| HS Code | 605296 |
| Product Name | LG Chem HDPE ME5000 |
| Manufacturer | LG Chem |
| Polymer Type | High Density Polyethylene (HDPE) |
| Melt Index 190 C 2 16 Kg | 0.35 g/10 min |
| Density | 0.954 g/cm³ |
| Tensile Strength At Yield | 26 MPa |
| Elongation At Break | >600 % |
| Flexural Modulus | 1200 MPa |
| Vicat Softening Point | 124 °C |
| Heat Deflection Temperature | 70 °C |
| Environmental Stress Crack Resistance Escr F50 | >1000 h |
| Hardness Shore D | 65 |
| Notched Izod Impact Strength | 15 kg·cm/cm |
| Mold Shrinkage | 2.0-3.0 % |
| Processing Temperature | 170-210 °C |
As an accredited LG Chem HDPE ME5000 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | LG Chem HDPE ME5000 is packaged in 25 kg woven bags on pallets, with 1,000 kg jumbo bags available. |
| Container Loading (20′ FCL) | LG Chem HDPE ME5000: 20′ FCL holds about 18 MT in 25 kg bags, unpalletized; palletized loads available on request. |
| Shipping | LG Chem HDPE ME5000 is shipped as non-hazardous polyethylene resin pellets in 25 kg bags, 500/1000 kg jumbo bags, or bulk. Transport in clean, dry trucks/containers; keep away from moisture, heat, and direct sunlight. Secure pallets and comply with local transport regulations. |
| Storage | Store LG Chem HDPE ME5000 in a cool, dry, well-ventilated warehouse away from direct sunlight, heat, sparks, and open flames. Keep original packaging closed and pallets off the floor to prevent moisture pickup. Avoid prolonged stacking or high temperatures that may cause blocking. Maintain clean, dust-controlled conditions, use first-in, first-out rotation, and follow local regulations. |
| Shelf Life | LG Chem HDPE ME5000 has an indefinite shelf life when stored cool, dry, and away from sunlight, heat, and contaminants. |
On accumulator-head extrusion blow moulding lines producing 25–220 L UN-rated packagings, LG Chem HDPE ME5000 is processed at a melt temperature of 185–205 °C with a die head temperature of 190–210 °C and a mould cooling water inlet of 10–15 °C. Transport compliance for dangerous goods packagings is governed by the UN Model Regulations, Sections 6.1.5.3, 6.1.5.4, 6.1.5.5, and 6.1.5.6; European ground transport under ADR 6.1.4 requires the UN marking and a certificate issued by an approved body, while US domestic shipments reference 49 CFR §178.509 for plastic drums and jerricans. The formulation for hazardous-liquid service is predominantly virgin ME5000 at 96–98 wt% with carbon black/UV masterbatch added at 2.0–4.0 wt%. Re-ground flash from the same production line is incorporated at 20–30 wt% of total weight; higher regrind fractions alter die swell consistency and reduce the hydrostatic burst margin at pinch-off seams, and the maximum allowable fraction is set by the packaging test certificate rather than by a fixed material limitation. Parison programming with 25–35% die gap modulation is required to maintain nominal wall thickness of 1.8–3.5 mm across pinch-off regions; mould carrier clamp force for a 220 L drum is tool-specific but is typically set at 800–1200 kN; cooling time ranges from 180–360 s depending on wall thickness and insert temperature. Terminal pack types include UN-marked 1H1 tight-head drums, 1H2 open-head drums, 3H1 jerricans, and 1H1 inner bottles for composite IBCs up to 1000 L.
