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Kumho Petrochemical KUMHO® ASA XC233Z

    • Product Name: Kumho Petrochemical KUMHO® ASA XC233Z
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales8@sinochem-nanjing.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 208886
    Manufacturer Kumho Petrochemical
    Brand KUMHO®
    Product Grade ASA XC233Z
    Polymer Type Acrylonitrile Styrene Acrylate (ASA)
    Appearance Opaque pellets
    Molding Shrinkage Percent 0.4-0.7
    Ul94 Flammability HB
    Processing Method Injection Molding
    Weather Resistance Good

    As an accredited Kumho Petrochemical KUMHO® ASA XC233Z factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing KUMHO® ASA XC233Z is supplied in 25 kg bags, typically palletized for industrial handling and shipment.
    Container Loading (20′ FCL) Kumho Petrochemical KUMHO® ASA XC233Z in 25 kg bags, loaded in a 20′ FCL dry container at about 20 MT.
    Shipping Kumho Petrochemical KUMHO® ASA XC233Z is shipped as non-hazardous polymer pellets in moisture-barrier 25 kg bags or octabins, palletized and stretch-wrapped. Store dry and cool, away from direct sunlight, moisture, and high heat. Not regulated for transport.
    Storage Store KUMHO® ASA XC233Z in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, ignition sources, and moisture. Keep in original, sealed packaging and prevent contamination by dust, water, or incompatible chemicals. Avoid prolonged high-temperature exposure and stack securely to prevent packaging damage. Follow first-in, first-out stock rotation and local safety regulations.
    Shelf Life The shelf life is typically 24 months when stored dry, below 30°C, in original unopened packaging.
    Application of Kumho Petrochemical KUMHO® ASA XC233Z

    The specification of KUMHO® ASA XC233Z for unpainted automotive cowl vent grilles, B-pillar covers, tailgate appliqués, and exterior mirror housing base shells follows from the requirement that moulded surfaces retain a colour difference ΔE*ab of not more than 3.0 after 1,500 kJ/m² xenon-arc weathering under SAE J2527 or ISO 4892-2:2013 Method A with daylight filters, while the unpainted part avoids the production cost and VOC burden of a separate painting line. In this downstream segment, the XC233Z grade is first dehumidified in a closed-loop desiccant dryer at 80°C for 3–4 h with a dew point of −40°C or lower, until residual moisture falls below 0.02 wt%; exceeding that threshold generates splay marks on grained Class A surfaces and reduces weld-line strength because moisture vaporises during plastication and interrupts melt-front fusion. The dried pellets are then fed to a reciprocating screw injection moulding machine with an L/D ratio of 20:1 to 24:1, a non-return valve, and a free-flow or shut-off nozzle; a barrel temperature profile of 230°C, 235°C, 240°C, and 245°C at the nozzle is maintained, giving a melt temperature of 240–250°C when measured by an immersion probe. The mould is held at 60–80°C with turbulent water circulation through all cavity plates, and a clamp force of 4.0–6.0 kN/cm² of projected part area is applied to prevent flash without introducing excessive cavity pressure that would increase moulded-in stress. Regrind generated from sprues and runners is incorporated at a maximum of 20 wt%; higher fractions are excluded from visible exterior panels because the reprocessing history lowers surface gloss and shifts the melt-flow balance at weld lines. The terminal component is a textured black or dark grey cover with a nominal wall thickness of 0.8–1.0 mm for cowl grilles and 1.2–1.5 mm for mirror housing bases, with a grain depth of 25–45 µm used to obscure minor flow lines and gate vestiges.

