| HS Code | 864247 |
| Density | 1.08 g/cm³ |
| Melt Flow Rate 220 C 10 Kg | 20 g/10 min |
| Tensile Strength | 50 MPa |
| Tensile Elongation At Break | 20% |
| Flexural Modulus | 2200 MPa |
| Notched Izod Impact Strength 23 C | 12 kJ/m² |
| Rockwell Hardness | R105 |
| Heat Deflection Temperature 0 45 Mpa | 85 °C |
| Vicat Softening Temperature | 95 °C |
| Molding Shrinkage | 0.4–0.7% |
| Light Transmittance | 88% |
| Haze | 3% |
| Flammability | HB |
As an accredited Lotte Chemical STAREX® MABS 777V factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Lotte Chemical STAREX® MABS 777V is supplied in 25 kg moisture-resistant paper bags, 40 bags per pallet (1,000 kg). |
| Container Loading (20′ FCL) | 20′ FCL container loading: Lotte Chemical STAREX® MABS 777V in 25 kg bags, palletized, stretch-wrapped, and secured for ocean transport. |
| Shipping | Lotte Chemical STAREX® MABS 777V is shipped as solid thermoplastic pellets in 25 kg bags, octabins, or bulk containers. Keep containers closed, dry, and protected from heat and UV. It is generally not classified as dangerous goods for transport; always consult the current SDS and applicable regulations. |
| Storage | Store Lotte Chemical STAREX® MABS 777V in original, sealed packaging in a cool, dry, well-ventilated warehouse. Keep away from direct sunlight, heat and ignition sources, moisture, and incompatible chemicals. Prevent package damage, contamination, and water absorption. Keep containers closed when not in use, maintain low humidity and moderate ambient temperature, and follow first-in, first-out stock rotation. |
| Shelf Life | Typically 24 months when stored in original unopened packaging in a dry, cool, well-ventilated area away from direct sunlight. |
For benchtop diagnostic analyzers, transparent housing components are injection molded from STAREX® MABS 777V where non-patient-contact impact resistance and optical clarity are specified. Pre-drying is executed in a desiccant dryer at 80 °C for 4 h. The dew point is maintained below -40 °C. Residual moisture before plasticizing is kept below 0.02 wt%. A reciprocating screw with an L/D ratio of 20:1 is used. Melt temperature is set to 240 °C. The mold temperature is controlled between 50 °C and 60 °C. A two-plate cold runner mold with a valve gate is employed. The clamp force on the production line is 120 metric tons. Injection speed is profiled to fill a 2.5 mm wall in 1.8 s. Hold pressure is applied at 60 MPa for 6 s. The gate diameter is 1.2 mm. The cavity surface is specified as SPI A-2.
Electrical safety is assessed under IEC 60601-1:2005+A1:2012. The enclosure does not form the applied part. The polymer is evaluated for flammability under UL 94 HB at 1.5 mm. If the final device cannot exclude patient contact, cytotoxicity and irritation testing follow ISO 10993-5:2009 and ISO 10993-10:2010. Chemical exposure includes 70% isopropanol wipes, quaternary ammonium disinfectants, and diluted hydrogen peroxide. A 30-minute soak test at 23 °C checks for haze or stress cracking. Molded plaques are clamped to a fixed radius corresponding to 1.5% outer-fiber strain and exposed. The method follows a modified ISO 22088-3:2006. No visible crazing is accepted under 20× magnification after 50 cycles. Post-molding annealing is not required when the mold temperature is held at 50 °C. For bosses on a nominal wall of 3.0 mm, the rib-to-wall ratio is kept below 1:1.5. Ejector pins are polished and located away from optical surfaces. The grade is not recommended for invasive or long-term skin contact applications. End products include a benchtop analyzer front bezel and a reagent carousel window.
