| HS Code | 851251 |
| Manufacturer | LG Chem |
| Product Name | LUPOS MABS TR-558AI |
| Polymer Type | MABS (Methyl Methacrylate-Acrylonitrile-Butadiene-Styrene) |
| Processing Method | Injection Molding |
| Specific Gravity | 1.08 |
| Melt Flow Rate | 10 g/10 min (220 °C/10 kg) |
| Tensile Strength | 45 MPa |
| Tensile Elongation At Break | 30% |
| Flexural Modulus | 2000 MPa |
| Notched Izod Impact Strength | 12 kg·cm/cm (23 °C) |
| Rockwell Hardness | R105 |
| Heat Deflection Temperature | 80 °C (1.82 MPa) |
| Vicat Softening Temperature | 95 °C |
| Light Transmission | 88% |
| Haze | 2% |
| Mold Shrinkage | 0.4–0.6% |
| Drying Conditions | 80 °C for 3–4 h |
| Melt Temperature | 210–240 °C |
| Mold Temperature | 40–60 °C |
As an accredited LG Chem LUPOS MABS TR-558AI factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | LG Chem LUPOS MABS TR-558AI is supplied in 25 kg net bags, palletized and lined for safe handling and storage. |
| Container Loading (20′ FCL) | 20′ FCL container loaded with LG Chem LUPOS MABS TR-558AI resin in 25 kg bags, palletized, shrink-wrapped, and secured for export. |
| Shipping | LG Chem LUPOS MABS TR-558AI is shipped as non-hazardous thermoplastic resin pellets, typically in 25 kg moisture-barrier bags or bulk octabins. It is not classified as dangerous goods for transport; no UN number, hazard class, or packing group applies. Keep dry and avoid heat, direct sunlight, and moisture during transit. |
| Storage | Store LG Chem LUPOS MABS TR-558AI in a cool, dry, well-ventilated area away from direct sunlight, heat, flames, and oxidizing agents. Keep containers tightly closed to prevent moisture and contamination; avoid dust generation and static discharge. Use suitable PPE and follow the manufacturer’s SDS. Do not store near food, feed, or drinking water. |
| Shelf Life | LG Chem LUPOS MABS TR-558AI typically has a 24-month shelf life when stored dry, cool, and in original unopened packaging. |
LG Chem LUPOS MABS TR-558AI is a transparent methyl methacrylate-acrylonitrile-butadiene-styrene injection-molding resin. The application scope is limited to sectors where the combination of refractive-index-matched rubber particles, moderate comonomer polarity, and melt-phase stability under controlled shear define a practical processing window. The scenarios below are restricted to established use classes: medical fluid-management accessories, cosmetic closures and jars, appliance control windows, flat optical scanning windows, toy and stationery transparent components, and food-contact bowl assemblies. Long-fiber compounding, large-container extrusion blow molding, and outdoor glazing are excluded because the grade is not specified for those process and exposure conditions.
In short-term indirect medical device applications, LUPOS MABS TR-558AI is processed into transparent snap-fit housings and fluid-path connectors where impact resistance after ethylene oxide sterilization is required. The applicable quality system is ISO 13485:2016; material qualification typically follows ISO 10993-5:2009 for cytotoxicity and ISO 10993-10:2021 for sensitization and irritation, with extraction ratios defined in ISO 10993-12:2021. Cleanroom molding is performed in an ISO 14644-1 Class 8 or tighter environment, with raw-resin lot traceability maintained to upstream polymerization records. The grade is not specified for long-term implantable contact or repeated steam autoclave cycling above 121 °C because the butadiene phase degrades under repeated steam exposure and measurable gel formation begins to shift optical clarity.
Formulation control in this sector is conservative. The neat resin is dried to ≤0.02 wt% moisture using a desiccant dryer set at 80 °C for 3–4 h with a dew point no higher than −30 °C. Silicone-based external lubricant is added at 0.1–0.3 wt% only when demolding forces in multi-cavity tools exceed 12 kN, because excess lubricant migrates to the weld line and reduces burst pressure in thin-wall Luer collars. Transparent masterbatch addition is limited to 0.5–2.0 wt%; higher loadings increase haze beyond 3% as measured per ASTM D1003-21. Clean in-house regrind is capped at 15 wt%, and only single-pass regrind is permitted after validation of Luer fit retention under ISO 594-2:2019.
