more than 5 °C across the web path; this produces diameter variation of ±0.05 mm and excessive strapping splice failure in downstream automatic bundling.

    Large-format pallet injection moulding with HDPE L5040TC is viable only when the tool and press are configured for low-melt-flow resin. The injection unit uses an accumulator-assisted plunger or a reciprocating screw with 100 mm to 140 mm diameter and a low compression ratio of 2.0:1 to 2.2:1; barrel temperatures are set from 200 °C at the feed zone to 230 °C at the nozzle, and the mould is run at 30 °C to 50 °C to limit shrinkage differentials. Shot weights for industrial pallets range from 5 kg to 15 kg, requiring clamp force of 15,000 kN to 30,000 kN and injection pressure of 80 MPa to 120 MPa. Holding pressure is profiled at 60 MPa for 30 s to 60 s, followed by cooling time of 180 s to 300 s for wall thicknesses of 25 mm to 40 mm. The finished pallet is tested to ISO 8611-1:2021 for rated load, racking, and impact; a common rejection mode is corner cracking during impact testing when the mould temperature varies by more than ±5 °C across the core face. Differential cooling produces residual stress that is measurable as warpage greater than 6 mm over a 1200 mm length. Melt flow rate drift from 0.40 g/10 min to 0.35 g/10 min in stored lots corresponds to a 15% reduction in spiral flow length and a 20% increase in injection pressure; warehouse ageing above 40 °C for more than 90 days therefore requires adjustment of the nozzle temperature by +5 °C. Pallet designs with grommets or metal reinforcements are avoided unless the insert preheat exceeds 110 °C, because polyethylene shrinkage around cold inserts initiates immediate stress cracks under load.

    For telecommunication duct and electrical conduit, HDPE L5040TC is extruded on a 60 mm single-screw extruder with 28:1 L/D ratio, feeding a spiderless pipe die. The melt temperature is held at 200 °C ± 5 °C, while the vacuum calibration tank is operated at -20 kPa to -30 kPa and water temperature 20 °C to 30 °C. Outer diameters range from 40 mm to 110 mm with wall thickness from 2.0 mm to 4.0 mm, and haul-off speeds of 5 m/min to 15 m/min are set to keep wall eccentricity below 0.1 mm. The duct is qualified under EN 61386-24 for buried conduit and is subjected to a compression test at 450 N per 200 mm span; ESCR is tested under ISO 16770 because installed duct can remain under cable load for decades. Pre-drying at 70 °C for 2 h is required when regrind from duct punch-outs exceeds 10 wt%, because moisture-induced surface voids are visible at the calibration sleeve and reduce impact resistance under ISO 3127.

    The processing windows above are non-generic because each conversion route has a separate thermal and geometric limitation. Table 1 consolidates the melt and tooling setpoints most commonly recorded in production trials; the values are screening windows tied to the equipment described in each segment, not vendor release limits.

    Conversion routeMelt temperatureTooling temperatureDraw ratio or shot dimensionKey process limit
    Extrusion blow moulding, 20–30 L jerricans185–205 °Cmould 10–20 °Cdie gap 0.8–1.5 mm, shot 1.2–2.1 kgpinch-off land 0.4–0.6 mm
    Thick-sheet thermoforming195–210 °Crolls 80–90 °Csheet 2–5 mm, draw ≤ 2.5:1regrind > 15 wt% lowers Charpy > 10%
    Corrugated drainage pipe185–195 °Ccorrugator water 15–25 °Cdrawdown ≤ 2.2:1, pipe 100–300 mmmelt fracture above 195 °C
    Monofilament/strapping200–220 °Coven 115–130 °C, quench 30–45 °Cdraw 6:1–10:1edge fibrillation above 8:1
    Pallet injection200–230 °Cmould 30–50 °Cwall 25–40 mm, shot 5–15 kgmould delta > ±5 °C causes > 6 mm warpage
    Telecommunication duct200 °C ± 5 °Ccalibration water 20–30 °C, vacuum -20 to -30 kPaOD 40–110 mm, wall 2–4 mmpunch-out regrind > 10 wt% requires predrying

    Finished-article compliance for HDPE L5040TC spans multiple application-specific protocols. The matrix below consolidates mechanical screening gates and regulatory checks used in downstream batch release. Pigments and colour masterbatches must be qualified separately because they carry their own food-contact and heavy-metal restrictions that are not addressed by the base resin certification.

