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Lotte Chemical STAREX® MABS 777A

    • Product Name: Lotte Chemical STAREX® MABS 777A
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    VTB
    Specifications
    HS Code 338836
    Density G Cm³ 1.08
    Melt Flow Rate 220 C 10 Kg G 10 Min 15
    Tensile Strength Mpa 42
    Elongation At Break 25
    Flexural Modulus Mpa 1900
    Izod Notched Impact Strength 23 C Kj M² 12
    Heat Deflection Temperature 1 82 Mpa C 75
    Vicat Softening Temperature C 90
    Rockwell Hardness R Scale 105
    Light Transmittance 88
    Haze 3
    Molding Shrinkage 0.4-0.6
    Water Absorption 24 H 0.2

    As an accredited Lotte Chemical STAREX® MABS 777A factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Lotte Chemical STAREX® MABS 777A is packaged in 25 kg moisture-barrier bags, palletized and stretch-wrapped for industrial shipment.
    Container Loading (20′ FCL) 20′ FCL container loading of Lotte Chemical STAREX® MABS 777A resin, palletized bags securely stowed and braced for ocean transport.
    Shipping Lotte Chemical STAREX® MABS 777A is typically shipped as non-hazardous thermoplastic pellets in moisture-resistant 25 kg bags or 1,000 kg jumbo bags, palletized and stretch-wrapped. No special UN hazard classification normally applies. Transport in clean, dry, ventilated conditions away from heat, sunlight, moisture, and contamination; avoid package damage.
    Storage Store Lotte Chemical STAREX® MABS 777A in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat sources, moisture, and incompatible materials such as strong oxidizers. Keep it in tightly closed original packaging, palletized off the floor, and protected from dust, water, and contamination. Avoid excessive stacking and prolonged outdoor exposure; observe local regulations and the SDS.
    Shelf Life Typical shelf life is 12–24 months from manufacture when stored unopened in a cool, dry place away from sunlight and moisture.
    Application of Lotte Chemical STAREX® MABS 777A

    A production line converting Lotte Chemical STAREX® MABS 777A into transparent rigid medical device components begins with closed-loop desiccant drying. Moisture is held below 0.05 wt% before plastication because free methyl methacrylate-acrylonitrile-butadiene-styrene copolymer hydrolyzes at elevated melt temperature. The grade is processed in a 24:1 L/D general-purpose injection screw with a non-return valve clearance below 0.05 mm. Melt temperature is set at 200–240°C. Mould temperature is maintained at 30–60°C. These conditions support thin-wall filling in luer lock hubs, IV catheter hubs, transparent fluid observation chambers and rigid pump housing windows. The polymer is supplied as natural transparent pellets. Converter-side cleanliness under ISO 13485:2016 is required for invasive or fluid-contact devices. Cytotoxicity is assessed under ISO 10993-5 and irritation/sensitization under ISO 10993-10. If supplier certification exists, the material can be screened against USP Class VI requirements. Ethylene oxide residual limits are set by ISO 10993-7. Regrind is 0% for critical medical parts unless revalidation of biocompatibility and mechanical performance is completed. Mould release agents must be avoided on contact surfaces, because silicone migration can shift surface tension and downstream adhesive bond strength. For assembly, solvent bonding using methyl ethyl ketone is generally not recommended; UV-curable adhesives requiring 365–405 nm light cure are used. The driving limitation is steam sterilization. MABS softens near 100°C; autoclave exposure at 121°C can produce dimensional collapse in load-bearing connectors. Ethylene oxide at 50–55°C is the usual production-compatible terminal sterilization route. Gamma exposure can be tolerated only after colour-shift evaluation at the specified dose because transparent MABS tends to yellow. Table 1 summarizes sterilization-compatible routes and technical limits.

