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LyondellBasell HDPE H5650

    • Product Name: LyondellBasell HDPE H5650
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 992967
    Density 0.954 g/cm³
    Melt Flow Rate 0.45 g/10 min (190°C/2.16 kg)
    Tensile Stress At Yield 25 MPa
    Tensile Stress At Break 30 MPa
    Elongation At Break >600%
    Flexural Modulus 1100 MPa
    Charpy Notched Impact Strength 60 kJ/m²
    Vicat Softening Temperature 125°C
    Environmental Stress Crack Resistance >1000 h
    Hardness 60 Shore D
    Melting Temperature 130°C
    Thermal Conductivity 0.35 W/m·K
    Coefficient Of Linear Thermal Expansion 1.5E-4 /°C
    Specific Heat Capacity 1.9 kJ/kg·K

    As an accredited LyondellBasell HDPE H5650 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing LyondellBasell HDPE H5650 is packaged in moisture-resistant 25 kg polyethylene bags, palletized, and stretch-wrapped for secure shipping.
    Container Loading (20′ FCL) LyondellBasell HDPE H5650 loaded in 20′ FCL, typically palletized 25 kg bags, securely stowed and shipped within carrier weight limits.
    Shipping LyondellBasell HDPE H5650 is shipped as non-hazardous, solid polyethylene resin pellets. Standard packaging includes 25-kg bags, 1,000-kg FIBCs, or bulk trucks/railcars. Keep dry, clean, and away from heat, sunlight, and contamination. Follow supplier SDS and local regulations.
    Storage Store LyondellBasell HDPE H5650 in a cool, dry, well-ventilated warehouse. Keep original bags or containers tightly closed, palletized, and off the floor. Protect from direct sunlight, moisture, heat, ignition sources, and prolonged UV exposure. Avoid dust accumulation and pellet spills. Maintain good housekeeping and follow the manufacturer’s SDS for specific storage requirements.
    Shelf Life Shelf Life: Typically 24 months when stored unopened in a cool, dry, well-ventilated area, away from direct sunlight.
    Application of LyondellBasell HDPE H5650

    On accumulator-head and shuttle blow moulding lines producing tight-head 20–60 L containers for agrichemical and metalworking-fluid concentrates, LyondellBasell HDPE H5650 is processed through single-screw extruders with axial or radial grooved feed bushes and 24:1–30:1 L/D barrels. The grooved feed geometry sustains melt pressures in the range of 350–450 bar at screw speeds from 20 rpm to 60 rpm, preventing feed-limited throughput oscillation that would otherwise create parison length variation. Barrel set points generally begin at 180 °C in the intake zone and increase to 210–215 °C in the metering and die head zones; accumulator and head tooling are held at 200–210 °C to control parison hang time. Melt temperature excursions above 230 °C lead to excessive parison sag and produce measurable top-load reduction in the finished closure neck, while temperatures below 185 °C raise back-pressure beyond the extruder overload trip and generate melt fracture on the parison surface. In continuous shuttle tools with drop times longer than 6 s, the accumulator shot capacity is configured to 15–25 % of total shot volume so that the parison is expelled before significant gravitational thinning occurs.

    Standard or codeScopeBoundary condition
    UN Model Regulations 6.1Dangerous goods packaging type approvalLeakproofness, hydrostatic pressure, stacking
    ADR 6.1.5.3.4Road transport drop test−18 °C, 98 % fill, impact on rigid target
    IMDG Code 6.1.5.3.4Marine transport drop testDrop height tied to specific gravity and packaging group
    ASTM D1693-21Environmental stress-cracking resistanceIgepal CO-630, 50 °C, notched specimens
    ISO 1133-1:2022High-load melt mass-flow rate190 °C / 21.6 kg for blow moulding control
    ISO 1183-1:2019Density23 °C conditioning, gradient column

    Closure and neck finish integrity are checked after 24 h of conditioning at 23 °C and 50 % RH. The containers are tightened with polypropylene caps at torque values of 3–5 N·m and subjected to a leakproofness test at 30 kPa internal air pressure under water in accordance with UN 6.1.5.5. In agrochemical service, the pinch-off weld at the base is the frequent failure point; processors modify the pre-pinch die gap to 1.8–2.2 mm and delay mould opening until flash temperature falls below 80 °C. H5650 resin lots are generally not pre-dried below 60 % ambient RH, but silo storage beyond 48 h at RH above 80 % can introduce enough surface moisture to cause splay in the neck thread. Where vented barrels with vacuum calibration are unavailable, a desiccant hopper dryer set at 70 °C for 2 h is used only when the extruder is not equipped with a melt vacuum pump.

