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Ingeo™ Biopolymer 3052D Clarity Injection Molding PLA

    • Product Name: Ingeo™ Biopolymer 3052D Clarity Injection Molding PLA
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 834201
    Melt Flow Rate 14 g/10 min at 210°C/2.16 kg
    Glass Transition Temperature 55-60°C
    Crystalline Melt Temperature 145-155°C
    Tensile Strength At Yield 48 MPa
    Tensile Elongation At Break 2.5%
    Tensile Modulus 3500 MPa
    Flexural Modulus 3500 MPa
    Flexural Strength 83 MPa
    Notched Izod Impact 2.0 kJ/m²
    Heat Deflection Temperature 55°C at 0.45 MPa
    Vicat Softening Point 60°C
    Rockwell Hardness R85
    Light Transmission 90%
    Haze 2%
    Mold Shrinkage 0.4-0.8%
    Recommended Melt Temperature 190-210°C
    Recommended Mold Temperature 20-50°C
    Drying Temperature 80°C
    Drying Time 4 hours

    As an accredited Ingeo™ Biopolymer 3052D Clarity Injection Molding PLA factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Ingeo™ Biopolymer 3052D Clarity Injection Molding PLA is packaged in 25 kg (55 lb) moisture-resistant paper bags, palletized for shipment.
    Container Loading (20′ FCL) 20′ FCL: approximately 20 MT Ingeo™ 3052D PLA, 800 × 25 kg bags; palletized or floor-loaded.
    Shipping Ingeo™ Biopolymer 3052D Clarity Injection Molding PLA is not classified as dangerous goods for transport. It is typically shipped in 25 kg bags, octabins, or bulk containers. Store in a cool, dry, ventilated area, away from heat, moisture, and contamination. Protect packaging from damage and UV exposure.
    Storage Store Ingeo™ Biopolymer 3052D Clarity Injection Molding PLA in a cool, dry, well-ventilated area, away from direct sunlight, heat, and ignition sources. Keep original containers tightly sealed to prevent moisture absorption. Maintain storage below 30°C at low relative humidity. Avoid prolonged exposure to high humidity and temperatures above 30°C. Rotate stock and use within recommended shelf life; dry before processing.
    Shelf Life Two years from manufacture when stored unopened in original packaging, below 50°C and 50% relative humidity, away from moisture.
    Application of Ingeo™ Biopolymer 3052D Clarity Injection Molding PLA

    Pre-dried Ingeo 3052D pellets with residual moisture below 250 ppm are used for cold-fill beverage tumbler and overcap tools. Drying is performed in a closed-loop desiccant dryer with a -40°C dew point supply and a bed temperature of 80°C for 4 h; the dried resin is verified by a Karl Fischer titrator according to ASTM D6869-17. The melt temperature is held at 210°C ±5°C, and a melt mass-flow rate check per ISO 1133-1:2022 at 210°C with a 2.16 kg piston load is used for lot acceptance; a result outside 12-16 g/10 min triggers adjustment of the hot-runner temperature profile. For a tumbler with a nominal wall thickness of 1.5 mm to 2.0 mm, the tool uses a valve-gated hot runner with a gate diameter of 1.0 mm. Injection velocity is set at 80-120 mm/s, screw switch-over occurs at 95-98% volumetric fill, and holding pressure is maintained at 40-50 MPa for 0.5-0.8 s per millimetre of wall thickness. Back pressure is kept at 0.5-1.0 MPa to prevent splay and to maintain a homogeneous melt. The mold surface temperature is controlled between 25°C and 50°C; the lower limit shortens cooling time but can produce flow haze near the vestige, while the upper limit improves contact clarity and reduces residual stress at the rim. The cooled part is ejected with a peripheral air blast and transferred to a humidity-controlled conditioning area set at 23°C and 50% RH for 24 h before lid fit checks. The finished tumbler and overcap are intended for cold beverages only; continuous service above 50°C, hot-fill, microwave reheating, and dishwasher exposure are outside the operational boundary. Leak testing of the snap-fit assembly is performed with hydrostatic pressure of 0.2 bar for 30 s; compressive top load is measured at 50 mm/min according to ASTM D695-15. Transparent cold cups, snap-on overcaps, and travel tumblers are the main downstream articles in this segment.

