| HS Code | 402459 |
| Product | LG Chem LUCENE mLLDPE HP1018BA |
| Polymertype | Metallocene Linear Low Density Polyethylene (mLLDPE) |
| Catalysttype | Metallocene |
| Density | 0.918 g/cm³ |
| Meltindex | 1.0 g/10 min (190°C/2.16 kg) |
| Meltingpoint | 118 °C |
| Vicatsofteningpoint | 100 °C |
| Tensilestrengthatyield | 10 MPa |
| Tensilestrengthatbreak | 30 MPa |
| Elongationatbreak | 600% |
| Dartdropimpact | 150 g |
| Elmendorftearstrengthmd | 120 g |
| Elmendorftearstrengthtd | 250 g |
| Haze | 6% |
| Gloss | 80% |
| Sealinitiationtemperature | 95 °C |
| Form | Pellets |
As an accredited LG Chem LUCENE mLLDPE HP1018BA factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | LG Chem LUCENE mLLDPE HP1018BA is supplied in 25 kg moisture-resistant bags, palletized at 1,000 kg per pallet. |
| Container Loading (20′ FCL) | 20′ FCL loaded with 25 kg bags of LG Chem LUCENE mLLDPE HP1018BA, palletized, shrink-wrapped, and secured for ocean shipment. |
| Shipping | LG Chem LUCENE mLLDPE HP1018BA is shipped as non-hazardous polyethylene pellets in standard 25 kg bags or octabins, palletized and stretch-wrapped. Use clean, dry trucks or containers at ambient temperature. Keep packaging closed, dry, and away from direct sunlight, heat, moisture, and contamination; no special DG classification. |
| Storage | Store LG Chem LUCENE mLLDPE HP1018BA in a cool, dry, well-ventilated area away from direct sunlight, heat sources, flames, and strong oxidizers. Keep original bags/containers closed and palletized to prevent moisture, dust, and contamination. Avoid prolonged UV exposure and excessive stacking. Use first-in, first-out inventory and follow the manufacturer’s SDS and local regulations. |
| Shelf Life | Shelf Life: Typically 24 months from manufacture when stored in original, unopened packaging in a cool, dry, well-ventilated area, away from sunlight. |
Blown film conversion of LG Chem Lucene HP1018BA for general food-contact packaging is set up on mono-layer and three-layer lines in which the extruder L/D is held between 25:1 and 30:1 and the die gap is set from 1.8 mm to 2.4 mm to compensate for the high backpressure associated with single-site catalyst resin. The nominal melt index of 1.0 g/10 min determined per ASTM D1238 at 190 °C under 2.16 kg and the nominal density of 0.918 g/cm³ determined per ASTM D1505 place the grade in the low-density sealing film class, while the narrow molecular weight distribution and short-chain branching distribution reduce shear-thinning relative to Ziegler-Natta butene LLDPE of equivalent melt index. On a 55 mm monolayer line with a grooved-feed extruder and spiral mandrel die, melt pressure at the breaker plate may be 10% to 20% higher than a conventional butene LLDPE at the same screw speed; the parameter most affected is die-pressure oscillation, and processors typically reduce screw speed by the same percentage or replace the Maddock barrier mixer with a low-shear metering section to keep melt temperature below 210 °C at the die exit. Frost line height is maintained between 400 mm and 800 mm below the die face at blow-up ratios from 2.0:1 to 3.0:1; higher blow-up ratios improve transverse direction tear measured according to ASTM D1922 but reduce bubble robustness if the melt temperature falls below 180 °C at the die lip. In coextruded food packaging, HP1018BA is placed as the sealant layer adjacent to HDPE or MDPE skins when stiffness is required, and seal strength is quantified under ASTM F88/F88M while heat sealability is profiled under ASTM F2029 at 0.5 s dwell and 0.28 MPa seal pressure. The relevant food-contact compliance framework is FDA 21 CFR 177.1520 for olefin polymers and EU Regulation No 10/2011 with overall migration testing performed on the finished film; converters must revalidate compliance when additive masterbatch addition exceeds 2% by weight because slip and antiblock residues can alter migration behaviour. The terminal packages include form-fill-seal pouches for fresh-cut produce, bakery bags, and pillow packs for snacks, in which seal-through-contamination performance and dart impact retention remain the two primary release criteria.
