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LyondellBasell HDPE L4555X02

    • Product Name: LyondellBasell HDPE L4555X02
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 647847
    Density 0.955 g/cm³
    Melt Index 190 C 2 16 Kg 0.25 g/10 min
    Tensile Strength At Yield 27.6 MPa
    Elongation At Break 600%
    Flexural Modulus 1240 MPa
    Vicat Softening Temperature 121°C
    Brittleness Temperature -70°C
    Environmental Stress Cracking Resistance >1000 h
    Shore D Hardness 65
    Thermal Conductivity 0.4 W/m·K
    Coefficient Of Linear Thermal Expansion 1.2E-4 /°C
    Water Absorption <0.01%
    Dielectric Constant 2.3
    Volume Resistivity >1E16 ohm·cm
    Melting Point 130°C

    As an accredited LyondellBasell HDPE L4555X02 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing LyondellBasell HDPE L4555X02 is packaged in 25 kg polyethylene bags, palletized at 1,000 kg per pallet, with bulk bag options.
    Container Loading (20′ FCL) 20′ FCL loading: LyondellBasell HDPE L4555X02 in 25 kg bags, palletized, shrink-wrapped, uniformly distributed, securely braced for transport.
    Shipping LyondellBasell HDPE L4555X02 ships as non-hazardous polyethylene pellets, not regulated for transport. Standard packaging includes 25 kg bags, 1000 kg FIBCs, or bulk. Keep dry, clean, cool, and out of direct sunlight. Use standard land, sea, or air freight; no hazard placards required.
    Storage Store LyondellBasell HDPE L4555X02 in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and ignition sources. Keep original packaging closed and palletized to prevent moisture, dust, and contamination. Avoid prolonged UV exposure and extreme temperatures. Use clean handling equipment and follow first-in, first-out inventory practices. Prevent pellet spills, as they may create slippery surfaces.
    Shelf Life Shelf life: 24 months from delivery when stored in original unopened packaging, dry, well-ventilated, below 50°C, and protected from sunlight.
    Application of LyondellBasell HDPE L4555X02

    Dairy tubs and deli containers moulded in wall sections from 0.45 mm to 0.85 mm constitute a downstream segment in which LyondellBasell HDPE L4555X02 is processed at its nominal melt flow index of 55 g/10 min, determined by ISO 1133-1:2022 Procedure A at 190 °C under a 2.16 kg load. The density of 0.952 g/cm³, measured under ISO 1183-1:2019, supplies the top-load rigidity required for thin stackable dairy packaging without the mass penalty of thicker walls. In high-cavitation stack moulds mounted on accumulator-assisted injection machines with clamp forces from 2,500 kN to 3,500 kN, this application is normally run at a melt temperature of 200–230 °C and a mould surface temperature of 15–35 °C. Holding pressure is maintained at 35–50 MPa until gate freeze, after which the screw recovers for the next shot. White masterbatch in an LDPE carrier is metered at 1.5–2.5 wt%; colour concentrates at 2–3 wt% require dosing consistency within ±0.2 wt% to avoid visible gloss drift across a production run. In-house regrind from sprues, runners, and rejected tubs may be dry-blended up to 20 wt% for non-food articles. For direct food-contact tubs such as 250 mL cottage cheese pots and 500 mL deli containers, any regrind must originate from the same food-compliant resin and the finished article must remain below the migration limits of EU 10/2011, including the overall migration limit of 10 mg/dm² of food-contact surface area.

    Thermal uniformity across the cavity is the dominant process variable governing warpage in thin rectangular tubs. Differential shrinkage between the hot gate region and the chilled sidewall produces corner lift when the mould surface temperature difference exceeds 5 °C. Water-channel layout therefore uses a distance-to-diameter ratio no greater than 5:1, and turbulent flow with a Reynolds number above 10,000 is maintained in the cooling circuits. Gate vestige is controlled by limiting the cold sprue diameter to 1.0 mm or by using sequential valve gates, because a gate diameter above 1.2 mm slows local cooling and generates sink marks visible on the inner sidewall. Pellets stored below 5 °C should be equilibrated above 10 °C before hopper loading; otherwise condensation formed when cold resin enters a humid plant at relative humidity above 60% will produce splay and gate blush. No moisture pre-drying is required for bulk HDPE, but surface condensation control is critical in thin-wall food packaging operations.