Production equipment includes three-zone injection units with screw L/D of 20:1 and compression ratio between 2.0:1 and 2.4:1. Melt temperature is held at 215–235 °C, measured at the nozzle by immersion probe, while mold temperature is maintained at 45–65 °C. Hot-runner valve gates with pneumatically actuated pins are preferred over cold sprue, but residence time in the manifold must not exceed 8 min at 235 °C. Longer residence shifts the melt from water-white to amber and increases the likelihood of black specks from degraded butadiene gel. Injection velocity is profiled to prevent jetting at the gate; cavity fill times of 0.4–1.2 s are typical for wall sections between 1.5 mm and 3.2 mm. Terminal parts include transparent diagnostic meter housings, IV line Luer guards, quick-connect couplings, and fluid level sight windows for pressure-monitoring modules.
Cosmetic packaging with LUPOS MABS TR-558AI is structured around chemical resistance to hydrocarbon emollients, isopropyl myristate, and denatured ethanol blends. Qualification begins with ISO 175:2010 immersion testing for mass change and stress-crack onset after 24 h at 23 °C; mass change above 1.2% in isopropyl myristate correlates with visible microcrazing on thread roots. EU cosmetic packaging must also satisfy the packaging safety assessment under Regulation (EC) No 1223/2009, and the material must not release substances in contradiction to REACH Annex XVII. For North American export, migration testing under the intended oil-based simulant is performed before commercial release because FDA 21 CFR 177.1020 reports alone do not provide formulation-specific clearance for every ester-based cosmetic contact condition.
Formula addition ratios in this segment differ from medical molding because optical clarity must survive repeated cap-on and thread engagement. Radiation-grade masterbatch is used at 0.8–2.5 wt%, preferably based on a carrier resin with melt-flow rate within 15% of TR-558AI to avoid visible marbling in thick jar bases. Benzotriazole UV absorber is compounded at 0.1–0.3 wt% to limit yellowing under retail display lighting, and hindered-amine stabilizer is added at 0.1–0.2 wt% when jars are exposed to UV-C sterilization in filling lines. Internal mold release is not used in transparent high-gloss side walls because it increases micro-scratch visibility after top-load assembly.
Molding uses polished tool inserts meeting SPI/SPE A1 finish; mold temperature is kept at 50–70 °C to replicate gloss without post-mold flame polishing. Sequential valve gating is programmed for oval compacts to push the weld line toward the hinge boss rather than the viewing surface. Secondary operations include hot stamping on the outer top surface and ultrasonic insertion of metal hinge pins; ultrasonic amplitude is limited to 20–30 µm to avoid vibratory heating above the Vicat softening region near 90–100 °C. Representative terminal articles are lipstick caps with internal snap beads, cream jar bodies with thread outer diameter above 30 mm, compact bases, and fragrance overcaps.
For appliance control-panel windows that are ultrasonically welded to opaque ABS chassis components, the selection of MABS TR-558AI turns on melt-compatibility at the weld interface rather than on bulk optical transmission alone. The relevant product safety standard is IEC 60335-1:2020 for household electrical appliances, with additional compliance under IEC 62368-1:2018 where the same window is used in AV/ICT equipment; restricted-substance conformity is assessed against RoHS 2011/65/EU Annex II and the current REACH SVHC candidate list. Formulation of transparent windows is deliberately additive-lean: a phosphite–hindered phenol stabilizer blend is compounded at 0.1–0.2 wt%, and any color masterbatch loading above 0.5 wt% raises haze nonlinearly to above 2.0% as measured by ASTM D1003-21. For static-dust control, bulk glycerol monostearate is restricted to 0.1–0.3 wt% or replaced by post-mold external antistatic coating, because bulk loads above that threshold reduce luminous transmittance by 1–2%.