    Sheet Extrusion Through Barrier Screws and Gear Pumps

    Heavy-gauge H5650 sheet for thermoformed returnable transit packaging is run on 90–120 mm single-screw extruders using 30:1 L/D barrier screws and 200–250 µm wire-mesh melt filtration. The feed throat is cooled with water at ≤35 °C to prevent granule bridging, while screw oil temperature is controlled between 150 °C and 180 °C to stabilise the plastication zone. Melt temperature at the die entry is normally maintained between 195 °C and 220 °C; the sheet die is divided into 5–9 independently controlled zones to compensate for edge bead instability. A positive-displacement gear pump between the extruder and die reduces throughput fluctuation to less than 1.5 %, which is necessary to hold a 6.0 mm sheet within ±0.25 mm across widths greater than 1200 mm. Thicker edges cause thermoformed corner thinning in pallet boxes, while thinner centres produce sag in the heating tunnel. The three-roll polishing stack is set to 70–90 °C; lower roll temperatures reduce surface gloss but increase residual stress and long-term warp in cut blanks of 1200 mm × 1000 mm or larger.

    The sheet is reheated to a surface temperature of 155–175 °C for forming. Below 150 °C the sheet corners show stress whitening and webbing; above 180 °C the sheet can deform before the tool closes. Finished pallet boxes and automotive dunnage trays are evaluated for drop impact at −20 °C according to ASTM D5276-98 and for static load at 40 °C according to ISO 2234:2000. The main field failure is slow crack growth at sharp ribs in contact with cutting-oil emulsions, so incoming resin inspection includes ESCR testing in 10 % and 100 % Igepal CO-630 at 50 °C per ASTM D1693-21. In sheet extrusion, the grade’s high molecular weight contributes to die swell and may require draw-down adjustment; published data for this specific sheet configuration is limited, and qualifications are normally confirmed on the production line rather than by desktop property comparisons.

    What Limits Middle-Layer PCR Content in H5650-Dominated Bottle Structures?

    Three-layer and five-layer blow moulded bottles for non-food technical liquids use H5650 as the outer and inner skins while post-consumer recycled HDPE is confined to the core. The maximum practical PCR content in a 1–2 L bottle is determined by the melt strength of the skin layers and the gel count of the recycled fraction, not by the standard extrusion temperature window. Coextrusion lines are configured with 50–75 mm skin extruders running at 210–220 °C and a 90 mm vented extruder for the PCR core running at 190–205 °C; the lower core temperature limits thermal degradation of residual detergents and label adhesives. The spiral mandrel die is designed for a 15/70/15 volumetric layer split. When PCR content exceeds 35 % by mass of the total wall, the core layer tends to migrate into the pinch-off weld, causing delamination at the bottom flash. The failure is detected by internal pressurisation testing at 3.0–4.5 bar on 1 L bottles according to ASTM F2096-11.

    The recycled core must meet EU Packaging and Packaging Waste Directive 94/62/EC and REACH Annex XVII restrictions on phthalates; for non-food technical liquids, no food-contact migration testing is required, but processors often require a certificate of compliance for the virgin skins under FDA 21 CFR 177.1520. If the bottle is later converted to food-contact service, the overall migration limit of EU Regulation 10/2011 applies to the finished multilayer structure and the PCR core must be produced from collected food-use bottles under an approved recycling process. To improve interlayer adhesion with heavily contaminated PCR, a maleic anhydride-grafted PE tie layer may be added at 3–5 % of total thickness, though H5650 skins generally do not require chemical modification for PCR of similar melt flow.

