| HS Code | 822101 |
| Productname | Ingeo™ Biopolymer 6302D Amorphous Staple Fiber PLA |
| Manufacturer | NatureWorks LLC |
| Polymertype | Polylactide (PLA) |
| Grade | 6302D |
| Form | Pellets |
| Appearance | Translucent natural pellets |
| Odor | Slight |
| Crystallinity | Amorphous |
| Specificgravity | 1.24 |
| Density | 1.24 g/cm³ |
| Meltflowrate | 10-25 g/10 min at 210°C/2.16 kg |
| Glasstransitiontemperature | 55-60°C |
| Meltingtemperature | 145-160°C |
| Processingtemperature | 200-230°C |
| Dryingtemperature | 80°C |
| Dryingtime | 4 hours |
| Moisturecontent | <0.1% |
| Biobasedcontent | 100% |
| Biodegradability | Biodegradable in industrial composting environments |
| Compostability | Certified compostable under EN 13432 and ASTM D6400 |
As an accredited Ingeo™ Biopolymer 6302D Amorphous Staple Fiber PLA factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Ingeo™ Biopolymer 6302D Amorphous Staple Fiber PLA is supplied in 25 kg moisture-barrier bags, palletized and stretch-wrapped for shipment. |
| Container Loading (20′ FCL) | 20′ FCL: Ingeo™ 6302D PLA staple fiber, typical loading capacity about 18–20 metric tons, depending on packaging and pallet configuration. |
| Shipping | Ingeo™ Biopolymer 6302D Amorphous Staple Fiber PLA is not classified as dangerous goods for transport. Ship in original packaging, keep dry, avoid excessive heat, moisture, and contamination. Handle as non-hazardous polymer fiber. No special transport placards required. Store away from strong oxidizers and ignition sources. Maintain moderate temperatures during transit. |
| Storage | Store Ingeo™ Biopolymer 6302D Amorphous Staple Fiber PLA in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep containers or bales closed and protected from moisture, dust, and strong oxidizers. Avoid excessive stacking and static buildup. Maintain good housekeeping; follow local regulations and manufacturer's SDS recommendations. Store away from acids, alkalis, and incompatible materials. |
| Shelf Life | Shelf life is two years from manufacture when stored unopened in a cool, dry place below 50°C and 80% relative humidity. |
The application envelope for Ingeo™ Biopolymer 6302D amorphous staple fibre is controlled not by a single melt transition but by a narrow thermal-bonding plateau coupled with a hydrolytic degradation boundary. The amorphous character suppresses the high crystallinity of conventional PLA, shifting thermally activated fibre-to-fibre bonding into a practical window of 120–150 °C depending on line speed, web density, and incoming fibre moisture. Moisture above 250 ppm before through-air or calendar bonding accelerates molecular weight loss and generates lot-to-lot tensile variability. The scenarios below are restricted to downstream sectors where PLA staple nonwovens have established industrial use: automotive interior trim substrates, hygiene acquisition layers, low-temperature filtration media, mattress panels, acoustic interior panels, and agricultural mats. Each scenario records the governing regulatory standard, a workable formulation window, the production sequence, and the finished article class.
| Application sector | Primary regulatory/technical method | Attribute evaluated | 6302D working ratio |
|---|---|---|---|
| Automotive interior trim | FMVSS 302, ISO 3795, VDA 278, DIN 75201-B | burn rate, VOC/fog emissions | 20–35 wt% |
| Hygiene ADL | ISO 10993-1:2018, ISO 9073-3, ISO 9073-6 | skin safety, tensile, strikethrough | 30–40 wt% |
| Filtration media | ISO 16890-1:2016, ISO 11057:2011 | particle efficiency, pressure drop | 30–50 wt% |
| Mattress/upholstery | 16 CFR 1633, TB 117-2013 | full-scale smoulder, heat release | 15–25 wt% |
| Acoustic panels | ISO 354:2003, ISO 11654:1997, ISO 9053-1 | absorption, airflow resistivity | 25–35 wt% |
| Agricultural mats | EN 13432/EN 14995, ISO 17556 | compostability, soil biodegradation | 60–100 wt% |
For this application class, 6302D is introduced as the thermally activated binder phase in a blended staple-fibre web that is subsequently needled and through-air bonded. Compliance at the vehicle level is governed by FMVSS 302 and ISO 3795 horizontal burn rate limits; interior-air emission performance is screened under VDA 278 thermal desorption and fogging under DIN 75201-B. In addition, material data sheets should reference REACH Annex XVII restrictions and, for production locations supplying EU OEMs, IATF 16949 control of incoming fibre moisture and melt-flow lot acceptance.
