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KUNLUN PP K4912

    • Product Name: KUNLUN PP K4912
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 565786
    Material Type Random Copolymer Polypropylene
    Melt Flow Rate 230 C 2 16kg 12 g/10min
    Density 0.90 g/cm³
    Tensile Yield Strength 27 MPa
    Elongation At Break 200%
    Flexural Modulus 950 MPa
    Izod Impact Strength 23 C 5 kJ/m²
    Vicat Softening Temperature 130°C
    Heat Deflection Temperature 0 45mpa 90°C
    Haze 10%
    Light Transmittance 88%

    As an accredited KUNLUN PP K4912 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing KUNLUN PP K4912 is supplied in 25 kg woven polypropylene bags with inner liner, palletized and shrink-wrapped for protection.
    Container Loading (20′ FCL) 20′ FCL loading of KUNLUN PP K4912: PP woven bags palletized, securely stowed, containerized for safe transport.
    Shipping KUNLUN PP K4912 is a polypropylene resin supplied as solid pellets. Ship as non-hazardous, dry cargo. Protect from moisture, direct sunlight, and extreme heat. Avoid crushing or contamination. Standard packaging in woven bags or bulk containers. Ensure clean, ventilated transport. No special dangerous-goods declaration required, but keep away from open flames.
    Storage Store KUNLUN PP K4912 in a cool, dry, well-ventilated area, away from direct sunlight, heat sources, and open flames. Keep containers tightly sealed to prevent moisture contamination. Avoid contact with strong oxidizers. Maintain indoor temperature and low humidity to preserve resin quality. Use clean, dry handling equipment and protect bags from damage.
    Shelf Life KUNLUN PP K4912 has a long shelf life; typically remains stable for two years when stored in cool, dry, ventilated conditions.
    Application of KUNLUN PP K4912

    In lower B-pillar trim carrier production, K4912 is selected for the combination of sub-zero impact resistance, medium-flow melt filling behaviour, and lower interior emissions relative to heavily plasticised olefin compounds. K4912 is a heterophasic ethylene-propylene impact copolymer with a continuous polypropylene homopolymer matrix and dispersed ethylene-propylene rubber domains. This structure allows energy absorption at low temperatures without external plasticisers. When moulded as a neat resin, the material is dried only when surface condensation is present; at relative humidity above 60%, hopper drying at 80 °C for 2 h prevents splay on visible surfaces. Colouration is typically achieved with a 2 wt% to 3 wt% polypropylene-based black or grey masterbatch. Injection moulding on a hydraulic or servo-hydraulic machine with clamp force between 12,000 kN and 16,000 kN is used for lower B-pillar trims up to 1.2 m in length. The nozzle melt temperature is maintained between 210 °C and 240 °C, while mould surface temperature is set at 20 °C to 40 °C for standard grained surfaces. Higher mould temperatures up to 50 °C are used when gloss consistency is required. Screw rotation speed is limited to 120 min⁻¹ with back pressure from 0.5 MPa to 1.0 MPa. Injection speed profiling is critical: initial flow front velocity is reduced to 20 mm/s to 30 mm/s at the gate to suppress tiger stripes, followed by a velocity increase to 80 mm/s to 120 mm/s in the main cavity. Two-stage holding pressure is applied at 60% of peak injection pressure for 6 s to 10 s, then at 35% for 2 s to 4 s. Compliance for interior parts is evaluated under VDA 277, VDA 270, and GB/T 27630 for volatile organic compounds, fogging, and in-vehicle air quality. Mechanical acceptance tests include ISO 179-1/1eA:2010 Charpy notched impact at 23 °C and −20 °C, and shrinkage is measured in accordance with ISO 294-4:2018 after 48 h at 23 °C and 50% relative humidity. The terminal products are lower B-pillar trim carriers, door lower substrates, and quarter-panel stiffener carriers. Production lines commonly observe weld line weakening at latch bosses and gloss differential at direct gate locations when the gate diameter is below 0.8 times the nominal wall thickness.

    What Limits Holding Pressure Effectiveness in Washing Machine Top Cover Moulding?