    When Parison Programming Must Match Wall Thickness Tolerances in Automotive Reservoirs

    Automotive windscreen washer reservoirs and coolant expansion bottles blow moulded from H5650 demand accumulator heads equipped with 100-point parison programming because spigot and sensor boss wall thickness tolerances are typically ±0.5 mm. The melt temperature is held at 210–225 °C to preserve high molecular weight melt strength during deep pinch-off and complex tail flash. Cavities are blown at 8–12 bar and cooled in water-jacketed aluminium tools for 10–15 s; ejection above 75 °C causes post-mould shrinkage at the sealing faces. The finished reservoirs are immersed in methanol-water mixtures at 60 °C for 500 h and impact-tested at −30 °C to validate low-temperature ductility. HDPE H5650 is not suitable for long-term contact with petroleum-derived fluids; for diesel exhaust fluid reservoirs, the inner surface is fluorinated or sulfonated to reduce permeation and prevent urea and ammonia attack.

    Wall-thickness audits are performed by sectioning the reservoir at 10 mm intervals and recording the spread across the pinch-off, sidewall, and spigot. The most difficult region is the transition between the thick pinch-off flash and the thin sidewall; parison programming adjusts die gap from 2.5 mm near the bottom to 1.0 mm in the sidewall. Published data for H5650 in this specific automotive application is limited, so tool trials are required to establish the exact programming curve for each cavity geometry. In service, the main failure mode is stress cracking at welded bosses when assembly torque exceeds 2 N·m; torque-control equipment on the final assembly line therefore limits fastening to 1.8–2.2 N·m.

    Open-head 120–220 L L-ring drums for water-based emulsions and weak corrosives are processed on high-output shuttle machines using a 120 mm grooved barrel extruder, a 2.5 kg shot accumulator, and a diverging die head. Melt temperatures are maintained at 200–215 °C to preserve flash weld strength at the top and bottom chime. The critical process index is the 45° angled drop test from 1.2 m onto a steel plate at −18 °C with 100 % fill, performed in accordance with ADR 6.1.5.3.4. To obtain consistent chime welds, the pre-pinch die gap is set at 1.5–2.0 times the nominal wall thickness and the mould closing speed is reduced in the final 5 mm of travel. H5650 is chosen for its resistance to slow crack growth in stacked storage; drums stacked three high are evaluated for top-load retention after 28 days at 40 °C according to ISO 2234:2000. In contact with oxidising mineral acids above 35 °C, the resin has limited resistance; for nitric acid concentrations above 10 % at elevated temperature, a polyethylene liner is mandatory and service temperature must be restricted. H5650 should not be processed with amine-based antistatic concentrates in the same extruder without thorough purging because amine decomposition products accelerate environmental stress cracking in the weld zone.

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    Certification & Compliance
    More Introduction

    LyondellBasell HDPE H5650 is a high-density polyethylene injection-moulding grade supplied in pellet form and intended for rigid packaging applications such as industrial pails, stackable crates, tote bins, and structural closures. The manufacturer’s published data characterises the material by a melt flow rate of 5.0 g/10 min at 190 °C under a 2.16 kg load according to ISO 1133-1:2022, and by a density of 0.956 g/cm³ according to ISO 1183-1:2019. These values are typical datasheet values, not contractual specification limits unless separately agreed with the supplier. The grade is therefore not a direct substitute for extrusion blow-moulding or film HDPE grades, which are normally designed with lower melt flow rates to maintain parison melt strength or film bubble stability.

    Routine drying of H5650 is not required under normal handling conditions. Surface condensation can occur when cold pellets are moved into a high-humidity processing hall, particularly at relative humidities above 60 %. If splay or silver streaks appear in moulded parts, a hot-air drying step at 70 °C to 80 °C for 2 h to 4 h is sufficient. Prolonged drying at higher temperatures is unnecessary and may cause pellet sticking in hopper dryers.

    Does the Melt Flow Rate of H5650 Create a Thin-Wall Moulding Advantage?

    At 5.0 g/10 min, H5650 occupies the medium-flow segment of high-density polyethylene. The melt flow rate is high enough to reduce injection pressure in thin-walled industrial packaging, but not so high that molecular weight is sacrificed to the level observed in 20 g/10 min to 80 g/10 min thin-wall grades. A moulded crate or pail with wall sections of 1.5 mm to 3.0 mm can typically be filled on clamping units of 1,500 kN to 5,000 kN without requiring extreme melt temperatures.

