| HS Code | 391481 |
| Material Type | High Density Polyethylene (HDPE) |
| Density | 0.959 g/cm3 |
| Melt Flow Rate 190c 5kg | 0.25 g/10 min |
| Tensile Strength At Yield | 24 MPa |
| Tensile Elongation At Break | >600% |
| Flexural Modulus | 1100 MPa |
| Charpy Notched Impact Strength 23c | 15 kJ/m2 |
| Vicat Softening Temperature | 127 °C |
| Brittleness Temperature | < -70 °C |
| Environmental Stress Crack Resistance | >5000 h |
| Oxidative Induction Time | >20 min |
| Carbon Black Content | 2.5% |
| Moisture Absorption | <0.01% |
| Thermal Conductivity | 0.4 W/mK |
| Coefficient Of Linear Thermal Expansion | 1.5E-4 /°C |
| Dielectric Constant | 2.3 |
| Volume Resistivity | >1E15 ohm·cm |
| Ul94 Flame Rating | HB |
As an accredited LyondellBasell HDPE ETP H5656 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | LyondellBasell HDPE ETP H5656 is packaged in 25 kg polyethylene bags, 55 bags per pallet (1,375 kg net). |
| Container Loading (20′ FCL) | 20′ FCL loading for LyondellBasell HDPE ETP H5656: 25 kg bags, approximately 18 metric tons net, securely stowed and weight-distributed. |
| Shipping | LyondellBasell HDPE ETP H5656 is a non-hazardous polyethylene resin supplied as pellets. It is packaged in 25 kg bags, bulk boxes, or bulk trucks/railcars. Ship under standard freight conditions in a dry, clean vehicle; avoid moisture, contamination, and excessive heat. No UN placards required. |
| Storage | Store LyondellBasell HDPE ETP H5656 in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, flames, and strong oxidizers. Keep original bags sealed on pallets, off the floor, to prevent moisture and contamination. Avoid prolonged UV exposure. Use first-in, first-out. Clean spills promptly, as pellets can be slippery. |
| Shelf Life | Stable HDPE resin; recommended shelf life is 24 months from delivery when stored dry, unopened, and protected from UV light. |
In corrugated HDPE drainage pipe conversion, HDPE ETP H5656 is let down with a polyethylene-based carbon black masterbatch at 20:1 to 25:1 by mass, yielding final carbon black dispersion between 2.0 wt% and 2.5 wt%. The compound is handled through a silo purge system to keep surface moisture below 200 ppm before entering a single-screw extruder with L/D 30:1 to 36:1. Barrel zone settings of 170 °C, 185 °C, 200 °C, 205 °C, and 210 °C keep melt temperature between 195 °C and 215 °C. The melt is forced through a 0.5 mm to 0.8 mm die gap onto corrugator forming blocks. Vacuum in the forming blocks is maintained at 0.06 MPa to 0.08 MPa to pull the outer wall into the mold cavities. Melt fracture appears when melt temperature drops below 190 °C or when die gap is reduced below 0.4 mm, producing shark-skin surface defects that lower ring stiffness. Production-scale corrugators running 4 m/min to 9 m/min require balanced air cooling between the inner mandrel and outer block to avoid double-wall weld-line distortion. Formulation boundaries for this track exclude filler loading above 1.0 wt% because filler increases creep modulus but reduces environmental stress crack resistance. The compound should not be combined with amine-based processing aids in the same extruder; heat stabilizer packages are pre-compounded and re-adding primary antioxidants above 0.10 wt% shifts melt viscosity downward and can destabilize wall thickness. Regrind use from corrugated pipe start-up and cut scrap is controlled at 15 wt% to 20 wt% maximum, with screen packs at 60/80/120 mesh removing gel contamination. At 20 wt% regrind, pipe stiffness per ASTM D2412 typically falls by 4% to 6% relative to virgin resin.