Production lines use three-zone injection screws with L/D of 20:1 and mold temperatures of 35–45 °C for flat windows, with diaphragm gates located away from weld-line zones that will later be ultrasonically welded. Weld energy directors are designed with apex angles of 60–90°, and 20 kHz ultrasonic welding is operated at amplitudes of 18–28 µm; amplitude above 35 µm generates fine flash and particulate inside sealed electromechanical compartments, a documented field-return source in particle-sensitive optical sensor assemblies. Representative terminal articles include air purifier front covers, vacuum cleaner canister windows, robot vacuum sensor lens covers, and transparent control panel inlays.
Flat scanning windows in office automation and retail point-of-sale equipment do not tolerate orientation-induced birefringence above a few nanometres of optical path difference because polarised light from barcode and card readers is distorted by residual stress. The governing safety compliance for the assembled equipment is IEC 62368-1:2018; optical transparency is tested per ASTM D1003-21, and weathering resistance for kiosk use is screened by ISO 4892-2:2021 method A for 300 h at 65 °C black-standard temperature. When the window is also exposed to touch, surface resistivity requirements are referred to IEC 61340-5-1:2016.
Formula addition ratios for this segment are constrained by the need to avoid bulk materials that lower optical transmission or increase scatter. Glycerol monostearate antistatic additive is used at 0.1–0.3 wt% only where measured surface potential on demolded windows exceeds 10 kV; otherwise the part is externally coated with a silica-based hard coat applied at 2–5 µm thickness. Laser-marking masterbatch is compounded at 0.05–0.15 wt% for point-of-sale windows requiring batch code engraving, and no regrind is allowed in flat scanning windows because repeated heat history increases gel counts and optical path difference by 15–30%. Published data for this specific flat-window configuration is limited; process capability must be confirmed on the target tool.
Molding is performed by injection-compression with a compression gap of 0.3–1.0 mm, clamp force between 1,500 kN and 2,500 kN for projected areas up to 0.3 m², and melt temperature at 210–230 °C to reduce molecular orientation in the gate region. Mold temperature is held at 55–75 °C with cartridge heater uniformity of ±1.5 °C across the optical surface. Cooling time is extended by 20–40% relative to standard injection molding to slow the surface-layer glass transition and reduce birefringence. Terminal parts are barcode scanner windows, point-of-sale touchscreen cover lenses, card reader windows, and printer scanner glass replacements.
Within toy and stationery transparency specifications, the dominant constraint is that colorant let-down ratio must remain low enough to avoid visible particle scatter from pigment agglomerates in translucent windows and barrel tubes. Chemical compliance is assessed by EN 71-3:2019+A1:2021 migration limits for 19 elements, ASTM F963-23 solubility limits for 8 heavy metals in accessible substrate materials, and CPSIA Section 108 lead and phthalate restrictions where the article is a children’s product. Masterbatch let-down is maintained at 1.5–3.5 wt% with pigment primary particle diameter below 1 µm; liquid color is dosed at 0.05–0.15 wt% for tinted transparent components, and in-house regrind is limited to 10 wt% unless lot-level heavy-metal traceability is maintained back to pigment certification.
Molding lines for this segment use conventional three-zone injection units, but fill speeds are set at 150–250 mm/s to suppress flow marks on curved transparent surfaces. Two-shot molding with a rotational platen is used for TPE overmolded edges on transparent building-block window inserts and pen barrel assemblies; TPE adhesion is achieved by melt bonding at interface temperature 190–210 °C without primer. Representative terminal articles include transparent window inserts for toy blocks, pen barrel tubes, sharpener covers, toy magnifier housings, and transparent backpack buckle covers.
Food-contact bowl assemblies processed by injection-compression molding impose a narrow band of allowable melt residence and shear because over-shear increases detectable free-rubber gel counts in aqueous contact. The material must be qualified under FDA 21 CFR 177.1020 where the acrylonitrile-butadiene-styrene copolymer composition is within permitted comonomer limits, and the supplier must confirm that the methyl methacrylate content is included in the relevant compliance coverage. For EU migration, compliance is established under Regulation (EU) No 10/2011 with total migration below 10 mg/dm² for aqueous, acidic, alcoholic, and fatty food simulants as appropriate. Specific migration of acrylonitrile must not exceed 0.02 mg/kg food, and butadiene must not exceed 0.01 mg/kg.