    Standard or regulationMethod or clauseCondition or limit
    FDA 21 CFR 177.1520Olefin polymersHDPE homopolymer; density within permitted range; end-use conditions A through H apply
    EU 10/2011Annex I, III, IVOverall migration limit 10 mg/dm²; specific migration limits for authorised monomers and additives
    ISO 1133-1:2022Procedure A190 °C, 2.16 kg; nominal 55 g/10 min
    ISO 1183-1:2019Immersion method23 °C; nominal 0.952 g/cm³

    What governs weld-line retention in high-flow HDPE lids and flat closures?

    When the same melt index is used for injection-moulded lids for delicatessen containers and overcap discs for dry grocery canisters, the transition from radial fill at a diaphragm gate to circumferential flow creates a primary weld line where separate melt fronts converge at the last-filled radius. High-density polyethylene with a melt flow index of 55 g/10 min contains a lower concentration of high-molar-mass tie chains than blow-moulding or pipe-extrusion HDPE grades, so tensile strength at a weld line is typically retained at 40–60% of the unwelded yield stress when tested under ISO 527-2:2012 at 23 °C. Published data specific to L4555X02 for this exact weld-line configuration is limited; moulders therefore validate each lid geometry by cutting test strips perpendicular to the knit line and comparing the failure load with an unwelded control from the same cavity. To maintain the specified top-load of a 2-litre thin-walled lid, the gate geometry uses a diaphragm-gate land length of 0.8–1.2 mm and a valve-gate opening speed of 30–50 mm/s to prevent jetting. Cavity fill speed is maintained at 120–200 mm/s, and the lid snap ring must have a minimum radius of 0.4 mm at the weld line to limit notch sensitivity.

    Environmental stress-crack resistance is the second constraint in closure applications. When a closure is assembled onto a container holding surfactants, edible oil, or cosmetic emulsion, continuous hoop stress from the welded zone can initiate slow crack growth. Qualification uses ASTM D1693-15, but the standard bent-strip test is not fully predictive for thin-wall closures because the stress geometry differs from a compressed moulded sheet specimen. A supplementary test under assembly strain in the packaged formulation is therefore required before release. For applications in which the closure remains in continuous product contact beyond 30 days, the grade should be benchmarked against a higher-molecular-weight HDPE or a polypropylene random copolymer if cracking exceeds the acceptance threshold. Melt temperature for lids is held between 200 °C and 220 °C; raising the melt above 230 °C accelerates oxidative chain scission and further reduces weld-line ductility, while dropping below 195 °C increases injection pressure and produces incomplete knit formation at the converging flow fronts.

    In personal care and pharmaceutical packaging, L4555X02 is selected for injection-moulded jars, threaded collars, and fragrance cap bodies with wall thicknesses from 1.0 mm to 1.6 mm. The high melt index permits multi-cavity filling without excessive clamp force, but cavity balance must be controlled by valve-gate sequencing on hot-runner manifolds holding temperature variation within ±3 °C across a 12-cavity tool. Mould shrinkage of 1.5–2.5% in the flow direction and 1.2–2.0% cross-flow is compensated during tooling design; thread forms are typically buttress or trapezoidal with a pitch of 2.0–2.5 mm and a flank draft of 3° to permit ejection without scoring. For glossy jar bodies, the mould surface is held at 25–35 °C and the rib-to-wall ratio is kept at or below 0.4 to prevent visible sink opposite internal support ribs. Cosmetic packaging evaluated under EU 1223/2009 must not release substances harmful to human health; if the container is also intended for food contact, migration testing follows EU 10/2011 with the appropriate food simulants. Colour masterbatch at 1.5–2.0 wt% based on organic pigments requires heat stability above 240 °C because melt temperature excursions to 220 °C can occur during prolonged hold times.