| Property | Standard | Control window |
|---|---|---|
| Density | ASTM D1505 | 0.954–0.958 g/cm³ |
| High-load melt index | ISO 1133-1:2022 at 190 °C/21.6 kg | 5.0–6.2 g/10 min |
| Carbon black content | ASTM D4218 | 2.0–2.5 wt% |
| Environmental stress crack resistance | ASTM D1693 Condition C | >1000 h |
| Pipe stiffness | ASTM D2412 | ≥320 kPa for 100 mm ID |
Corrugator cooling water inlet temperature is held at 15 °C to 20 °C, while the return water temperature is 25 °C to 30 °C. Return water above 35 °C slows outer-wall crystallization and causes formed corrugations to spring back; return water below 10 °C produces condensation and surface marking on the blocks. The inner die mandrel is typically set 2 mm to 3 mm larger than the finished inner wall diameter after shrink compensation. Finished products include agricultural drainage tubing, stormwater retention chambers, land-drain tile, and telecommunications duct qualified to NEMA TC 7.
Flat-die extrusion of HDPE ETP H5656 into 40 mil to 120 mil geomembrane begins with resin moisture control only when silo storage relative humidity exceeds 80% for more than 48 h; otherwise atmospheric handling is sufficient. The extrusion line typically uses a L/D 34:1 barrier screw with a 2.2 m flex-lip die. Melt temperature is held between 210 °C and 230 °C. Polished three-roll stack temperatures are set at 75 °C, 85 °C, and 90 °C to control gloss and frozen-in stress. The finished sheet is run through a structured embossing roll or nitrogen gas texturing station when textured geomembrane is required. For smooth liner, gauge variation across 4 m width is kept below ±5%. Formulation for geomembrane converts at 97.0 wt% resin to 3.0 wt% carbon black/stabilizer masterbatch, resulting in final carbon black concentration near 2.0 wt%. The stabilizer system is not modified by post-addition. Welded seam trials evaluate sheet under ASTM D5397 notched constant tensile load at 50 °C in 10% Igepal CO-630 solution; a transition time below 400 h indicates insufficient stress crack resistance for landfill base liner service. Oxidative induction time measured per ASTM D3895 at 200 °C must remain above 80 min for exposed black liner grades. Fusion wedge welding parameters for 2.0 mm sheet typically use wedge temperature 260 °C to 280 °C, speed 1.0 m/min to 1.6 m/min, and roller pressure 0.15 MPa to 0.25 MPa. Peel tests on welds use ASTM D6392; shear tests use ASTM D1004. Failure in the sheet rather than the weld is required for landfill liner qualification. Terminal products include landfill cap liners, mine heap leach pads, pond liners, and secondary containment flooring.
Accumulator-head blow molding of HDPE ETP H5656 into 25-L UN-rated jerrycans operates with a 80 mm extruder, L/D 24:1 to 30:1, and a die gap of 0.8 mm to 1.2 mm. Melt temperature is kept between 180 °C and 200 °C. Parison swell in this regime ranges from 25% to 60%, depending on die geometry and accumulator push rate. Clamp force is set at 1.5 kN to 2.5 kN per litre of container volume, so a 25-L tool requires 40 kN to 65 kN. When the parison sags more than 15% of initial length, wall-thickness variance exceeds 0.4 mm and drop-impact results under ASTM D2463 become inconsistent. The die head temperature is trimmed 5 °C lower than the accumulator to restore melt strength without raising back pressure above 25 MPa. Parison programming uses a 20-point wall-thickness controller; the die gap is widened to 1.2 mm at the bottom and reduced to 0.7 mm at the top to compensate for sag during inflation. The accumulator push speed is set at 15 mm/s to 30 mm/s. Faster push causes melt fracture at the die lip. Blow pressure is 0.6 MPa to 0.8 MPa and blow time is 35 s to 60 s for 2.0 mm nominal wall.
The compound is dry-blended with 1.5 wt% to 2.0 wt% color masterbatch and processed without filler. No post-consumer recycle is used in UN-certified dangerous goods containers unless a 25 wt% internally generated regrind stream is validated by drop testing at -18 °C per ADR 6.1.3 and IMDG Code Chapter 6.1. Food-contact liners for non-hazardous liquids are qualified under 21 CFR 177.1520 for olefin polymers. ESCR testing on blow molded containers uses ASTM D1693 Condition B; the minimum acceptable time is 200 h for 10% Igepal CO-630 at 50 °C. Terminal products include 20-L to 30-L jerrycans, tight-head industrial drums, and intermediate bulk container liners.