    Sterilization processTypical exposure windowSuitability for STAREX® MABS 777A transparent medical mouldingsMain control standard
    Ethylene oxide50–55°C, 50–65% RH, 4–6 hPreferred for low-heat transparent components; haze shift must be tested per ASTM D1003ISO 11135, ISO 10993-7
    Gamma irradiation25 kGy maximumLimited by yellowing; not recommended for colour-critical lenses without evaluation; published data for this specific grade under gamma is limitedISO 11137
    Electron beam25 kGy maximumMay retain colour better than gamma in some lots; full lot qualification requiredISO 11137
    Steam autoclave121°C, 15 minNot recommended for load-bearing connectors; dimensional softening risk near 100°CISO 17665

    What Limits Detergent Stress-Cracking Resistance in Transparent Kitchenware?

    Injection moulding of STAREX® MABS 777A into transparent kitchenware is constrained less by melt flow than by environmental stress cracking in hot alkaline dishwashing media. Food-contact certification must be verified against the supplier’s declaration; converters may test final articles under Regulation (EU) 10/2011 or FDA 21 CFR 177.1020 if the grade is covered. The preferred melt temperature is 215–230°C. Mould temperature is raised to 60°C for high-gloss surfaces. Pre-drying at 80°C for 3–4 h in a desiccant dryer is mandatory. In-house spruce and runner regrind is limited to 10 wt% for food-contact inner surfaces unless migration testing demonstrates no adverse effect. The end-product range includes stackable drinking tumblers, transparent salad bowls, refrigerator boxes and water pitcher bodies. The operational boundary is repeated exposure to high-temperature dishwasher detergents. Stress cracking is most severe at gate weld lines and sharp rim radii. Articles should be designed with radius greater than 0.5 mm at transitions to reduce stress concentration. The material is not suitable for hot-fill above 85°C or microwave reheating. Alkaline detergent at elevated temperature accelerates crazing; therefore maximum service exposure should be limited to residential dishwasher cycles up to 65°C unless part geometry is validated by cyclic stress-crack testing.

    Thick-walled cosmetic jar bases molded from STAREX® MABS 777A require a different thermal strategy than thin-wall housewares. Crystal clear side walls of 8–12 mm demand low shear and long hold times rather than high injection speed. The melt temperature is set at 225–240°C. The mould temperature is held at 60–70°C to preserve surface polish and delay skin solidification. Two-stage holding pressure is applied; the first stage packs the gate region, the second stage compensates for volumetric shrinkage without inducing residual stress. Gate seal time is determined by process simulation and verified by weigh-shot studies. A release masterbatch may be added at 0.05–0.10 wt% when deep jars show ejection stick. This addition changes haze slightly, so light transmission must be checked under ASTM D1003. The resulting articles—cream jars, balm containers and clear over-caps—are intended for ambient contact with cosmetic formulations. Compatibility is defined by the specific cream base. Esters, essential oils and solvent blends above 20% loading can generate environmental stress cracking in the polymer. Packaging compliance follows EC 1223/2009 for cosmetic safety and REACH Annex XVII for restricted substances. Post-consumer recycled feedstocks are not used in this application without full migration and odour panel testing. The main rejection defect is gate vestige and sink mark, which is controlled by sequencing valve gates and maintaining a cushion between 3–5 mm. Regrind from thick-wall sprues is limited to 15 wt% and only reintroduced into non-food cosmetic packs after dust removal and magnet trapping.

    Home Appliance Indicator Windows and Control Dial Caps with Tight Haze Budgets.

    Transparent windows for washing machine programme dials, air conditioner display bezels and refrigerator control panels are produced from STAREX® MABS 777A in thicknesses of 1.0–2.5 mm. The production issue is not short-shot filling but silver streak and floating tramp metal from regrind. Pre-drying reaches 0.04 wt% moisture or lower. Melt temperature is kept at 210–230°C. Mould temperature is set at 40–60°C. Hot runner systems with externally heated manifolds are used to eliminate cold slug and reduce colour shift. Weld line placement is moved outside the lens viewing zone by relocating the gate or by sequential valve gate control. Optical haze is tested against ASTM D1003. Transmittance is measured on molded plaques, not pellets. The finished articles include control knob caps, indicator lenses and transparent door windows. Electrical safety is governed by IEC 60335-1. Flammability is reported according to UL 94 HB, and the grade is covered by the supplier’s Yellow Card only where verified. Non-food appliance parts may contain up to 20 wt% closed-loop regrind if impact and haze remain within drawing limits. The main incompatibility is long-term exposure to citrus-based cleaning agents and aromatic plasticizers from gaskets; such contact can produce micro-crazing at molded-in stresses.