    Washing machine top covers and dispenser housings are flat, ribbed parts in which gate freeze-off limits the ability of holding pressure to compensate volumetric shrinkage. K4912 can be used for these parts when low-temperature impact is needed for transit and installation before final assembly. The recommended melt temperature is 220 °C to 240 °C at the nozzle, with a mould surface temperature of 35 °C to 50 °C for high-gloss top covers. A centre-gated hot runner or a direct sprue with a cold runner is used; gate diameter should be at least 0.8 times the local wall thickness to delay gate freeze-off. Holding pressure is maintained at 65% to 75% of peak injection pressure until gate freeze is detected by cavity pressure decay, typically 8 s to 14 s for a nominal 2.5 mm wall. Rib-to-wall thickness ratio is held at 0.5 to 0.7 to avoid sink marks on the exposed surface; rib root radius is kept at 0.25 mm to 0.4 mm. Surface antistatic treatment is accomplished with a 0.5 wt% to 1.0 wt% internal antistatic masterbatch to reduce dust attraction during assembly. The terminal products are top cover frames, detergent dispenser housings, and control panel brackets. Compliance for appliance components is evaluated under IEC 60335-1 Clause 30.2 glow wire testing at 650 °C, and ball pressure resistance is assessed according to IEC 60695-10-2 at 125 °C. Dimensional acceptance is based on ISO 294-4:2018 shrinkage measurement, with warpage controlled by symmetrical cooling channel placement. The primary failure mode in production is post-mould bow along the long axis caused by differential shrinkage between the ribbed underside and the unreinforced top surface; this is corrected by reducing mould temperature variation below 5 °C across the parting line.

    Thick-wall returnable logistics units moulded from K4912 encounter volumetric shrinkage and post-mould warpage rather than melt flow limitation as the dominant process constraint. Foldable crates, distribution pallets, and cold-store tote bodies are produced with wall thickness from 4 mm to 6 mm. The material is processed as neat resin or with up to 20 wt% clean in-house regrind, provided the regrind is uniformly mixed by a screw with L/D ratio of 20:1 or greater. Nozzle melt temperature is set from 210 °C to 230 °C, and mould surface temperature is held between 15 °C and 30 °C to balance cycle time and shrinkage. Injection speed is moderate to avoid jetting; a three-stage packing profile is applied, starting at 80% of peak injection pressure for 4 s, then 60% for 8 s, then 40% for 6 s. The packing profile is adjusted until part weight variation across 20 consecutive shots remains below 0.3%. Cooling channels are placed at a distance of 1.5 times the hole diameter from the cavity surface. Post-demoulding dimensional stabilisation is required for 48 h before critical dimensions are measured according to ISO 294-4:2018. Shrinkage anisotropy in unreinforced K4912 is typically lower than in homopolymer PP but still requires corner gussets and rib spacing control. The terminal products are injection-moulded foldable crates, distribution pallets, and cold-store tote bodies. Mechanical validation for pallet units follows ISO 8611-1:2021 for rated load, stacking, and impact resistance. The primary production defect is sink marks over rib junctions; this is mitigated by keeping rib thickness below 0.7 times the nominal wall and using gas counterpressure where tooling permits. Representative parameter gradients for unfilled K4912 appear in the following table.

    Nominal wall thicknessNozzle melt temperatureMould surface temperaturePacking pressurePacking timeCooling time
    2.0 mm220 °C to 240 °C30 °C to 50 °C60% to 70%4 s to 8 s8 s to 12 s
    4.0 mm215 °C to 235 °C20 °C to 40 °C65% to 75%8 s to 14 s18 s to 25 s
    6.0 mm210 °C to 230 °C15 °C to 30 °C70% to 80%14 s to 22 s30 s to 45 s

    When Electrical Enclosure Tooling Demands Gate-to-Flow Ratios Exceeding 1:120

    Low-voltage consumer units and distribution boxes require long flow lengths, wall sections that range from 2.0 mm to 3.5 mm, and dimensional stability after knockout and outlet port features are formed. K4912 can be moulded into these parts when the tooling gate-to-flow ratio approaches 1:120; however, multiple edge gates or a hot runner drop are recommended to prevent excessive pressure loss. The nozzle melt temperature is set at 230 °C to 250 °C, with mould temperature from 20 °C to 40 °C. Carbon black or grey colour is introduced at 1.5 wt% to 2.0 wt% to provide consistent colour and ultraviolet screening. High injection speed is used to fill long flow paths, but shear rate at the gate is kept below 40,000 s⁻¹ to avoid degradation of the ethylene-propylene rubber phase. Holding pressure is set at 70% to 80% of peak injection pressure for 8 s to 16 s depending on boss wall thickness. Material compliance for electrical enclosures is evaluated under UL 94 HB for flammability class, IEC 60695-2-11 glow wire at 650 °C for unattended appliance boundaries, and IEC 60112 for comparative tracking index if insulation coordination requires a minimum CTI. The terminal products are low-voltage distribution boxes, consumer unit housings, and switchgear covers. The primary process fault is weld line low-temperature impact reduction at moulded knockout openings; this is controlled by relocating gates or adding overflow tabs. If flame-retardant performance is required, K4912 is not normally supplied as a flame-retardant grade; compounding with an intumescent halogen-free system at 25 wt% to 30 wt% alters flow and impact, and published data for this specific K4912 configuration is limited.

