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INEOS Styrolution Luran®S ASA 797SE UV-WHP29435

    • Product Name: INEOS Styrolution Luran®S ASA 797SE UV-WHP29435
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales8@sinochem-nanjing.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 119227
    Product INEOS Styrolution Luran®S ASA 797SE UV-WHP29435
    Polymer Type ASA (acrylonitrile-styrene-acrylate)
    Uv Stabilization UV stabilized
    Density 1.06 g/cm³
    Melt Volume Flow Rate 6 cm³/10 min (220 °C/10 kg)
    Tensile Modulus 2300 MPa
    Tensile Strength At Yield 50 MPa
    Elongation At Break 15%
    Charpy Notched Impact Strength At 23 C 9 kJ/m²
    Vicat Softening Temperature B 50 105 °C
    Heat Deflection Temperature At 1 8 Mpa 95 °C
    Water Absorption After 24 H 0.3%
    Mold Shrinkage 0.4 to 0.7%
    Ul 94 Flammability Rating HB

    As an accredited INEOS Styrolution Luran®S ASA 797SE UV-WHP29435 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing INEOS Styrolution Luran®S ASA 797SE UV-WHP29435 is packaged in 25 kg moisture-resistant polyethylene bags, palletized and securely wrapped.
    Container Loading (20′ FCL) 20′ FCL: palletized 25 kg bags of INEOS Styrolution Luran®S ASA 797SE UV-WHP29435, shrink-wrapped and secured for ocean shipment.
    Shipping INEOS Styrolution Luran® S ASA 797SE UV-WHP29435 is shipped as non-hazardous thermoplastic ASA granules in moisture-protected bags or octabins on pallets. Keep dry, cool, and away from direct sunlight; avoid contamination. It is not classified as dangerous goods for transport; standard freight applies. Store in closed packaging.
    Storage Store INEOS Styrolution Luran® S ASA 797SE UV-WHP29435 in a cool, dry, well-ventilated area away from direct sunlight, heat, ignition sources, and oxidizing materials. Keep containers closed to prevent moisture ingress and contamination. Use original packaging, avoid excessive stacking, protect from static discharge and dust accumulation, and follow the supplier’s SDS and local regulations for safe storage and handling.
    Shelf Life The shelf life is 24 months from delivery when stored dry, cool, and in original unopened packaging.
    Application of INEOS Styrolution Luran®S ASA 797SE UV-WHP29435

    In unpainted exterior mirror housing production, INEOS Styrolution Luran® S ASA 797SE UV-WHP29435 is predried at 80 °C for 4 h in a closed-loop desiccant dryer with a dew point of −30 °C or lower. Residual moisture above 0.02 % is a known cause of splay, silver streaks, and micro-crazing at the gate transition, defects that cannot be hidden by post-treatment because the part is unpainted. The melt is processed at 240 °C to 270 °C, with a flat profile from rear zone to nozzle of 240 °C/250 °C/255 °C/260 °C. Mould temperature is held at 60 °C to 80 °C to balance Class A surface gloss against weld-line impact retention. On a 450 t hydraulic injection moulding machine running a two-cavity mirror housing tool with a projected area of 820 cm² per shot, clamp force demand is maintained at 4.5 kN/cm². A cold runner diameter of 4.0 mm to 6.0 mm and a gate land length of 0.8 mm to 1.2 mm prevent premature freezing at the gate. Because the housing is moulded in a single unpainted operation, the UV-WHP29435 stabilisation package is the only protection against long-term surface cracking; accelerated weathering is benchmarked to ISO 4892-2 at 1,500 kJ/m² xenon-arc exposure, with acceptance limited to a colour difference ΔE < 3.0 and no cracking at 20× magnification. Published data for this exact exposure level on the 797SE UV-WHP29435 grade in a mirror housing geometry is limited; approval testing on the production tool is mandatory.

    Weld-line strength in the mirror housing is a process conflict because the unpainted surface demands high mould temperature for gloss stability, while a higher mould temperature lowers flow resistance at the meeting angle and can reduce impact retention at the knit line. When the boss for the mirror bracket is side-gated, the melt front divides and recombines at an angle below 30°; tensile strength at that weld line may fall to 60–75 % of the nominal value from ISO 527-2. To control this, the tool is fitted with a sequentially controlled valve gate and a cavity pressure sensor placed 12 mm downstream of the last fill point. Short shots are run at 0.5 MPa increments to map the weld-line displacement before final switch-over. Switch-over from injection to holding pressure is set at 95 % of peak cavity pressure, not by screw position alone, which prevents overpacking at the boss root and reduces sink marks on the unpainted surface. Mould texture is specified as a chemical grain with depth of 0.06 mm to 0.12 mm; deeper grain hides surface defects but reduces gloss retention after 1,200 h of xenon exposure. The final part is inspected to ASTM D523 for specular gloss at 60°, with lower and upper control limits defined by the OEM grain standard, not by generic material datasheets.