    For transparent consumer audio housings and wearable electronics windows, STAREX® MABS 777A is usually processed at wall sections below 1.2 mm. Hot runner drops and high clamp force are not required; the limiting factor is gate blush around pinpoint gates. Gate diameter is set by flow simulation rather than fixed rule; gate blush is reduced by a radiused gate exit and high melt temperature. Drying is done at 75–80°C for 3–4 h. Melt temperature is set at 215–235°C and the mould is chilled to 25–40°C to reduce cycle time. Injection speed is profiled from fast filling to slow pack, with switchover at 95–99% of shot volume. The typical end products are ear cup shells, smartwatch charging dock lenses and transparent earbud LED diffusers. Regulatory status follows RoHS 2011/65/EU and REACH SVHC obligations. UL rating must be confirmed for the actual wall thickness. Circuit board adhesives and polyurethane cushions can migrate plasticizer; this is prevented by specifying non-ester adhesives. Outdoor use is not recommended without UV stabilization because the transparent matrix will yellow. Regrind of clean sprues and runners is permitted at 10–20 wt% if the resulting haze remains below the product specification, but lower regrind is used for laser-marked surfaces.

    When Transparent Toys Must Satisfy EN 71-3 Migration Limits.

    Transparent toy vehicle windows, construction set panels and electronic learning device lenses made from STAREX® MABS 777A must combine impact resistance with extractable-metal control. The mechanical requirement is assessed by EN 71-1 torque and tension tests after impact; the chemical requirement is tested under EN 71-3 for nineteen elements. U.S. import work is governed by ASTM F963-17 and CPSIA lead and phthalate restrictions. Colouring masterbatches are restricted to heavy-metal-free pigments. Regrind is limited to 10 wt% and only from documented internal production, because external recycled feedstock breaks traceability. Processing uses a melt temperature of 210–225°C and a mould temperature of 35–50°C to reduce degradation-related odour. Pre-drying at 80°C for 3–4 h is required. Sharp edges and small parts are controlled by the toy standard, not the polymer supplier. The final components include transparent side windows for ride-on vehicles, bubble level windows, and clear display cases for electronic toys. The material is not recommended for mouthing articles or teething surfaces unless exhaustive migration and extraction studies are completed. Dishwasher exposure is not a design condition.

    Molding LED Diffusers Without Compromising Luminous Uniformity.

    LED fixture diffusers and lens rings molded from STAREX® MABS 777A require a balance between luminous transmittance and hiding of point-source LEDs. The processing window is narrower than appliance parts because diffusing masterbatches alter melt flow and mould deposit. A low-dust diffuser masterbatch is added at 0.2–0.8 wt% depending on LED pitch and target light distribution. Melt temperature is held at 215–230°C. Mould temperature is kept uniform at 50–60°C to minimise stress birefringence visible under polarised light. The screw is a low-shear design with a compression ratio of 2.0:1 to protect the diffuser particle size distribution. End articles include cylindrical diffuser covers, flat lens panels and decorative transparent rings in luminaires. Photometric measurements are performed on the final luminaire per IES LM-79-19; material transmission is referenced to ASTM D1003. Luminaire safety follows IEC 60598-1. The material is not suitable for high-power LED modules that raise lens surface temperature above 75°C, because dimensional stability and transmission decay can occur. Regrind is limited to 10 wt% for optical surfaces because even slight streaking affects luminous uniformity.

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    Certification & Compliance
    More Introduction

    Lotte Chemical STAREX® MABS 777A is a methyl methacrylate–acrylonitrile–butadiene–styrene copolymer supplied as pellets for injection-molding applications. The grade is assigned to the transparent MABS category because the methacrylate comonomer shifts the visible-light scattering behavior of the butadiene-toughened styrene-acrylonitrile system. This product is specified in technical sourcing documents for rigid parts that require optical clarity combined with practical room-temperature impact strength. Lot-specific property values are controlled according to the test methods listed below; the manufacturer’s certificate of analysis supersedes representative class ranges.