    ApplicationStandard or regulationTest conditionScreening gate
    UN jerricans and drumsUN 6.1.5.3-18 °C, 1.2 m dropno leakage
    UN jerricans and drumsUN 6.1.6pack group II air pressure, 30 minno leakage
    ESCR screeningASTM D1693 Condition A50 °C, Igepal CO-630 100%F50 ≥ 600 h
    Slow crack growthISO 1677080 °C, 4 MPa≥ 500 h
    Tensile yieldISO 527-250 mm/min≥ 24 MPa
    Flexural modulusISO 1782 mm/min≥ 1100 MPa
    Charpy notched impactISO 179/1eA-20 °C≥ 10 kJ/m²
    Food contactFDA 21 CFR 177.1520(c)food types and conditions of usemigration limits per 21 CFR 177.1520(c)
    EU food contactEU Regulation 10/2011simulants A, B, D2; 10 days at 40 °Coverall migration 10 mg/dm²
    RoHS restricted substances2011/65/EU Annex IIXRF screeningPb 1000 ppm, Cd 100 ppm, Hg 1000 ppm, Cr(VI) 1000 ppm
    REACH SVHC declarationEU 1907/2006/EC Article 33candidate list0.1 wt% per article
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    Certification & Compliance
    More Introduction

    LyondellBasell HDPE L5040TC is a high-density polyethylene resin positioned for extrusion blow molding, heavy-gauge sheet, and industrial hollow parts where parison stability and environmental stress-crack resistance are primary processing constraints. The material is typically supplied as natural or pre-colored pellets with a density of 0.950 g/cm³ measured according to ISO 1183-1 and ASTM D1505, and a melt flow index of 0.40 g/10 min at 190 °C/2.16 kg according to ISO 1133-1 and ASTM D1238. The high-load melt index at 21.6 kg is reported at 40 g/10 min, indicating a high-molecular-weight HDPE with sufficient shear thinning to reduce extruder backpressure while retaining melt strength for large-diameter parisons.

    During continuous extrusion blow molding, the high-load melt index of L5040TC lowers head pressure relative to lower-HLMI grades at equivalent throughput, but die swell and parison sag behavior are not identical to standard 0.950 g/cm³ HDPE resins. Processors should measure die swell on the target tooling before locking the die-gap program and set the programmed axial wall thickness with reference to actual pinch-off weld geometry. Without this verification, wall-thickness variation on containers above 20 L may exceed ±0.10 mm, particularly in the lower pinch-off region where parison predeformation is greatest.

    Specification Benchmarks and Test Method Cross-Reference

    Typical property values for LyondellBasell HDPE L5040TC are tabulated below as a cross-reference to the analytical methods most frequently used for incoming inspection and part qualification. These values are typical lot-average data, not fixed specification limits. Release testing is commonly limited to melt flow index, density, and high-load melt index, while mechanical and thermal properties are confirmed on a campaign basis or when process deviations occur.

    Property Test Method Typical Value Unit
    Density ISO 1183-1 / ASTM D1505 0.950 g/cm³
    Melt flow index at 190 °C/2.16 kg ISO 1133-1 / ASTM D1238 0.40 g/10 min
    High-load melt index at 190 °C/21.6 kg ISO 1133-1 / ASTM D1238 40 g/10 min
    Tensile yield strength at 50 mm/min ISO 527-2 / ASTM D638 23 MPa
    Elongation at break ISO 527-2 / ASTM D638 >600 %
    Flexural modulus ISO 178 / ASTM D790 1200 MPa
    Shore D hardness ISO 868 / ASTM D2240 64 —
    Vicat softening temperature A50 ISO 306 126 °C

    Short-term tensile and flexural data should not be used alone for structural design. Environmental stress-crack resistance is the critical long-term property for aggressive wetting agents and industrial chemical containment. When ESCR data are required, lot-specific testing under ASTM D1693-B in 100% Igepal CO-630 or ASTM D2561 for molded bottles is recommended because published data for this specific configuration is limited. For hydrostatic pressure service, ISO 9080 regression analysis is mandatory, and L5040TC is not automatically equivalent to a PE 100 pipe grade without product-specific long-term validation.

    What Limits Processing Stability on Continuous Extrusion Lines?

    The principal operating boundary for L5040TC is melt-temperature control. Single-screw extruders with L/D ratios between 24:1 and 30:1 and barrier flight geometry are preferred; open-groove feed sections with forced cooling improve conveying stability for a 0.950 g/cm³ high-density material. A typical barrel temperature profile from feed to metering is 180 °C, 190 °C, 200 °C, 205 °C, and 210 °C, with adapter and die head set at 210 °C to 215 °C. Melt temperatures above 230 °C initiate oxidative chain scission, observed in continuous operations as progressive head-pressure loss, reduced parison hang time, and lower pinch-off weld burst strength. Melt temperatures below 190 °C may produce sharkskin melt fracture and surging, particularly on high-compression screws without an adequate mixing section.