Formula addition is limited to the neat resin and direct reuse of clean, uncured process scrap from the same food-contact lot at no more than 20 wt%; no external mold release, no color masterbatch, and no antistatic additive are added unless separately food-contact approved. The regrind fraction must be re-dried to ≤0.02 wt% moisture and its melt-flow stability verified by ISO 1133-1:2022 before re-introduction. Processing uses injection-compression with a melt temperature of 210–235 °C, mold temperature of 55–75 °C, and compression stroke of 2–5 mm to minimize frozen-in stress at the bowl rim. Terminal articles include blender jar covers, food processor bowl lids, storage canister bases, and transparent measuring cup bodies; repeated dishwasher exposure above 65 °C is not recommended because alkaline detergent swelling accelerates stress cracking in the rim area.
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LG Chem LUPOS MABS TR-558AI is an injection-molding grade of methyl methacrylate–acrylonitrile–butadiene–styrene supplied for transparent components that require a controlled balance of optical transmission, impact resistance, and thin-wall processability. The grade is differentiated from opaque ABS by methyl methacrylate comonomer, which shifts the refractive index of the continuous styrene–acrylonitrile matrix toward the dispersed butadiene rubber phase and reduces visible-light scattering. Supplier technical literature lists a density of 1.09 g/cm³ when tested to ISO 1183-1:2019, a melt mass-flow rate of 21 g/10 min at 220 °C under a 10.0 kg load when measured to ISO 1133-1:2022, and a tensile stress at yield of 46 MPa under ISO 527-2/1A/50. The same literature reports Charpy notched impact strength of 9 kJ/m² at 23 °C under ISO 179-1/1eA, flexural modulus of 2500 MPa under ISO 178:2019, luminous transmittance of 90 % under ISO 13468-1, and haze of 1.8 % under ISO 14782 on 2.0 mm plaques. These values are representative literature data and must be confirmed against the lot certificate because published data for TR-558AI lot-to-lot variation is limited.
Before melt processing, the resin should be dried in a desiccant dryer with a dew point no higher than -40 °C. Residual moisture above 0.05 wt% hydrolyzes ester and nitrile groups during plastication, producing silver streaks, surface splay, and increased haze in transparent parts. Drying at 80 °C for 4 h is a common starting point; extension to 6 h is typical when ambient relative humidity exceeds 60 %. Moisture verification should follow ISO 15512:2019 by Karl Fischer titration or an equivalent calibrated moisture analyzer. Once dried, material transfer to the machine throat should use sealed lines and dried-air purge to limit reabsorption during extended hopper residence.
On a reciprocating injection molding machine, a general-purpose screw with 20:1–25:1 L/D and compression ratio 2.0:1–2.5:1 is generally suitable, provided the check ring is free-draining and the nozzle is a shut-off type to prevent drool. Melt temperature at the nozzle is normally maintained in the interval of 220–250 °C; mold temperature is usually 40–70 °C, with higher values used for polished optical surfaces. Back pressure in the range of 3–7 MPa melt pressure improves melt homogeneity without excessive shear heating. Screw surface speed below 0.5 m/s and total melt residence time below 8 min reduce yellowing and black speck formation in long-cycle automated cells.
| Processing parameter | Typical range | Measurement or control method |
|---|---|---|
| Desiccant dryer inlet temperature | 80 °C | Dryer thermocouple calibration |
| Drying time | 4–6 h | Timer or moisture analyzer |
| Residual moisture after drying | < 0.05 wt% | ISO 15512:2019 |
| Melt temperature at nozzle | 220–250 °C | Infrared pyrometer or penetration thermocouple |
| Mold temperature | 40–70 °C | Thermocouple in mold steel |
| Back pressure | 3–7 MPa | Machine hydraulic or melt pressure transducer |
| Screw surface speed | 0.2–0.5 m/s | Machine setting |
| Residence time at melt temperature | < 8 min | Shot size and cycle calculation |
In standard ABS, the continuous styrene–acrylonitrile matrix and the dispersed polybutadiene rubber phase have refractive indices that differ sufficiently to cause multiple scattering of visible light, yielding an opaque product. Methyl methacrylate comonomer in MABS raises the refractive index of the matrix closer to that of the butadiene rubber, reducing the scattering cross-section. The effect is amplified by controlling the rubber phase morphology: butadiene-rich domains are retained at small particle diameters and low volume fractions, shifting scattering behavior toward the Rayleigh–Gans regime. If the rubber particle size is too large or the phase contrast remains above approximately 0.01 refractive index units, haze increases rapidly. Injection molding conditions that generate high shear can deform rubber domains, alter the apparent particle aspect ratio, and produce anisotropic haze; anisotropic optical behavior is therefore more sensitive in gate regions and weld lines than in simple plaques.