    How Does MABS 777A Differ from Standard Opaque ABS and Polycarbonate?

    Standard injection-molding ABS contains butadiene-rich rubber particles dispersed in a styrene-acrylonitrile matrix. The refractive-index mismatch between the rubber phase and the SAN matrix causes multiple scattering; total luminous transmittance through a 3 mm plaque measured in accordance with ISO 13468-2 is typically below 20%. MABS 777A uses methyl methacrylate in the continuous phase to narrow that refractive-index difference and reduce optical haze. Transparent MABS grades commonly achieve total luminous transmittance between 88% and 91% on a 3 mm polished plaque; product-specific values for MABS 777A are stated in the supplier’s datasheet.

    Compared with polycarbonate, MABS 777A provides higher melt flow and lower processing temperature, but lower heat resistance and lower multi-axial impact. Polycarbonate has a Vicat softening temperature above 140°C, whereas transparent MABS typically remains below 100°C under ISO 306/B50. Compared with PMMA, MABS 777A offers higher notched impact strength but lower surface hardness and lower resistance to alcohol-induced stress cracking. Compared with transparent polystyrene, it provides better environmental stress crack resistance and higher elongation at break. Within the STAREX MABS family, MABS 777A is differentiated by flow length, optical clarity, and practical impact retention; exact grade-to-grade comparisons are made using the same mold and test plaque protocol.

    On injection molding lines equipped with general-purpose screws of 20:1 to 24:1 L/D, MABS 777A requires pre-drying to a residual moisture content below 0.03% by weight. Desiccant dryers operating at 80–85°C for 3–4 h with an air dew point of −30°C or lower are used to prevent hydrolysis of the grafted rubber phase and subsequent silver streaking. Moisture-related surface defects are assessed visually against a polished reference under 60° gloss measurement according to ASTM D523. Melt stock temperature measured by an immersion thermocouple at the nozzle is typically maintained between 230°C and 250°C. Back pressure and screw speed are restricted because shear heating increases melt stock temperature above the set point; screw rotation speed should be low enough to prevent yellowness index drift above 1.2 units under ISO 17223. Shot size is normally limited to 70% of screw capacity, and barrel residence time is kept below 8 min. Regrind addition above 20% by weight tends to degrade optical clarity and notched impact strength, so regrind use is controlled gravimetrically.

    A common configuration for transparent closures is a 40 mm single-screw injection unit with a 22:1 L/D general-purpose screw and a 16-cavity hot runner. Hot runner drops are set 5–10°C higher than the front barrel zone but should not exceed 260°C. Gate diameters of 0.5–1.0 mm are typical for wall thicknesses of 1.5–3.0 mm. Below 0.4 mm, shear heating at the gate increases the risk of localized haze and yellowing. Field observations from transparent MABS molding show that short shots and hold-pressure release before gate freeze-off produce internal sink marks and optical density variations that are not corrected by longer screw recovery time. Published degradation rate constants for MABS 777A are limited, so thermal stability should be verified by melt-flow tracking over a 20-minute dwell using ISO 1133-1.

    When Hot Runner Manifolds Exceed the Recommended Melt Stock Temperature

    Thermo-oxidative degradation of the butadiene-rich graft phase occurs when stagnant melt in hot runner drops remains above 260°C. The failure signature is an increase in yellowness index, black specks from crosslinked rubber particles, and a drop in notched Izod impact below 6 kJ/m² measured under ISO 180/A. In multi-cavity tools, uneven filling caused by gate freeze-off can create residence time differences across cavities; the last-filled cavity often shows lower transmittance and higher haze because the melt front has cooled. Process engineers reduce manifold temperatures only after pressure-drop measurements at the gate confirm acceptable fill pressure. Gate seal time is established by part weight stabilization; too-short hold time produces sink and optical density gradients, while too-long hold time raises gate vestige without improving mechanical properties.