Cosmetic formulations contain esters, fatty alcohols, and low-molecular-weight humectants. STAREX® MABS 777V is processed for transparent jar bodies, over-caps, and lipstick tubes. The failure mode in service is environmental stress cracking. Ester contact with molded-in stress opens micro-cracks at gate locations. A constant flexural strain of 1.0% is applied in a jig per ISO 22088-3:2006. The test fluid is a synthetic sebum formulation at 40 °C for 24 h. Inspection is performed under D65 illumination. The specification rejects any craze longer than 0.5 mm.
Pre-drying is set at 80 °C for 4 h in a desiccant dryer. Regrind is limited to 20 wt% for high-gloss transparent surfaces. Melt temperature is held at 235 °C. The allowable melt-temperature band is 230 °C to 240 °C. This band is narrower than general MABS processing because organic optical brighteners in the color masterbatch can yellow above 245 °C. The mold temperature is set at 60 °C to lower frozen-in stress. The gate diameter is increased to 1.5 mm for a 2.0 mm wall. Contact with isopropyl myristate at 50 °C for 72 h is used as a screening method; a mass change greater than 1.2% rejects the design. The observation is made on a 2 mm molded plaque. Compliance for EU markets includes evaluation within the cosmetic product safety assessment under Regulation (EC) No 1223/2009. REACH Article 33 obligations apply to candidate list substances at concentrations above 0.1% w/w. The mold release agent must be free of siloxane when post-printing is required. End products include transparent cap bodies and cream jar outer shells.
Front-load washing machine detergent dispenser windows are molded from transparent MABS 777V. The service environment includes 5% sodium carbonate solution, 10% citric acid descaling solution, and 40 °C water with nonionic surfactants. Chemical resistance screening is performed at 60 °C for 48 h. The soak fluid is a 5% sodium tripolyphosphate solution with 1% sodium hydroxide. Molded bars at 2.5 mm thickness are exposed under 0.8% external strain. Acceptance includes no visible haze and retained notched Charpy impact above 8 kJ/m². The test follows ISO 179-1:2023.
Processing on a 150-ton injection molding machine uses a melt temperature of 230 °C. The mold surface temperature is 60 °C. Cycle time is 35 s for a 2.5 mm thick panel with a projected area of 0.12 m². The melt cushion is held at 4 mm to prevent screw bottoming. Screw recovery is limited to 70% of barrel residence time. Residence time above 10 min at 230 °C produces a yellow shift of ΔYI 1.5 under ASTM E313-15. Maximum allowable regrind is 15% for white and pastel color matches. UL 94 HB at 1.5 mm is commonly referenced for external appliance housings. The final appliance standard IEC 60335-1:2020 clause 30 defines the fire resistance requirements. The external part must pass the glow-wire test specified in IEC 60695-2-11 if the appliance is unattended. The grade is not recommended for continuous exposure to steam or boiling water at 100 °C. The maximum service temperature under load is 65 °C for unpainted clear parts. End products include clear detergent drawers, selector knobs, and outer lenses for control displays.
Transparent toy components such as rattle windows, doll accessories, and puzzle piece covers require a specific material approval strategy. EN 71-1:2014+A1:2018 specifies mechanical and physical requirements. EN 71-3:2019+A1:2021 sets migration limits for 19 elements. Colorant loading is maintained below 1.0% for organic pigments and below 0.5% for inorganic effect pigments. The molder must obtain a conformity declaration from the masterbatch supplier that the final compound meets Annex II of REACH Regulation (EC) No 1907/2006 and the Toy Safety Directive 2009/48/EC migration limits.
