| HS Code | 649868 |
| Volume Resistivity Ohm Cm | >1e15 |
| Surface Resistivity Ohm | >1e15 |
| Ul94 Flame Rating | HB |
| Molding Shrinkage Percent | 0.4-0.7 |
As an accredited INEOS Styrolution Luran SAN 358N Crystal Clear factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | INEOS Styrolution Luran SAN 358N Crystal Clear is supplied in 25 kg moisture-resistant bags, palletized for safe industrial storage and transport. |
| Container Loading (20′ FCL) | 20′ FCL container loading for INEOS Styrolution Luran SAN 358N Crystal Clear, packaged in 25 kg bags, palletized and secured for shipment. |
| Shipping | INEOS Styrolution Luran SAN 358N Crystal Clear is shipped as non-hazardous thermoplastic pellets, usually in 25 kg moisture-proof bags on pallets. Store and transport dry, cool, and protected from sunlight, heat, and contamination. Inspect packaging for damage and follow standard industrial handling practices. No special transport classification is normally required. |
| Storage | Store INEOS Styrolution Luran SAN 358N Crystal Clear in a cool, dry, well-ventilated area, preferably in closed original packaging. Keep away from direct sunlight, heat sources, moisture, and strong oxidizing agents. Avoid prolonged storage at elevated temperatures to prevent degradation or caking. Ensure containers are tightly sealed when not in use, and follow local regulations and the safety data sheet. |
| Shelf Life | Shelf life is typically 24 months from delivery when stored dry at room temperature in unopened original packaging. |
In high-volume cosmetic packaging lines running 96-cavity hot-runner tools, the limiting production variable is not cavity filling but post-ejection surface haze and gate vestige transfer through transparent outer shells. INEOS Styrolution Luran SAN 358N Crystal Clear is processed as the base resin at 100 wt%, with color masterbatch additions held between 2 wt% and 4 wt%, silicone-based external mold release at 0.1–0.2 wt%, and regrind limited to 20 wt% only where lot-specific haze after three reclaim cycles remains below 1.5% when measured on 3 mm plaques under ASTM D1003. The resin’s high-flow character, with published melt volume-flow rate in the 22–26 cm³/10 min range at 220 °C/10 kg per ISO 1133-1:2022, supports short-fill-prone thin-wall appendages on outer caps and collars without excessive injection pressure. Compliance obligations derive primarily from Regulation (EC) No 1223/2009 Article 17 for cosmetic product safety, Directive 94/62/EC for packaging heavy-metal limits of 100 mg/kg aggregated across lead, cadmium, mercury, and chromium VI, and REACH Article 33 for candidate-list substances above 0.1% w/w in finished articles. Downstream conversion on production-scale lines uses 120–180 t clamp injection molding machines with three-zone general-purpose screws of L/D 20:1, melt temperatures from 230 °C to 250 °C, mold temperatures from 45 °C to 60 °C, injection speeds of 50–120 mm/s, holding pressure 50–70 MPa, and cooling times of 8–14 s for wall thicknesses between 1.5 mm and 2.5 mm. Valve-gated hot runners are preferred to prevent gate vestige transfer onto Class-A exterior surfaces. Terminal product types include transparent outer fragrance caps, decorative collars, lipstick outer shells, compact bases, and serum bottle bodies. Direct continuous contact with undiluted ethanol above 40% or with high-terpene perfume concentrates is not recommended for this SAN grade because stress-cracking risk rises sharply in weld-line zones and around thread root radii.
The answer is conditional: short-cycle exposure to diluted citric acid and common food oils does not degrade visible transparency, but high-pressure steam, undiluted cold-pressed citrus oil at service temperatures above 38 °C, and repeated mechanical shock in dishwasher basalt racks expose the known boundary of this material. The applicable food-contact framework for transparent appliance components is FDA 21 CFR 177.1040, covering acrylonitrile-styrene copolymers intended for repeated-use food-contact articles, together with EU Regulation (EU) No 10/2011 Annex I where overall migration must not exceed 10 mg/dm² and substance-specific migration limits are verified according to EN 1186-1 and EN 13130-2. Formulation at the converting floor excludes external mold release agents that could migrate into aqueous food simulants; virgin Luran SAN 358N Crystal Clear is used at 100 wt%, food-approved color masterbatch at 0.001–0.005 wt% for blue toning, and regrind is held to 10 wt% maximum for direct-contact parts because repeated heat history shifts residual acrylonitrile migration behavior. Downstream production consists of injection molding thick-wall reservoirs with 200–350 t clamp machines, melt temperature 230–245 °C, mold temperature 50–70 °C, packing pressure 60–80 MPa, and cooling time 25–40 s for nominal 4 mm wall sections. Terminal product types include coffee machine water tanks, juicer hoppers, beverage dispenser reservoirs, and spice grinder windows. The notched Charpy impact of approximately 2 kJ/m² per ISO 179-1/1eA means the grade is unsuitable for high-drop blender jar bases or steam-sterilized pressure bowls; part design must eliminate sharp internal corners and flow-front collision planes where citrus oil and hot water combine to accelerate environmental stress cracking.