Extrusion lamination lines that deposit HP1018BA onto woven polypropylene or biaxially oriented polypropylene use slot dies with die widths above 1500 mm and air gaps from 150 mm to 250 mm. The low density of 0.918 g/cm³ and single-site molecular architecture lower the seal initiation temperature relative to conventional LLDPE, but the same architecture reduces draw resonance during high-speed extrusion coating only when the melt temperature is kept within a narrow band. On a 90 mm single-screw extruder with 30:1 L/D running a slot die at 220 °C, neck-in can exceed that of LDPE by 10 mm to 20 mm per edge at the same air gap and line speed, making edge trim calculations and coat-weight uniformity more sensitive than conventional LDPE coating. Hot-tack strength is measured according to ASTM F1921 Method B at 0.3 s delay after seal initiation; the test is used to qualify sealant webs for vertical form-fill-seal lines where product settlement loads the seal before crystallisation is complete. Published data for this specific extrusion-coated configuration of HP1018BA is limited; converters therefore run design-of-experiment matrices with two variables, coat thickness and chill roll temperature, before committing a production line. The terminal structures are woven polypropylene sacks for cement, pet food, and resin granulate, where the HP1018BA sealant web is applied as a 20 µm to 40 µm extrusion laminate and must withstand drop tests defined by individual logistics specifications.
High-gauge industrial liners made from HP1018BA are processed at melt temperatures lower than those used for Ziegler-Natta octene LLDPE because residence-time degradation in the metering section can generate gel particles detectable as fish eyes in 100 µm film under a defect threshold of 0.02 mm². Blown film lines with internal bubble cooling and 65 mm extruders at L/D 30:1 run the grade at die gaps from 1.8 mm to 2.4 mm and blow-up ratios from 2.0:1 to 2.5:1 so that dart impact resistance measured under ASTM D1709 Method B and Elmendorf tear resistance measured under ASTM D1922 are balanced across machine and transverse directions. Internal bubble cooling can increase mass throughput by 20% to 30% on a 250 kg/h line, but if the frost line height is reduced below 300 mm to prevent bubble deflection, machine-direction tear values fall faster than transverse-direction tear values because amorphous orientation freezes near the die exit without sufficient relaxation. HP1018BA is used as an inner liner for heavy-duty sacks and as a secondary barrier inside woven bulk containers, not as a load-bearing fabric; creep under sustained static load and UV resistance under exposure require additional layers and stabilisers that are outside the grade’s standard formulation. Thickness is generally controlled to 80 µm to 120 µm in repeat orders, and tensile properties are verified under ISO 527-3 after conditioning at 23 °C and 50% RH per ASTM D618.