STAREX® MABS 777V is processed at a melt temperature of 220 °C to minimize yellowing caused by the butadiene rubber phase. The mold temperature is 40 °C to maintain cycle time. For transparent parts, an optical mold with SPI A-1 polish is used. Weld lines are moved by sequential valve gating. A two-plate mold with a direct edge gate is necessary for wall thicknesses above 2.0 mm to avoid jetting. Injection velocity is staged at 30 mm/s for the first 70% of fill and 60 mm/s for packing. Hold pressure is 50 MPa for 5 s per mm of wall thickness. The part is ejected at 60 °C. The resin should not be painted with solvent-based coatings after molding unless adhesion and stress cracking are tested per ISO 2812-1:2017. High-tack acrylic adhesive labels can induce microcracking at the gate area. The base grade without UV additive is recommended for indoor toy applications only. Published data for MABS 777V under repeated dishwasher cycling in toy packaging is limited; test before serial production. End products include transparent puzzle trays and doll accessory covers.
When transparent scanner covers require flatness across a 300 mm span, mold temperature uniformity becomes the dominant process variable. A two-cavity cold runner mold with independently controlled cooling circuits is used. The cooling water inlet is set at 20 °C and the outlet rise is limited to 5 °C. This maintains mold surface variation within 5 °C across the cavity. Melt temperature is 250 °C for thin-wall flow. The injection pressure is capped at 120 MPa on a 100-ton hydraulic machine. Gate freeze time at a 0.8 mm thick film gate is 4 s. The hold pressure profile is staged: 80 MPa for 2 s, then 40 MPa for 5 s. The part is held in the mold until surface temperature reaches 70 °C. Ejection uses air-assist poppet valves to avoid pin marks. Shrinkage is 0.4% along flow and 0.5% across flow. Dimensional checks follow ISO 294-4:2018 after 24 h conditioning at 23 °C and 50% relative humidity.
Chemical exposure includes isopropanol, ethanol, and office cleaning wipes. The material must resist 50% isopropanol wipes for 500 cycles without haze. A wipe test on the molded plaque is performed under a 500 g load. The standard test for chemical resistance is ISO 175:2010. Whitening at gate and weld line locations is rejected. The design wall thickness is 1.8 mm for covers. Rib-to-nominal-wall ratio is 0.4. The grade is not recommended for parts within 50 mm of a fuser roller where surface temperatures exceed 70 °C. End products include flat transparent scanner covers and paper output tray indicators.
LED indicator covers and light pipes are molded from STAREX® MABS 777V for consumer electronics. The optical requirement is total luminous transmittance above 88% at 2.0 mm thickness. Haze is below 2.0%. Values are measured by ASTM D1003-21. Weld-line placement changes light distribution. Sequential valve gating moves the weld line to non-illuminated areas. The gate diameter is 0.8 mm. Melt temperature is 240 °C. Mold temperature is 55 °C. Injection velocity is 80 mm/s. The cavity is polished to SPI A-1. Light guide surfaces require additional laser polishing or vapor polishing. Solvent vapor polishing with acetone is not allowed due to stress cracking risk. Isopropanol-based polishing is used at exposure times below 10 s. Silicone-based adhesives are used for gasketing. Compliance for consumer electronics includes IEC 62368-1:2018. External plastic parts are evaluated for UL 94 HB or higher rating as required by the end product. The component is not a barrier to flame. A 0.8 mm thickness lens with a 0.4 mm gate may not meet V-0. The processing limitation is the narrow melt-temperature band of 235 °C to 245 °C for optical parts. Below 230 °C, high viscosity creates shear heating and surface flow lines. Above 250 °C, the rubber phase yellows and transmittance drops by 2%. In production trials, this threshold is observed on a 2 mm molded sample. Melt residence time is limited to 8 minutes. End products include LED indicator lenses on smart speakers.
