| HS Code | 331220 |
| Density | 0.90 g/cm³ |
| Melt Flow Rate | 22 g/10 min (230°C/2.16 kg) |
| Tensile Modulus | 1500 MPa |
| Tensile Strength At Yield | 32 MPa |
| Elongation At Yield | 8% |
| Flexural Modulus | 1400 MPa |
| Notched Izod Impact Strength | 30 J/m (23°C) |
| Heat Deflection Temperature | 100°C (0.45 MPa) |
| Vicat Softening Temperature | 150°C |
| Melting Point | 165°C |
| Rockwell Hardness | 95 R |
| Water Absorption | <0.01% |
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LyondellBasell Beon3D PPG 2290S1 Natural is a compounded short-glass-fibre-reinforced polypropylene feedstock supplied for material-extrusion additive manufacturing in filament and pellet formats. The product prefix “PPG” within the Beon3D portfolio denotes a polypropylene matrix carrying chopped glass fibre, while the “2290” block identifies the specific reinforcement level and melt-flow modification, “S1” identifies the stabiliser package, and “Natural” designates an unpigmented, non-nucleated colour state. The grade is intended for extrusion-based platforms operating with nominal filament diameters of 1.75 mm or 2.85 mm and with hardened plastication components. Because the base resin is a semicrystalline polyolefin, equilibrium moisture uptake is lower than that of polyamide or PETG under ISO 62; however, condensation on cold filament surfaces after vacuum-pouch opening remains a handling variable. Product specification sheets should be requested from the supplier and checked against batch-level certificates of analysis before qualification builds, particularly because short-glass fibre length distribution can shift melt viscosity even when the nominal glass loading is unchanged.
For mechanical property reporting, PPG 2290S1 Natural is characterised by ISO 527-2 for tensile properties, ISO 178 for flexural properties, ISO 75-2 for heat deflection temperature, ISO 179-1/1eA for Charpy notched impact, and ISO 1183-1 for density. The chopped glass reinforcement raises the tensile modulus of printed specimens relative to unfilled polypropylene by a factor within the approximate range of 2.5× to 3×, while elongation at break falls from ductile polypropylene values above 10% to semiductile values commonly below 5%. Heat deflection temperature under 0.45 MPa is increased by the glass network, but printed values depend on layer height, infill density, and test specimen orientation under ISO/ASTM 52921. Values obtained from injection-moulded plaques prepared according to ISO 294-4 do not transfer directly to additively manufactured parts.
Short-glass-fibre feedstocks impose specific wear conditions on material-extrusion equipment. The nozzle and any upstream melt-wetted surfaces should be hardened steel or ruby; brass nozzles are unsuitable because chopped glass filaments accelerate bore erosion, producing diameter increase and pressure loss after roughly 2–4 kg of throughput on a conventional single-nozzle FFF platform. A minimum nozzle diameter of 0.4 mm is recommended to reduce clogging; larger 0.6 mm or 0.8 mm orifices are preferable when printing high-flow tooling. Processing temperatures for short-glass PP compounds typically fall in the 240–260°C nozzle band, with heated enclosure temperatures of 45–60°C where available. When spool packaging has been opened in an environment above 60% relative humidity, drying at 80°C for 4 h in a desiccant dryer or vacuum oven reduces moisture-related porosity. Polypropylene build surfaces or polyolefin adhesion promoters are required; polyimide tape and polycarbonate sheets are not suitable for consistent release-free printing.
Because glass fibre length distribution after compounding can shift melt viscosity by several percent, extrusion multiplier and retraction settings should be re-verified for each incoming lot. A melt volume-flow rate test under ISO 1133-1 at 230°C with a 2.16 kg load provides a practical lot-to-lot comparison against the certificate of analysis. Batch-to-batch variation also affects die swell at the nozzle; a diameter check using a dual-axis laser micrometer detects filament ovality above 0.03 mm that can cause feed-roller slip in Bowden-driven systems. Due to the semicrystalline nature of polypropylene and the sensitivity of glass-fibre-matrix coupling, nozzle temperature control should be maintained within ±5°C of the selected setpoint. An uncontrolled overshoot above 270°C promotes matrix oxidation and fibre-matrix debonding, while an excursion below 230°C increases melt viscosity and can strip filament in extruder feed gears.