    Process limits in this segment are defined by two competing failure modes. At melt temperatures above 260°C, the acrylic ester impact-modifier phase in unfilled ASA may begin to degrade, producing brownish edge discolouration and a rise in melt-flow instability that causes gate-area streaks on textured surfaces. Below 230°C, high molecular orientation at the gate results in jetting, and the fusion of multiple flow fronts is insufficient, leading to weld-line failure in crash-adjacent trim parts. For B-pillar covers and mirror housings, a fan gate with a thickness of 0.8–1.2 mm located on a hidden edge is preferred over a pin gate; the fan gate produces a uniform flow front and moves gas traps to the last-filled, non-visible corner. A short holding-pressure decay from 60 MPa to 30 MPa over 4–6 s reduces sink marks without overpacking the gate, while a back pressure of 0.5–1.0 MPa during charging homogenises the colour concentrate and prevents free pigment agglomerates. Weld-line integrity of cowl vent grilles is evaluated by ISO 179-1/1eA Charpy notched impact testing on 4 mm moulded bars; a typical unfilled high-impact ASA grade returns 25–40 kJ/m² at 23°C, although published data for this specific XC233Z configuration is limited and the batch certificate should be consulted. Dimensionally, the injection-moulded part must meet the OEM gauge repeatability and Cpk requirements; a post-moulding fixture may be used for 1 min to control warpage on long cowl grilles with length-to-width ratios above 4:1. Material compliance for exterior trim generally includes a manufacturer IMDS declaration, REACH SVHC confirmation under Regulation (EC) No 1907/2006 as amended, and OEM-specific weathering specification verification. Because the part is unpainted, accelerated weathering is performed on moulded plaques, not on resin pellets; test coupons are moulded at 250°C and 70°C tool temperature before exposure. The acceptance criterion of ΔE*ab ≤3.0 after 1,500 kJ/m² under SAE J2527 or ISO 4892-2:2013 cycle 1 is a common starting point, but individual automotive programmes may specify 2,000–3,000 kJ/m² and a gloss retention of at least 60% measured by ISO 2813 at 60° geometry.

    What Limits Capstock Layer Thickness When XC233Z Is Co-Extruded Onto PVC or Modified-ABS Core Profiles?

    For building and construction profiles, XC233Z is considered as a weatherable capstock layer over a lower-cost PVC or modified-ABS core in window lineals, fascia boards, deck rail covers, and garage door trim. The dominant process constraint is not melt temperature alone, but the differential thermal expansion and viscosity mismatch at the capstock-core interface. A functional minimum cap thickness of 0.10 mm is required to prevent ultraviolet transmission to the core; at the upper end, thicknesses above 0.25 mm for PVC and 0.50 mm for modified-ABS cores increase the risk of edge curl, interfacial shear, and delamination during downstream cutting or thermal cycling. The XC233Z cap layer is processed through a 32:1 L/D single-screw extruder with a barrier flight screw and a melt pump; barrel temperatures are set at 205°C, 210°C, 215°C, and 220°C at the adapter, while the melt temperature is held at 210–225°C. A dual-manifold co-extrusion die or a feedblock with a temperature-isolated central lip feeds the capstock and core separately; the PVC core is processed at 175–185°C, and the interfacial melt temperature is kept below 230°C to limit gel formation in the impact-modification phase of the ASA layer. The terminal profile is usually cut to length, milled, and heat-welded at corners; capstock continuity at welded corners is achieved by leaving a 5–8 mm cap-free zone on the reverse side so that the weld bead is produced from the core material and then covered with a profile overcap.

    The thickness limit is also governed by weatherability economics and strain compatibility. Above the upper thickness threshold, the capstock begins to contribute a disproportionate share of the profile's deflection under thermal load because the coefficient of linear thermal expansion of unfilled ASA is approximately 0.8–1.0 × 10⁻⁴ K⁻¹ as determined by ISO 11359-2:2021, while a rigid PVC core may be in the range of 0.6–0.7 × 10⁻⁴ K⁻¹. In direct sun, a dark fascia board can experience a surface temperature of 60–70°C; the resulting differential strain at the capstock-core boundary is the primary cause of long-term delamination, not UV degradation of the capstock itself. Adhesion is checked on co-extruded specimens by ISO 2409 cross-cut testing after 7 d of immersion in 40°C water; a classification of 0 or 1 is required at the cut edges. Colour fastness of the ASA capstock is evaluated on weathered samples by ISO 105-A02; a grey scale rating of 4 or better after 3,000 h of xenon-arc exposure to ISO 4892-2:2013 cycle 1 with daylight filters is a typical specification for façade and deck cladding. For window lineals, an additional requirement may be the retention of impact strength after weathering; notched Izod specimens cut from co-extruded lineals are tested under ISO 180:2023 at 23°C before and after exposure, and a reduction above 30% is considered a rejection signal because it indicates embrittlement of the capstock or core degradation. Regulatory documentation for the building segment includes EN 13501-1:2018 reaction-to-fire classification if the profile is used in external wall cladding or façade elements, and supplier declarations of conformity to EN 477:2018 for unplasticized PVC profile extrusions where applicable.