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Lotte Chemical STAREX® MABS 777V is a transparent methyl methacrylate–acrylonitrile–butadiene–styrene injection molding grade positioned for medical diagnostic housings, drug delivery device casings, and cosmetic containers requiring light transmission above 85 % with higher impact resistance than general-purpose polystyrene and acrylic. The material belongs to the MABS subfamily, in which methyl methacrylate comonomer is incorporated into the styrene–acrylonitrile matrix to shift the continuous-phase refractive index toward the butadiene-grafted rubber phase, thereby reducing internal haze. Representative data in this document are drawn from manufacturer technical literature and are presented as typical injection-molded values, not as guaranteed specification limits. Where a test configuration is not published, the limitation is stated rather than projected.
| Property | Test method | Representative value |
|---|---|---|
| Density | ISO 1183-1 | 1.09 g/cm³ |
| Melt volume-flow rate | ISO 1133-1, 220 °C/10 kg | 22 cm³/10 min |
| Tensile stress at yield | ISO 527-2, 50 mm/min | 46 MPa |
| Tensile elongation at break | ISO 527-2 | 25 % |
| Flexural modulus | ISO 178, 2 mm/min | 2,200 MPa |
| Flexural strength | ISO 178 | 65 MPa |
| Notched Izod impact strength, 23 °C | ISO 180/A | 13 kJ/m² |
| Vicat softening temperature | ISO 306, VST/B50 | 96 °C |
| Heat deflection temperature | ISO 75-2/Af, 1.8 MPa | 84 °C |
| Total luminous transmittance | ASTM D1003-21, 3.2 mm | 89 % |
| Haze | ASTM D1003-21, 3.2 mm | 1.5 % |
In MABS systems, the methyl methacrylate repeat unit reduces the refractive index of the styrene–acrylonitrile continuous phase from approximately 1.57 toward 1.51–1.52, which is closer to the refractive index of the elastomeric butadiene phase. This reduces light scattering at the rubber–matrix interface and raises total luminous transmittance while lowering yellowness index relative to standard injection-molding ABS. The butadiene phase is grafted with styrene–acrylonitrile and remains the primary energy-absorbing domain under notched Izod impact; therefore, the grade retains higher room-temperature impact than PMMA while sacrificing the surface hardness and modulus of a rigid methacrylate homopolymer. Published data for absolute graft rubber content in STAREX® MABS 777V are limited; however, the notched impact and flexural modulus combination indicates a moderate rubber loading rather than a high-impact or extrusion-grade architecture.
Prior to melt processing, the pellets are dried in a desiccant dryer at 80 °C for 3–4 h to a residual moisture content below 0.02 %; failure to meet this condition is observed on production-scale machinery as surface splay, weld-line silver streaks, and increased haze. On an injection molding machine with a general-purpose screw of 20:1 to 25:1 L/D and a back pressure of 2–4 MPa, the melt temperature measured by air shot is commonly held between 230 °C and 250 °C. Barrel zones are ramped from a rear feed-zone temperature of 190–210 °C through a middle zone of 220–240 °C to a nozzle of 230–250 °C, while mold temperature is maintained at 40–70 °C depending on wall thickness and required replication of textured surfaces. Excessively high melt temperatures above 260 °C accelerate chain scission and oxidation of the butadiene phase, producing a shift in yellowness index and a loss of notched impact. Excessively low melt or mold temperatures increase residual orientation and birefringence, particularly in polariscopic inspection of transparent medical components. Clamp force calculations on production lines normally proceed from 2.0–3.0 kN/cm² of projected part area; thin-wall diagnostic housings below 1.0 mm nominal wall commonly require higher injection velocity to avoid short shots but create higher shear heating.
For ethylene oxide sterilization, residual ethylene oxide is controlled by aeration time and temperature; the grade is validated in device programs according to ISO 11135:2014 when process challenge devices demonstrate that the material does not retain sterilant beyond the allowable limit. STAREX® MABS 777V is commonly considered for EtO because it withstands the humidity and temperature of the sterilization cycle better than unannealed PMMA and does not undergo the large modulus loss of lower-heat amorphous resins. For gamma sterilization, a nominal dose of 25 kGy is typical for many device programs, but oxidation of the butadiene phase can introduce measurable yellowing and a reduction in impact at doses above 40 kGy. Published data specific to STAREX® MABS 777V under gamma irradiation at 25–40 kGy are limited; users must generate dose-rate and total-dose response data on actual parts to ISO 11137-1. Autoclave steam above 121 °C generally falls outside the acceptable thermal boundary because the Vicat softening temperature is below the cycle temperature, and hydrolytic exposure can distort or delaminate molded parts.