    Outdoor Structural Foam Moulding and Weathering Resistance in K4912-Based Furniture Shells

    Outdoor chair shells, table slats, and planter walls made from K4912 may be produced by low-pressure structural foam or solid injection moulding with chemical blowing agent. The structural foam route is used when sink mark elimination and part weight reduction are more important than surface appearance. A chemical blowing agent masterbatch is let down at 0.5 wt% to 1.0 wt%, while a hindered amine light stabilizer masterbatch is added at 2 wt% to 4 wt% and a pigment masterbatch at 2 wt%. Screw L/D ratio of 22:1 or higher is sufficient for dispersion. Melt temperature is maintained between 210 °C and 230 °C, and mould temperature is kept at 20 °C to 30 °C because high mould temperature can extend cycle time without visible benefit for textured surfaces. Weathering validation is performed according to ISO 4892-2:2013 xenon arc exposure; colour change and notched impact retention are measured before and after exposure. Specific xenon-arc retention data for K4912 in outdoor furniture formulations are often supplier- or compounder-specific and should not be extrapolated from standard PP grades. The operational boundary is defined by pigment selection: copper phthalocyanine blue concentrates above 0.5 wt% can accelerate thermo-oxidative degradation unless the antioxidant package is adjusted. Terminal products are textured outdoor chair shells, table slats, and planter walls. The most common production defects are splay from moisture on cold pellets and flow hesitations at rib intersections; pellet handling at controlled ambient humidity below 60% or hopper drying at 80 °C for 2 h is applied.

    Cold-chain container lids moulded from K4912 require demoulding uniformity under rapid cycle times because low mould temperatures used to shorten cycles also raise crystallisation undercooling and can increase differential shrinkage. The parts are typically thin-wall access panels, insulated container lids, and battery compartment covers for transport refrigeration units. Melt temperature at the nozzle is set at 210 °C to 230 °C, while the mould surface temperature is held between 10 °C and 20 °C. A 2 wt% grey or black masterbatch is used when colour coding is required. Ejector pin speed is limited to 20 mm/s to 40 mm/s to avoid stress whitening; draft angles are increased to 1.0° minimum, and hinge bosses are designed with root radii above 0.5 mm. Low-temperature mechanical acceptance is evaluated with ISO 179-1/1eA:2010 Charpy notched impact at −20 °C, and service load testing follows customer-specific drop test protocols from 1.2 m at −10 °C. For food-contact secondary packaging, compliance is assessed under FDA 21 CFR 177.1520 or EU Regulation 10/2011 with overall migration testing according to EN 1186. The terminal products are cold-chain storage lids, insulated container access panels, and refrigeration equipment covers. Processing limitations include increased brittle failure risk when the melt residence time exceeds 10 min above 240 °C, and regrind use above 20 wt% should be avoided in these low-temperature service parts unless Charpy impact at −20 °C is revalidated on the production batch.

    Compounding houses use K4912 as a high-impact carrier resin when a balanced-flow, low-temperature-toughened compound is required for domestic appliance structural bases. On a co-rotating twin-screw extruder with L/D ratio 40:1 and screw speed 350 min⁻¹ to 500 min⁻¹, talc or calcium carbonate is side-fed at 10 wt% to 20 wt% while the base resin is gravimetrically dosed. Barrel temperature from 200 °C to 230 °C and pelletising under vacuum prevent moisture-related porosity. The resulting compound is tested for flexural modulus according to ISO 178:2019 and notched impact according to ISO 179-1/1eA:2010. Filler addition above 20 wt% sharply reduces weld line strength; published compound-specific data for K4912 in high-talc formulations is limited. Terminal products from the compound are appliance structural bases, fan shrouds, and pump housings.

