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LG Chem SAN 81HF

    • Product Name: LG Chem SAN 81HF
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 855524
    Polymer Type Styrene Acrylonitrile Copolymer (SAN)
    Density 1.07 g/cm³
    Melt Flow Rate 20 g/10 min (200°C/5 kg)
    Tensile Strength At Yield 70 MPa
    Tensile Elongation At Break 3%
    Flexural Strength 110 MPa
    Flexural Modulus 3,400 MPa
    Izod Impact Strength Notched 23 C 25 J/m
    Rockwell Hardness R 120
    Heat Deflection Temperature 1 82 Mpa 89°C
    Vicat Softening Temperature 108°C
    Coefficient Of Linear Thermal Expansion 6.5e-5 cm/cm/°C
    Volume Resistivity >1e15 ohm·cm
    Dielectric Constant 60 Hz 2.8
    Dissipation Factor 60 Hz 0.01
    Dielectric Strength 20 kV/mm
    Light Transmittance 89%
    Haze 1.0%
    Refractive Index 1.57
    Water Absorption 24 Hr 0.2%
    Mold Shrinkage 0.3-0.7%

    As an accredited LG Chem SAN 81HF factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing LG Chem SAN 81HF is packaged in 25 kg multiwall paper sacks, palletized and shrink-wrapped for industrial shipment and storage.
    Container Loading (20′ FCL) 20′ FCL loaded with LG Chem SAN 81HF in 25 kg bags, palletized and secured for ocean shipment.
    Shipping LG Chem SAN 81HF is a styrene-acrylonitrile copolymer resin, typically supplied as pellets. Generally not regulated as dangerous goods for transport; confirm with the current SDS. Ship in dry, cool, ventilated conditions, protected from moisture, UV, and ignition sources, complying with local regulations.
    Storage Store LG Chem SAN 81HF in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, flames, and strong oxidizers. Keep original containers or bags tightly closed to prevent moisture, dust, and contamination; protect from physical damage. Use first-in, first-out stock rotation, avoid excessive stacking, ensure spill containment, and follow the manufacturer’s SDS and local regulations.
    Shelf Life Stored cool, dry, and sealed, LG Chem SAN 81HF typically has a shelf life of 24 months from production.
    Application of LG Chem SAN 81HF

    Across multi-cavity injection tools producing clear food-contact appliance windows, the operating problem is not plastication rate but the balance of drying, melt cushion, and gate freeze-off required to maintain a flat, low-stress transparent part. SAN 81HF is dried in desiccant dryers at 80°C for 4 h to bring residual moisture below 0.05% before plastication; brief exposure to ambient air above 55% RH can raise surface moisture and produce silver streaks within 30–60 min. Melt temperatures are held between 215°C and 240°C, with mould temperatures of 40–70°C for unfilled grades. Back pressure is set from 5–10 bar hydraulic, and the screw is sized so that shot weight remains between 30% and 70% of barrel capacity; outside this range the residence time distribution widens. A cushion of 3–6 mm is held to keep the sealing ring active during hold pressure. Valve-gated hot tip systems with tip diameters from 1.0 mm to 1.5 mm are preferred over edge gates because shear at the gate promotes a surface layer of oriented polymer that appears as gate blush. Food-contact parts manufactured from SAN 81HF are evaluated under EU Regulation (EU) No 10/2011 and FDA 21 CFR 180.22; the EU migration test applies an overall migration limit of 10 mg/dm², while the specific migration of acrylonitrile is controlled at 0.01 mg/kg of food or food simulant. Colour masterbatch letdown ratios are normally 2–4 wt% for transparent tints, and regrind is kept below 20 wt% to limit yellowness shift measured under ASTM E313. Final components include food processor bowl covers, electric kettle water-level windows, rice cooker control-panel lenses, and water dispenser sight tubes. In production-scale tools with 24 or more cavities, vent depths are limited to 0.02–0.05 mm to avoid flash while still allowing gas evacuation; the land length is kept below 1 mm. Gate freeze-off time is established by increasing hold pressure until part mass stabilises across all cavities, then increasing by 5–10% as a buffer, rather than extending hold time at lower pressure.

    What Limits Gate Diameter in Thin-Wall Cosmetic Compact Bases?