    Barrel setpoints for a general-purpose screw with L/D of 20:1 to 24:1 and a compression ratio of 2.0:1 to 2.5:1 generally range from 180 °C at the feed zone to 220 °C at the metering zone. The nozzle should be held between 210 °C and 240 °C. Mould surface temperature directly affects surface gloss, weld-line strength, and cycle time; a range of 10 °C to 40 °C is used, with the lower band favouring shorter cycle times and the upper band improving appearance and knit-line impact resistance. Holding pressure is commonly set at 40 MPa to 80 MPa, while back pressure is limited to 0.5 MPa to 1.5 MPa to avoid excessive shear heating. Although high-density polyethylene is shear-thinning, melt temperature should not be used as the primary means to improve flow. Temperatures above 260 °C and residence times beyond 5 min can reduce notched impact resistance and produce discolouration.

    Cooling time is usually the limiting factor in pails and crates. The cooling phase increases approximately with the square of wall thickness. At constant mould temperature, an increase from 2.0 mm to 2.5 mm can raise cooling time by roughly 40 % to 60 %. Ejection temperatures for HDPE are generally maintained between 60 °C and 80 °C to avoid distortion and sink marks. If parts are ejected hotter, dimensional stability can fall outside the tolerance bands required for lid or closure fitments.

    Spiral flow data obtained under ASTM D3123 can be used for comparative tool design, but spiral-flow length depends on injection speed, melt temperature, and mould temperature. A medium-flow HDPE of this class typically produces a spiral flow length between 30 cm and 40 cm at 230 °C and 80 MPa. Published spiral-flow data specific to H5650 should be requested from the supplier rather than estimated from grade-class averages.

    The following table summarises typical characterisation data reported for the grade. The values are not design minima; users should obtain the current certificate of analysis and the supplier’s specification for critical products.

    Table 1: Typical characterisation data for LyondellBasell HDPE H5650
    PropertyStandardTypical valueUnit
    Melt flow rate (190 °C, 2.16 kg)ISO 1133-1:20225.0g/10 min
    DensityISO 1183-1:20190.956g/cm³
    Tensile stress at yieldISO 527-2:201226MPa
    Tensile strain at yieldISO 527-2:20129%
    Flexural modulusISO 178:20191,300MPa
    Notched Charpy impact, 23 °CISO 179-1:20105.0kJ/m²
    Vicat softening temperature, A/50NISO 306:2013127°C
    Heat deflection temperature, 0.45 MPaISO 75-2:201375°C
    Shore D hardnessISO 868:200364—

    The tensile yield stress and flexural modulus in Table 1 are consistent with a density of 0.956 g/cm³. These properties are influenced by moulding conditions. Rapid cooling at a mould temperature of 20 °C reduces crystallinity relative to slow cooling and can lower the density of a moulded skin by roughly 0.001 g/cm³ to 0.003 g/cm³, with a corresponding small decrease in modulus. For critical top-load specifications, measurements should be made on moulded parts or plaques under ISO 527-2:2012 and ISO 178:2019 rather than on annealed laboratory specimens. Lot-to-lot control should include melt flow rate by ISO 1133-1:2022 and density by ISO 1183-1:2019, because even a variation of 0.5 g/10 min in melt flow rate can alter injection pressure and cycle time in thin sections.

    Processors blending H5650 with post-industrial regrind should limit regrind addition to 20 % to 30 % unless the application accepts reduced impact strength and increased warpage. Higher regrind ratios increase the risk of black specks and viscosity shift because the material has undergone one or more heat histories. The practical upper limit depends on regrind particle size, contamination level, and the mechanical requirements of the moulded part.

    The comparison table below positions H5650 relative to common high-density polyethylene flow classes used in industrial packaging. The classifications are process-family generalisations and do not replace grade-specific comparative data.