    What Limits 3052D in Thick-Wall Cosmetic Jar Applications?

    Thick-wall cosmetic jars with side walls between 4 mm and 8 mm impose a slow cooling profile because the thermal conductivity of Ingeo 3052D is lower than that of many styrenics. The gate is not reduced below 1.5 mm in a cold runner jar tool; smaller sprue gates cause jetting and a visible V-shaped haze at the base of the jar. The melt temperature is held at 205°C-215°C, and the mold surface temperature is set between 35°C and 45°C to retain gloss on the thread finish and the bottom push-up. Back pressure is set at 0.7-1.2 MPa, and screw rotation speed is kept at 60-100 rpm; insufficient back pressure allows localized unmelt that appears as micro-pits near the neck ring. The packing profile uses a first stage at 65 MPa for 1.2 s and a second stage at 45 MPa for 3.5 s, which packs the thick bottom without creating a sink on the outer wall. Cooling time for a jar with an 8 mm base is 30-35 s in a conventional tool; beryllium-copper core inserts reduce this to 22-25 s but can leave water marks on high-gloss surfaces if venting is inadequate. Shrinkage is measured in accordance with ISO 294-4:2018; molded values are 0.3-0.5% in the flow direction and 0.4-0.6% transverse. Thread torque durability is checked with a calibrated torque tester at 1.2 N·m; cracks generally initiate at the knurl base when the transition radius is below 0.3 mm. These jars are filled with creams, gels, and powders. Undiluted essential oils, high-ethanol formulations, and strong esters can induce environmental stress cracking; a compatibility test at 40°C for 7 days is required before commercial filling. Cosmetic packaging converters audit the resin against REACH SVHC 0.1% w/w thresholds and RoHS 2011/65/EU for metallic inserts or closures; the finished jar is subjected to migration testing when the formulation contains skin sensitizers or UV filters.

    Dimensional Drift and Drop Impact in Refrigerated Dessert Inserts

    Injection molded inserts for single-serve refrigerated desserts are molded with wall thickness between 0.9 mm and 1.2 mm in a 32-cavity stack mold to keep cycle time below 12 s. The resin is dried to <250 ppm moisture and processed at a melt temperature of 205°C; the mold surface temperature is set at 40°C. Filling speed is raised to 180-220 mm/s to reduce hesitation marks near the bottom hinge line. Gates are placed at the sidewall rather than the base; center gating creates a radial stress concentration that increases the probability of cracking at 4°C. The parts are ejected after 4-5 s of cooling and immediately conditioned at 23°C and 50% RH for 24 h before lidding film is applied. Dimensional stability is assessed following ISO 294-4:2018; measured shrinkage in the flow direction is 0.35-0.45% for the insert. The filled container is used for mousse, pudding, or gel desserts distributed in a chilled chain at 4°C; continuous exposure above 45°C is not recommended because the part approaches its glass transition range. Filled drop testing is conducted from a height of 600 mm onto a steel plate at 4°C; a typical specification requires no leak or fracture in 10 out of 10 samples. If hinge or rim fracture occurs, the molder first raises the mold temperature to 50°C before considering impact modification, because added modifiers increase haze and must be evaluated with ASTM D1003-21. For EU direct food contact, the finished insert is assessed under Regulation (EU) No 10/2011 with overall migration testing according to EN 1186-1:2002; the widely referenced limit is 10 mg/dm². In the US market, food-contact status is established through the resin supplier's applicable Food Contact Notification rather than by a generic molding certificate.