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    Certification & Compliance
    More Introduction

    KUNLUN PP K4912 is a high-flow polypropylene random copolymer supplied as natural pellet feedstock for high-speed injection molding of thin-wall, low-haze articles. The grade is positioned within the Kunlun polypropylene portfolio for applications requiring a nominal melt mass-flow rate of 60 g/10 min when measured at 230 °C under 2.16 kg in accordance with ISO 1133-1:2022 Procedure A. The density of the unfilled resin is specified as 0.90 g/cm³ when tested to ISO 1183-1:2019 at 23 °C. Because the matrix is a random copolymer rather than a homopolymer or an impact copolymer, the comonomer units interrupt chain regularity sufficiently to reduce haze while retaining a narrower processing window than that of general-purpose injection-molding homopolymers. The resin is formulated for low odor and low organic volatiles in the finished article, which extends to food-contact containers, disposable medical appliances, and transparent housewares. Published data for a single globally harmonized specification across all production sites is limited; therefore, the values stated here should be verified against the lot-specific certificate of analysis before tool trials.

    Industrial use of K4912 is concentrated in multi-cavity tools with hot-runner valve-gate systems. The melt-flow classification influences minimum wall thickness and cycle-time capability. Cavity-filling imbalance is controlled more by runner manifold thermal uniformity than by resin lot when MFR remains within the certificate range. The resin does not require predrying when stored in sealed packaging at relative humidity below 60 %; after exposure to humid air for more than 24 h, a desiccant dryer with a dew point of −30 °C or lower and an air temperature of 80 °C for 2 h to 4 h is recommended to prevent surface splay and weld-line porosity.

    Material Specification and Batch-Release Test Matrix

    The manufacturer’s certificate of analysis for KUNLUN PP K4912 typically reports melt mass-flow rate, ash content, tensile stress at yield, flexural modulus, notched impact strength, haze, and yellowness index. The table below identifies the test standards commonly used for incoming inspection and product release. Acceptance limits are lot-specific; the table intentionally omits fixed universal minima because published data for a consolidated global specification is limited.

    Parameter Test method Release evaluation
    Melt mass-flow rate ISO 1133-1:2022 230 °C, 2.16 kg; consistency against certificate
    Density ISO 1183-1:2019 0.90 g/cm³ class; shrinkage prediction
    Tensile stress at yield ISO 527-2:2012 1A injection-moulded specimen; demolding and snap-fit integrity
    Flexural modulus ISO 178:2019 2 mm/min crosshead speed; top-load and denesting stiffness
    Charpy notched impact ISO 179-1:2023 23 °C; moderate toughness, not a low-temperature impact grade
    Haze ASTM D1003-21 Optical clarity for transparent sidewalls
    Yellowness index ASTM E313-20 Color control for white and natural articles
    Ash content ISO 3451-1:2019 Contamination and additive loading
    Food-contact suitability FDA 21 CFR 177.1520, EU Regulation 10/2011 Migration-controlled formulation; lot-specific compliance

    The table is not a substitute for the certificate of analysis. Different production sites may use in-house methods aligned with these standards. In the European Union, food-contact compliance must be confirmed under EU Regulation 10/2011, including overall migration and specific migration limits for the intended simulant. The resin is not suitable for load-bearing engineering applications where long-term tensile creep resistance under continuous stress above 10 MPa is required.

    In thin-wall packaging tools with wall stock between 0.35 mm and 1.2 mm, the high-flow character of K4912 reduces injection pressure relative to lower-MFR random copolymers. Melt temperatures between 220 °C and 250 °C are generally required; mold temperatures between 20 °C and 50 °C are used to balance surface gloss and cycle time. Back pressure should be kept low, typically 5 bar to 15 bar, to avoid excessive shear heating and molecular-weight degradation. Screw rotation speed must be limited to 50 min⁻¹ to 150 min⁻¹ depending on screw diameter and recovery time. High injection velocity is preferred for thin sections; however, velocity above 300 mm/s in hot-runner systems can create shear imbalance and gate blush.

    Because the resin is a random copolymer with a high MFR, residence time at melt temperature should not exceed 10 min in the barrel. Prolonged residence time promotes chain scission, yellowing, and loss of impact resistance. Purging with a low-MFR PP or commercial barrel purge after shutdown reduces black-speck formation. Processing at melt temperatures above 280 °C is contraindicated because volatile degradation products may compromise organoleptic neutrality and regulatory status. Cavity-pressure-based switching from velocity to pressure control is recommended. Set switch-over at 95 % to 98 % of cavity fill, with hold pressure between 600 bar and 900 bar hydraulic pressure or corresponding melt pressure depending on machine. Packing time for a 0.8 mm wall is generally 0.4 s to 0.8 s; for a 1.2 mm wall, 1.0 s to 2.0 s. These are starting parameters and must be confirmed on the specific tool. Production-scale qualification should record cavity-to-cavity mass variation; if imbalance exceeds 0.5 %, runner thermocouple placement and gate land geometry are normally corrected before adjusting the resin lot.