Compared with transparent ABS grades, MABS typically provides lower haze for the same impact modification level, but its transparency remains below that of PMMA because the multiphase morphology cannot be eliminated entirely. The optical balance is measured by ISO 13468-1 luminous transmittance and ISO 14782 haze. In multi-cavity production, the practical lower wall thickness is limited by flow length and gate design; molded parts below 0.8 mm may require elevated melt temperature and higher injection velocity, which in turn shortens the available residence-time budget before degradation begins.
Mold-surface preparation exerts a strongly nonlinear effect on optical appearance. Polished cavities should be maintained to SPI A-2 or better, with diamond-paste finishing below 3 µm particle size to avoid micro-scratches that scatter light. Vent depths in the cavity parting line are typically held at 0.02–0.03 mm for MABS to allow gas evacuation without flash. For parts with projected area above 100 cm², vacuum-assisted venting may be needed to prevent burn marks or flow hesitation along the fill front. Hot-runner systems with valve-gated drops reduce gate blush and drool but require higher maintenance discipline because degraded material can accumulate behind the valve pin and release periodically into the melt stream as black or yellow specks.
Residual moisture in MABS at levels above 0.05 wt% hydrolyzes the methacrylate and nitrile groups during plastication, producing surface splay, silver streaks, gate blush, and an increase in haze. The failure signature appears on the molded component as fan-shaped silver streaking originating from the gate or from hot-runner drop tips; in transparent parts this is an immediate visual reject criterion. For hot-runner systems, moisture-related defects can be difficult to distinguish from thermal decomposition. A moisture analyzer operating at 160 °C or Karl Fischer titration per ISO 15512:2019 should be used to confirm dryness before start-up after weekend shutdowns or after regrind addition.
Drying at 80 °C for more than 6 h is generally unnecessary if the dryer dew point remains below -40 °C. Overdrying is not a major degradation risk at this temperature, but pellet bridging in the hopper can occur if the ambient plant air is very humid and the dried material is allowed to re-absorb moisture. Transfer lines should be sealed and purged with dried air, and hopper residence time should not exceed 30 min at high ambient humidity. Measuring moisture at the machine throat rather than at the dryer outlet identifies reabsorption failures in transfer lines and hopper vents that cannot be seen visually before molding.
Within the LUPOS MABS product family, TR-558AI is positioned for high-flow, thin-wall molding while retaining notched impact strength. The high-flow design reduces filling pressure in multi-cavity tools with flow-length-to-wall-thickness ratios above 150:1, but it can increase sensitivity to gate blush if injection velocity is uncontrolled. Compared with opaque high-impact ABS grades, TR-558AI sacrifices some rubber content to preserve transparency; consequently, low-temperature impact resistance is lower than opaque ABS and should be validated for cold-impact applications at -20 °C or below using ISO 179-1/1eA.
Rheological evaluation of high-flow MABS at 220 °C and apparent shear rates from 100 s⁻¹ to 1000 s⁻¹ shows a shear-thinning response typical of multiphase styrenic melts. The power-law index for high-flow MABS is generally in the range of 0.3–0.5, although published capillary viscosity data for TR-558AI specifically is limited and should be generated for critical thin-wall tooling. In practical terms, shear thinning reduces the pressure drop in thin sections at increasing flow rate, but gate freeze-off remains rapid because heat conduction to the mold wall dominates once the melt stops advancing. This places a premium on precise switch-over from velocity control to pressure control; late switch-over raises packing pressure near the gate and increases birefringence, while early switch-over produces sink marks and poor replication of polished surfaces.