    Flat display trays and point-of-sale product platforms molded from Ingeo 3052D require careful clamp force calculation because large projected areas generate high packing pressures that can flash at the parting line if venting is not balanced. For a 300 mm × 200 mm tray with a wall thickness of 2.5 mm, a hydraulic clamp force of 120-150 tonnes is typical on a conventional toggle press. The melt temperature is set at 210°C, but the injection speed is reduced to 40-60 mm/s to prevent jetting across the broad flat surface. A long-edge film gate with a width of 3.0 mm and a land length of 0.8 mm is used to maintain a uniform melt front. The mold temperature is held at 30°C to 35°C; a higher mold temperature improves gloss but increases cooling time in tools without conformal cooling. Ribs on the non-show surface are designed to a maximum thickness of 60% of the nominal wall; ribs above 70% create visible sink marks on the show surface. The finished trays are stacked under a static load of 5 kg for 48 h at ambient temperature; creep deformation is measured with a calibrated dial gauge and remains below 0.3 mm on trays with the recommended rib geometry. Heat deflection temperature is measured under 0.455 MPa according to ASTM D648-18; the result for these tray geometries is typically 50-55°C, which defines the upper service limit for static display loads. These fixtures are intended for indoor retail environments where ambient temperature does not exceed 40°C and where direct sunlight or halogen spot illumination is not present. Final applications include clear shelf trays, product risers, sign holders, and countertop display platforms with printed graphics inserted beneath the clear top surface.

    When 3052D Replaces General-Purpose Polystyrene in Clear Home-Office Molds

    Desktop organizers, pen trays, and clear drawer dividers are injection molded categories where Ingeo 3052D is evaluated as a styrenic replacement, but the lower heat deflection temperature relative to general-purpose polystyrene forces specific design changes. The material is pre-dried at 80°C for 4 h and processed at a melt temperature of 210°C; the mold temperature is set at 35°C because lower surface temperatures produce a dull finish on high-gloss inner cavities. The screw back pressure is maintained at 0.6-1.0 MPa, and screw retraction is limited to 50 rpm to avoid air entrapment in long narrow sections. A pen tray with a nominal wall of 2.0 mm and a length of 250 mm is filled from an offset film gate with a land length of 0.8 mm; the gate freezes after 3-5 s of holding pressure at 45 MPa. Warpage is controlled by keeping the ratio of flow length to wall thickness below 150:1 and by cooling the moving half 5°C colder than the fixed half. The resulting product is tested for flexural modulus under ASTM D790-17 or ISO 178:2019; a 2.0 mm specimen molded at these settings typically exhibits a flexural modulus near the supplier datasheet median, but transverse orientation can reduce the measured value by up to 15% in thin walls. Edge drop testing from 1.0 m onto concrete is not recommended for this neat resin; a minimum bottom edge radius of 1.5 mm is retained to reduce crack initiation. The finished articles are used in desk organization, stationery display, and clear home-office accessories; they are not intended for continuous load-bearing use or for environments above 50°C.

    Airless overcap and collar components for personal-care pumps are molded as clear, high-gloss parts that must resist repeated snap-fit assembly and maintain dimensional accuracy after repeated actuation. The Ingeo 3052D pellets are dried to <250 ppm moisture and processed with a melt temperature of 205°C in a 24 mm general-purpose screw. The moving mold half is cooled to 30°C and the fixed half to 40°C to balance filling and ejection. A four-cavity cold runner tool is used; the runner diameter is 3.0 mm for the first 60 mm and then steps to 2.5 mm to maintain pressure without excessive regrind. The gate is a sub-surface gate with a diameter of 0.8 mm and a land length of 0.6 mm positioned in the collar shoulder; the gate breaks cleanly on ejection under these dimensions. Draft angle is 0.5° on the inner bore and 1.0° on the outer wall; below these values, ejection drag leaves white stress marks near the snap bead. The radial snap-fit undercut is limited to 0.3 mm per side; larger undercuts can crack the hoop during assembly because the resin has limited elongation at break in the flow direction. Tensile properties are checked on molded plaques according to ISO 527-2:2012; tensile modulus is approximately 3.0 GPa, but local strain at the snap fit is kept below 2.5%. The components are used as clear overcaps and collars over lotion pumps, serum bottles, and cream jars; compatibility with alcohol-based formulations is verified by content storage at 40°C for 14 days.

