| HS Code | 106519 |
| Chemical Name | Polylactic Acid (PLA) |
| Cas Number | 26100-51-6 |
| Physical Form | Pellets |
| Color | Natural |
| Density | 1.24 g/cm³ |
| Bulk Density | 0.7-0.8 g/cm³ |
| Melt Flow Rate 210 C 2 16 Kg | 10-15 g/10 min |
| Relative Viscosity | 3.3 |
| Glass Transition Temperature | 55-60°C |
| Melting Temperature | 175°C |
| Crystallization Temperature | 100°C |
| Thermal Degradation Temperature | >300°C |
| Moisture Content | <0.025% |
| L Lactide Content | >99% |
| Residual Lactide | <0.3% |
| Tensile Strength | 70 MPa |
| Tensile Modulus | 3.5 GPa |
| Elongation At Break | 3% |
| Flexural Modulus | 3.8 GPa |
| Notched Izod Impact Strength | 2.5 kJ/m² |
| Heat Deflection Temperature | 55°C |
| Vicat Softening Temperature | 60°C |
| Biobased Carbon Content | 100% |
| Compostability | Industrial compostable |
| Food Contact | Suitable |
As an accredited Luminy LX930U Medium Viscosity Fiber-Grade PLA factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Luminy LX930U Medium Viscosity Fiber-Grade PLA is supplied in 25 kg moisture-barrier foil-lined bags, palletized for industrial shipment. |
| Container Loading (20′ FCL) | Luminy LX930U PLA palletized in bags, loaded into a 20′ FCL, securely strapped, desiccated, and sealed for standard export. |
| Shipping | Luminy LX930U Medium Viscosity Fiber-Grade PLA is shipped as non-hazardous, solid polymer pellets in moisture-barrier liners, fiber drums, or cartons. It is not regulated for transport and requires no UN number, hazard class, packing group, or marine pollutant label. Keep dry, cool, and protected from moisture. |
| Storage | Store Luminy LX930U Medium Viscosity Fiber-Grade PLA in a cool, dry, well-ventilated area, away from direct sunlight, heat, moisture, and oxidizing agents. Keep original containers sealed until use. Maintain relative humidity below 50% and temperatures preferably between 10–30°C. Practice first-in, first-out rotation; avoid prolonged storage above 40°C to prevent hydrolytic degradation and quality loss. Protect from contamination and moisture ingress. |
| Shelf Life | Luminy LX930U has a 12-month shelf life when stored in unopened original packaging, cool and dry below 30°C, protected from moisture. |
On a commercial staple fiber extrusion line producing needle-punched nonwoven precursor from Luminy LX930U Medium Viscosity Fiber-Grade PLA, the resin is first dried in a desiccant dryer at 80 °C until residual moisture falls below 250 ppm, because hydrolytic chain scission in the extruder becomes measurable above this threshold. The dried chips are conveyed under closed-loop dry air into a single-screw extruder with an L/D ratio of 30:1, a compression ratio of 3:1, and a screen pack using 40–60 µm stainless steel mesh to remove gel particles. Melt temperature at the die exit is held between 195 °C and 210 °C, with a residence time below 8 min, to limit lactide regeneration and prevent spinnability loss. The spinneret plate carries 1,200–2,000 holes with a capillary diameter of 0.3–0.5 mm; quench air is supplied at 18–22 °C and 0.30–0.50 m/s, and the tow is drawn at a draw ratio of 2.8:1–3.4:1 across a 65–85 °C hot-water or steam-assisted draw bath. The crimped tow is cut into staple fibers of 38–51 mm and 6–8 dtex, then carded, cross-lapped, and needle-punched at 350–600 penetrations/min to produce a fabric mass of 180–400 g/m². In this segment the formulation uses 100 phr of LX930U without melt-phase diluents; spin finish is applied at 0.3–0.5 wt% of dry fiber mass to control carding electrostatic charge. End products include temporary erosion-control blankets, nonwoven geotextile separation layers in drainage trenches, and biodegradable mulching sheets. Compliance for this application is anchored to ISO 9001 for process control, EN 13432 or ASTM D6400 for compostability claims, ASTM D4595 for grab tensile strength, ASTM D6241 for static puncture resistance, and ASTM D4355 for UV resistance when exposed for more than 30 days at the surface. A production-scale bottleneck observed on carding lines is rapid static build-up at relative humidity below 35%, which raises fly waste by 4–6% and can be partially offset by maintaining the spin finish level in the upper half of the stated range.