Heavy-gauge shuttle thermoforming shifts the risk from melt instability to surface cooling uniformity in HDPE ETP H5656 sheet. Extruded sheet thickness between 2.0 mm and 6.0 mm is conditioned at 80 °C for 4 h when ambient relative humidity is above 70%; moisture beyond 300 ppm creates micro-bubbles at the plug-contact surface. The thermoformer uses a shuttle oven with top and bottom quartz heaters set to 330 °C and 350 °C zone temperatures. Sheet surface is brought to 160 °C to 175 °C before forming. Plug assist is executed with syntactic foam or HDPE plugs at 70 °C to 90 °C, and the mold is maintained at 80 °C to 110 °C. Cycle times for 4 mm sheet fall between 90 s and 130 s. Part warpage increases when demolding occurs above 70 °C; dimensional stability against a flatness fixture is checked after 24 h at 23 °C/50% RH. Sheet extrusion for heavy-gauge thermoforming uses a 120 mm extruder, L/D 36:1, flat die width 1500 mm, lip gap 2.0 mm to 6.5 mm. The roll stack is set at 70 °C/80 °C/85 °C. Line speed for 4 mm sheet is 3.5 m/min to 5.0 m/min. Regrind from trim and rejected parts is fed back at 20 wt% to 25 wt% with virgin HDPE ETP H5656 using gravimetric blending. Loading above 30 wt% reduces flexural modulus measured to ASTM D790 by more than 8% and produces visible knit lines at corners. The application-specific control set includes tensile yield strength above 22 MPa per ASTM D638 Type IV and ESCR above 300 h per ASTM D1693 Condition B. Terminal products include automotive returnable dunnage trays, battery transport trays, pallet tote lids, and chemical drum sump trays.
Monofilament extrusion for industrial netting runs a 45 mm to 65 mm single-screw extruder with L/D 30:1 and a spinneret hole diameter of 1.2 mm to 2.0 mm. The melt phase is kept at 205 °C to 220 °C. Quenching occurs in two sequential water baths held at 35 °C and 45 °C; a quench temperature below 30 °C freezes a coarse spherulitic skin that limits drawability. The as-spun filament is drawn at 8:1 to 12:1 between a heated godet at 90 °C and a second godet at 110 °C. A low draw ratio below 7:1 leaves tensile break stress below 300 MPa measured by ASTM D2256. Draw resonance at ratios above 12:1 appears as periodic diameter variation exceeding ±5%. The compound is stabilized with a HALS/UV package at 0.20 wt% to 0.45 wt% added as a 10 wt% masterbatch. No filler is permitted in monofilament for netting; filler above 0.5 wt% initiates surface crazing under knotted-load conditions. Published data for this specific configuration in HDPE ETP H5656 monofilament is limited, so laboratory screening using ASTM D3822 for filament tensile and ASTM D638 for compression-molded controls is recommended before production. The oriented filament is annealed at 105 °C to 115 °C for 0.5 s to 1.5 s to reduce shrinkage. Free shrinkage per ASTM D2259 must be below 5% at 130 °C. Terminal products include anti-bird netting, fish cage netting, construction safety netting, and geogrid joining filaments.