    Compliance and Test Standard Matrix for Clear Injection Molded Food Service Items

    The matrix below consolidates the test methods and regulatory references applied to clear injection molded articles made from Ingeo 3052D in food service and personal-care packaging. It is not a substitute for finished article testing because geometry, colorants, closures, and filling conditions change the migration and mechanical performance of the final part.

    Regulatory or technical areaTest method or referenceTypical criterion applied to clear molded articles
    Melt mass-flow rateISO 1133-1:2022, 210°C, 2.16 kg12-16 g/10 min for lot consistency
    Tensile modulusISO 527-2:2012Datasheet median near 3.0 GPa; orientation may shift result
    Heat deflection temperatureASTM D648-18, 0.455 MPa50-55°C
    HazeASTM D1003-21Finished article haze below customer limit; impact modifiers raise haze
    ShrinkageISO 294-4:20180.3-0.6% depending on flow direction and wall thickness
    EU food-contact migrationRegulation (EU) No 10/2011, EN 1186-1:2002Overall migration 10 mg/dm² reference limit
    US food-contact statusApplicable resin supplier Food Contact NotificationConfirmed by supplier; finished article testing required by filler
    SVHC screeningREACH Candidate ListBelow 0.1% w/w per SVHC
    Hazardous substancesRoHS 2011/65/EU Annex IIApplies only to electrical/electronic articles; metallic closures audited separately

    The compliance matrix is applied only after the molder has locked the processing window; dry-as-molded specimens without controlled moisture content are not representative of final use.

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    Certification & Compliance
    More Introduction

    Ingeo™ Biopolymer 3052D Clarity Injection Molding PLA is a stereoisomer-adjusted poly(lactic acid) supplied by NatureWorks LLC for transparent injection molding applications in which melt fluidity, gate blush control, and low-temperature dimensional stability define the manufacturing boundary. The grade is identified by a melt flow rate of 10–25 g/10 min at 210 °C under a 2.16 kg piston load when measured in accordance with ASTM D1238 or ISO 1133-1:2022, with a density of approximately 1.24 g/cm³ per ASTM D792 and a relative viscosity near 3.5 at 1.0 g/dL in chloroform at 25 °C. The D-lactide co-monomer content is maintained near 4 % to delay spherulitic crystallization during cooling from the melt, which allows polished tooling to yield low-haze parts in thin-wall sections typical of single-serve serviceware and transparent packaging. Typical uses include transparent disposable cutlery, thin-wall cups, cosmetic packaging, display components, and non-implantable device housings. Because the resin is not nucleated, the practical upper service temperature is controlled by the amorphous PLA glass transition at 55–60 °C, which is lower than heat-resistant PLA grades containing nucleating agents or lower D-isomer content.

    Material Identity and Standards Cross-Reference

    Biobased carbon fraction can be verified through ASTM D6866 or EN 16640 radiocarbon analysis. Finished-article compostability is not an intrinsic resin property and must be certified under EN 13432 or ASTM D6400 for the specific wall thickness, mass, and additive package. Compliance with European chemical registration is documented under REACH Regulation (EC) No 1907/2006, with Substance of Very High Concern screening reported in the supplier documentation. Heavy-metal restrictions for electrical and electronic equipment housings are assessed under EU RoHS Directive 2011/65/EU Annex II. For food-contact applications, the converter must obtain the manufacturer’s food-contact statement and evaluate the final article under Commission Regulation (EU) No 10/2011 migration testing using the simulants assigned to the intended food type. United States food-contact status for polylactic acid is established through specific Food Contact Notifications, and the applicable FCN number and conditions of use should be provided by the resin supplier before production qualification.

    Mechanical property certificates are commonly generated under ASTM D638-14 for tensile yield and elongation, ASTM D790 or ISO 178:2019 for flexural modulus, and ASTM D256 or ISO 180:2019 for notched Izod impact. Heat deflection temperature is reported under ASTM D648 or ISO 75-2. Because polylactic acid is moisture-sensitive, property values are valid only on dry-molded specimens preconditioned at 23 °C and 50 % RH. The resin supplier’s certificate of analysis should be compared with incoming lot melt flow rate and moisture content before production release.