Resin certificates of analysis are insufficient for water-contact housings because the purchased article, not the pellet, carries the regulatory burden. For clear filter bowls and sump housings, the controlling standards are NSF/ANSI 61 Section 4 for health effects in drinking water system components, NSF/ANSI 42 for aesthetic effects in mechanical filtration units, FDA 21 CFR 177.1040 where export markets require food-contact equivalency, and EU Regulation (EU) No 10/2011 for European drinking-water-adjacent plastic parts. The molder or compounder must obtain formulation-specific certification because regrind, colorants, and processing aids alter the extractable profile; no resin supplier certification transfers directly to the finished article. Formulation discipline for potable pressure-bearing transparent housing includes virgin SAN 358N at 100 wt%, zero regrind unless the finished article is revalidated, blue masterbatch at 0.01–0.05 wt%, and exclusion of non-listed silicone or oleamide lubricants. Production-scale processing uses 200–400 t clamp injection molding machines, melt temperature 235–250 °C, mold temperature 55–80 °C, and hot-runner manifold temperatures below 240 °C to avoid resin stagnation yellowing. Post-mold annealing at 75–85 °C for 2 h is applied to lower residual hoop stress in threaded bowl closures. Terminal product types include sediment filter bowls, clear sump housings, brine tank windows, and clear drain covers. The formulation is not recommended for UV reactor sleeves where 254 nm irradiation produces measurable yellowing, nor for continuous exposure to chlorinated water above 60 °C because oxidative attack at stressed thread roots can reduce burst margin.
| Normative reference | Scope | Verification requirement for finished clear housing |
|---|---|---|
| NSF/ANSI 61 Section 4 | Drinking water system components | Extraction testing at 25 °C and 60 °C; total organic carbon, turbidity, and leachate metals evaluated on the molded article |
| NSF/ANSI 42 | Aesthetic effects for filtration components | Extractables and turbidity reduction performance verified on complete filter housing |
| FDA 21 CFR 177.1040 | Acrylonitrile-styrene copolymers in repeated food contact | End-test verification under intended conditions of use; residual monomer control |
| EU Regulation (EU) No 10/2011 Annex I | Plastic materials for food contact | Overall migration ≤10 mg/dm²; acrylonitrile-specific migration per Annex I using EN 13130-2 |
When injection molders replace polycarbonate in refrigerator interior light diffusers, the driving constraint shifts from heat distortion to short-glass-free surface quality and stress birefringence under polarized inspection. Luran SAN 358N Crystal Clear is processed at 100 wt% virgin resin, with optical diffuser masterbatch between 0.5 wt% and 2.0 wt%, regrind at 0 wt% for visible lens surfaces because minor lot-to-lot throwback alters luminance uniformity, and UV stabilizer at 0.3 wt% where the diffuser sits within 50 mm of high-blue-peak white LED arrays. The applicable flammability benchmark is UL 94 HB for non-current-carrying interior components, with IEC 60695-2-11 glow-wire temperature applicable only when the part is within 3 mm of energised connections; this SAN grade is limited to non-live optical covers. Downstream injection molding uses 150–350 t clamp machines, sequential valve-gated hot runners to prevent weld-line streaks in large lenses, melt temperature 230–250 °C, mold temperature 60–80 °C, packing pressure 40–60 MPa, and tool surfaces polished to SPI A-1 diamond finish. Luminous transmittance on 3 mm plaques remains in the 89–90% range per ASTM D1003, and stress birefringence below 60 nm/cm is required by Babinet compensation on qualified optical surfaces. Terminal product types include refrigerator interior light diffusers, freezer ceiling lenses, transparent shelf fronts, and dairy compartment lids. Mounting directly beneath COB LED modules exceeding 85 °C is outside the operational boundary because Vicat B/50 softening near 101 °C per ISO 306 leaves insufficient margin under assembly clamp creep.