    Electrical Enclosure Dimensional Stability and Outdoor Weatherability Requirements

    Outdoor telecommunications terminal enclosures, EV charger pedestal housings, and utility meter boxes are downstream applications where injection-moulded XC233Z must satisfy dimensional stability after thermal cycling, outdoor weatherability, and the purchaser's flammability documentation. The processing sequence begins with drying at 80°C for 3–4 h to below 0.02 wt% residual moisture; a dehumidifying dryer is mandatory because a hot-air tray dryer does not reliably achieve the required dew point. The enclosures are moulded on a reciprocating screw machine with a 22:1 L/D screw and a shut-off nozzle; barrel temperatures of 230–245°C and a tool temperature of 60–80°C are used. A nominal wall thickness of 2.5–3.0 mm is maintained throughout flat surfaces; bosses are cored with an outer diameter at least 2.0× the thread diameter and connected to side walls by 0.8–1.0 mm ribs to avoid sink marks and warpage. The moulded linear shrinkage of an unfilled ASA grade is generally in the range 0.4–0.7% when measured by ISO 294-4:2018, and tool design compensates for anisotropic shrinkage by reducing the cavity length in the flow direction by 0.1–0.2% relative to the transverse axis. A draft angle of 1.0–1.5° per side on textured surfaces is specified to maintain demoulding without scuffing.

    The relevant flammability statement for XC233Z is typically UL 94 HB at 1.5 mm or 3.0 mm thickness, as recorded on the UL Yellow Card for the certified grade composition. For electronic enclosures that require UL 94 V-0, this unfilled weathering resin is not suitable; a flame-retarded ASA or PC/ASA blend must be selected instead. Outdoor suitability is documented through UL 746C F1 testing, which involves UV exposure, water immersion, and thermal ageing of moulded test bars; if the end-product certification requires an F1 rating, the moulder must use the exact grade and regrind level listed in the UL file, because changes in pigment loading or regrind fraction can invalidate the listing. Long-term dimensional stability is checked by IEC 62208:2011 for empty enclosures used in low-voltage switchgear and controlgear units; the enclosure is subjected to a 70°C dry heat test for 7 d and a −25°C cold test for 7 d, after which the enclosure must retain its declared degree of protection. The terminal component is an injection-moulded housing with a gasketed door or fascia, UV-stabilised cable glands, and self-tapping screw bosses; it is assembled without post-painting or coating. A process quality issue encountered in this segment is warpage after the first 24 h of free-standing shrinkage, particularly on long narrow enclosures with a length-to-width ratio above 3:1. The problem is controlled by adopting a balanced runner layout, placing the gate at the geometric centre of the hidden rear wall, and holding the part in a cooling jig for 60–90 s after ejection. If the part is to be hot-stamped or laser-marked, the marking area must be free of mould release agents; mould releases are excluded from the moulding cell because they contaminate the surface and create adhesion failure in gasketing and labels. The weatherability of the moulded enclosure is confirmed by ISO 4892-2:2013 cycle 1 with a total radiant exposure of 2,000 kJ/m²; after exposure, the specimen must show a change in Charpy notched impact strength of no more than 20% relative to an unexposed control, measured by ISO 179-1/1eA at 23°C.