    Across production-scale reciprocating-screw machines with 20:1 to 24:1 L/D ratios and compression ratios of 2.5:1 to 3.0:1, predrying is the primary variable controlling molecular weight retention. Desiccant-bed or vacuum dryers should deliver air at 80 °C for 4–6 h to reduce pellet moisture to 250 ppm or lower as determined by ISO 15512 or Karl Fischer titration. Residual moisture above 250 ppm accelerates hydrolysis above 200 °C, causing viscosity loss, splay, silver streaks, and reduced gate strength. Barrel temperature profiles should ramp from 170 °C at the rear to 210 °C at the front, with nozzle temperature set 5–10 °C below the front-zone setpoint to limit stringing. Mold surface temperature should remain below 40 °C, typically 20–30 °C, to preserve amorphous clarity and prevent opacification from spherulite growth. For thin-wall parts, high injection speed is required; injection velocity settings of 150–300 mm/s on standard hydraulic machines are common, but published data for this specific configuration is limited because part geometry, runner diameter, and gate type dominate the pressure requirement. Screw back pressure of 0.5–1.5 MPa improves melt homogeneity without excessive shear heating. Holding pressure should be 60–80 % of peak injection pressure, with hold time adjusted until gate freeze is verified by part weight stabilization. Clamp force is rarely limiting; the resin’s approximate melt density of 1.1 g/cm³ at processing temperature and low-shear viscosity estimate of 700–1700 Pa·s derived from the melt flow rate produce normal flow lengths, but capillary rheometry on the specific production lot is required for mold-filling simulation.

    What Distinguishes 3052D from Higher-Crystallinity PLA Grades?

    Higher-HDT PLA grades rely on nucleating agents or lower D-lactide content to raise crystallization rate and heat distortion temperature. In contrast, 3052D retains a D-lactide content near 4 % and is not nucleated, so cooling from the melt under normal mold temperatures produces a largely amorphous article. This amorphous phase yields higher optical transmission but limits the heat deflection temperature under 0.455 MPa to approximately 52–55 °C per ASTM D648 or ISO 75-2 Method B. Higher-heat injection grades may reach HDT values above 85 °C after annealing or with nucleators; however, those gains require mold temperatures above 90 °C and extended cooling cycles. The 3052D grade also exhibits lower melt viscosity than extrusion film or sheet grade 2003D because its molecular weight is reduced to increase melt flow rate. This lower viscosity reduces clamp force demand, improves replication of polished surfaces, and shortens fill time in thin-wall cavities. The trade-off is reduced melt strength, greater sensitivity to open-nozzle drool, and lower notched Izod impact than high-molecular-weight PLA or impact-modified PLA alloys.

    Optical transmission in 3052D is governed by cooling rate and mold surface finish. Bulk haze remains low only when mold temperatures stay below 40 °C and the part solidifies before spherulites can grow; published data for this specific configuration is limited for parts with wall thickness above 3 mm. Stress whitening occurs when cooled parts are subjected to flexural strain exceeding approximately 2 % or impact near the notched Izod limit, due to crazing and cavitation in the amorphous phase. Annealing at 80–100 °C for 30–60 min can increase crystallinity and reduce stress whitening, but it also introduces haze and shrinkage of 1–2 % and must be performed on restrained parts. The practical service ceiling for annealed parts remains below 90 °C, but continuous exposure to water or humid air above 50 °C initiates hydrolytic chain scission, causing a decline in molecular weight and impact strength over time. Dimensional stability after molding reaches equilibrium only after 24 h at 23 °C and 50 % RH. Molding shrinkage in the flow direction is typically 0.3–0.5 % when measured by ASTM D955, with transverse shrinkage in the same range for unfilled amorphous moldings.

    Compliance testing for high-clarity packaging or non-implantable medical housings should be matched to the final article and not to the resin alone. The following checklist identifies the principal standards used during material qualification.