Formulation addition ratio is bounded by two production failure modes. At 20 wt% 6302D or below, thermal-bond point density after needling is insufficient, producing peel-prone edges and delamination during trim-press forming. Above 35 wt%, the amorphous fibre forms resin-rich surface domains, increases web shrinkage through the through-air oven, and causes visible scuffing at the calendar. Representative production blends fall between 25 wt% and 30 wt% 6302D, with 45–55 wt% flax or hemp fibre and 20–25 wt% recycled PET or viscose carrier fibre. Basis weight is set between 600 g/m² and 1200 g/m²; door-trim backing typically uses 600–800 g/m², while trunk side liners and wheel-arch underlay use 900–1200 g/m².
Production-scale equipment behaviour defines the process sequence: fibre opening, fine opening, carding on a 2.0–2.5 m width card, cross-lapping to the target web weight, tandem needlepunch at 1200–1800 punches/cm², and through-air thermal bonding. The through-air oven is set at 135–150 °C, with the bonding plateau established by differential scanning calorimetry for each incoming lot; the product core temperature is constrained not to exceed 165 °C. Incoming fibre is pre-dried to below 250 ppm moisture when ambient relative humidity exceeds 60%. Needle loom gauge and barbed-needle specification are set by the carrier-fibre geometry; on lines with 15×18×36 triple-angled needles, tensile retention after bonding is measured by ISO 9073-3, and thickness recovery by ISO 9073-2. Finished article types include door-trim panel backing, rear package-tray substrates, trunk side liners, and wheel-arch underlay.
A hygiene acquisition or distribution layer containing 6302D is evaluated not as a homopolymer PLA web but as a thermoplastic binder phase in a cellulosic or hydrophilic polyester matrix. A production-typical ADL web at 30–60 g/m² contains 30–40 wt% 6302D, 40–60 wt% viscose or cotton, and 0–20 wt% hydrophilic PET, with the cellulosic fraction adjusted to the target liquid acquisition time. Skin-contact safety data are generated under ISO 10993-1:2018 and ISO 10993-3:2014 when the article falls within a medical-device or long-term skin-contact classification; performance is measured by ISO 9073-3 for strip tensile, ISO 9073-6 for liquid absorption time, and ISO 9073-2 for thickness stability under compression. On 3.2–3.5 m width carding lines, 6302D develops higher static charge than polypropylene binder fibre, so the carding room is held at 55–65% RH and the fibre is treated with antistatic finish to maintain carding speeds above 150 m/min. Through-air bonding is performed at 130–145 °C for 3–8 s, producing discrete fibre-to-fibre bonds while preserving loft and pore volume. The terminal product classes are acquisition/distribution layers for infant diapers, adult incontinence pads, and feminine hygiene pads. The operational boundary is that PLA is not naturally hydrophilic; strike-through consistency comparable to polypropylene bicomponent reference webs requires a durable surface finish and cannot be achieved by fibre ratio alone.