| Conversion mode | Equipment configuration | Melt temperature range | Critical dimensional parameter | Primary test standard |
|---|---|---|---|---|
| Monolayer blown food film | Grooved-feed extruder, L/D 25:1 to 30:1, spiral mandrel die | 180 °C to 210 °C | Die gap 1.8 mm to 2.4 mm; BUR 2.0:1 to 3.0:1 | ASTM D1238, ASTM D1709, ASTM F88/F88M |
| Extrusion coating or lamination web | 90 mm single-screw, 30:1 L/D, slot die with air gap 150 mm to 250 mm | 200 °C to 220 °C | Coat thickness 20 µm to 40 µm; chill roll temperature 15 °C to 30 °C | ASTM F1921, ASTM F2029 |
| Heavy-duty liner blown film | 65 mm extruder, IBC-controlled bubble, L/D 30:1 | 180 °C to 205 °C | Final film gauge 80 µm to 120 µm; frost line 300 mm to 600 mm | ASTM D1709, ASTM D1922, ISO 527-3 |
On agricultural silage lines, the decision to use HP1018BA as a core rather than a surface layer changes the required cling additive dosage and the frost line control strategy. Silage wrap is usually produced as a three-layer or five-layer blown film with total thickness between 20 µm and 30 µm; HP1018BA occupies the core layer when high puncture resistance measured under ASTM D5748 is required against corn stover ends and chopped cobs, while EVA or polyisobutylene-modified skins supply the tack that holds film to the bale. The lack of measurable surface tack from HP1018BA itself means that converters cannot substitute it directly for a high-EVA cling layer without coextruding tacky skins. Ultraviolet stabilisation is provided by hindered amine light stabilisers at total use levels from 0.3% to 0.8% by weight depending on film thickness and storage duration; accelerated weathering is verified under ISO 4892-3 and the result is compared against a non-stabilised control rather than assumed. Acid-scavenger selection is also critical because fermentation acids released from silage can migrate through the film and accelerate HALS depletion in the tie layers; converters must evaluate peel stability by checking interlayer adhesion after 500 h of accelerated acid exposure, although published data for HP1018BA in this exact test configuration is limited. Bubble geometry on these lines typically uses a stalk bubble with frost line height above 500 mm and blow-up ratio from 3.0:1 to 4.0:1; the resulting orientation improves tear propagation resistance under ASTM D1922 but reduces bubble stability if wind conditions in the production hall create fluctuation above 0.5 m/s. The terminal product is bale wrap for dairy and biogas operations, in which film failure occurs most often at the puncture point created by a cut stem, not at the seal or surface layer.
Cast-film conversion of HP1018BA into stretch hood webs is governed by the balance between elastic recovery and puncture resistance rather than by melt strength alone. A three-layer cast line with a 65 mm main extruder and 30:1 L/D typically operates with a die gap from 0.6 mm to 0.8 mm and a chill roll temperature between 15 °C and 25 °C; the film is drawn to final thickness from 60 µm to 120 µm and is used at stretch ratios between 45% and 65% depending on pallet width and load height. Tensile properties are measured under ISO 527-3, while puncture resistance is measured under ASTM D5748 and should be reported at both 23 °C and -18 °C when cold-climate distribution is part of the logistics chain. In operation, the film must retain sufficient elastic recovery to pull back under the pallet; if the chill roll temperature is set above 25 °C, the amorphous phase relaxes too quickly and the hood loses load retention within 24 h. Edge trim regrind in cast film can exceed 20% of the total feed and may increase gel deposition on the die lip if the screen pack is not maintained; continuous melt filtration with 125 µm or finer screen packs is used on production lines running high regrind ratios. HP1018BA can be used as the middle layer between LLDPE or LDPE skins, but a 100% HP1018BA web may initiate machine-direction tear at corners more readily than a blended structure under ASTM D1922; the decision is made by comparing corner puncture reports from the palletiser, not from laboratory tensile data alone. Terminal use includes pallet unitisation of bagged resin, bottled beverages, and gypsum board stacks, where the film is stretched over the load and shrunk by controlled relaxation rather than applied heat.