Fuel tank blow moulding with ME5000 is a six-layer coextrusion operation in which parison temperature, layer distribution, and EVOH continuity govern carburant permeation and low-temperature impact. The standard layup is outer HDPE, regrind, adhesive tie layer, EVOH, adhesive tie layer, inner HDPE; ME5000 is allocated to outer and inner layers, and post-moulder trim is returned to the regrind layer. EVOH barrier layer thickness is held between 1.5% and 3.0% of total wall thickness, adhesive tie layers are combined at 3.0–5.0 wt% of the parison, and the regrind layer may reach 35–40 wt% of total throughput only if barrier continuity and ESCR after thermal ageing remain within type-approval limits. Compliance is anchored to UN ECE R34 for mechanical strength, fire resistance, and fuel tightness; evaporative emission limits reference 40 CFR Part 86 and CARB LEV III, with barrier performance measured by oxygen transmission rate per ASTM D3985-17. Six extruders feed a multi-layer accumulator head; individual zone temperatures are set to 190–220 °C for HDPE layers, 205–220 °C for tie layers, and 195–215 °C for EVOH, with EVOH held below 230 °C to prevent gel formation. Die-head channel pressure differentials of 0.5–1.5 MPa are used to equalise layer thickness after parison swell; parison drop time is 3–8 s; inflation air pressure is 0.6–0.9 MPa; mould temperature is held at 12–25 °C. Terminal articles include multi-layered petrol tanks, diesel tanks, SCR urea solution tanks, and closed fuel filler necks produced on sequential coextrusion tooling. Published data for ME5000 in six-layer fuel tank configurations is limited to converter-specific layer distribution studies; the ranges above reflect production practice and require line-specific DOE validation because EVOH continuity varies with accumulator head tooling.
Because organophosphate and pyrethroid formulations are often delivered in xylene, cyclohexanone, or alkylbenzene solvents, unfilled ME5000 containers require post-mould fluorination or polyamide/EVOH coextrusion to control permeation and panel chemical attack. US pesticide container design and residue removal requirements are set in 40 CFR Part 165 with label requirements in 40 CFR Part 156; the EU CLP Regulation (EC) No 1272/2008 and transport provisions in ADR 6.1.4 govern classification and packaging integrity. The melt formulation is dominated by ME5000 at 96–98 wt% with colour/UV masterbatch at 2.0–4.0 wt%; barrier improvement is not achieved by additive loading but by post-process fluorination that converts the first 1–2 μm of the inner surface to a fluorinated barrier layer, or by a coextruded polyamide inner layer at 3–5 wt% of total structure where solvent swelling is severe. Fluorination is run inline after moulding at gas-phase fluorine concentrations of 0.5–1.0 vol% in nitrogen at 25–40 °C for 10–30 s, followed by purging to below 1 ppm residual F2. Blow moulding temperatures for ME5000 are held at 190–205 °C; mould cooling water is 10–15 °C. Terminal pack formats are 1 L, 5 L, 10 L, and 20 L bottles with fluorinated or coextruded barrier constructions, typically paired with 45 mm or 63 mm closures. Published data for the fluorinated ME5000 container permeation rate is limited to customer-specific barrier validations, so the residence and concentration parameters above should be verified on the actual tool.
For vertical water storage tanks in the 500–5000 L range, accumulator-head blow moulding of ME5000 is governed less by melt temperature than by parison sag and cooling shrinkage. Potable water contact is evaluated under NSF/ANSI 61 in North America and AS/NZS 4020 in Australia/New Zealand; product standards reference ISO 11469 for resin identification and EN 12566-1 for septic tanks where applicable. UV-stabilised tanks use 2.0–2.5 wt% carbon black masterbatch, which is the minimum range that provides long-term weatherability in HDPE outdoor service; antioxidant systems are supplied in the base grade and are not increased above the resin supplier limit. Large-part blow moulding uses parison programming with 100 or more wall-thickness control points; die gap modulation is adjusted over 30–40% of maximum stroke; shot weights of 20–100 kg require longitudinal parison support or pre-blow timing to limit sag-induced thinning below 3 mm. Mould cooling is run with water at 8–15 °C; cooling cycles for a 5000 L tank are production-specific and typically range from 45–90 min; internal air circulation after demoulding controls post-mould shrinkage of 1.5–2.0%. Terminal products include 500 L to 5000 L vertical storage tanks, potable water tanks, rainwater harvesting tanks, and EN 12566-1 septic tanks.