TR-558AI sits between PMMA and general-purpose transparent ABS in optical, mechanical, and processing characteristics. Compared with PMMA, MABS has lower tensile strength and lower surface hardness, but higher notched impact strength and better resistance to alkaline cleaners. Compared with transparent ABS, MABS achieves higher luminous transmittance and lower haze for a similar rubber content, although the melt viscosity and thermal stability are different. The following comparative table lists typical values for three transparent materials under common test methods. The PMMA and transparent ABS values are representative commercial-grade comparators, not specific LG Chem products; published data for exact comparative configurations is limited and should be verified against supplier datasheets.
| Property | Test method | MABS TR-558AI | PMMA | Transparent ABS |
|---|---|---|---|---|
| Density | ISO 1183-1:2019 | 1.09 g/cm³ | 1.19 g/cm³ | 1.07 g/cm³ |
| Luminous transmittance | ISO 13468-1 | 90 % | 92 % | 88 % |
| Haze | ISO 14782 | 1.8 % | 1.0 % | 2.5 % |
| Tensile stress at yield | ISO 527-2/1A/50 | 46 MPa | 72 MPa | 48 MPa |
| Flexural modulus | ISO 178:2019 | 2500 MPa | 3300 MPa | 2400 MPa |
| Charpy notched impact at 23 °C | ISO 179-1/1eA | 9 kJ/m² | 2 kJ/m² | 11 kJ/m² |
| Vicat softening temperature | ISO 306/B50 | 104 °C | 108 °C | 102 °C |
Compared with polycarbonate, MABS has lower heat deflection temperature and lower notched impact strength, but it can provide adequate performance in transparent covers and housings where continuous service temperature remains below 90 °C and where exposure to alkaline cleaners is more frequent. Polycarbonate remains the preferred choice when heat deflection temperature above 125 °C is required or when impact resistance must be retained below -20 °C. MABS also offers lower density than polycarbonate and can be processed at lower melt and mold temperatures, reducing energy input and clamp-force demand in high-cavitation tools.
In diagnostic device housings and transparent consumer electronics overlays, TR-558AI is processed into components requiring dimensional stability and low haze after exposure to isopropanol and common hospital disinfectants. Chemical compatibility is not universal: molded parts show environmental stress cracking when exposed to ketones, aromatic hydrocarbons, and some chlorinated solvents, particularly if high molded-in stress is present after ejection. Compliance for medical devices must be established on the final device under ISO 10993-1:2018, not inferred from the base resin. For general-purpose transparency, SVHC documentation under REACH and restricted substances under RoHS Directive 2011/65/EU should be confirmed at lot level from the supplier declaration.
When regrind is incorporated at levels above 20 wt%, hopper segregation and optical variability may increase because the regrind particle size distribution differs from virgin pellet size. Production experience on multi-cavity hot-runner molds has shown that gate blush and jetting can be reduced by using valve-gated nozzles and by profiling injection velocity from 60 mm/s to 120 mm/s in the first 20 % of fill volume, but these settings are mold-specific and should be established by short-shot studies. The grade should not be processed on screw designs intended exclusively for polyolefins with deep feed sections and low compression ratios; insufficient shear and poor melting result in unmelted rubber agglomerates that appear as white specks in transparent parts.
Thermal aging of molded parts under continuous exposure above 80 °C can produce yellowing and loss of impact at extended exposure times; the oxidative stabilization package is designed for intermittent high-temperature exposure rather than continuous hot-air service. Compatibility with steam autoclave cycles is not a generic property and must be validated on the specific part geometry because wall thickness, gate stress, and residual moisture all influence haze and warpage after 121 °C autoclave exposure. For applications requiring repeated disinfection with quaternary ammonium compounds, alcohol-based cleaners, or hydrogen peroxide vapor, chemical compatibility testing under load is required; environmental stress cracking can occur below the short-term tensile stress of the resin when molded-in stress exceeds critical values for the chemical environment.