In cable-innerduct profile extrusion, pressure sizing of the HDPE ETP H5656 tube is preferred over free extrusion because residual ovality must remain below 2% for fiber-optic pulling operations. The line uses a 60 mm grooved-feed extruder with L/D 36:1 and a die land length ratio of 15:1. Melt temperature is controlled at 190 °C to 205 °C. The sizing sleeve is held at 20 °C to 25 °C and vacuum is maintained at 0.02 MPa to 0.04 MPa. A line speed of 15 m/min to 40 m/min depends on wall thickness from 0.8 mm to 1.6 mm. The extrudate is cooled in a 10 m water spray chamber and then printed with pull-line markings. Surface defects occur when melt exits above 210 °C; the outside wall develops axial scoring at the sizing entry due to insufficient quench. Regrind from start-up and printing rejects is limited to 15 wt%. The innerduct is tested for crush resistance per ASTM D2412 with parallel-plate loading; at 25% deflection, the load is held for 60 s to confirm recovery to at least 90% of original diameter. A QC compliance matrix is applied before coils are released.
| Application | Standard | Checkpoint |
|---|---|---|
| Smooth-wall coilable HDPE conduit | ASTM F2160 | Wall thickness ±0.1 mm; ovality <2% |
| Material classification | ASTM D3350 | Density 0.954–0.958 g/cm³; ESCR >300 h |
| Telecom raceway coil | NEMA TC 7 | Pull-line marking intact; no melt fracture |
Inline perforation and coiling are performed under constant reel tension of 0.5 N/mm² to prevent layer crushing. Pre-installation site bends are limited to 10 times the outside diameter for cold forming; tighter bending at ambient temperatures below 5 °C introduces stress whitening on the compression side of the conduit. Terminal products include fiber-optic innerduct, cable protection raceways, and microduct bundles for air-blown fiber installation.
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LyondellBasell HDPE ETP H5656 is supplied as a medium-flow high-density polyethylene resin with a nominal density of 0.956 g/cm³ and a melt flow rate of 5.6 g/10 min at 190 °C under a 2.16 kg load, as determined according to ISO 1183-1 and ISO 1133-1:2022. The grade occupies a stiffness-flow position that permits use in thin-wall injection molding, overcaps, closures, crates, housewares, and industrial containers where rapid filling, surface replication, and dimensional repeatability are required. The designation H5656 identifies the specific balance of density and flow within the ETP series; lot-specific certificates should be reviewed before tooling decisions because batch-to-batch variation remains within the supplier’s specification window.
The representative values below are not guaranteed minima or maxima; they are supplied for preliminary engineering comparisons only.
| Property | Test method | Representative value |
|---|---|---|
| Density | ISO 1183-1 | 0.956 g/cm³ |
| Melt flow rate, 190 °C/2.16 kg | ISO 1133-1:2022 | 5.6 g/10 min |
| Tensile stress at yield | ISO 527-2/1A/50 | 28 MPa |
| Flexural modulus | ISO 178 | 1450 MPa |
| Notched Izod impact, 23 °C | ISO 180/A | 4.5 kJ/m² |
| Vicat softening temperature, A50 | ISO 306 | 126 °C |
| Mold shrinkage | ISO 294-4 | 1.5–2.0 % |
The combination of 0.956 g/cm³ density and 5.6 g/10 min melt flow rate places the material between low-flow fractional-melt HDPE grades used in extrusion blow molding and high-flow injection molding specialties. Dimensional stability is governed primarily by mold temperature uniformity, packing pressure, and gate freeze time, with the indicated shrinkage envelope applying only under standardized ISO 294-4 specimen conditions.
Fractional-melt HDPE grades used in extrusion blow molding typically exhibit melt flow rates below 1.0 g/10 min at 190 °C/2.16 kg. Their higher molecular weight increases melt strength and parison sag resistance, but the same molecular architecture raises injection pressure, shortens flow length, and reduces cavity replication in thin-wall tools. ETP H5656 operates as a lower-viscosity HDPE, meaning that the limiting processing constraint shifts from pressure drop to thermal degradation, gate blush, and venting. At equivalent melt temperature, the medium-flow grade can fill wall sections in the 0.6–1.5 mm range when gate geometry, runner balance, and cavity venting are adequate.
The trade-off is environmental stress cracking resistance and notched impact. ETP H5656 is not a direct substitute for PE100 bimodal pipe resins classified under ISO 9080, and sustained internal pressure applications should not be assumed without hydrostatic design basis data. Similarly, large-part extrusion blow molding that demands high parison melt strength should remain with a fractional-melt HDPE unless multilayer construction or alternative processing aids compensate for the lower molecular weight.