    When Thermoforming Is Selected Over Injection Moulding for Spa Cabinets and RV Exterior Panels

    When the downstream part geometry includes large, lightly stressed panels with deep draw features, thermoforming of extruded XC233Z sheet is selected instead of injection moulding because tooling costs are lower for short production runs below 5,000 units per year. The conversion route begins with sheet extrusion on a 38:1 L/D, 90–120 mm vented single-screw extruder equipped with a melt pump and a horizontal three-roll polishing stack. XC233Z pellets are dried to below 0.02 wt% residual moisture using 80°C air with a dew point of −40°C; vented extrusion is not a substitute for drying when sheet thickness exceeds 2 mm because moisture in the core generates microvoids that become visible as silver streaks after thermoforming. The barrel temperature profile is 210°C at the feed zone, increasing to 225°C at the die adapter, with a melt temperature of 220–235°C; the polished roll stack is maintained at 80–90°C for the top and middle rolls and 70–80°C for the lower roll to produce sheet with low residual orientation. The sheet is then stored for 24 h at 20–25°C and 50% relative humidity before forming, allowing moisture equilibration at the surface to reduce static charge and dust pick-up.

    The forming operation uses a single-sided thermoforming machine with a pressure box and a temperature-controlled aluminium plug assist. The sheet surface temperature is brought to 150–170°C, measured with an infrared pyrometer calibrated to 0.95 emissivity; below 150°C, the material tears at sharp corners; above 170°C, excessive sag and webbing occur, and the sheet thickness becomes difficult to control. The draw ratio is kept below 1:1 unless an initial plug pre-stretch is applied; without pre-stretch, corner wall thickness drops below 1.5 mm, and impact strength in the finished spa cabinet panel becomes inadequate. Positive forming pressure of 3–5 bar is used, and the aluminium mould temperature is held at 80–110°C to minimise frozen-in stress. After forming, the part is trimmed on a 3-axis or 5-axis CNC router, and sharp edges are de-burred or flame-polished. Chemical exposure is a critical performance parameter for spa cabinets; moulded and thermoformed samples are immersed in 50 ppm free chlorine solution at 40°C for 28 d according to ISO 175:2010, and the mass change after immersion is recorded. For unfilled ASA, swelling is usually low, but published data for this specific XC233Z formulation under chlorinated water is limited; laboratory coupons must be evaluated before production release.

    Outdoor performance of thermoformed spa cabinet and RV body panels is assessed by ISO 4892-2:2013 cycle 1 xenon-arc weathering with daylight filters, with a total radiant exposure of 2,000–3,000 kJ/m²; the acceptance criterion is a ΔE*ab of ≤3.0 and a minimum gloss retention of 60% measured under ISO 2813 at 60°. Additionally, the formed part is conditioned for 72 h at 70°C in an air-circulating oven to detect anisotropic post-shrinkage; dimensional change of the formed contour is measured with a comparator and must not exceed 0.5% of the overall dimension. If the part is bonded or sealed, the bond lines must be free of processing oils, and a corona or plasma pre-treatment at 5–10 W/m²/min may be required to raise the surface energy above 40 mN/m. The terminal product is a lightweight exterior panel, spa cabinet side skirt, or RV compartment door with weatherable colour moulded in, without post-coating.

    Garden power tool housings and marine deck hatch frames demand combined UV, impact, and chemical resistance.

    Garden power tool housings, marine deck hatch frames, and outdoor sports equipment shells are produced from XC233Z where the part must withstand direct sunlight, occasional fuel or oil splashes, and impact at low ambient temperatures. The injection-moulding conditions overlap with automotive exterior trim: melt temperature 240–250°C, mould temperature 60–80°C, and residual moisture below 0.02 wt%. However, the tooling and part design differ because these components often carry structural or semi-structural loads and have frequent snap-fit features. Snap-fit arms are designed with a length-to-thickness ratio of 5:1 to prevent brittle failure at the gate or at the arm root; the gate is located away from snap-fit features to avoid a weak boundary layer at the flow front. The mould parting line is placed on non-visible edges, and deep undercuts are formed with lifters or slides; a minimum mould-open stroke of 3× the undercut depth is used. The terminal part is an unpainted, coloured housing or frame with a wall thickness of 2.0–3.0 mm, textured to hide flow lines and scratches.