The operational boundary for this use is set by moisture regain of the staple after drying; at storage relative humidity above 60%, chip moisture can rise above 300 ppm within 24 h in unsealed hoppers, causing spinneret drool and filament breaks. Needle-punched geotextiles made from PLA should not be exposed to continuous wet alkaline soil with pH above 8.5 at temperatures above 30 °C for more than 180 days, as the fiber loses tensile strength faster than the design lifetime of permanent synthetic geotextiles. In temporary erosion-control use, this degradation is functional; in structural separation use, it is a disqualifying limitation unless a site-specific degradation assessment has been performed.
Spunbond nonwoven production from LX930U requires the same aggressive pre-drying as staple spinning; however, the line configuration differs in that molten polymer is distributed by a gear pump into spin beams across a 2.4–3.2 m web width, with spinneret throughputs between 0.8 g/hole/min and 1.4 g/hole/min and melt filtration through 50 µm sintered metal candle filters. The die exit melt temperature is maintained at 205–220 °C; higher temperatures are used only when line speed exceeds 250 m/min, but total residence time in the extruder and spin beam must remain below 8 min to prevent molecular weight degradation. Quench air at 15–20 °C with an air speed of 0.80–1.20 m/s is fed from a closed cabin to stabilize filament attenuation before the web reaches the moving conveyor. The formulation for hygiene and medical spunbond uses 96–98 wt% LX930U with 2–4 wt% TiO₂ masterbatch for opacity and 0.10–0.20 wt% processing stabilizer masterbatch; melt lubricants are omitted to preserve calender bond strength. The web is compacted and thermal calender bonded at 130–145 °C with a nip pressure of 40–80 N/mm and an embossed calender roll having 12–18% bond area. The bonded roll is then slit to final width and wound for converting. End products include hygiene topsheets, medical gown outer layers, disposable protective apparel, and sterile barrier packaging substrates. The product is tested under Oeko-Tex Standard 100 for skin contact, ISO 10993-5 for cytotoxic potential when supplied as a medical gown or sterile packaging component, EN ISO 11607-1 for sterile barrier system packaging, and REACH Annex XVII for restricted substances. For compostable hygiene claims, ASTM D6400-23 or EN 13432 disintegration and biodegradation criteria apply.
| Test domain | Standard designation | Typical acceptance basis |
|---|---|---|
| Melt volume-flow rate | ISO 1133-1:2022 | Lot-specific certificate against datasheet range |
| Skin-contact safety | Oeko-Tex Standard 100 | Annex 4 product class II or III |
| Cytotoxicity | ISO 10993-5:2009 | Cell viability ≥ 70% |
| Sterile barrier system | EN ISO 11607-1:2020 | Validated sterile presentation |
| Compostability | ASTM D6400-23 / EN 13432:2000 | ≥ 90% carbon conversion in 180 days |
When basis weight drops below 12 g/m², calender bonding becomes a cliff-edge process because the low fabric mass stores less heat and the thermal transfer path through the web is shorter. The melting point of LX930U is close to 150–160 °C, so the calender surface must remain below 145 °C to prevent film-like loss of air permeability and product tensile failure. At 12 g/m², an increase of 5 °C in calender temperature can reduce air permeability by 25–30% while raising tensile strength by only 8–12%. Line operators therefore run bond area at the lower end of the specification for lightweight hygiene fabrics, and the calender roll release surface is maintained with a PTFE sleeve to reduce pickup of partially fused filaments. Published data for this exact LX930U configuration below 10 g/m² is limited; pilot trials are required before production speeds exceed 300 m/min.