Retail display lighting troughs impose a low mechanical demand but an unforgiving optical consistency demand; shot-to-shot luminance variation above 1.2% across a 600 mm rail is immediately visible when inspected with a 45°/0° photometer on ten consecutive shots. Published production-scale data for this specific retail display configuration is limited, so the processing window is derived from general SAN injection molding practice and should be confirmed with lot-specific certificates. Compliance requirements are less severe than food or water contact, but include REACH Article 33 for SVHC content above 0.1% w/w, Directive 94/62/EC heavy-metal limits of 100 mg/kg, and exclusion of cadmium-based pigments under Annex XVII of REACH. Formulation uses virgin SAN 358N at 100 wt%, color masterbatch between 1 wt% and 3 wt%, regrind up to 30 wt% only on non-optically critical rear panels, and no external mold release on visible surfaces. Downstream processing applies open-nozzle injection molding on 80–250 t clamp machines, melt temperature 230–245 °C, mold temperature 40–60 °C, 3 mm nominal wall thickness, and total cycle time 25–35 s. Terminal product types include transparent risers, divider panels, sign holders, and counter trays. Load-bearing use should not exceed a uniformly distributed load of 0.5 kN/m² on simply supported 300 mm spans unless a higher flexural safety factor is verified by ISO 178 testing on the finished panel; this grade is not a substitute for polycarbonate in high-impact anti-pilfer guards.
Converting office supply chains require that transparent pen barrels survive daily contact not only with sebaceous hand oils but also with isopropanol-based cleaning wipes without developing microcrazes. For writing instruments sold into European and North American markets, compliance must address ISO 11540:2014 for cap vent area and cap sizing to prevent asphyxiation hazards, EN 71-3 migration of elements where products are marketed to children, and REACH Annex XVII restrictions for lead, cadmium, and phthalates in accessible components. The molding formulation consists of virgin Luran SAN 358N Crystal Clear at 100 wt%, color masterbatch at 1–3 wt%, internal lubricant at 0.1–0.2 wt% to stabilize thin-wall flow, and regrind capped at 15 wt% to preserve consistent lot optical clarity. Downstream production runs on 80–180 t clamp injection molding machines with 64–128-cavity hot-runner valve-gate tools, melt temperature 240 °C, mold temperature 50 °C, injection speed 150 mm/s, and a minimum wall thickness of 1.2 mm for transparent barrels. Terminal product types include transparent pen barrels, mechanical pencil guide tubes, desk organizer trays, and correction fluid bottle bodies only where the fluid is water-based; direct contact with ketone-based inks, aromatic solvents, or acetate-based adhesives must be avoided because environmental stress cracking initiates at feed throat gate scars and ultrasonic weld joints.
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The resin designated INEOS Styrolution Luran SAN 358N Crystal Clear is an amorphous styrene-acrylonitrile copolymer supplied as transparent natural pellets. It is specified for injection moulding of thin-wall, optically critical components that require dimensional stability and resistance to aqueous, alcoholic, and lipidic contact media. The grade is differentiated from general-purpose polystyrene by a higher acrylonitrile content, which increases polarity, raises heat deflection temperature, and improves resistance to oils, fats, detergents, and many household chemicals. The material is typically processed without internal lubricants or release agents that would compromise clarity, although mould-release sprays are applied only when ejection forces exceed tool capability. Typical datasheet values include density 1.08 g/cm³ (ISO 1183), melt volume-flow rate 22 cm³/10 min at 220 °C/10 kg (ISO 1133-1), tensile modulus 3700 MPa (ISO 527-2), tensile stress at yield 72 MPa, notched Charpy impact strength 2 kJ/m² at 23 °C (ISO 179/1eA), and Vicat softening temperature 106 °C (ISO 306 method B50). Light transmittance through a 3 mm plaque is 90%, with haze below 1% (ASTM D1003). These are typical values, not specification limits; final part properties depend on gate geometry, flow length, packing pressure, and annealing history.