    Gate blush in high-gloss SAN 81HF compact bases is governed by the temperature of the frozen skin formed during the first 0.1–0.3 s of filling and by the temperature recovery at the gate during packing. When the gate diameter is below 0.8 mm, shear rates at the gate can exceed 50,000 s⁻¹, producing local molecular orientation that remains visible after cooling. Processing therefore uses a two-stage injection velocity profile: a slower filling speed of 20–40 mm/s until the melt front has passed the gate, followed by 60–120 mm/s to complete the cavity before hesitation marks form. Melt temperature is maintained at 210–230°C to reduce the risk of yellowing in light tints; mould temperature is set between 60°C and 80°C when the tool surface is SPI/SPE #A1 diamond polish. Gloss measured at 60° under ASTM D523 remains above 90 GU on polished cavities, but a drop of 5–10 GU near the gate normally indicates an excessively high injection speed. Pearl or effect pigments are introduced at 2–3 wt% only after side-feeding or pre-compounding, because gravimetric dosing at the throat with this grade produces colour swirl in thin-wall lenses. Cosmetic pack components require sensory and chemical resistance testing rather than food-contact migration; chemical resistance is assessed after 72 h immersion in emollient simulants containing isoamyl acetate and liquid paraffin, and stress-cracking is checked under a constant strain of 0.75% in ethanol/water solutions. Compliance is limited to REACH (EC 1907/2006), RoHS Directive 2011/65/EU, and packaging heavy metal limits from EU Directive 94/62/EC where the sum of lead, cadmium, mercury, and chromium VI is not to exceed 100 ppm. Ejection requires ribs with draft angles between 0.5° and 1.5° because SAN 81HF retains stiffness up to its Vicat temperature range; release pressure spikes are managed with mould-release additives at 0.1–0.3 wt%. Typical final products are lipstick tube bodies, compact bases, jar closures, over-caps for serum packaging, and clear side windows in prestige secondary cartons.

    Process variableCosmetic compact baseFood-contact appliance windowAutomotive instrument cluster lens
    Residual moisture before processing0.03% max0.05% max0.04% max
    Melt temperature range210–230°C215–240°C215–235°C
    Mould temperature range60–80°C40–70°C60–80°C
    Injection velocity profile20–40 mm/s gate, then 60–120 mm/s40–80 mm/s through hot tip, then 80–150 mm/s30–60 mm/s to gate, then 60–100 mm/s
    Hold pressure on melt50–80 MPa40–70 MPa50–75 MPa
    Back pressure3–7 bar5–10 bar4–8 bar
    Regrind allowance10% max20% max15% max
    Primary appearance standardASTM D523 60° glossASTM D1003 hazeISO 4892-2 after xenon exposure

    Where transparent SAN 81HF is converted into automotive interior switch lenses and instrument cluster windows, the controlling factor shifts from flow length to haze retention after thermal ageing at 80–90°C and the reduction of moulded-in birefringence under polarised light inspection. The recommended ultraviolet stabilisation consists of a benzotriazole UV absorber at 0.2–0.5 wt% and a low-molecular-weight hindered amine light stabiliser at 0.1–0.3 wt% compounded before pelletising; dry-blending at the press is not sufficient for interior parts exposed to daylight through the windshield. Melt temperature is held at 215–235°C to limit the formation of chromophoric species, and hot runner channels are sized for a shear rate below 1,000 s⁻¹. Mould temperature from 60–80°C keeps the frozen skin thick enough to improve scratch resistance but remains below the Vicat softening boundary so that ejection can occur without deformation. Injection velocity is reduced as the flow front passes through gate inserts of 0.8–1.2 mm; this technique lowers flow-induced orientation. Parts are not post-mould annealed unless OEM specifications demand dimensional stabilisation for 1 h at 85°C, because excessive annealing converts residual stress into creep distortion in cantilever snap features. Weathering validation uses ISO 4892-2 xenon arc testing with a window glass filter; the acceptance criterion is typically haze increase measured by ASTM D1003-13 of less than 2% after 500 kJ/m² at 340 nm, though published data for this specific grade under every OEM cycle is limited. Final components are push-button lenses, climate control display covers, shift indicator windows, and sensor lens retainers inside the passenger cabin.

    When Transparent Office Equipment Windows Are Converted Without Flame-Retardant Additives

    For printer carriage windows, scanner cover lenses, and router display panels, SAN 81HF is selected because thin-wall transmittance and dimensional repeatability can be maintained without the high processing temperatures required by polycarbonate. In these conversions the melt is held between 210°C and 230°C, which is 60–80°C below typical PC conditions, lowering purge volume and barrel residence time. Parts with wall thickness of 1.0–1.6 mm are injected through pin gates of 0.6–1.0 mm; the high-flow grade fills narrow bosses and snap hooks around display frames without excessive pressure, but the process must avoid melt jetting by positioning gates against an opposing wall and using a first-stage injection speed below 30 mm/s. Electronic accessory components are assessed under IEC 62368-1:2023 for information technology equipment; clear SAN 81HF parts are typically classified UL 94 HB at the required wall thickness, but flame-retardant additives are not incorporated because halogenated or phosphorus systems reduce transparency and raise density. Static-related dust adhesion is controlled by ionising air bars at the mould rather than by adding antistatic masterbatch, since surface resistivity and light transmission are negatively affected at loading levels above 1 wt%. Shrinkage in the flow and transverse directions is predicted using ISO 294-4:2018; moulds for these parts usually compensate for anisotropic shrink with a nominal cavity allowance of 0.4–0.6% depending on wall thickness. Final parts include transparent covers for printer carriages, scanner document windows, router status lenses, and copier control-panel covers.