Airlaid acquisition layers and absorbent core wraps are produced from bicomponent staple fibers in which LX930U is used in the sheath to lower thermal-bonding onset while a higher-viscosity PLA forms the core to retain fiber integrity during through-air bonding. The sheath-to-core mass ratio is set between 30:70 and 50:50; below 30:70, bond points are discontinuous and the web loses tensile integrity, while above 50:50, the core is insufficiently load-bearing and the bonded fabric collapses under calender pressure. The formulation for the sheath melt uses 100 phr LX930U; a bonding-enhancing masterbatch is normally not required, but if a lower through-air temperature is needed to protect co-located cellulose pulp, 5–10 wt% of a low-melting PLA copolymer can be added to the sheath. Spin finish is applied at 0.4–0.6 wt% on the finished fiber to control fiber-to-fiber friction during carding. The bicomponent spinneret is configured with 288-hole segments and a split cross-section in which the sheath occupies 25–35% of the fiber perimeter. Through-air bonding is carried out at 130–150 °C for 8–15 s at an air speed of 1.0–1.5 m/s; the upper temperature limit is set below the onset of PLA degradation, because aldehyde odor and filament discoloration appear rapidly when the sheath exceeds 165 °C for more than 20 s. End products include acquisition-distribution layers for absorbent hygiene products, wrap sheets for core stabilization, and low-weight thermal-bonded nonwovens for cosmetic mask substrates. Compliance for this segment follows Oeko-Tex Standard 100 product class I or II, ISO 20706-1 for fiber linear density, ISO 5079 for single-fiber tensile properties, EDANA/INDA nonwoven test methods for acquisition time and rewet, and ASTM D6400-23 where compostability is claimed.
A recurring production-scale issue on carded airlaid lines is fiber clumping when spin finish exceeds 0.6 wt%, because the binder fibers become too adhesive at room temperature and the card web develops stick points. Conversely, spin finish below 0.4 wt% raises the electrical charge on the fiber surface, causing fiber wrap on licker-in rollers and an increase in web weight variation to ±8%. The process window is therefore narrow and is set by a closed-loop dosing system on the finish applicator. Bicomponent fibers containing LX930U in the sheath should not be used in absorbent cores that are later exposed to high-humidity ageing above 50 °C and 85% relative humidity for more than 3 months without verifying residual tensiles, because PLA undergoes hydrolytic degradation at a measurable rate even at these moderate conditions.
Between the first and second godet set on a draw-texturing line, partially oriented yarn spun from LX930U is subjected to cold drawing at 1.5:1–1.8:1 and heated false-twist texturing at 120–145 °C to produce draw-textured yarn of 68–167 dtex. The spin beam is fed by a single-screw extruder with an L/D ratio of 25:1–30:1, and the melt is filtered through 40–60 µm mesh before passing to a spinneret with 36–72 holes. Quench air at 18–22 °C and 0.40–0.60 m/s cools the filament bundle, and take-up speed is held between 2,500 m/min and 3,500 m/min to set the partially oriented yarn morphology. The downstream draw-texturing machine applies a D/Y ratio of 1.8–2.4 and a primary heater temperature of 120–145 °C; secondary heater temperature is kept below 110 °C to avoid loss of crimp. The formulation for apparel filament uses 100 phr LX930U with 0.8–1.5 wt% TiO₂ delustering masterbatch for semi-dull appearance; spin finish is applied at 0.5–1.0 wt% and an antistatic finish additive at 0.05–0.10 wt% is included for warping and knitting. End products include warp-knit tops, seamless underwear panels, activewear jerseys, and woven shirting where low thermal stability is acceptable. Compliance for apparel yarn is verified under Oeko-Tex Standard 100 product class II, ISO 2062 or ASTM D2256 for yarn tensile properties, ISO 20706-1 for fiber linear density, and REACH Annex XVII for restricted substances. Dyeing is performed with disperse dyes at 100–105 °C and pH 5.0–5.5; alkaline scouring or reduction clearing above pH 8.5 must be avoided because PLA fiber strength drops rapidly under hot alkaline hydrolysis.