    Because the part is unpainted, regrind from rejected housings is reused only if the material is ground and dried in a closed loop. Regrind content above 10 wt% reduces the weld-line elongation at break to a level that may not meet the relevant OEM exterior trim specification. The exact impact of regrind depends on the degree of thermal degradation during the first pass, so melt flow index is checked after every 4 h of production. An MFR increase above 25 % relative to virgin value indicates thermal history damage and requires a reduction in regrind ratio or a drop in melt temperature. The final mirror housing is also checked for dimensional stability at 80 °C for 2 h; width and length change above 0.3 % is not accepted. This test is more severe than a general datasheet prediction because the welded boss constraints distort the part after residual stress relaxation.

    What changes when UV-stabilised ASA replaces painted ABS in cowl vent grilles?

    Replacing painted ABS with Luran S 797SE UV-WHP29435 in a cowl vent grille eliminates a secondary painting operation but shifts the weather resistance burden entirely into the polymer matrix. The part must tolerate direct sunlight, windscreen-washer fluid overflow, and under-bonnet heat at the plenum interface. Wall thickness is specified at 2.0 mm to 2.8 mm, and rib-to-wall ratio is limited to 0.5 to 0.7 to avoid sink marks opposite the rib intersections. The tool is heated with water up to 80 °C; for multi-cavity tools with more than 8 cavities, oil temperature control is used to keep inter-cavity variation below ±2 °C. A flow-hindering rib at the windshield cowl edge changes filling order; weld lines are moved into hidden areas by adjusting gate location rather than by increasing injection speed alone. The finished grille is subjected to ISO 4892-2 with interval evaluation at 1,000 kJ/m²; chalking is assessed by ISO 4628-6, and a maximum rating of 1 is retained for visible surfaces. Permanent set after loading is measured at 80 °C for 24 h; longitudinal shrinkage is held below 0.25 % to prevent disengagement from the cowl seal retainers.

    Between the cowl and the plenum chamber, static soak temperatures can exceed 70 °C after engine stop, and ethanol-based screen wash solutions can pool at the drainage channel. ASA is specified because it does not stress-crack in short-term contact with ethanol/water mixtures up to 30 % ethanol, while the predecessor ABS grade showed micro-cracking at the snap-fit bosses. Validation includes immersion for 24 h at 60 °C in a 10 % ethanol/water solution under 0.4 % outer-fibre strain, followed by dart impact at −20 °C. A lot is rejected if more than 2 of 12 samples show brittle failure. Dimensional change after chemical immersion is measured according to ISO 175; mass change above 0.8 % triggers a redesign of the drainage channel. The snap-fit retention force is tested after ageing to ensure that the service removal force stays above 25 N, because low-force fits on unpainted surfaces loosen after repeated thermal cycling. Published data for this specific grade in the ethanol/water stress-cracking condition is limited; component validation on the production tool is required.

    Regrind from sprues and rejected parts is reused at a level up to 15 wt% only if the material is kept free of dust and is dried under the same conditions as virgin material. Higher regrind fractions reduce Charpy notched impact at −20 °C; impact strength falls by approximately 10 % for every 5 wt% increase above 15 wt%. The exact loss depends on actual hot-runner residence history and cannot be predicted from datasheet values alone. Moisture analyser measurement is recorded for every drying hopper before start-up; a reading above 0.02 % requires a further 2 h of drying before injection begins. For colour-matched parts, masterbatch addition is kept at 2–3 wt% with an ASA/SAN carrier. Pigment packages containing titanium dioxide above 8 wt% in the masterbatch can increase melt viscosity enough to shift switch-over point; the processing window must be revalidated after any colour change.

    Coextrusion of a UV-stabilised ASA cap layer onto PVC window lineals places the thermal stability burden on the die lip and the first calibration block. The ASA is fed through a separate single-screw extruder with screw diameter 45 mm to 60 mm and an L/D ratio of 30:1. Barrel temperatures are set from 200 °C to 220 °C, and melt temperature is held at 215 °C with a tolerance of ±5 °C. Temperature excursions above the upper limit generate low-molecular-weight degradation products that appear as yellow streaking at the die lip; excursions below the lower limit raise melt viscosity and reduce cap layer encapsulation at the profile edges. The cap layer thickness is specified at 0.2 mm for a 3 mm profile wall, corresponding to roughly 7 % of total wall cross-section. Die lip adjustment is performed with the ASA melt pump running at 8 bar to 12 bar backpressure; melt pressure variation greater than ±0.5 bar produces local thickness bands after calibration. Vacuum calibration tanks are set at −0.02 MPa to −0.06 MPa. If the first calibration block temperature falls below 15 °C, the cap layer skin freezes before adhesion to the PVC substrate develops, and delamination risk rises sharply.