Stationary sodium hypochlorite and alum dosing tanks in water treatment plants are blow moulded from ME5000 with an integrally moulded flange and reinforcing ribs to resist hoop stress cycling at up to 0.05 MPa internal pressure. Design validation for stationary tanks refers to DVS 2205-1 for calculation of thermoplastic tanks, ASTM D1998-15 for polyethylene upright storage tanks, and EN 12573-1 for welded static tanks where subsequent welding is required. For black water-treatment tanks, carbon black masterbatch is added at 2.0–2.5 wt%; for natural translucent tanks used with ultrasonic level sensors, no masterbatch is used and UV stabilisers are supplied as part of the grade package. Extrusion blow moulding is performed with annular accumulator heads at a melt temperature of 190–210 °C; parison programming holds wall thickness at 4–8 mm at weld seams; cooling water is 10–18 °C; post-mould annealing at 80 °C for 2 h reduces residual stress at the sidewall-to-bottom transition. Sodium hypochlorite service is limited to 5–15 wt% NaOCl and sustained fluid temperatures below 40 °C; higher concentrations or temperature cycling can accelerate environmental stress cracking in the weld area. Terminal articles include vertical cylindrical dosing tanks, conical-bottom mixing tanks, and rectangular tank inserts from 100 L to 10,000 L.
In underhood fluid reservoirs, blow moulders use ME5000 for windshield washer reservoirs, coolant expansion tanks, and clutch/brake fluid reservoirs where low-temperature impact retention and weld-line ductility are specified. Material compliance is evaluated under ISO 527-2:2012 for tensile properties at weld lines, ISO 179-1:2023 for Charpy impact at -30 °C, and ISO 75-2:2013 for heat deflection temperature; coolant-contact testing follows OEM specifications referenced to production part drawings. The formulation uses 1–2 wt% carbon black masterbatch for UV-shielded reservoirs; regrind is capped at 20 wt% for underhood reservoirs to maintain weld-line impact after thermal ageing. Extrusion blow moulding is run with a melt temperature of 190–210 °C, die head at 200–210 °C, mould cooling at 10–20 °C, and secondary trimming/fusion-welding of bracket mounts under 0.4–0.6 MPa clamping pressure. Terminal products include 2–10 L washer reservoirs, 1–5 L coolant expansion tanks, and 5–20 L hydraulic fluid reservoirs for commercial vehicle platforms. Published data for ME5000 in underhood reservoir service is limited to OEM-specific material approvals and heat-aging protocols.
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LG Chem HDPE ME5000 is a high-density polyethylene injection-molding resin within the LUTENE-H series. The grade is positioned by a nominal melt flow index of 5.0 g/10 min under 190°C/2.16 kg loading according to ISO 1133-1:2022 and a nominal density of 0.954 g/cm³ according to ISO 1183-1:2019. The product is supplied in pellet form for rigid injection-molded articles requiring a controlled balance between melt flow, stiffness, impact resistance, and environmental stress-crack resistance. Typical applications include industrial pails, crates, tote boxes, caps, closures, and general technical moldings with wall thickness generally in the range of 1.5 mm to 4.0 mm. The values presented below are representative datasheet values and are not specification limits; lot-specific values are controlled by the manufacturer certificate of analysis.
| Property | Method | Unit | Representative Value |
|---|---|---|---|
| Melt flow index | ISO 1133-1:2022 | g/10 min | 5.0 |
| Density | ISO 1183-1:2019 | g/cm³ | 0.954 |
| Tensile strength at yield | ISO 527-2:2012 | MPa | 27 |
| Tensile elongation at break | ISO 527-2:2012 | % | >500 |
| Flexural modulus | ISO 178:2019 | MPa | 1,050 |
| Notched Izod impact at 23°C | ISO 180:2023 | kJ/m² | 6.0 |
| Vicat softening point, Method A50 | ISO 306:2022 | °C | 122 |
| Shore D hardness | ISO 868:2003 | — | 63 |
| Water absorption after 24 h | ISO 62:2008 | % | 0.01 |
| Mold shrinkage after 24 h | ISO 294-4:2018 | % | 1.5–2.5 |
Mechanical data for injection-molded HDPE are dependent on specimen preparation, mold temperature, shear history, and conditioning time. Tensile yield and flexural modulus values should be compared only among specimens produced under identical conditions and tested according to the same standard. The elongation at break value above 500% indicates ductile failure under the stated tensile conditions, but it does not predict part-level impact performance in the presence of weld lines, sharp corners, or molded-in stress.