Before processing, the pellets must be dried to a residual moisture content below 0.1%. Production-scale desiccant dryers with inlet-air dew point of −30 °C or lower and bed temperature of 80 °C are used for 2–4 h when packaging has been exposed to ambient relative humidity above 60%. Undried material produces splay, gate blush, and subsurface voids in transparent mouldings; increasing melt temperature does not correct these defects. Conveying lines from the dryer to the feed throat should be closed, dry, and oil-free to prevent re-humidification and contamination by ambient dust, which is visible as black specks in crystal-clear parts.
| Property | Typical value | Test method |
|---|---|---|
| Density | 1.08 g/cm³ | ISO 1183 |
| Melt volume-flow rate (220 °C/10 kg) | 22 cm³/10 min | ISO 1133-1 |
| Tensile modulus | 3700 MPa | ISO 527-2 |
| Tensile stress at yield | 72 MPa | ISO 527-2 |
| Tensile strain at yield | 3% | ISO 527-2 |
| Charpy notched impact strength (23 °C) | 2 kJ/m² | ISO 179/1eA |
| Vicat softening temperature B50 | 106 °C | ISO 306 |
| Heat deflection temperature A (1.8 MPa) | 101 °C | ISO 75-2 |
| Heat deflection temperature B (0.45 MPa) | 104 °C | ISO 75-2 |
| Light transmittance (3 mm) | 90% | ISO 13468-2 |
| Refractive index | 1.569 | ISO 489 |
| Haze (3 mm) | <1% | ASTM D1003 |
| Water absorption (24 h, 23 °C) | 0.2% | ISO 62 |
| Coefficient of linear thermal expansion (23–80 °C) | 7.0 × 10−5 K−1 | ISO 11359-2 |
| Flammability (1.6 mm) | HB | UL 94 |
The melt temperature measured at the nozzle should be maintained between 230 °C and 260 °C. The lower boundary is set by incomplete plastication and high melt viscosity, which produce short shots and flow lines in sections below 1.5 mm. The upper boundary is set by thermal degradation of the acrylonitrile segments, observed as yellowing, silver streaks, and a reduction in notched impact strength. Total melt residence time should not exceed 5 min; longer hold times in hot-runner manifolds or injection barrels produce progressive discoloration. Barrel temperature profiles from rear zone to nozzle are generally set at 210–230 °C, 230–250 °C, 240–260 °C, and 240–260 °C. Mould temperature is maintained at 40–70 °C; the higher end of this range improves knit-line strength and reduces flow-induced birefringence but increases cooling time and shrinkage variation across the part.
Injection velocity should be high enough to prevent premature freeze-off in thin-wall flow channels. Filling times below 2 s are typical for wall thicknesses of 1–2 mm. Hydraulic injection pressure should be adjusted to maintain a melt pressure of 70–120 MPa at the nozzle during filling, measured with a nozzle pressure transducer. Machine size, barrel capacity, and screw wear shift this value. Holding pressure is set as a percentage of filling pressure and is held until the gate freezes; for needle-gated cosmetic closures, gate freeze time is often 0.5–2 s. Back pressure of 0.3–0.7 MPa is applied during screw recovery to homogenize melt temperature without adding excessive shear heat. Screw rotation is limited to the lower half of the machine manufacturer’s recommended range for SAN to avoid shear heating.
For crystal-clear SAN, a three-zone general-purpose screw with L/D 20:1 to 22:1 and compression ratio between 2.0:1 and 2.5:1 is normally sufficient. A low-compression screw or a barrier screw may reduce over-shear but is not mandatory. The non-return valve must seat cleanly; leakage increases residence time and produces brown streaks. Venting is critical at the last barrel zone and mould cavity. Vacuum venting or generous parting-line vents of 0.02–0.03 mm depth prevent gas burning and silver streaks. Hot-runner systems for transparent SAN require externally heated manifolds with individually controlled nozzles; internal heaters and dead zones create local residence times above 5 min and cause yellow/brown streaks. Purging should be performed with GPPS or a commercial SAN purge compound. Acetal or PVC residues, and amine-containing additives, should not be present in the screw or hot-runner system because degradation products can contaminate the SAN melt and produce surface defects.