    Mold surface temperature of 50°C is typically the minimum for polished transparent surfaces. Lower mold temperatures may produce flow hesitation lines that appear as parabolic haze bands and reduce weld-line strength. Weld-line impact retention in transparent MABS is commonly 30–50% lower than the bulk value, so load-bearing sections are located away from weld lines during mold design. Mated mold surfaces should maintain vent gaps of 0.02–0.03 mm to release trapped gas without allowing flash; blocked vents create burn marks and local optical defects.

    In cosmetic packaging and personal-care component manufacturing, MABS 777A is selected for transparent closures and side walls where surface gloss above 100 GU at 60° is required from polished tool steel with roughness below 0.1 µm Ra. The material is suited to thin-wall flow lengths, but chemical compatibility with formulations containing alcohols, esters, or hydrocarbons must be validated by stress-cracking tests such as ISO 22088-3. MABS 777A cannot be recommended for repeated exposure to ketone-based solvents or strong acids, and molded-in stress above 10 MPa increases susceptibility to environmental stress cracking.

    For diagnostic and medical device housings, the material is evaluated for short-term contact with diluted detergents and alcohol-based disinfectants. Ethylene oxide sterilization is generally less damaging to MABS than steam autoclave because heat deflection temperatures below 100°C cause distortion under steam load. Gamma or electron-beam sterilization above 25 kGy can shift yellowness index and reduce elongation at break; dose mapping under ISO 11137-1 is required before production release. Published sterilization tolerance data for this specific MABS 777A configuration may be limited, and application-specific validation remains the responsibility of the device manufacturer.

    Optical Quality, Sterilization Tolerance, and Regulatory Compliance Matrix

    Grade-specific regulatory status is supplied in the Lotte Chemical material safety data sheet and any applicable food-contact statement. The test methods used for incoming inspection and comparative benchmarking are summarized in the table below. Each method requires standardized specimen conditioning at 23°C and 50% relative humidity for 24 h unless stated otherwise. The representative ranges are characteristic of transparent MABS chemistry and are not lot-specific acceptance limits for MABS 777A.

    Representative property ranges for transparent MABS chemistry
    Property Test method Specimen / condition Representative range
    Density ISO 1183-1 23°C, immersion method 1.08–1.10 g/cm³
    Melt mass-flow rate ISO 1133-1 220°C, 10.0 kg Grade-specific; injection-molding flow class
    Tensile yield stress ISO 527-2 Type 1A, 50 mm/min 42–52 MPa
    Flexural modulus ISO 178 80 mm × 10 mm × 4 mm 1900–2400 MPa
    Notched Izod impact ISO 180/A 23°C, 80 mm × 10 mm × 4 mm 8–15 kJ/m²
    Vicat softening temperature ISO 306/B50 50 N load, 50°C/h 91–99°C
    Total luminous transmittance ISO 13468-2 3 mm plaque, D65 illuminant 88–91%
    Haze ASTM D1003 / ISO 14782 3 mm polished plaque ≤2.0%

    Processing control limits applied to transparent MABS on production injection molding machines are shown below. These are starting-point ranges from general MABS processing practice and are not a substitute for machine-specific optimization.

    Processing control ranges for transparent MABS on injection molding lines
    Parameter Typical control range Measurement / equipment
    Residual moisture before molding ≤0.03% by weight Karl Fischer titration or ISO 15512
    Dryer dew point ≤−30°C Desiccant dryer hygrometer
    Melt temperature at nozzle 230–250°C Immersion thermocouple
    Mold surface temperature 40–70°C Contact probe or thermography
    Shot size ≤70% of screw capacity Injection unit
    Residence time ≤8 min Buffer timer
    Regrind addition ≤20% by weight Gravimetric blender

    Regulatory compliance for electrical and electronic equipment requires confirmation that the grade meets Directive 2011/65/EU RoHS Annex II restrictions and that no substances of very high concern exceed the threshold stated in EU REACH Article 33. For food-contact applications, compliance is not inherent to the polymer alone; a finished-article migration assessment under EU 10/2011 or FDA 21 CFR 177.1520 is required based on the actual processing conditions and food simulant. The material’s use in medical device housings must be supported by manufacturer biocompatibility data referenced to ISO 10993-1.

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