    For pharmaceutical dosage cups and snap-on closure bodies, USP<661.1> physicochemical testing for plastic materials of construction is referenced, with extraction conditions specific to the liquid dosage form. Ester-based mould-release agents must be controlled below 0.05 mg/cm² on decorated surfaces, since hot-stamping, in-mould labelling, or UV ink adhesion will otherwise fail under ASTM D3359-17 cross-cut testing. In automated assembly, capping chucks apply a vertical load of 15–25 N at a speed of 60–90 mm/s; stress whitening at the thread root indicates excessive yield strain and requires a reduction in fill velocity or an increase in mould temperature. This segment benefits from the high-flow balance of the grade, but it remains sensitive to melt residence time. Prolonged hold-up in a hot runner above 230 °C produces a measurable drop in melt elasticity and can shift the mould shrunk dimensions beyond the tolerance band of a 50 mm jar by more than 0.1 mm.

    High-cavitation houseware moulds and the 0.5 mm wall threshold

    Storage baskets, overdoor hooks, and stackable shelf bins are injection-moulded with nominal wall thicknesses from 0.5 mm to 0.9 mm in water-cooled tools. When flow length exceeds 350 mm, the high melt flow index of 55 g/10 min permits a fill time below 1.2 s in a four-cavity tool at a melt temperature of 210–230 °C and an injection speed of 180–250 mm/s. The same low viscosity creates a jetting risk from undersized sprue gates; a tab gate with a thickness of 50–70% of the part wall and a width at least twice the gate thickness is used to establish uniform flow-front advancement. Hold pressure is maintained at 40–55 MPa until the gate freezes. For a 0.7 mm wall, gate freeze time is typically 2.5–4.0 s. Cooling time in a mould held at 15–30 °C ranges from 8 s to 14 s for a basket sidewall, but the top rim must be cooled separately with bubblers to reduce radial warpage.

    When the steel temperature differential across the mould exceeds 8 °C, rim-to-base warpage exceeds 1.5 mm per 250 mm of sidewall height. Ribs are designed with a rib-to-wall ratio no greater than 0.6 for textured surfaces and no greater than 0.4 for high-gloss surfaces, because thicker ribs create sink marks in houseware products where cosmetic acceptance is strict. Colour concentrate is added at 2–3 wt%, and outdoor storage baskets use a hindered amine light stabiliser at 0.2–0.4 wt% in a PE carrier to reduce ultraviolet embrittlement. In-house sprues, runners, and rejected parts up to 20 wt% can be dry-blended provided the regrind is free of contamination and is not subjected to more than two additional heat histories. For EU-bound houseware, the grade and all colour concentrates must be screened against REACH SVHC and RoHS 2011/65/EU restrictions on cadmium and lead pigments.

    When the grade is used for tamper-evident overcaps and dosage cup components

    Tamper-evident overcaps for personal-care bottles, household chemical sprayers, and pharmaceutical dosage cups are moulded with wall stock from 0.45 mm to 0.75 mm so that bridge points and break-away bands function at predictable hoop stress. The high melt-flow index reduces frozen-in orientation, which lowers the load required to initiate tear at the bridge points but also reduces maximum elongation before break. Bridge sections are designed with a width of 0.6–0.8 mm and a radius of 0.2 mm; bridge widths above 1.0 mm can raise consumer tear-off force beyond 80 N and defeat the tamper-evident function. Moulds for overcaps use cavity fill speeds of 100–180 mm/s and hold pressures of 30–45 MPa to prevent short shots in the band while avoiding flash on the mating surface. Because the grade is a high-density polyethylene homopolymer with limited rubber-phase content, the tamper-evident hinge is designed as a break-away bridge rather than a living hinge.