Short-term thermal resistance is defined by HDT/A of 101 °C at 1.8 MPa and HDT/B of 104 °C at 0.45 MPa (ISO 75-2). The Vicat softening temperature of 106 °C (ISO 306 method B50) is a better indicator for rigid transparent parts exposed to hot water or dishwasher spray, but it is not a continuous-use limit. Continuous use in air is typically limited to 85 °C for stressed parts; above this temperature, creep occurs at ribs, bosses, and weld lines. Annealing at 70 °C for 2 h can reduce moulded-in stress and improve dimensional stability in hot-fill applications, but parts must be cooled slowly to prevent surface haze. The coefficient of linear thermal expansion is 7.0 × 10−5 K−1 between 23 °C and 80 °C (ISO 11359-2), which is lower than that of GPPS and contributes to lower shrinkage anisotropy in flat closures. Water absorption after 24 h at 23 °C is 0.2% (ISO 62); sustained exposure to high humidity can produce dimensional growth of 0.1–0.3%, and tolerances should be correspondingly relaxed on moisture-sealed assemblies.
Chemical resistance is selective. The material withstands dilute acids, alkalis, aliphatic hydrocarbons, vegetable oils, detergents, and many cosmetic solvents, but is attacked by ketones, esters, chlorinated aliphatic hydrocarbons, and concentrated oxidizing acids. Stress cracking can occur when transparent parts are exposed to strong solvents while moulded-in stress exceeds 10–15 MPa. Designers should not use this grade where continuous contact with acetone, methyl ethyl ketone, or ethyl acetate is expected. Published data for this specific configuration is limited for aggressive cosmetic formulations containing high concentrations of ketones or terpenes; compatibility testing under ASTM D543 is recommended before production release.
Compared with GPPS, Luran SAN 358N raises HDT/A from approximately 75 °C to 101 °C and tensile modulus from 3300 MPa to 3700 MPa under comparable ISO 75-2 and ISO 527-2 methods. GPPS exhibits lower resistance to environmental stress cracking in contact with olive oil, citrus oils, and many household cleaners; SAN grades are preferred for cosmetic jars, filter bowls, and appliance housings that contact such media. The SAN surface has higher chemical resistance but lower scratch resistance than PMMA. PMMA offers slightly higher light transmittance, typically 92% at 3 mm (ISO 13468-2), and higher surface hardness, but its density is 1.19 g/cm³ and its water absorption is 0.3–0.4% after 24 h. The 1.08 g/cm³ density of 358N translates to approximately 9% lower part mass at equal volume, which is significant in multi-cavity closures and packaging.
Within the Luran SAN crystal-clear product line, the 358N grade occupies the high-flow, general-purpose position. Lower-flow grades such as 368R provide higher Vicat softening and greater notched impact strength for thick-wall or hot-fill parts, but they require higher fill pressure in thin-wall tools. Higher-flow grades may generate lower injection pressure but can reduce impact strength and increase flash at parting lines. Grade selection should be based on flow-length-to-thickness ratio, gate type, and chemical exposure; no single resin grade is optimal for all transparent applications. Converters who currently run GPPS in thin-wall closures can often switch to 358N without major tool modifications, but the barrel should be purged and the melt temperature raised to the SAN range before production.
For food-contact and cosmetic packaging, the final article must be tested under the relevant migration framework. The raw material is designed for compliance with EU Regulation (EC) No 10/2011 on plastics intended for food contact and 21 CFR § 177.1040 for styrene-acrylonitrile copolymers, but the converter must verify migration against the specific food simulant, temperature, time, and contacting surface area. RoHS compliance is assessed under Directive 2011/65/EU, and REACH obligations attach to the European supplier. Medical device applications are not a primary datasheet claim; published data for this specific configuration under ISO 10993 biocompatibility is limited, and end-users must perform their own biological evaluation.
In a typical transparent cosmetic jar or household goods moulding with a nominal wall thickness of 1.5–2.0 mm, the dominant processing risk is not filling but thermal degradation in the hot-runner manifold and moisture-induced splay. Multi-cavity tools with unbalanced runner lengths show visible differences in gloss and haze if the manifold temperature variation exceeds 5 °C. Production-scale operation therefore requires independent hot-runner nozzle control, desiccant drying with −30 °C dew point, melt temperatures below 260 °C, and residence times under 5 min. Parts ejected with excessive residual stress can be identified by polarised-light inspection; when stress birefringence is visible at gates and weld lines, annealing or gate relocation is required before the part is approved for cosmetic packaging. The material does not require post-mould conditioning for non-food applications, but transparent parts should be packed soon after ejection to avoid dust contamination and surface abrasion. No additional surface coating is needed for clarity; external hardcoats are not recommended because adhesion to SAN is limited.