    Household storage containers and bathroom dispenser bodies represent the most process-stable conversion route for SAN 81HF: they are moulded at 215–235°C melt temperature and 40–60°C mould temperature with wall thicknesses from 1.5–2.5 mm, and they are evaluated under DIN EN 12875-1 for mechanical dishwashing resistance only when repeated hot-water contact is claimed; high-fat or high-alcohol food contact is not assumed unless specific migration testing under EU 10/2011 is completed on the finished article.

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    Certification & Compliance
    More Introduction

    In high-cavitation injection molding of transparent rigid components, lot-to-lot melt viscosity controls fill consistency more than any single mechanical property. LG Chem SAN 81HF is a high-flow styrene acrylonitrile resin specified for thin-wall housings, diagnostic covers, cosmetic packaging, filter bodies, and appliance lenses where mold-filling resistance must remain below that of general-purpose SAN. The material is a statistical copolymer of styrene and 24–28 wt% acrylonitrile. The absence of a butadiene rubber phase distinguishes it from ABS and preserves the clarity and stiffness required in non-impact applications. According to manufacturer technical literature, 81HF is supplied in natural pellet form with a density of approximately 1.07 g/cm³ when measured under ISO 1183-1:2019. Melt viscosity is controlled by molecular-weight adjustment rather than external plasticizer addition, moving the processability envelope toward longer flow length while accepting a reduction in notched impact strength relative to medium-flow SAN grades.

    Typical processing applications are confined to indoor or stabilized service. The grade is suitable for injection molding of transparent covers, slider trays, filter housings, and multi-cavity connectors with wall thickness between 1.0 mm and 2.5 mm. It is not intended for load-bearing structural parts or for continuous hot-water exposure above its heat deflection limit.

    What separates a high-flow SAN from general-purpose polystyrene and ABS?

    General-purpose polystyrene exhibits lower melt viscosity and higher light transmission, but lacks the nitrile functional group that gives SAN its resistance to aliphatic hydrocarbons, fats, and many household detergents. ABS contains a grafted polybutadiene rubber phase that provides high notched impact strength but eliminates transparency and reduces flexural modulus. LG Chem SAN 81HF occupies an intermediate position: the acrylonitrile segment raises heat deflection temperature and chemical stress-crack resistance compared with GPPS, while the absence of rubber keeps the material translucent and stiff. Compared with medium-flow SAN grades, 81HF has a higher melt volume-flow rate under ISO 1133-1:2022, shorter molecular relaxation time, and lower melt pressure at equivalent fill speed. The trade-off is a measurable reduction in notched Izod impact and a narrower processing window at the upper melt-temperature limit.

    Representative natural-grade values from current manufacturer documentation are listed in Table 1. Values are not release limits and vary by production location, grade lot, and color concentrate.

    Table 1. Representative physical properties for LG Chem SAN 81HF, natural grade.
    PropertyTest standardRepresentative value
    DensityISO 1183-1:20191.07 g/cm³
    Melt volume-flow rate, 220 °C, 10 kgISO 1133-1:202228 cm³/10 min
    Tensile stress at yieldISO 527-2:201270 MPa
    Tensile elongation at breakISO 527-2:20123.0 %
    Flexural modulusISO 178:20193400 MPa
    Notched Izod impact, 3.2 mm, type 1AISO 180:20231.5 kJ/m²
    Vicat softening temperature, VST B/50ISO 306:2022105 °C
    Heat deflection temperature, 1.8 MPaISO 75-2:201388 °C
    Rockwell hardness, R scaleASTM D785-23120
    Mold shrinkage, parallel/normalISO 294-4:20180.3–0.6 %

    The flexural modulus of approximately 3400 MPa places 81HF above unfilled ABS and below typical polycarbonate in stiffness. The notched Izod value of 1.5 kJ/m² is intentionally low; designers must avoid snap-fit geometries with high local stress concentration unless gate location, radii, and wall thickness are adjusted to reduce notch sensitivity. Mold shrinkage in the range of 0.3–0.6 % is anisotropic and depends on packing pressure, gate freeze time, and flow orientation. Dimensional control therefore cannot be predicted from resin data alone and requires cavity-pressure verification.