On a general-purpose single-screw injection molding machine with screw diameter between 25 mm and 80 mm, L/D ratio from 20:1 to 25:1, and compression ratio from 2.5:1 to 3.5:1, the resin is plasticated between 200 °C and 240 °C. Mold surface temperatures from 10 °C to 40 °C are common for rapid cycles, although large flat parts may require higher mold temperatures to reduce sink marks, flow lines, and post-mold distortion. Injection velocity should be set to fill the cavity within 0.5–1.5 s for thin-wall configurations, with hold pressure maintained until gate seal. Packing pressure below the compressibility threshold results in volumetric shrinkage at the gate, elevated warpage, and variable part mass.
Weld lines are a critical processing boundary. Flow fronts meeting at a weld line reduce tensile strength, and in unfilled HDPE the retained strength frequently falls between 50 % and 80 % of the parent material when melt temperature is maintained above 220 °C and the weld line is shifted away from high-stress zones. Published data for this specific configuration is limited; mold-filling simulation, short-shot studies, and tensile testing across the weld line using ISO 527-2/1A are required for safety-critical or pressure-containing components. Entrapped air must be removed through end-of-fill vents because air compression at the weld front lowers weld strength and promotes surface delamination.
In applications where the molded article contacts surfactants, fatty oils, or alcohol-based solutions at 40–60 °C, environmental stress cracking becomes the primary failure mode. Medium-flow HDPE grades exhibit lower environmental stress cracking resistance than high-molecular-weight pipe grades, so the relevant test method should be ASTM D1693-15e1 condition B or ISO 22088-3 on molded plaques with notching and wetting agents matched to service conditions. Production-scale failures observed on automatic molding lines often initiate at the injection gate or at sharp internal corners; corner radii below 0.5 mm act as stress risers and should be avoided in ESCR-sensitive parts.
Notched Izod impact measured at 23 °C under ISO 180/A is a screening value only. It does not predict puncture resistance, drop impact, or performance in the presence of stress cracking fluids. When regrind fractions exceed 15 wt%, the melt residence time distribution broadens and the notched impact of the molded article can decline due to molecular weight reduction. Closed-loop granulate handling is acceptable if the regrind is free of polypropylene, EVA, and label adhesives. Machine-specific trials should evaluate Izod impact after 5, 10, and 15 regrind passes because published data for this specific formulation is limited.
Food-contact compliance is not determined solely by the base resin. The finished article must be evaluated with its complete additive and colorant formulation under the intended time–temperature exposure conditions. For HDPE ETP H5656, the following instruments are relevant to initial qualification.
| Regulatory instrument | Applicability | Verification requirement |
|---|---|---|
| FDA 21 CFR 177.1520 | Olefin polymers in contact with food | Finished article must satisfy end-use migration testing under the applicable 21 CFR section. |
| Regulation (EU) No 10/2011 | Plastic materials and articles intended for food contact | Overall migration and specific migration limits must be confirmed under the intended food-contact conditions. |
| Regulation (EC) No 1907/2006, REACH | Substance registration and SVHC communication | Supplier declaration is required for the specific batch and for any added masterbatch. |
| Directive 2011/65/EU, RoHS Recast | Electrical and electronic equipment | Polymer matrix is generally not a source of restricted heavy metals or brominated flame retardants; pigments and additives may alter status. |
Tooling for ETP H5656 requires gate sizes above 1.0 mm for cold-runner systems when wall thickness exceeds 2.0 mm; smaller gates may produce shear heating, gate blush, or premature freeze-off in high-cavitation molds. Hot-runner systems should be designed with thermally uniform manifolds and no dead zones because the medium-flow resin is sensitive to residence time at elevated temperatures. The practical processing boundary is defined by the onset of surface defects and molecular weight loss, not by the inability to fill the cavity. Avoid combination with amine-based additives and unsaturated hydrocarbon process aids unless compatibility is confirmed, because additive interactions can alter color, odor, and food-contact migration behavior.