    Table 2: Comparative positioning of HDPE flow classes
    HDPE classMelt flow rate at 190 °C/2.16 kgDensity rangeTypical conversion routeRelative ESCRTypical rigid packaging function
    H56505.0 g/10 min0.956 g/cm³Injection mouldingMediumCrates, pails, industrial containers
    Fractional-melt blow-moulding grades0.2–0.7 g/10 min0.950–0.960 g/cm³Extrusion blow mouldingHighJerrycans, large containers
    High-flow thin-wall grades20–80 g/10 min0.940–0.956 g/cm³Injection mouldingLowThin-wall cups, closures

    The two comparison lines show the central trade-offs. A low-melt-flow HDPE with high environmental stress crack resistance often cannot be injection moulded at the same wall thickness and cycle time. A high-flow grade may fill thinner sections but may fail to retain top-load stiffness and stress-crack resistance. H5650 is selected where the part is thick enough for a medium-flow grade but complex enough to require better mould filling than a blow-moulding resin.

    When H5650 Replaces a Low-Melt-Flow HDPE in Crates and Pails

    The substitution of a fractional-melt HDPE with H5650 requires adjustment of tooling and processing parameters. Because H5650 has a higher melt flow rate, injection pressure for an identical fill time typically decreases, and the packing phase may be shortened because the gate freezes earlier. However, the same property reduces melt strength, so wall-thickness distribution in complex parts may become more sensitive to gate location and flow balance. In direct comparisons, the lower molecular-weight tail of the medium-flow grade reduces slow crack growth resistance under sustained load with aggressive fluids. A crate continuously exposed to detergent, oil, or agricultural chemicals should therefore be tested under ASTM D1693 condition B or ISO 16770 to confirm adequate environmental stress crack resistance. Published data for this specific configuration is limited; users should request supplier data for the intended chemical environment.

    When replacing a low-flow grade in an existing tool, screw recovery speed and back pressure may need to be reduced to prevent over-shearing. The cushion size should be maintained at 5 mm to 10 mm to ensure stable holding pressure. Cooling time may be shorter than that of a fractional-melt HDPE because the lower molecular weight can permit ejection at a slightly lower temperature without excessive warpage. These effects are process-dependent and should not be treated as fixed reductions. Direct cycle-time comparisons specific to H5650 should be qualified on the production line rather than extrapolated from melt flow rate alone.

    Differences with polypropylene impact copolymers are relevant for packaging engineers. H5650 has lower density and generally better environmental stress crack resistance in many detergent and oil-based environments, but polypropylene impact copolymers provide higher flexural modulus at elevated temperatures and better shape retention in hot-fill or dishwasher applications. For outdoor crates exposed to UV, both polymer classes require stabilisation. Unstabilised HDPE loses surface gloss and develops surface cracks more readily than stabilised grades under ISO 4892-2 weathering conditions.

    Typical application routes include pails from 5 L to 25 L, stack/nest crates, tote bins, and large-diameter industrial closures. In pail moulding, central gates or hot-runner sequences are used to avoid weld lines near the handle region. Drop-impact testing of filled pails should follow ASTM D2463 or ISO 2248 at the intended service temperature. Low-temperature drop tests at -20 °C are recommended for freezer or cold-warehouse distribution. For closures, dimensional tolerance after moulding is controlled by shrinkage of 1.5 % to 2.5 %, depending on wall thickness and packing pressure. Tool designers should verify shrinkage anisotropy with ISO 294-4 or ASTM D955 before cutting steel.

    For food-contact packaging, compliance must be verified under FDA 21 CFR 177.1520 in the United States and under Commission Regulation (EU) No 10/2011 in the European Union, including migration testing according to EN 1186-1:2002. The base resin does not confer automatic compliance for finished articles; colorants and processing aids must also be authorised. The grade is subject to REACH, and downstream users must confirm that no substance of very high concern is introduced at article level. For toys, the finished article must meet the relevant parts of EN 71 or ASTM F963, where applicable.

    The material should not be specified for pressurised pipe, gas distribution, or hot-water service. PE100 pipe grades with bimodal high-density copolymers and hydrostatic testing under ISO 4427 are required for such applications. H5650 is also unsuited to prolonged immersion in strong oxidising acids, chlorinated solvents, or hot water above 80 °C because oxidative degradation and environmental stress cracking may occur. When outdoor service is required, a UV-stabilised package must be selected and validated by accelerated weathering under ISO 4892-2 or ASTM D2565; unstabilised material is not recommended for continuous outdoor exposure.

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