    Flow–Impact Trade-off and Hot-Runner Pressure Requirements

    High-flow SAN is produced by shifting the molecular-weight distribution downward. This reduces melt-viscosity-dependent pressure drop, improves thin-wall filling, and shortens cooling time, but also reduces chain entanglement density and notched impact resistance. In hot-runner systems, the practical benefit is lower injection pressure and reduced clamp force demand for a given projected area. Published data for this specific configuration is limited, but processing records on multi-cavity hot-runner tools show that high-flow SAN grades frequently reduce hydraulic injection pressure by 10–25 % compared with medium-flow grades at the same fill time. The exact reduction depends on manifold diameter, gate style, shear heating, and part geometry rather than resin flow index alone.

    The processing window is bounded at the upper end by thermal degradation and at the lower end by incomplete plastication. Melt temperatures above 240 °C can initiate yellowing, molecular-weight loss, and surface splay from volatile decomposition products. Melt temperatures below 200 °C produce high melt viscosity, poor gate filling, and short shots. Barrel zone temperature variation should therefore be maintained within ±5 °C when molding high-flow SAN, particularly in direct-gated tools with long melt residence times.

    When thin-wall fill time falls below 0.4 s, melt temperature becomes the controlling variable

    Thin-wall parts with nominal wall thickness below 1.5 mm require fast injection speeds and high shear heating at the gate. In such tools, the measured melt temperature during air shot may understate the actual temperature at the gate by 10–20 °C because of viscous dissipation. If fill time decreases below 0.4 s, melt-temperature control, gate diameter, and non-return valve function dominate process capability. A reciprocating screw with an L/D ratio of 22:1 to 25:1, compression ratio of 2.2:1 to 2.6:1, and a check-ring non-return valve with seat clearance below 0.05 mm provides reproducible shot weight and prevents backflow during packing. Mold temperature should be held between 40 °C and 70 °C to balance melt-front advance and surface gloss. Lower mold temperatures reduce cycle time but increase molded-in stress and weld-line visibility.

    Back pressure is typically set between 0.35 MPa and 0.70 MPa to homogenize melt temperature without excessive viscous heating. Screw surface speed is generally limited to 0.1–0.2 m/s to avoid shear-induced degradation. Injection velocity should be profiled so that the melt-front velocity remains constant; deceleration at the end of fill reduces gas traps and gate blush. Hot-runner manifold and nozzle temperatures are maintained between 215 °C and 230 °C, with direct temperature verification at each drop because high-flow SAN is sensitive to hot-spot formation in partially filled manifolds.

    Drying, Residence-Time Limits, and Barrel Temperature Profiling Are Not Independent

    SAN absorbs moisture from humid air. At relative humidity above 60 %, unpredried pellets can generate splay, streaks, and embrittlement during molding. The resin should be dried in a desiccant dryer at 80 °C for 3–4 h to a residual moisture content below 0.02 % by weight. Drying air should have a dew point of −29 °C or lower and airflow of at least 3.7 m³/h per kg/h of polymer throughput. Hopper loading must minimize exposure to plant air when ambient humidity exceeds 60 %, and transfer lines should be purged with dried air.

    Residence time is operationally critical. At melt temperatures above 230 °C, total residence time should not exceed 5 min, including hot-runner hold time during stoppages. When production is interrupted for more than 10 min, the barrel and hot runner should be purged with a styrenic purge compound or GPPS. Avoid flame-retardant or additive packages containing free amines and strong bases, which can accelerate hydrolysis of the acrylonitrile segment and cause surface crazing at gate areas.

    Regulatory status must be verified from the supplier’s certificate of compliance for the specific production lot. Table 2 summarizes common compliance declarations applicable to natural-grade LG Chem SAN 81HF.

    Table 2. Common regulatory and marking references for LG Chem SAN 81HF.
    Regulatory referenceScopeTypical status
    FDA 21 CFR 177.1040Acrylonitrile/styrene copolymers in food-contact articlesCompliant subject to end-use conditions and acrylonitrile monomer migration limits
    EU 10/2011Plastics in food-contact materialsCompliance as starting resin must be confirmed by final article migration testing; overall migration limit 10 mg/dm²
    REACH (EC) No 1907/2006SVHC, Annex XVII restrictionsNo SVHC above 0.1 % w/w declared by supplier for natural grade
    RoHS 2011/65/EULead, mercury, cadmium, hexavalent chromium, PBB, PBDECompliant for natural grade conditioned on supply-chain documentation
    ISO 11469:2016Plastics identification markingMark as >SAN<

    Applications observed on production lines include transparent diagnostic housing covers, cosmetic compact bases, battery charger shells, and small appliance indicator lenses. In each case, the limiting factor is not tensile strength but gate blush, weld-line visibility, and stress cracking under repeated exposure to hand creams or cleaning agents. Annealing at 60–65 °C for 1–2 h may be specified to lower molded-in stress for chemically loaded parts. The grade should not be specified for components requiring UL 94 V-2 or better unless a specific flame-retardant formulation is qualified, because the natural high-flow SAN is not inherently flame-retarded.

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