Blown film lines producing frozen food contact structures from HP1018BA are operated with the same die gap and blow-up ratio as general packaging, but the evaluation protocol changes because the film is loaded near its glass transition region under sub-zero storage. The film is conditioned at -18 °C for 4 h before dart impact testing under an adaptation of ASTM D1709 Method A; because the standard method is written for 23 °C conditioning, converters maintain an internal low-temperature method for comparative release and retain the 23 °C baseline required by specification. Seal strength is re-tested after freezing according to ASTM F88/F88M on filled pouches, because seal area contamination by ice fines and vegetable waxes can produce lower values than the laboratory seal specimen. For frozen vegetable and ice cream pillow packs, thicknesses from 40 µm to 70 µm are common, and the film is usually coextruded with a slip-modified skin to reduce blocking during freezer-elevated humidity packaging rooms. HP1018BA is not suited for freezer-to-microwave direct heating above 100 °C because the sealant layer can creep under thermal stress, and converters must switch to HDPE or PP sealant webs when the terminal package is heated. Published data for HP1018BA in direct microwave contact is limited; qualification therefore requires migration testing under EU Regulation No 10/2011 and sensory evaluation of the cooked food simulant. The terminal products include retail bags for frozen vegetables, fruit mixes, and ice cream bricks, where low-temperature dart impact retention and seal integrity at -18 °C are release criteria.
Medical sterile barrier webs using HP1018BA are produced on cleanroom blown film lines where particulate contamination is controlled below 10 particles/m³ at 5 µm and larger under ISO 14644-1 Class 7 monitoring. The grade is used as a sealant layer in pouches and lidding for devices sterilised by ethylene oxide or gamma irradiation; the film is often coextruded with HDPE or MDPE for stiffness, with HP1018BA facing the medical-grade paper or Tyvek web. Seal strength is verified under ASTM F88/F88M, and the complete sterile barrier system is validated under ISO 11607-1:2019 and ISO 11607-2:2020 rather than by film data alone. In ethylene oxide sterilisation, the film’s seal layer must allow gas penetration while preventing microbial recontamination after closure; post-sterilisation off-gassing is conducted below 60 °C to reduce the risk of seal creep and dimensional change. Gamma irradiation validation is performed under ISO 11137-1; published data for HP1018BA after gamma exposure above 45 kGy is limited, so converters must verify post-irradiation tensile and seal strength before releasing packaged devices. Additive packages must be reviewed against biocompatibility data, and the film must comply with FDA 21 CFR 177.1520 and EU Regulation No 10/2011 for food-contact equipment if the same cleanroom line is used for food packaging. The terminal products are pouches for syringes, catheters, surgical gowns, and procedure kits, in which particulate control, seal integrity, and sterilisation tolerance are the primary acceptance criteria.
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LG Chem LUCENE HP1018BA is a metallocene-catalysed linear low-density polyethylene resin classified within the LUCENE mLLDPE product family. The grade is supplied as pelletized ethylene/1-hexene copolymer for blown film conversion. Nominal values from the published product data sheet list a density of 0.918 g/cm³ and a melt index of 1.0 g/10 min determined at 190 °C under 2.16 kg load. Density is reported under ASTM D1505 or ISO 1183-1; melt index is reported under ASTM D1238 or ISO 1133-1:2022. These values are nominal rather than release specifications, and individual lots should be verified against the certificate of analysis.
| Parameter | Nominal Value | Test Designation |
|---|---|---|
| Density | 0.918 g/cm³ | ASTM D1505 / ISO 1183-1 |
| Melt index, 190°C/2.16 kg | 1.0 g/10 min | ASTM D1238 / ISO 1133-1:2022 |
| Comonomer | 1-hexene | FTIR or 13C NMR internal method |
| Form | Pellets | Visual/in-line |
The metallocene catalyst produces a narrow molecular weight distribution and a homogeneous distribution of 1-hexene along the polymer chain. This molecular architecture differentiates HP1018BA from conventional Ziegler-Natta LLDPE grades and from autoclave high-pressure LDPE. In high-temperature gel permeation chromatography, metallocene LLDPE grades of this class exhibit lower Mw/Mn than Ziegler-Natta LLDPE, which reduces viscosity at high shear and lowers motor load in spiral mandrel dies. The homogeneous comonomer distribution narrows the melting range and reduces the population of weakly bonded tie chains that limit dart impact performance. Dart impact strength is measured under ASTM D1709 or ISO 7765-1; tensile properties under ASTM D882 or ISO 527-3; and tear resistance under ASTM D1922 or ISO 6383-2. Because these values are gauge-dependent, direct substitution into a specification requires testing on the target film line rather than relying on nominal datasheet values.