    Impact strength in these outdoor segments is characterised at 23°C and −30°C using ISO 179-1/1eA Charpy notched impact tests on 4 mm bars; a typical unfilled high-impact ASA has a notched impact strength above 20 kJ/m² at 23°C and above 6 kJ/m² at −30°C, but the exact XC233Z values must be confirmed on the batch certificate. Fuel and oil exposure is evaluated by immersion in ASTM reference fuel C or ISO 1817 test liquids at 23°C for 48 h; the part should not exhibit tackiness, cracking, or a mass change greater than 2%. For marine deck hatch applications, accelerated weathering is combined with salt spray per ISO 9227:2022 for 500 h, followed by ISO 4892-2:2013 cycle 1 exposure to 1,500 kJ/m². The acceptance criterion is a ΔE*ab of ≤3.0 after weathering and no visible surface chalking or microcracking at 10× magnification. Chemical stress-cracking resistance is checked by applying 0.5% strain to moulded bars under a constant-strain jig and exposing the bars to methyl ethyl ketone or isopropanol for 24 h; the absence of visible crazing is required.

    Outdoor acceptance matrix referenced for downstream segments using KUMHO® ASA XC233Z
    SegmentStandard / methodConditionAcceptance criterion
    Automotive exterior trimSAE J2527 / ISO 4892-2:20131,500–3,000 kJ/m²ΔE*ab ≤ 3.0; gloss retention ≥ 60%
    Building capstockISO 4892-2:2013 cycle 13,000 hGrey scale 4 per ISO 105-A02; ΔE*ab ≤ 3.0
    Electrical enclosureUL 746C F1F1 outdoor protocolNo mechanical failure; impact retention ≥ 80%
    Thermoformed spa/RV panelISO 4892-2:2013 cycle 12,000–3,000 kJ/m²ΔE*ab ≤ 3.0; gloss retention ≥ 60%
    Garden/marine housingISO 4892-2:2013 + ISO 9227:20221,500 kJ/m² + 500 h salt sprayΔE*ab ≤ 3.0; no chalking/cracking
    Portable AC/power electronicsIEC 60068-2-14:2009 test Nb−20°C to 60°C, 50 cyclesNo cracking; mass tolerance ±0.5%

    Portable air conditioner side shrouds, outdoor heat pump fan grilles, and solar charge controller boxes constitute a separate downstream lane in which XC233Z is processed as a thin-wall injection-moulding resin with flowability, dimensional stability, and resistance to photo-oxidative embrittlement. The moulding cell operates with a high-speed accumulator-assisted injection machine with a 25:1 L/D barrier screw and a two-stage hydraulic system capable of injection speeds above 300 mm/s; thin-wall ribs of 0.8–1.2 mm wall thickness require a melt temperature at the upper end of the window, 245–255°C, while the tool is held at 60–80°C. The gate is placed at the thickest section, and the cavity is vented with 0.02–0.03 mm vent depth along the last-filling edges to prevent burn marks and short shots. Drying is identical to other ASA applications: 80°C for 3–4 h to below 0.02 wt% residual moisture. The finished thin-wall part is ejected with a uniform wall thickness of 1.5–2.0 mm and a mass tolerance of ±0.5% per shot; the dimensional control is verified by weighing each shot during process validation and by thermal cycling per IEC 60068-2-14:2009 test Nb, −20°C to 60°C, 50 cycles.

    Compliance for portable AC shrouds and outdoor power electronics housings is structured around IEC 60335-1:2020 household appliance safety, including glow-wire testing of plastic parts in unattended appliances under IEC 60695-2-11:2021; for unfilled ASA the glow-wire ignition temperature may be in the range of 550–650°C depending on thickness and colourant, and published data for XC233Z at the required thickness must be verified before approval. The relevant outdoor exposure criterion is UL 746C F1 outdoor suitability when used in electrical equipment enclosures; alternatively, manufacturer-specific weathering standards may demand 1,500 kJ/m² xenon-arc exposure with ΔE*ab ≤3.0. The terminal component may include an IR-transparent window or LED light pipe produced from a separate optical resin; the XC233Z frame is not used in the optical path because its light transmittance in the visible range is below 50% at 1 mm wall thickness, and the hiding power of pigmented ASA limits its use to structural, non-transmitting sections.

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