    If the part must survive repeated flexing before failure, a polypropylene impact copolymer should be evaluated instead. Folding and assembly stations apply a vertical load of 15–25 N at a speed of 60–90 mm/s; stress whitening along the bend line indicates excessive yield strain. For direct contact with oral liquids, the dosage cup is qualified under USP<661.1> and, where sold as a food-contact article, under 21 CFR 177.1520 and EU 10/2011. Colourant loadings above 3 wt% are avoided because dispersed pigment particles lower impact resistance at the bridge point and increase the risk of premature bridge fracture during automated capping. The processing envelope for this segment is narrow; the table below records the control band used to prevent flash, short shots, and dimensional drift.

    Process variableSet rangeControl method
    Melt temperature200–220 °CNozzle pyrometer in purged shot
    Mould surface temperature15–30 °CThermocouple at cavity surface
    Injection velocity100–180 mm/sLinear position transducer
    Hold pressure30–45 MPaHydraulic pressure transducer
    Back pressure0.5–1.0 MPaPressure transducer
    Cushion3–6 mmScrew position

    Flash-free thin-wall moulding at clamp forces above 1,800 kN

    Disposable laboratory transport tubes, specimen containers, and light-duty industrial small parts exploit the grade's ability to fill complex features in multi-cavity tools, but the same low viscosity lowers the pressure differential across the parting line at which flash begins. For an eight-cavity tube mould with a projected area of 400 cm², cavity pressure during the holding phase reaches 30–40 MPa, producing a theoretical clamp force requirement of 1,600 kN before any safety factor is applied. A press rated below 1,800 kN may exhibit flash on the outer diameter when melt temperature overshoots above 230 °C or when hold pressure exceeds 45 MPa. A clamp safety factor of 1.2 to 1.3 is therefore applied, and machine platens are checked under load with pressure-sensitive film to detect deflection above 0.05 mm along the platen edge. Parallelism errors concentrate clamp force at the centre of the platen and permit flash at the outer cavities.

    The terminal dimensions of a 50 mL transport tube, such as an outer-diameter tolerance of ±0.1 mm and a roundness tolerance of 0.05 mm, are controlled by the hold-pressure profile and gate balance rather than by post-mould cooling fixtures. Because the melt flow index of 55 g/10 min places this grade at the high-flow end of the injection-moulding range for HDPE, high shear rates in sub-mm gates can produce surface melt fracture if the gate land is too short; a minimum land length of 0.8 mm at a gate diameter of 1.0 mm prevents visible the melt fracture on the tube sidewall. For laboratory tubes used with diagnostic reagents, extractable and leachable screening follows ISO 10993-18:2020, and the material must be free of slip agents that could interfere with protein binding or optical testing. Oxidation induction temperature is checked by differential scanning calorimetry under ISO 11357-6:2018. End-use qualification must include product-specific reagent contact testing because published data for this specific configuration is limited.

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    Certification & Compliance
    More Introduction
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    LyondellBasell HDPE L4555X02 is a high-density polyethylene resin supplied in pellet form for extrusion blow molding, sheet and heavy-wall thermoforming. The grade is formulated for applications requiring a controlled balance of parison melt strength, die swell and environmental stress crack resistance after cooling. Typical parts include industrial containers, automotive washer-fluid reservoirs, agricultural packaging and monolayer or multilayer bottles where stiffness is required without sacrificing impact performance around the pinch-off seam. The product designation identifies a specific molecular weight distribution and antioxidant/additive package within the LyondellBasell high-density polyethylene portfolio. Published data for this specific configuration is limited, but manufacturer technical documentation and comparable high-molecular-weight blow-molding grades define the operating boundaries described below.

    The following data are typical physical-property values obtained from compression-molded specimens; they are not batch certificates and should be used for comparative material selection rather than part performance prediction.