The optical response of HP1018BA is influenced by crystallite size and surface roughness. Haze under ASTM D1003 and gloss under ASTM D2457 are typically governed by the uniform incorporation of 1-hexene and by the cooling conditions at the frost line. The BA designation in the LG Chem LUCENE nomenclature is associated with a film-grade additive package that adjusts slip and antiblocking behaviour. The precise additive loading is governed by the product data sheet and supply contract. Surface additive bloom rates depend on storage temperature, and coefficient of friction can continue to shift after 48 h to 72 h of film ageing.
At equivalent density and melt index, HP1018BA typically exhibits a narrower melting distribution than a Ziegler-Natta butene LLDPE. The differential scanning calorimetry trace under ISO 11357-3 shows a reduced population of low-melting, highly branched molecules and a reduced population of high-melting, low-comonomer fractions. This structural difference modifies seal behaviour. Hot tack force is measured under ASTM F1921; seal strength is measured under ASTM F2029 or ASTM F88. The actual reduction in seal bar temperature for HP1018BA relative to a butene LLDPE must be established on the target jaw configuration, because dwell time, jaw pressure, and film thickness dominate the thermal gradient across the seal interface.
Conventional butene LLDPE has a broader melting transition and may require higher seal bar temperatures to achieve equivalent seal strength. At the same film gauge, HP1018BA generally provides higher puncture resistance and higher dart impact strength; however, Elmendorf tear in the machine direction under ASTM D1922 can be lower than that of a high-pressure LDPE-rich blend, while transverse tear is generally higher. The balance should be established on the target film line.
Compared with autoclave LDPE, HP1018BA has lower melt strength because the metallocene backbone lacks long-chain branching. The shear viscosity at low rates is lower, and extensional viscosity has less strain hardening. This means a monolayer LDPE film of melt index 1.0 g/10 min can be processed at narrower die gaps and higher output stability than HP1018BA under identical conditions. However, the mLLDPE grade delivers higher dart impact strength and lower seal initiation temperature at equivalent film gauge. There is no linear low-density product that matches both the seal initiation of an mLLDPE and the bubble stability of an autoclave LDPE; therefore blends are used in industrial practice.
In blown film conversion, HP1018BA is not processed as a direct drop-in for an LDPE of identical melt index. The absence of long-chain branching reduces strain hardening in the bubble, and the melt exhibits less resistance to draw resonance. On a standard 24:1 to 30:1 L/D grooved-feed extruder, melt temperatures are generally controlled in the range 180 °C to 220 °C, and die gaps are usually set at 1.5 mm to 2.4 mm rather than the 0.8 mm to 1.2 mm gap common for high-pressure LDPE. The wider gap reduces shear stress in the die land and prevents irregularities at the extrudate surface. Blow-up ratios are commonly maintained between 2.0 and 3.5. In lines equipped with internal bubble cooling, the throughput limit is determined more by cooling air exchange than by screw recovery; without internal cooling, frost line height must be increased to compensate for the lower melt strength.
Converters running 100% HP1018BA on air-cooled monolayer lines observe a narrower stable bubble window than with a 70:30 mLLDPE:LDPE blend. The incorporation of 10 wt% to 30 wt% high-pressure LDPE raises extensional viscosity and stabilises the bubble without eliminating the seal initiation benefit. A feed system with minimised fines generation is required because metallocene pellets can generate fines if regrind handling is aggressive. Pre-drying is not generally required; if surface condensation exists after cold storage, desiccant drying at 60 °C for 2 h is sufficient. Processing above 240 °C should be avoided because thermal degradation may shift the melt index and increase gel levels. The processing window also narrows when the die gap falls below 1.0 mm or when the blow-up ratio exceeds 3.5.