Production-scale compounding of this product family occurs on twin-screw extruders with downstream pelletising or filament drawing. Glass fibre is typically side-stuffed after the polypropylene melt zone to preserve fibre length; excessive screw severity reduces fibre length and lowers notched impact. When re-extruded through a single-screw FFF extruder with an L/D ratio of 30:1 or longer, additional fibre attrition occurs, so printed parts may show slightly lower modulus than compounded pellets. On pellet-fed additive cells using screw L/D ratios of 24:1 to 32:1, the main bottleneck is usually feed stability rather than plastication capacity. Irregular pellet geometry or excessive fines can cause surging, which appears as layer-width oscillation. Fines from glass-fibre handling should be removed by screening before the vacuum loader.
Layer-to-layer fusion, rather than bulk compound strength, governs anisotropy in PPG 2290S1 Natural. When specimens are printed flat and pulled in the XY plane, measured strengths often approach 60–70% of equivalent injection-moulded polypropylene compound values; when loaded perpendicular to layers, retained strength is commonly 20–40% of the XY value depending on layer height, extrusion temperature, and enclosure temperature. This directional response is amplified by glass-fibre orientation within the deposition path and by the low surface energy of polypropylene, which reduces interlayer diffusion. Reporting Z-axis strength without specifying layer height, extrusion width, print speed, and chamber temperature is therefore non-transferable. Design safety factors should be derived from printed-specimen data rather than from bulk compound data sheets.
Unfilled Beon3D PP grades provide higher elongation and lower nozzle abrasion, but their flexural modulus and heat deflection temperature are insufficient for load-bearing fixtures that must maintain dimensional accuracy during paint-cure or electrocoating cycles. PPG 2290S1 Natural replaces the unfilled product when the design requirement is stiffness retention above 90°C and resistance to hydrocarbon-based cleaning solvents. Compared with glass-filled PLA, the polypropylene matrix offers improved resistance to aqueous alkali and lower equilibrium moisture uptake under ISO 62; however, flexural modulus is lower and build-surface adhesion is more demanding. Compared with glass-filled ABS, chemical resistance to ketone-based solvents is better, but upper-temperature resistance and post-print surface finish are generally lower. The table below provides a directional comparison; entries reflect material class behaviour and are not batch-specific certificates.
| Property or behaviour | Test method | PPG 2290S1 Natural | Unfilled PP | Glass-filled PLA | Glass-filled ABS |
|---|---|---|---|---|---|
| Tensile modulus | ISO 527-2 | High for PP | Low | Higher | Intermediate |
| Elongation at break | ISO 527-2 | Low single digits | Ductile, above 10% | Low single digits | Low single digits |
| Heat deflection temperature | ISO 75-2 | Above unfilled PP | Lower | Intermediate | Intermediate |
| Moisture uptake | ISO 62 | Low | Low | Intermediate to high | High |
| Chemical resistance to aqueous alkali | ISO 175 | Retains mechanical integrity | Retains mechanical integrity | Degrades | Intermediate |
| Nozzle wear | Production field data | High, hardened steel required | Low | High, hardened steel recommended | Low to moderate |
Within the Beon3D portfolio, grades designated “PP” without the “G” are unfilled and are preferred for non-abrasive, low-stiffness applications such as flexible clips and packaging nests. Mineral-filled grades may offer lower anisotropic warpage but lower tensile strength than glass-filled material. PPG 2290S1 Natural sits in the medium-fibre-loading range and is more suitable than mineral-filled grades for structural ribs because glass fibres retain load-bearing capacity after moisture uptake. Exact glass loading should be obtained from the supplier technical datasheet; published data for this specific configuration may be limited to the manufacturer’s test certificate.
In paint-shop fixture service, components printed from PPG 2290S1 Natural are candidates for masking fixtures, electroplating carriers, and solvent-borne cleaning jigs, provided that chemical compatibility is verified under ISO 175 using the actual solvent and exposure duration. Polypropylene reservoirs retain mechanical strength in contact with many dilute acids, alkalis, and hydrocarbon solvents, but concentrated oxidising acids such as nitric acid or fuming sulphuric acid attack the polymer at elevated temperatures. Continuous service above the Vicat softening point reported on the current datasheet is not recommended, and creep testing under ISO 899-1 at the service temperature is more predictive than heat deflection temperature for load-carrying fixtures. The natural colour state avoids carbon black fillers that can alter radio-frequency or microwave transmission in adhesive-curing operations, but it may require painting or marking after printing for part identification.