On industrial draw-texturing equipment, the main operational boundary is the narrow heater temperature window; when the primary heater exceeds 145 °C, broken filaments increase by 3–5% per shift and deposition on the heater plate produces yarn tension variation. When the heater is below 120 °C, crimp contraction after knitting is insufficient and fabric hand becomes boardy. Published data for LX930U-specific false-twist texturing at line speeds beyond 800 m/min is limited; pilot-scale runs are required before converting a production line to PLA from polyester because the lower melting point changes heat-transfer and friction behavior in the twist unit. The fiber should not be specified for uniforms or workwear that requires pressing, ironing, or industrial laundering at temperatures above 130 °C, because elongation retention after 20 industrial wash cycles at 75 °C may fall below 50%.
High-loft hollow conjugate fiber for bedding and outdoor insulation is manufactured from LX930U using a capillary profile spinneret with 7–9 holes per filament to create a hollow cross-section and 20–30% void content. The extrusion line is configured with a throughput per hole of 1.0–1.6 g/min, a draw ratio of 2.4:1–3.0:1, and a crimp box set to 10–14 crimps/25 mm; crimp retention after compression is the key performance variable. The formulation uses 100 phr LX930U for the fiber itself, while the external surface treatment is a silicone-based finish applied at 0.5–1.2 wt%, which reduces fiber-to-fiber friction and increases loft recovery. The downstream process involves opening, carding, cross-lapping, and blowing the staple into a mattress or garment quilting; the final batting is then bonded by a low-melt adhesive powder at 5–10 g/m² or by needle-punching at moderate puncture densities. End products include duvet fill, mattress comfort layers, quilted outdoor insulation, and pillow batting. Compliance for this segment includes Oeko-Tex Standard 100 product class I for infant-contact articles and 16 CFR 1632 for mattress pad cigarette ignition resistance where the product is supplied as a finished padded component.
The limit for this application is recovery after compression ageing. When exposed to 60 °C and 80% compression for 24 h, PLA hollow fiber can exhibit a thickness loss above 35%, which disqualifies it from load-bearing seating or mattress core applications requiring long-term resilience. In contrast, loft loss in storage bedding at 20–25 °C and 50% relative humidity remains below 10% after 30 days. The hollow fiber should not be processed through dryers or steaming chambers above 120 °C for more than 10 min because the hollow structure collapses and the fiber becomes flat, reducing fill power by 25–30%. On fiber opening lines, throughput above 250 kg/h reduces fiber orientation and increases neps unless the pre-opener and fine-opener wire settings are adjusted; at throughput above 300 kg/h, fibers with a silicone finish below 0.5 wt% generate static fly and the feeding duct becomes choked at elbows.
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Luminy LX930U is a medium-viscosity fiber-grade polylactide resin supplied by TotalEnergies Corbion for melt spinning, spunbond nonwoven production, staple fiber, and bicomponent fiber conversion. The grade is positioned between low-flow extrusion PLA and high-flow injection-molding PLA; its molecular architecture is selected to maintain spin-line tension without generating excessive spin-pack pressure during continuous filament attenuation. Representative material data for the class include a density of 1.24 g/cm³ by ISO 1183-1:2019, a glass transition temperature of 55–60 °C by ISO 11357-2:2020, and a crystalline melting temperature of 150–160 °C by ISO 11357-3:2018. Melt mass-flow rate is controlled within a medium-viscosity fiber-spinning band at 210 °C/2.16 kg under ISO 1133-1:2022; lot-specific values are reported on the certificate of analysis because melt flow shifts with moisture content and stereo-isomer distribution. The D-lactide content is typically held in a narrow interval near 1.4–1.6 mol% to balance spin-line crystallization with post-draw orientation development.