    Moisture uptake is not a routine drying concern under covered indoor storage, but condensation on cold pellet surfaces can introduce surface moisture. If pellets are transferred from outdoor storage below 0 °C into a humid indoor area, a desiccant dryer at 80 °C for 2 h is sufficient to suppress melt-pressure oscillation and localized surface defects. At relative humidity above 60%, sustained hopper residence times beyond 4 h are not recommended unless the hopper is blanketed with dry air at a dew point below −30 °C.

    Large-part blow molding of fuel tanks, intermediate bulk containers, and multi-layer agricultural chemical containers with L5040TC requires accumulator-head or reciprocating-screw equipment rather than shuttle presses optimized for lower-HLMI grades. On a 60 mm accumulator-head line with a 25:1 L/D screw, wall-thickness distribution across a 200 L container is maintained by closed-loop die-gap control with programmed axial profiles. Switchover from a standard 0.950 g/cm³ HDPE to L5040TC typically requires revision of the die-gap profile by 0.10 mm to 0.15 mm at the lower pinch-off zone. Mold closing speed also affects weld integrity; closing speeds below 200 mm/s may permit the preform to cool below the high-melt-strength plateau before compression is complete, reducing pinch-off weld strength.

    When Lower-HLMI Blow Molding Grades Are Replaced by L5040TC

    For an HDPE with density 0.950 g/cm³, the high-load melt index of 40 g/10 min is higher than many general-purpose blow molding resins in the same density class, which commonly exhibit HLMI values between 25 g/10 min and 35 g/10 min. The practical difference is lower pressure drop across screen packs, adapters, and die-head tooling at constant throughput. Capillary rheometry under ASTM D3835 shows the viscosity-shear rate curve relative to lower-HLMI grades crosses over at intermediate shear rates: the viscosity of L5040TC remains higher at low shear rates relevant to parison sag, while the material flows more easily at high shear rates within the extruder screw channel. This permits melt-temperature reduction of 5 °C to 10 °C without exceeding maximum head pressure, reducing thermal degradation and color shift in natural or white parts.

    The grade is not a direct drop-in replacement for low-sag or high-flow HDPE grades used in thin-wall consumer containers where cycle-time reduction dominates. Its flexural modulus of 1200 MPa provides higher top-load stiffness than HDPE grades with flexural modulus in the range of 900–1000 MPa, but the higher molecular weight may reduce injection molding flow length by 10% to 15% relative to a 0.40 g/10 min injection molding HDPE at identical melt temperature. Injection molding is therefore restricted to thick-wall industrial articles with clamp force estimates of 5.5 kN/cm² to 7.0 kN/cm² based on projected area for initial machine selection.

    Chemical compatibility must be evaluated against the specific fill formulation. HDPE L5040TC is not recommended for continuous exposure to strong oxidizing acids, aromatic hydrocarbons, or chlorinated solvents at elevated temperatures. In surfactant-containing aqueous formulations, ESCR testing under ASTM D1693-B at 50 °C is required because stress cracking accelerates with temperature and mold-induced residual stress. For agricultural chemical containers, part-level stack testing and closure torque retention under ASTM D2659 may be necessary to establish service life under warehouse load conditions.

    Regulatory and Recyclate Boundaries

    When L5040TC is combined with post-consumer recyclate, the blend must be re-characterized because the high-load melt index of the recyclate fraction can shift the composite melt flow. Recyclate addition above 20 wt% alters the melt-viscosity balance in a non-linear manner; viscosity additivity follows logarithmic mixing at constant shear stress. A blend containing 30 wt% recycled HDPE with an HLMI of 60 g/10 min can raise the blend HLMI beyond 45 g/10 min, which may reduce parison hang time below acceptable limits for large-part tooling. Unless on-line melt-viscosity control or periodic HLMI testing is implemented, the recyclate fraction should be limited to 20 wt%.

    Regulatory compliance is supplied under the manufacturer’s generic REACH and RoHS documentation. No food-contact or pharmaceutical suitability is implied absent current grade-specific FDA 21 CFR 177.1520 or EU Regulation 10/2011 verification. For potable-water applications, compliance with NSF/ANSI 61 or equivalent regional certification must be confirmed on the finished article rather than inferred from raw resin documentation. In applications involving multi-material laminates or barrier layers, migration testing must account for the full layer structure and the specific processing history because adhesion layers and tie resins can alter the overall extractables profile.

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