Polypropylene absorbs aliphatic hydrocarbons moderately; prolonged immersion in naphtha at room temperature under ISO 175 can lead to slight swelling and modulus reduction. Aromatic hydrocarbons and chlorinated solvents swell the matrix more aggressively, so tight dimensional tolerances cannot be maintained in those environments. When electroplating carriers are exposed to electroless nickel baths at 80–90°C, short-term survival is possible, but blind holes and internal printed channels must be sealed to prevent bath absorption and subsequent outgassing. Static dissipation is poorer than filled ABS because unfilled polypropylene has high surface resistivity; anti-static additives or external ionisation may be required in explosive-atmosphere handling.
The coefficient of linear thermal expansion of glass-filled polypropylene is lower than unfilled polypropylene but still higher than steel. Fixtures aligning metal components should allow 0.8–1.0 mm/m adjustment for thermal expansion between 20°C and 80°C. Differential expansion with aluminium or steel frames can induce interlayer stress and cracking at fastener bosses, so oversized holes or elastomeric grommets are required. Layer height and extrusion width affect both surface finish and mechanical performance. A layer height of 0.15–0.20 mm with an extrusion width of 0.40–0.50 mm on a 0.4 mm nozzle balances interlayer fusion and glass-fibre damage; print speeds above 60 mm/s can reduce melt residence time and lower Z-axis fusion.
Post-print machining operations such as drilling, tapping, and milling are feasible with carbide tooling. Glass fibres cause tool wear, but spindle speeds below 300 m/min for 6 mm carbide end mills reduce heat softening. Threaded inserts should be installed with ultrasonic or heat staking, not self-tapping thread-forming screws, because the layer-to-layer interface may crack under hoop stress. Fatigue data for FFF-printed glass-filled polypropylene under cyclic loading are limited; published data for this specific configuration is limited, and injection-moulded SN curves should not be transferred without applying knockdown factors for interlayer porosity and surface roughness.
Before releasing this feedstock for production, documentation for Beon3D PPG 2290S1 Natural should be reviewed under Directive 2011/65/EU for RoHS-restricted substances and under Regulation (EC) No 1907/2006 for REACH substance or article obligations. The natural grade does not contain intentionally added carbon black, organic pigments, or flame-retardant additives; therefore flammability classification under UL 94 is expected to be HB, not V-0 or V-2. Food-contact compliance under FDA 21 CFR 177.1520 or equivalent migration legislation is not implied unless explicitly affirmed by LyondellBasell in writing for the finished printed article. End users in the European Union must confirm whether the printed object is an article or packaging under Article 3 of REACH.
| Regulatory or technical attribute | Standard or regulation | Expected result for Natural PP feedstock |
|---|---|---|
| Restriction of hazardous substances | Directive 2011/65/EU | No intentionally added Pb, Hg, Cd, Cr(VI), PBB, PBDE |
| Chemical registration | Regulation (EC) No 1907/2006 | Verify current substance/article status with supplier |
| Flammability classification | UL 94 | HB unless a flame-retardant package is specified |
| Density | ISO 1183-1 | Differentiates unfilled PP from glass-filled PP |
| Melt flow rate | ISO 1133-1 | Compare with supplier batch certificate |
| Printed-specimen coordinate system | ISO/ASTM 52921 | Orientation and infill density must be reported |
Incoming inspection should include melt volume-flow rate by ISO 1133-1, filament diameter by laser micrometer, and density by ISO 1183-1. Density is a useful low-cost check for glass loading because unfilled polypropylene and glass-reinforced polypropylene differ by approximately 0.15 g/cm³; a lot falling outside the expected density band indicates a potential compounding error. Unopened spools should be stored at 10–30°C in sealed pouches with desiccant. Opened material that is not dried should be used within 24 h if ambient humidity exceeds 60%, or returned to sealed containment with desiccant. The material should not be combined with copper-based anti-static additives without verification, because transition metal ions accelerate thermo-oxidative chain scission at processing temperatures. Long-term UV exposure promotes surface oxidation and gloss loss; unpigmented natural polypropylene is not UV-stabilised unless stated in the datasheet.