The melt temperature range for general injection molding is 200°C to 240°C, with the preferred operating band between 210°C and 230°C. Barrel temperature profiles should be arranged with the rear zone from 180°C to 200°C, the central zone from 200°C to 220°C, and the front zone and nozzle from 210°C to 230°C. Melt temperatures above 280°C should be avoided because the stabilizer package is not intended for prolonged exposure at elevated temperatures, and oxidative degradation can generate discoloration, viscosity shifts, and surface defects. The recommended hot-runner manifold temperature, where applicable, is 220°C to 240°C; hot-runner systems with dead spots should be assessed for resin hold-up because stagnant HDPE melt can degrade rapidly at the upper end of the processing window.
Mold surface temperature is normally set between 20°C and 40°C. At the lower boundary, cycle time is shortened and ejection may be improved for stiff geometries, but surface gloss decreases and flow marks can appear in thin-wall sections. At 40°C, surface replication improves and internal stress is reduced, but cooling time increases for wall thickness above 3.0 mm. Mold temperature non-uniformity should be controlled to less than 10°C across the cavity because differential shrinkage in an HDPE with 0.954 g/cm³ density and a crystallization temperature near 117°C to 122°C can generate bowing in rectangular crates and dimensional variation exceeding the 0.5% post-molding tolerance band commonly used for industrial containers.
Injection velocity should be set to achieve a cavity filling time of 1.0 s to 2.5 s for wall thickness between 2.0 mm and 3.0 mm. Peak injection pressures are commonly observed between 70 MPa and 100 MPa on machines with screw diameters from 35 mm to 60 mm. Hold pressure is normally 50% to 80% of peak injection pressure and must be maintained until gate freeze. If hold pressure is released before gate freeze, the gate acts as a pressure relief path and sink marks form at thick bosses or rib intersections. Gate freeze time for sprue-gated parts with a gate diameter of 2.5 mm to 3.5 mm should be determined by pressure-drop monitoring or acoustic methods rather than by a fixed timer, because the actual freeze time varies with melt temperature and mold temperature.
LG Chem HDPE ME5000 does not require drying at ambient conditions because its water absorption is near 0.01% under ISO 62:2008. However, pellets stored in cold warehouses can carry surface condensation when loaded directly into a room-temperature hopper. In that condition, pre-drying at 70°C for 1 h to 2 h in a desiccant or hot-air dryer is sufficient to suppress surface splay. Drying must not exceed 90°C or 4 h because prolonged heating can sinter pellets and bridge the hopper throat on single-screw machines.
Purging after processing can be conducted with a polyolefin purge compound or a lower-flow HDPE. Purge temperatures should not exceed 240°C. If barrel shutdown exceeds 15 min, the barrel temperature should be reduced to 160°C to 180°C to limit thermal degradation in the residual melt pool. Start-up after an extended shutdown should include a fresh polyethylene purge before the production material is reintroduced.
In injection-molded industrial pails with a nominal capacity of 20 L, LG Chem HDPE ME5000 is used for body and handle geometries where wall thickness is typically 2.0 mm to 2.8 mm and where drop impact after filling must be maintained at low ambient temperatures for regulated packaging. The combination of 5.0 g/10 min melt flow and 0.954 g/cm³ density permits complete cavity filling in multi-cavity tools without raising the melt temperature to the point where odour or degradation risk becomes significant. Gate design for pail bodies is typically a centrally located sprue or hot-tip gate with a retained gate diameter of 3.0 mm or larger; smaller gates restrict flow and increase shear heating, which can locally lower viscosity and create visible flow lines at the gate.
Crates and tote boxes with grid-rib construction require attention to sink marks at rib intersections. For free-standing ribs with a base radius of 0.6 mm to 0.8 mm, rib thickness should be limited to 0.55 to 0.65 times the adjacent wall thickness to avoid visible sink opposite the rib. With ME5000, a rib-to-wall ratio of 0.60 maintains ejection force within the limits of standard ejector pins and reduces the risk of excessive top-load deformation. Higher-flow HDPE grades may fill rib intersections more easily, but they can reduce environmental stress-crack resistance and top-load creep in service environments exposed to dairy, meat, or citrus processing fluids.