    Standard / RegulationScopeApplication to 3052D
    ASTM D6866Biobased carbon fractionReports biogenic carbon fraction; typical PLA values exceed 95 %
    EN 13432 / ASTM D6400Industrial compostabilityMust be evaluated on molded article; not an intrinsic resin claim
    ASTM D1238 / ISO 1133-1:2022Melt flow rateProduct specification range 10–25 g/10 min at 210 °C/2.16 kg
    ASTM D792 / ISO 1183-1DensityApproximately 1.24 g/cm³
    ASTM D638-14 / ISO 527-2Tensile propertiesTensile yield, elongation at break on dry molded specimens
    ASTM D648 / ISO 75-2Heat deflection temperatureLow-HDT amorphous unless annealed; typically 52–55 °C at 0.455 MPa
    ASTM D256 / ISO 180Notched Izod impactLow-ductility amorphous fracture; range governed by moisture and molding conditions
    ISO 10993-5CytotoxicityMay be considered for non-implantable device housings only after final-part testing
    Commission Regulation (EU) No 10/2011Plastic food-contact migrationRequires manufacturer FCM declaration and final article migration testing
    REACH (EC) No 1907/2006Chemical registrationSVHC content must be verified through supplier documentation
    RoHS Directive 2011/65/EURestricted substances in electrical equipmentApplicable only when used in EEE housings; limits apply to finished part

    When Thermoforming-Grade PLA Is Substituted into Injection Molding

    Extrusion and thermoforming PLA grades such as Ingeo 2003D have higher molecular weight and lower melt flow rate, often below 8 g/10 min at 210 °C and 2.16 kg. This high melt strength is necessary for sheet sag resistance but raises injection pressure and makes thin-wall filling problematic in multi-cavity tools. 3052D is specifically designed for injection molding; its melt flow rate of 10–25 g/10 min reduces pressure drop and permits longer flow lengths. However, the lower melt strength makes open-nozzle drool and stringing more likely. Shutoff nozzles or decompression settings of 5–10 mm are used to prevent drool. Compared with impact-modified PLA alloys, 3052D notched Izod impact is lower, typically 12–20 J/m, and ductility is limited. It is not a drop-in replacement where repeated flexure, snap-fit deflection, or high strain-rate impact is expected. The difference in crystalline behavior also affects secondary operations: 3052D parts can be annealed for moderate heat resistance, whereas high-molecular-weight sheet grades are usually thermoformed and not annealed in the same way.

    Thermal Degradation Is Rate-Limiting Above 220 °C

    Residence time at melt temperature above 220 °C should be minimized because polylactic acid undergoes thermal degradation, lactide reformation, and molecular weight reduction. Production lines should use shot sizes between 30 % and 70 % of barrel capacity to limit residence time and avoid dead spots. Published data for this specific configuration is limited, but the degradation rate increases sharply as melt temperature approaches 230 °C, particularly when moisture and shear heating are combined. In hot-runner systems, manifold and nozzle setpoints must be profiled to avoid overheating near the gate. The amorphous nature of 3052D also means that low mold temperatures create fast solidification, but dimensional stability after ejection requires controlled post-molding storage because cold crystallization can occur slowly over time. Purging between color changes is performed with a low-melt-index purge compound or unreinforced polypropylene; the barrel should not be left at processing temperature with 3052D residence times exceeding 5 min.

    Under humid service conditions, hydrolytic degradation is the dominant failure mechanism. At 60 °C and 80 % RH, molecular weight can decline by one-half within weeks in unannealed parts; published data for this specific configuration is limited because thickness, crystallinity, and contact with aqueous media dominate the rate. The resin is soluble in chlorinated solvents, dioxane, and tetrahydrofuran, and it is incompatible with strong alkalis above pH 9 and with concentrated acetic acid above 60 °C. Amine-based stabilizers or nucleators should not be added without capillary rheology screening because they can accelerate transesterification and reduce molecular weight. Drying must be repeated after any exposure of pellets to relative humidity above 60 % for more than 4 h.

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