Conditional use in low-temperature dust-collection needlefelts and pleatable filter media must be qualified against the hydrolytic boundary of amorphous PLA rather than against the thermal limits of polypropylene or polyester. Continuous exposure to humid air above 60 °C accelerates chain scission, so 6302D is not a drop-in replacement for continuous-duty baghouse service. A workable addition ratio is 30–50 wt% 6302D blended with 50–70 wt% jute, hemp, or recycled PET staple at 600–1000 g/m² for needled felt. Regulatory and technical compliance for general ventilation filters is assessed under ISO 16890-1:2016; cleanable filter media for dust collectors are tested under ISO 11057:2011 for pressure-drop evolution and dust loading. The production sequence is carding, cross-lapping, needlepunch at 1000–1600 punches/cm², singeing to remove loose surface fibre, and heat-setting at 135–150 °C for dimensional stability. Pleated filter media receive an additional calendering step at 110–130 °C to consolidate bonding points without closing the pore structure. Terminal article categories include low-temperature cleanable bag filters, pleated panel media for low-thermal-load HVAC units, and oil-sorption mats where biodegradation is not a primary service requirement. Published filtration-efficiency data for 6302D in cleanable bag filters is limited, so full-scale pressure-drop and dust-loading validation under ISO 11057 is required before commercial qualification.
Thermally bonded needlepunch webs containing 6302D can be laminated into mattress cover and border constructions, but the fibre contributes no inherent flame-retardant function and its melt-drip behaviour must be evaluated in the finished article. Under full-scale testing to 16 CFR 1633, a practical nonwoven mattress panel formulation is 15–25 wt% 6302D, 30–45 wt% FR viscose, and 30–45 wt% high-tenacity PET, with optional phosphate-based flame-retardant finish applied by spray or foam at 10–25% wet pick-up. Amine-based flame-retardant additives are avoided because residual amines accelerate hydrolytic breakdown of PLA during through-air bonding and post-lamination aging. The production route includes garnetting, cross-lapping, needlepunch, thermal bonding at 140–150 °C, and lamination to a knit or nonwoven shell fabric. Under 16 CFR 1633, the assembly must be retested as a finished mattress set because the PLA-containing layer alters the heat-release profile and melt-drip pattern compared with polyester-rich control panels. Upholstered furniture components are screened under TB 117-2013 smoulder resistance. Finished articles include mattress cover panels, border wraps, and upholstery backing layers; where full-scale flammability margin is narrow, the 6302D fraction is kept at the lower end of the range to minimize thermoplastic drip.
For interior acoustic panels and office partition substrates, the primary engineering problem is maintaining predictable air-flow resistance and panel stiffness while bonding the amorphous PLA fibre. The fibre is blended at 25–35 wt% with 65–75 wt% recycled cotton, wool, or hemp fibre; basis weight is typically 300–900 g/m², and panel density after needling and thermal bonding is controlled between 150 kg/m³ and 400 kg/m³. Acoustic performance is tested under ISO 354:2003 and rated under ISO 11654:1997; air-flow resistivity is measured by ISO 9053-1. The production sequence is carding, cross-lapping, needlepunch at 1200–1600 punches/cm², and through-air bonding at 135–150 °C with a controlled web-core residence time of 10–30 s. Because the amorphous fibre has no sharp melting endotherm, the bond window is set by DSC lot screening rather than by a fixed thermoplastic grade; bonded panels are inspected for edge shrinkage and caliper variation. Finished article types include free-hanging acoustic baffles, wall panels, and partition infill substrates. Published acoustic data for 6302D in specific panel configurations is limited, so ISO 354 and ISO 9053-1 must be re-run on each panel construction.
Agricultural and horticultural nonwoven mats produced from 6302D alone or blended with flax, jute or hemp exploit the hydrolytic degradability of PLA in soil contact. The composite is typically carded, cross-lapped, and needlepunched at 300–600 g/m²; thermal bonding is used only when installation requires a stiffer mat, with the through-air oven held at 135–145 °C for 5–12 s. A workable formulation is 60–100 wt% 6302D and 0–40 wt% lignocellulosic fibre, with the upper cellulosic limit set by wet-strength loss and mat collapse. Biodegradation claims require validation under EN 13432 for packaging or EN 14995 for non-packaging articles; soil biodegradability is evaluated under ISO 17556. User-facing performance before exposure is tested under ISO 9073-3 for tensile strength and ISO 9073-4 for tear resistance. The critical operational boundary is that PLA degradation is hydrolysis-controlled: in saturated soil and at pH above 8, chain scission accelerates, while in dry soil the mat can persist well beyond one season. Terminal article categories include biodegradable weed-control mats, erosion-control blankets, seed-retention mats, and nursery overwintering covers.