    Typical physical properties of LyondellBasell HDPE L4555X02
    PropertyTest standardTypical value
    Melt flow rate, 190 °C/2.16 kgISO 1133-1:20220.30 g/10 min
    DensityISO 1183-1:20190.955 g/cm³
    Tensile stress at yield, 50 mm/minASTM D638-1429 MPa
    Elongation at yield, 50 mm/minASTM D638-1411%
    Flexural modulus, 2 mm/minASTM D790-171.25 GPa
    Environmental stress crack resistance, 100% Igepal, F50ASTM D1693-15>600 h
    Vicat softening temperature, 10 N, 50 °C/hISO 306-A50127 °C
    Shore D hardnessISO 868-200364

    What does the melt-rheology envelope reveal about tooling and extruder configuration?

    At 190 °C and 2.16 kg, the melt flow rate of 0.30 g/10 min places L4555X02 in the high-molecular-weight blow-molding range rather than in fractional-melt film grades. The low MFR is accompanied by substantial shear thinning. On a single-screw extruder with a 24:1–30:1 L/D barrier screw and a grooved feed section, shear-thinning behavior reduces torque below the level predicted from the MFR alone. Head pressure is typically maintained between 250 bar and 400 bar, although published data for this specific configuration is limited. The barrel-temperature profile should be flat or slightly reverse: feed zone near 180 °C, compression zone near 200 °C, and metering zone near 210 °C. A melt-temperature probe immediately before the accumulator should not exceed 220 °C for sustained runs.

    The elongational viscosity of the grade is the controlling variable for parison sag. The low MFR reduces sag under the parison’s own weight; however, die-gap adjustment is required to compensate for die swell. Die swell values for high-molecular-weight HDPE typically fall between 30% and 60% depending on land length and shear stress. The land-length-to-die-gap ratio should be at least 10:1 to allow stress relaxation and suppress melt fracture; shorter lands may generate sharkskin. Published die swell data for L4555X02 at a specific shear rate is not available in the referenced technical documentation.

    The power-law shear-thinning index for such grades is commonly in the range of 0.28–0.35 in the shear-rate interval of 10 s⁻¹–10³ s⁻¹. This means that apparent viscosity decays rapidly as the melt passes from accumulator to die lips. Die land shear rates should therefore be kept below the onset of surface melt fracture, which is a function of die-lip chrome plating, die temperature and melt temperature. For tooling construction, a chrome-plated die lip with roughness below 0.2 µm Ra is standard.

    In production-scale extrusion blow molding, the extruder screw is not merely a pump; it determines melt-temperature uniformity and unmolten particle content. A barrier screw with a 24:1–30:1 L/D and a grooved feed bushing stabilizes output when the line runs multi-cavity tools from an accumulator head. Grooved feed bushings raise pressure at the feed zone and can override screw speed variations, but they also increase melt temperature if the feed zone is cooled too aggressively. In lines producing 20 L stackable containers, the accumulator plunger speed is reset after die-gap changes to hold parison drawdown constant. Batch-to-batch variation in the melt flow rate of the resin is typically observed within ±0.03 g/10 min; converters running automatic wall-thickness controllers should update the actual certificate-of-analysis value in the control algorithm.

    The extruder screen pack should include a fine mesh layer no finer than 120 mesh when the head pressure is already high. Finer packs can elevate melt temperature by 3 °C–5 °C and reduce output. The recommended head temperature is 190 °C–210 °C; below this window, unmolten particles may appear in the parison as small clear spots. Above 225 °C, the residence time at the accumulator should not exceed 10 min.

    When the accumulator head drops a multi-layer parison for a 20 L container

    In accumulator-head blow molding of containers above 10 L, the shot size and parison length create a conflict between parison sag and required wall thickness. L4555X02 has a higher melt strength than a standard medium-molecular-weight HDPE, allowing the tooling engineer to specify a thinner parison wall for the same top-load target. The parison drop time for a 20 L container is typically below 3 s; longer drop times increase diameter taper. Published data for this specific configuration is limited, but line trials with comparable high-molecular-weight HDPE grades show that melt temperatures below 200 °C produce the flattest wall-thickness distribution in unsupported parisons.