Compared with high-heat extrusion PLA, LX930U has a lower melt viscosity and a less aggressive crystallization response, allowing longer spin-line residence before brittle solidification and reducing the tendency for premature neck formation during take-up. Compared with injection-molding PLA, the grade retains higher molecular weight and lower melt-flow rate, giving greater melt strength for attenuation without excessive shear heating. The principal technical difference is not thermal stability but rheological design: medium-viscosity fiber-grade PLA is formulated to run against a spin beam without generating high filter pressure, while preserving sufficient chain entanglement for draw ratios from 2:1 to 4:1. The narrower D-lactide window also distinguishes LX930U from packaging resins, because D-lactide content directly controls nucleation density, crystallite growth rate, and the onset of cold crystallization during the quench and drawing stages.
| Characteristic | Method | Representative value or range |
|---|---|---|
| Density | ISO 1183-1:2019 | 1.24 g/cm³ |
| Melt mass-flow rate | ISO 1133-1:2022 at 210 °C/2.16 kg | 10–30 g/10 min class; lot certificate required |
| D-lactide content | Supplier HPLC | 1.4–1.6 mol% typical |
| Glass transition temperature | ISO 11357-2:2020 | 55–60 °C |
| Crystalline melting temperature | ISO 11357-3:2018 | 150–160 °C |
Because LX930U is a fiber-grade PLA rather than an injection-molding or thermoforming resin, its stabilization package and viscosity profile are aligned with continuous filament orientation rather than thin-wall cavity replication. Converters substituting packaging-grade PLA in fiber lines frequently observe unstable necks, draw resonance, and reduced filament tenacity when the resin is not matched to the downstream drawing system.
On a single-screw spunbond line using an L/D 30:1 extruder and positive-displacement metering pump, LX930U is normally predried to below 250 ppm residual moisture before feed. Barrel temperature settings for continuous operation are commonly set from 180 °C at the feed section to 220–230 °C in the metering section, with spin-pack temperature held near 225 °C. At these conditions, the medium-viscosity resin produces lower spin-pack pressure drop than high-heat extrusion PLA but higher pressure than injection-molding resin; filter pack area must be matched accordingly. When dryer dew point rises above -40 °C or when pellets remain uncovered at 60 % RH for extended periods, hydrolytic chain scission reduces melt strength and creates periodic filament breaks. The failure mode is usually observed as diameter fluctuation, die-face accumulation, and deposition of oligomeric material on the quench air diffuser. Barrel residence time should also be monitored; holding melt above 230 °C for more than 15 min can shift MFR upward and increase lactide volatility, altering fabric hand and creating deposits in the spin beam. If a converter requires spin-pack pressure coefficients for a specific filter pack geometry, published data for this specific configuration is limited; empirical trials on the target beam are required.
Converter practices developed for PET do not transfer directly to LX930U. The melting point of 150–160 °C permits lower barrel and spin-pack temperatures than PET, but the processing window is narrower; melt temperatures below 210 °C can produce unmelted gels and elevated extruder torque, while melt temperatures above 240 °C accelerate thermal degradation. Unlike PET, PLA does not require a long crystallization drying stage, but it is more hydrolytically sensitive at melt temperature. Recycled edge trim must be dried below 250 ppm before re-extrusion, and closed transfer from dryer to extruder is necessary to prevent moisture regain in humid production halls. Quench air settings must be recalibrated because lower melt density and different thermal diffusivity change the filament temperature gradient; PET-type quench rates can freeze an amorphous skin before core orientation develops, producing lower tenacity and higher boiling-water shrinkage. Additives containing primary or secondary amines should not be blended into the sheath or core unless specifically validated, because aminolysis accelerates chain scission in the polyester backbone. For equipment cleaning, purging with high-MFR polyolefin at 180–200 °C before PLA start-up can reduce cross-contamination, but the line must be fully drained because PLA and PET are melt-incompatible and form stratified deposits at the die lip.