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Ingeo™ Biopolymer 6302D is an amorphous poly(L-lactide-co-D-lactide) resin specified for conversion into staple fiber on conventional short-staple spinning lines. The grade is characterized by a glass transition temperature of 55–60 °C measured by differential scanning calorimetry according to ISO 11357-2:2020 and by the absence of a measurable melting endotherm under ISO 11357-3:2018. This thermal signature separates 6302D from semi-crystalline PLA fiber grades such as 6202D, which exhibit a crystallization exotherm and a melting endotherm above 160 °C. The amorphous chain packing is obtained through a controlled D-lactide fraction that interrupts stereochemical regularity and suppresses lamellar crystallization; the melt therefore remains amorphous after quench and yields a broad softening window rather than a sharp solid-to-liquid transition. Resin density is supplied as 1.24 g/cm³ per ASTM D792-20, with a melt flow rate within the fiber-grade range of 15–30 g/10 min at 210 °C and 2.16 kg per ASTM D1238-20. As-shipped moisture content is specified at ≤0.25 % by weight per ISO 15512. The high-flow, low-crystallinity position of 6302D within the Ingeo fiber portfolio supports low-temperature thermal bonding, sheath-core binder formulations, and fiberfill where lower calender energy input is required.
The critical structural difference is the absence of a crystalline reinforcement phase after fiber formation. Semi-crystalline PLA staple fiber develops oriented crystallites during drawing and heat-setting, producing a melting endotherm normally between 160 °C and 180 °C and a heat of fusion in the range of 30–50 J/g when tested by ISO 11357-3:2018. Amorphous 6302D does not develop this crystalline network; its mechanical and thermal-load response is controlled primarily by chain entanglement and the proximity of the use temperature to the glass transition. The practical consequence is a lower hot-air bonding threshold. Published thermal-bonding data for amorphous PLA fiber grades indicate calender bonding can be initiated in the 90–120 °C range, whereas semi-crystalline PLA binders require temperatures near 130–150 °C. Single-fiber tenacity for amorphous PLA typically falls between 2.0 cN/dtex and 3.0 cN/dtex, below the 3.5–5.0 cN/dtex range typical of oriented semi-crystalline PLA staple fiber, because the amorphous phase lacks load-bearing crystallites. The amorphous grade also exhibits lower shrinkage resistance above 50 °C and should not be selected for applications requiring sustained dimensional stability above its glass transition.
| Property / Response | Amorphous 6302D Staple Fiber PLA | Semi-Crystalline PLA Fiber Grade Reference |
|---|---|---|
| Glass transition temperature | 55–60 °C | 60–65 °C |
| Melting endotherm | Absent | 160–180 °C |
| Crystallization exotherm | Absent or negligible | Present on controlled cooling |
| Thermal-bonding window | 90–120 °C | 130–150 °C |
| Single-fiber tenacity | 2.0–3.0 cN/dtex | 3.5–5.0 cN/dtex |
| Continuous-use dimensional stability above 50 °C | Limited | Improved by crystalline phase |
On production-scale staple fiber conversion equipment, 6302D is processed through single-screw extruders with barrier screws and an L/D ratio of 24:1 to 30:1. The melt temperature at the spinneret is maintained between 210 °C and 230 °C, lower than many semi-crystalline PLA fiber grades because the amorphous resin reaches acceptable spinline viscosity at reduced barrel temperatures. Quench air velocities are typically held at 0.3–0.6 m/s, and spinneret hole diameters of 0.25–0.40 mm are used for staple fiber production. Draw ratios between 2.5:1 and 4.0:1 are applied across the take-up and draw stand; the suppressed crystallization rate of 6302D permits lower draw temperatures than semi-crystalline PLA, although excessive draw stress produces melt fracture and filament break. In high-humidity environments above 60 % RH, pre-drying in a desiccant dryer at 80 °C for 4–6 h to reach a melt moisture level of ≤0.025 % by weight is required. Moisture-induced chain scission is observable as spinneret drips, reduced drawability, and a measurable drop in apparent melt viscosity, which compromises fiber uniformity and increases end-break frequency on the spin beam.