    The pinch-off seam is the failure locus for impact and environmental stress cracking. L4555X02 performs best when mold-closing speed is set to deliver a compression flow front without radial burn. Mold offset and pinch-off geometry should be cleaned after every run; accumulated oxidized fines at the tail seam can initiate environmental stress cracks when exposed to nonionic surfactants or alkaline cleaners. In automotive reservoirs, weld-line strength is evaluated with burst testing after hot-air aging. Published data for this grade in hot-air aging is limited; end users should qualify against the specific chemical package.

    Blow-pin calibration and cooling-time management govern cycle time more than resin choice. The grade has a Vicat softening temperature of 127 °C and a Shore D hardness of 64, which permits demolding at average part surface temperatures near 70 °C–80 °C. Mold cooling channels should maintain the cavity side at 10 °C–20 °C; lower temperatures increase condensation risk, while higher temperatures extend the post-blow cooling stage. Cycle-time reductions below the cooling limit can create post-mold shrinkage and top-load loss in containers.

    The differentiation of L4555X02 from other HDPE grades is most visible in the melt-flow and stress-crack comparison.

    Comparative positioning of L4555X02 against common HDPE processing families
    ParameterL4555X02Fractional-melt film HDPEHigh-flow injection HDPE
    Melt flow rate, 190 °C/2.16 kg0.30 g/10 min0.05–0.10 g/10 min20–30 g/10 min
    Density0.955 g/cm³0.945–0.950 g/cm³0.960–0.965 g/cm³
    Tensile stress at yield29 MPa25 MPa32 MPa
    ESCR, 100% Igepal, F50>600 h>1000 h<50 h
    Primary conversion routeExtrusion blow molding, sheetBlown filmInjection molding

    The principal trade-off is that injection molding grades sacrifice stress crack resistance for flow, while fractional-melt film grades have higher stress crack resistance but lower melt flow. L4555X02 occupies the blow-molding middle ground. In extrusion blow molding, the combination of 0.30 g/10 min MFR and 0.955 g/cm³ density yields a stiffer container than lower-density film resins while retaining enough flow for accumulator heads. The density difference of approximately 0.005 g/cm³ may appear small; however, top-load stiffness scales with wall thickness cubed, so small density changes are only one part of part design.

    Melt fracture onset is governed by die-lip shear and chrome geometry

    Surface melt fracture in this material class typically appears as matte bands or sharkskin on the outer parison surface. It occurs when the wall shear stress at the die land exceeds a critical threshold. For high-molecular-weight HDPE, the threshold is often between 0.2 MPa and 0.4 MPa at melt temperatures near 190 °C–210 °C; published data for L4555X02 at specific blow-molding die gaps is limited. Reducing extruder speed, raising die temperature by 5 °C, or widening the die land can suppress the defect. A polished chrome die lip with roughness below 0.1 µm Ra extends the shear-rate window before melt fracture onset.

    Regulatory compliance and migration-test boundaries

    The base resin is documented for food-contact use under FDA 21 CFR 177.1520, which covers olefin polymers. That citation does not provide unconditional approval for every finished article; the converter must verify extractives and end-use migration because processing aids, colorants, and regrind alter the compliance profile. The grade is also managed within REACH registration obligations and is evaluated under RoHS 2011/65/EU for restricted heavy metals. No specific medical-grade statement is implied unless a separate letter is provided.

    For high-humidity storage, external surface moisture should be removed by drying at 60 °C–80 °C for 1 h–2 h if visible condensation is present. The resin is not hygroscopic, but pellet-surface water can produce surface defects and increase melt-pressure fluctuations. Avoid sustained melt temperatures above 230 °C and accumulator residence times beyond 10 min; the combined condition accelerates oxidative chain scission and creates gels in the parison. The grade should not be blended with acidic purging compounds or left stagnant across a shutdown without purging because carbonized residue can detach into the next production batch.

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