In sealant web applications, the lower seal initiation temperature of HP1018BA allows the sealing jaw setpoint to be reduced relative to conventional LLDPE, which can reduce thermal distortion of the outer optical layer in biaxially oriented polypropylene or polyester laminates. The substitution is more straightforward in blown coextruded structures where the sealant layer thickness is above 12 µm. Below this thickness, melt strength limitations and gauge variation require blending with LDPE or the use of a larger die gap. The seal performance should be qualified using ASTM F2029 on the actual laminate for heat seal strength and ASTM F1921 for hot tack after the packaging machine has been set. Hot-tack results are dependent on jaw dwell, sealing pressure, sealant thickness, and contamination; therefore, the resin supplier’s nominal values cannot be directly transferred into a production specification.
Slip additives based on erucamide can create a cliff-edge effect in coefficient of friction for mLLDPE films. Below the migration threshold, kinetic COF may remain above 0.4; above the threshold it can fall to 0.1 to 0.2. The exact threshold depends on layer thickness and additive masterbatch. Converters should plot coefficient of friction against additive dose rather than assuming linearity. Kinetic and static coefficients are determined under ISO 8295 or ASTM D1894.
In extrusion lamination, HP1018BA is not generally used as the primary web because it lacks the neck-in control and melt draw stability of an autoclave LDPE. When used as a secondary or sealant layer, the melt temperature must be kept below 220 °C and the air gap minimised to avoid excessive edge neck-in. Published data for this specific configuration is limited. The resin is also not recommended for cast film or extrusion coating without pilot-line evaluation, because the processing window may be narrowed by the lower melt strength relative to high-pressure LDPE.
Polyolefin food-contact compliance is standard-dependent and grade-independent only within defined density and extractable limits. HP1018BA is represented by the supplier as suitable for use in food-contact films under EU and US frameworks, provided that the final structure passes migration testing on the actual packaging. The conformance boundaries listed in the following matrix are regulatory limits, not resin properties.
| Regulatory Obligation | Standard or Regulation | Conformance Boundary |
|---|---|---|
| EU food-contact plastics | Regulation (EU) No 10/2011 | Overall migration limit 10 mg/dm²; specific migration limits for additives |
| US food-contact olefin polymer | FDA 21 CFR 177.1520 | Density, extractables, and end-use limitations per paragraph (c) |
| REACH SVHC declaration | Regulation (EC) No 1907/2006, Article 33 | SVHC concentration 0.1% w/w per article |
| Heavy metals in electrical and electronic products | RoHS Directive 2011/65/EU, Annex II | Pb, Hg, Cd, hexavalent Cr, PBB, PBDE limits |
Regardless of the base resin status, a food-contact packaging product must be tested in its final state. Overall migration into aqueous, acetic acid, ethanol, and olive oil simulants is measured under EN 1186-2, EN 1186-4, or EN 1186-8, depending on the food type and contact temperature. The converter must also consider specific migration limits for slip and antiblock additives, which are not defined by the polymer backbone. HP1018BA cannot be assumed compliant for high-temperature retort, microwaving, or fatty food contact above 70 °C without a documented migration study on the finished film. Supply-chain documentation should include a lot-specific certificate of analysis, a declaration of SVHC content under REACH Article 33, and, where required for electrical or electronic packaging, a RoHS Directive 2011/65/EU Annex II statement.
Storage in a covered, dry area at 20 °C to 30 °C preserves pellet flow and limits condensation. Bags should be resealed after use to prevent moisture absorption that causes surface defects in cast or blown film. Long-term storage above 40 °C may reduce additive performance and increase pellet-blocking tendencies. Batch-to-batch variation is controlled by the supplier’s release limits, but additive bloom rates differ between seasons and can shift coefficient of friction after 72 h of film ageing. Converters should establish internal control limits for coefficient of friction and seal strength after 48 h ageing rather than using immediate post-extrusion values.