Calender bonding of 6302D requires control of nip pressure and roll gap because the amorphous softening plateau is broad and the fiber begins to flow under pressure at temperatures only 30–60 °C above its glass transition. Excessively narrow calender gaps produce film-like bond points, squeeze the binder phase out of the nonwoven structure, and reduce bond-point peel strength measured by ISO 9073-3. Insufficient gap pressure at low roll temperature yields weak bonds with delamination under tensile loading. The operational boundary is therefore set by the softening plateau rather than a crystalline melting point. Above 130 °C, the amorphous fiber loses fibrous geometry and can adhere to the calender rolls; below 90 °C, adequate bond formation is not achieved on high-speed nonwoven lines. Because the amorphous phase has no reinforcing crystallites, continuous exposure near 50 °C or above can induce progressive shrinkage and compression set. Finished products should not be specified for autoclave sterilization or for service environments exceeding 60 °C, and dimensional stability should be verified according to ISO 17052 for any application with elevated-temperature exposure.
Wet processing of 6302D staple fiber must avoid alkaline scouring baths above pH 9; alkali-catalyzed hydrolysis cleaves the polyester backbone and reduces molecular weight. Melt-phase reprocessing with additives that release free amines at process temperature should likewise be avoided because amine groups can accelerate chain scission. The fiber is supplied in baled form with a cut length commonly between 38 mm and 64 mm, and linear density can be selected from 1.5 denier to 6.0 denier depending on downstream carding and nonwoven formation. Fiber finish is applied during spin finish application or top-coating; the finish type and level must be specified for the intended thermal-bonding process because excess finish reduces bond strength and creates roll contamination. A finish level of 0.20–0.40 % by weight is typical for staple fiber entering carded nonwoven lines, but published data for a single standard finish chemistry is limited and finish selection should be confirmed through bond-strength testing.
| Parameter | Test Method / Reference |
|---|---|
| Melt flow rate | ASTM D1238-20 |
| Density | ASTM D792-20 |
| Glass transition temperature | ISO 11357-2:2020 |
| Moisture content | ISO 15512 |
| Bio-based carbon content | ISO 16620-2:2019 or ASTM D6866 |
| Food-contact status | Must be confirmed for the finished article under FDA 21 CFR or EU Regulation (EU) No 10/2011 |
| Chemical registration | EU REACH registration status must be verified for the specific imported article or formulation |
In thermal-bonded nonwoven structures, 6302D is most frequently used as the binder component in sheath-core fibers, where a high-tenacity core such as PET or PP provides load-bearing capability while the amorphous PLA sheath bonds at reduced calender temperatures. The grade is also converted into low-melting staple fiber for needle-punched filtration media, absorbent hygiene material, and compressed fiberfill for insulated garments and mattress pads. In filtration media, the amorphous PLA binder contributes to low-energy bonding but limits maximum service temperature; published data for high-temperature filter performance of 6302D-based needle-punched fabrics is limited. In hygiene applications, the bio-based carbon content and lower bonding energy are relevant selection factors, but migration and extractables testing under the intended food-contact or skin-contact regulatory framework must be completed on the finished nonwoven because the resin alone does not constitute a regulatory clearance. Compared with semi-crystalline PLA fiber grades, 6302D offers a lower activation temperature for bonding and reduced crystallinity-driven stiffness, but the trade-off is reduced thermal resistance, lower tenacity, and a narrower service envelope above ambient temperature.