Moisture control is the primary processing boundary for LX930U. PLA pellets equilibrate with humid air to roughly 0.3–0.5 wt% at 50 % RH, while melt processing requires residual moisture below 250 ppm, preferably below 100 ppm for low-denier staple and spunbond output. Hydrolysis at melt temperature follows chain-scission kinetics in which water reacts with ester linkages, reducing molecular weight and increasing melt-flow rate. The reaction liberates lactic acid, which autocatalyzes further hydrolytic degradation and causes MFR drift during extended runs. Drying in a desiccant dryer at 80 °C for 4–6 h with a dew point of -40 °C or lower is the established control. Pellet bed temperature must not exceed 90 °C because surface tack and hopper bridging can occur near the glass transition. Hot-air tray dryers are less suitable for fiber production because dried pellets re-absorb moisture quickly during manual transfer; a closed hopper-to-extruder system is recommended. For lines using edge trim re-extrusion, trim must be pelletized, dried under identical conditions, and limited to a controlled mass fraction to avoid broader molecular weight distribution and increased denier variability.
Orientational crystallization during spin drawing determines the balance between tenacity and shrinkage in drawn staple. At draw ratios from 2:1 to 4:1, amorphous chain segments align along the filament axis; subsequent annealing at 80–100 °C under tension develops crystallites that reduce boiling-water shrinkage. Single-filament tenacity and elongation are measured by ISO 5079:2020; nonwoven tensile properties are evaluated by ISO 9073-3:1989 or equivalent fabric standards. If cold drawing is performed at ambient temperature, the glass transition near 55–60 °C permits orientation but leaves residual stress, leading to shrinkage when the fiber is exposed to bonding or hygiene-line temperatures. In this respect, the grade differs from high-D fiber PLAs that remain predominantly amorphous and from low-D high-heat extrusion grades that crystallize rapidly enough to limit high-draw processing.
Incoming resin inspection for LX930U should include melt mass-flow rate, pellet moisture, and thermal profile verification against the certificate of analysis. Melt-flow testing by ISO 1133-1:2022 detects hydrolysis or thermal degradation before the resin enters the spin beam. Pellet moisture by Karl Fischer or heated moisture balance is used to confirm dryer efficiency. Thermal analysis by ISO 11357-3:2018 verifies melting and crystallization transitions for the lot.
| Quality parameter | Method | Application in process control |
|---|---|---|
| Melt mass-flow rate | ISO 1133-1:2022 | Detection of hydrolysis or thermal degradation |
| Pellet moisture | Karl Fischer or heated moisture balance | Dryer efficiency and feed control |
| Melting and crystallization | ISO 11357-3:2018 | Verify lot thermal profile |
| Filament tensile | ISO 5079:2020 | Draw ratio and tenacity validation |
| Nonwoven tensile | ISO 9073-3:1989 | Fabric grade acceptance |
Lot acceptance should compare certificate values for MFR, D-lactide content, and melting temperature against internal qualification limits. A change in melt-flow rate greater than ±15 % from the qualified baseline, after moisture correction, indicates contamination, hydrolytic damage, or unintended raw-material substitution and requires quarantine of the dryer and spin beam. Finished nonwoven fabric should be tested for basis weight, tensile strength, and shrinkage according to the relevant ISO methods for the intended end-use specification. Regulatory compliance for food-contact or hygiene applications must be confirmed against the supplier’s declaration for EU Regulation 10/2011, FDA 21 CFR 175.300, or application-specific migration requirements; generic fiber-grade PLA cannot be assumed compliant in all matrices without testing.