Closures and caps produced from ME5000 are typically limited to industrial threaded closures rather than thin-wall beverage closures. The melt flow index of 5.0 g/10 min is lower than the 18 g/10 min or higher flow grades normally required for high-speed beverage caps with wall thickness below 1.0 mm. For industrial threaded closures with wall thickness of 2.0 mm to 3.5 mm, the grade provides adequate thread formation and low creep under torque. The recommended core temperature in closure molds is 30°C to 40°C; core temperatures below 20°C can generate high ejection forces and stress whitening in internal threads.
The primary distinction between LG Chem HDPE ME5000 and the adjacent LUTENE-H grades is controlled by melt flow. ME4000 at 4.0 g/10 min is selected where higher molecular weight contributes to greater impact strength and environmental stress-crack resistance at the cost of higher injection pressure. ME8000 at 8.0 g/10 min is selected for shorter cycle times and reduced clamp force, but with lower environmental stress-crack resistance and a higher tendency to stress whitening under impact. ME5000 occupies an intermediate position in this range. Because the melt flow index increases from 5.0 g/10 min to 8.0 g/10 min when substituting ME8000, the apparent shear viscosity at 220°C is reduced; however, the standard datasheet does not provide a capillary viscosity curve, so the exact pressure reduction on a given tool must be measured directly.
For ESCR-sensitive packaging, the lower-flow grades including ME4000 and ME5000 are generally preferred over ME8000 and ME9180 because higher molar mass fractions increase the time to craze initiation in the presence of surfactant solutions. Comparative testing under ASTM D1693-15 Method B in 10% Igepal CO-630 at 50°C is used to establish differences, but the values are geometry-dependent and cannot be transferred from one wall thickness to another. When converting an existing ME8000 tool to ME5000, the melt temperature should be increased by 5°C to 10°C to compensate for the higher viscosity, and hold pressure should be increased by 5% to 15% to maintain packing. These adjustments should be validated with short-shot studies and gate freeze measurements on the production tool.
Published data for weld-line strength, tensile creep modulus, and coefficient of friction of this exact grade in specific application geometries is limited. Material qualification should therefore include weld-line Izod impact and drop-impact tests on the production tool. The results from standard laboratory Izod specimens do not sufficiently represent the impact response of molded parts with weld lines, ribs, and gate orientation effects.
In extrusion and blow-molding operations, LG Chem HDPE ME5000 is not the preferred grade. The melt flow index of 5.0 g/10 min can produce inadequate melt strength, parison sag, and wall thickness variability in blow molding. For extrusion blow molding, grades with lower melt flow and specific molecular architecture should be selected instead. In injection molding, mechanical recycling of ME5000 regrind can be incorporated into operations at levels up to 30% by weight with virgin resin, but this must be treated as a tool-specific practice. Regrind from dark industrial crates may shift density slightly and lower notched impact if contamination from mineral fillers or other polymers is present.
Regulatory and handling boundaries are summarized in the following matrix. Compliance for food-contact applications is not established by the resin supply alone; the final article must be tested under the intended food-contact conditions.
| Requirement | Reference instrument | Boundary or status |
|---|---|---|
| Food contact in the United States | FDA 21 CFR 177.1520 | Olefin polymer class; final article compliance depends on end-use conditions and migration testing |
| Food contact in the European Union | Regulation (EU) No 10/2011 | Final article migration testing required; overall migration limit 10 mg/dm² for general food contact unless otherwise specified |
| REACH | Regulation (EC) No 1907/2006 | Substance registered; SVHC content below 0.1% w/w per lot certificate |
| RoHS in electrical and electronic equipment | Directive 2011/65/EU | Lead 0.1% w/w, cadmium 0.01% w/w, mercury 0.1% w/w, hexavalent chromium 0.1% w/w, PBB and PBDE 0.1% w/w; applicable only where the molded part is an EEE component |
| Storage | Manufacturer handling guidance | Keep below 50°C, avoid direct UV exposure, use within 12 months; avoid contamination with metallic residues or incompatible polymer regrind |
Processors should verify all regulatory statements against the current manufacturer product safety data sheet and certificate of analysis, because resin formulations and additive packages may be adjusted while the grade designation remains unchanged. The operational limits stated here are based on published material data and standard injection-molding practice for HDPE of this melt flow and density class; however, published data for this specific configuration is limited for certain specialized applications, and production trials remain the definitive qualification method.