    What Distinguishes K4912 from General-Purpose PP Homopolymers and Impact Copolymers?

    The selection of K4912 over general-purpose polypropylene grades is controlled by three variables: melt-flow classification, optical clarity, and low-temperature impact requirements. Unlike a general-purpose homopolymer with an MFR below 35 g/10 min, K4912 permits filling of thinner sections at lower injection pressure, but the random-copolymer structure lowers the continuous-use temperature and increases creep compliance. Compared with impact copolymers containing discrete rubber domains, K4912 provides lower haze and higher gloss, but notched impact strength at low temperature is significantly lower; the grade is not recommended for applications subjected to impact below −10 °C.

    Attribute K4912 high-flow random copolymer General-purpose homopolymer Conventional impact copolymer
    Melt mass-flow rate 60 g/10 min nominal; ISO 1133-1:2022 2–35 g/10 min class; ISO 1133-1:2022 2–40 g/10 min class; ISO 1133-1:2022
    Optical character Low haze, high clarity; ASTM D1003-21 Translucent, higher haze Opaque to translucent with rubber haze
    Stiffness Moderate flexural modulus; ISO 178:2019 Higher flexural modulus Lower-to-moderate flexural modulus
    Low-temperature toughness Moderate; not for impact below −10 °C Low High; suitable at −30 °C
    Processing window Narrow; residence time below 10 min Wide Wide
    Regulatory use Food and medical compliant if lot-specific certificate confirms EU Regulation 10/2011 Compliant grades available Compliant grades available
    Typical applications Thin-wall cups, containers, closures, medical disposables Housewares, rigid packaging, closures Automotive interior components, appliance housings, durable goods

    The comparative behavior is governed by the polymer architecture. Homopolymers contain no ethylene comonomer and therefore exhibit higher crystallinity, higher modulus, and lower optical transparency. Impact copolymers add an ethylene-propylene rubber phase that increases energy absorption but also increases haze and lowers stiffness. K4912 occupies the intermediate position: the random ethylene distribution reduces spherulite size sufficiently for optical clarity, while the high MFR permits thin-wall filling. The trade-off is a lower continuous-use temperature and reduced creep resistance compared with homopolymers.

    When Secondary Operations Demand Low Volatile Residue and Organoleptic Neutrality

    K4912 is selected for food-contact and medical applications where off-taste, odor, and volatile organic compound carryover are controlled. The base stabilization package is designed to limit total volatile organic compounds under standardized headspace or thermo-desorption methods, although published data for the exact threshold is lot-specific. Users should specify the following extraction methods when qualifying lot changes: GC-MS headspace according to VDA 278:2011 or equivalent; sensory evaluation according to DIN 10955:2004 for taste transfer; and overall migration in food simulants according to EN 1186-1:2002 as required under EU Regulation 10/2011. For medical disposables, biocompatibility is governed by the sterilized finished device rather than by the resin alone; ethylene oxide, gamma, and electron-beam sterilization may generate different extractable profiles and should be validated under ISO 10993-1:2018.

    Gamma irradiation above 25 kGy can yellow and embrittle polypropylene random copolymers; electron-beam doses above 35 kGy may increase chain scission unless radiation-tolerant stabilizer blends are added. K4912 is not formulated as a radiation-grade resin; published data for this specific configuration is limited. Hot-fill boundaries should also be evaluated. Sustained service above 90 °C is not recommended; heat deflection temperature under 0.45 MPa for random copolymers generally falls below 90 °C when measured according to ISO 75-2:2013 method B.

    Conversion of K4912 in high-speed packaging lines requires qualification of the entire system: resin rheology, hot-runner balance, mold venting, and downstream handling. Shrinkage after demolding is anisotropic and must be characterized by ISO 294-4:2018 on the actual cavity geometry; general shrinkage data from edge-gated tensile bars is insufficient for dimension-critical closures. The grade is supplied with a nucleating additive that increases crystallization temperature and reduces haze, but this may increase differential shrinkage between longitudinal and transverse flow directions. Tool design should therefore compensate for warpage using mold-flow simulation calibrated with pvT data measured by ISO 17744:2004 or equivalent. Incoming resin lots should be screened for MFR stability because variations greater than ±5 g/10 min from the nominal 60 g/10 min can shift injection pressure, pack time, and closure dimensions in high-cavitation tools.

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