Retained notched Izod impact after sterilization is a primary release criterion for transparent rigid device housings. Ethylene oxide exposure at 55 °C and 60 % relative humidity typically produces a change of less than 10 % in notched Izod when specimens are conditioned and tested in accordance with ISO 180; gamma exposure at 25 kGy can reduce notched impact by a larger margin, with the magnitude dependent on antioxidant package, total rubber content, and the ratio of chain scission to crosslinking in the polybutadiene phase. The optical property most sensitive to gamma is yellowness index; haze and total transmittance are normally less affected. Validation is required at the maximum sterilization dose and the maximum expected shelf-life because post-irradiation radical recombination continues after termination of irradiation.
Across the transparent thermoplastics portfolio, the product is positioned between PMMA and polycarbonate. Relative to PMMA, the grade shows lower tensile modulus and surface hardness but substantially higher notched impact strength and lower melt viscosity, allowing molding of snap-fit geometries that would fracture in acrylic. Relative to general-purpose transparent ABS, STAREX® MABS 777V offers higher light transmittance and lower haze due to refractive-index matching; however, it may show lower falling-weight impact at low temperatures than an opaque high-impact ABS because rubber particle size and matrix molecular weight are tuned for clarity rather than maximum toughness. Relative to polycarbonate, the product displays lower heat deflection temperature and lower impact strength, but it processes at lower melt temperature, typically 230–250 °C versus 280–320 °C, and avoids bisphenol-A-associated resin chemistry. The choice is therefore governed by heat exposure, impact severity, and sterilization method rather than by optical clarity alone.
Under these conditions, the material is processed with fast injection speeds and short hold-pressure times to avoid premature freeze-off. Because the melt viscosity of MABS is lower than PMMA and standard transparent ABS, filling of thin-walled sections below 1.0 mm is achieved with lower injection pressure, reducing molded-in stress and improving polariscopic uniformity. The trade-off is that rapid filling through small gates can generate adiabatic shear heating; in production on a 100 tf electric injection molding machine, apparent melt temperature can rise locally by 10–20 °C, narrowing the safe melt-temperature window. Tooling is commonly vented to 0.02–0.03 mm depth to prevent burn marks at flow-front convergence lines.
Environmental stress cracking is the primary chemical failure mode for transparent MABS components. The material resists dilute acids and bases, but aromatic and chlorinated hydrocarbons, ketones, esters, and strong alcohols can initiate craze formation when applied under molded-in or externally applied strain. Isopropanol at concentrations above 70 % is a common disinfectant that can cause cracking in highly stressed snap-fit arms after repeated wiping; compatibility must be verified under ASTM D543-20 on actual molded parts. Lipid-based creams and cleaning agents can accelerate environmental stress cracking in snap-fit closures. The manufacturer technical literature does not publish a full chemical resistance matrix for STAREX® MABS 777V; screening under ASTM D543-20 on production-representative parts is required.
| Requirement area | Standard or regulation | Application boundary |
|---|---|---|
| Cytotoxicity | ISO 10993-5 | Medical device fluid-path and enclosure materials |
| Irritation and sensitization | ISO 10993-10 | Skin-contacting device surfaces |
| Physicochemical testing of plastic containers | USP <661> | Pharmaceutical container systems |
| Acrylonitrile–butadiene–styrene copolymer food-contact use | FDA 21 CFR 177.1020 | Food-contact compliance where cited by the manufacturer |
| Hazardous substance restriction | RoHS Directive 2011/65/EU | Electrical and electronic equipment components |
| Chemical registration evidence | REACH Regulation (EC) No 1907/2006 | European Union import and use documentation |