    Adhesion between the ASA cap and PVC substrate is assessed by a peel test on a 25 mm strip at 23 °C; a peel force of less than 2 N/mm indicates insufficient fusion. The coextruded profile is tested for weathering by ISO 4892-2 at 2,000 kJ/m², with colour change measured to ISO 7724-2 and limited to ΔE < 5. A chalking rating better than 1 on ISO 4628-6 is required for white and grey capstock. Not all ASA cap layers tolerate PVC stabiliser migration equally; published data for the UV-WHP29435 package in this exact PVC coextrusion configuration is limited, so a 2 h production trial on the target profile geometry is used to verify encapsulation quality before release. The final profile is used in exterior window lineals, mullion covers, and door outers, where the cap layer replaces paint or coextruded PMMA. The process boundary is that ASA capstock is not recommended for direct contact with aromatic solvents or ketone-based cleaning agents during installation, because these solvents induce environmental stress cracking within hours.

    Temperature control at the die lip is more critical than in neat PVC extrusion because the ASA melt layer is thinner and has a shorter residence time. A hot die zone above 225 °C in the capstock channel creates surface roughness at the ASA-PVC boundary, visible as wave marks on the profile face after calibration. The haul-off speed is matched to the PVC substrate speed with slip adjustment below 2 %; higher slip creates interfacial shear that reduces peel strength by 30–40 %. The process window is therefore defined by the interaction of melt temperature, haul-off tension, and first calibration block temperature. A change in any one parameter greater than ±5 °C, ±0.5 %, or ±2 °C respectively requires a revalidation of peel adhesion and weathering performance on the next production lot.

    When a lower-temperature mould is required for multi-cavity agricultural cowl tools

    Agricultural equipment covers are often moulded with mould temperatures of 40 °C to 60 °C because large tools with deep draw are difficult to heat uniformly. This lower mould temperature reduces surface gloss, but for satin-grain cowl surfaces the main requirement is impact retention after UV exposure and occasional fuel contact. The UV-WHP29435 package permits unpainted black cowls on tractor engine side panels with a grain depth of 0.10 mm to 0.20 mm. Parts are shot at melt temperatures of 240 °C to 255 °C; higher melt temperatures raise odour and increase deposit formation on the cavity surface. The tool is vented at the last-fill corners with 0.02 mm land depth to prevent diesel-smoke burn marks. Draft angle on textured surfaces is held at 1.5° minimum, and bosses are cored to 60 % of nominal wall thickness to avoid sink marks opposite mounting points. Impact requirement at −30 °C is tested with a 2 kg impactor at 500 mm height on 12 random parts; no crack longer than 10 mm is accepted. The same parts are checked for flexural modulus after 1,000 h of xenon exposure to ISO 4892-2, with a minimum retention of 85 % relative to unaged values.

    Short-term contact with diesel is validated by ISO 175 immersion for 48 h at 23 °C; the maximum change in mass is limited to 0.8 %. Long-term contact with high-aromatic fuel fractions is not recommended because ASA softens; published data for this specific grade under biodiesel blends is limited. The main production failure mode is edge cracking at the snap-fit retention hooks when the mould temperature is held too low and the part is ejected with sharp internal stress. Stress relaxation is improved by increasing holding pressure time by 2 s and by maintaining a post-moulding annealing step at 70 °C for 2 h for parts thinner than 2.0 mm. The final cowl is installed without painting; the surface is specified with a satin grain that hides minor flow lines but exposes any gate blush. Gate design therefore uses a tab gate length of 1.0 mm and a land width of 3.0 mm to reduce shear heat at the entrance. Tool maintenance intervals are set by gloss degradation of the textured cavity, not by the resin itself; re-texturing of the cavity is required when 60° gloss exceeds the upper control limit on three consecutive batches.

    For dark grey and black cowls, a carbon black masterbatch is added at 2–3 wt%. The selected masterbatch carrier must be ASA or SAN; a polycarbonate carrier produces local viscosity splitting and surface clouding at the flow front. After the colour change is made, the new compound is checked for MFR by ISO 1133-1 at 220 °C/10 kg. A shift in MFR greater than 15 % from the approved baseline requires a new gate-freeze study because the holding time must be extended to keep the gate open until the part is fully packed. Agricultural cowl tools are typically large enough that cavity pressure sensors are located in the last-fill zone only; sensor readings below 35 MPa at switch-over are treated as a short-shot risk and trigger immediate holding pressure adjustment on the next cycle.

    Where outdoor electrical distribution boxes are specified for coastal or high-UV sites, the enclosure is moulded in a wall thickness of 2.5 mm to 3.5 mm, with stiffening ribs placed only on the internal face. The UV-stabilised ASA is used as an unpainted housing material to prevent topcoat delamination at enclosure corners after 1,000 h QUV-B. Impact performance is evaluated at low temperature according to IEC 62208, and UV resistance is assessed under UL 746C F1 conditions; the base material carries a UL 94 HB classification, which limits the enclosure to non-current-carrying housings where no internal ignition source is present. Glow-wire testing is performed under IEC 60695-2-11 at 650 °C; flame duration above 2 s is treated as a failure. Creepage and clearance distances are designed after dimensional stability tests at 70 °C, with longitudinal shrinkage held below 0.25 %.

    Warpage across the door opening is controlled by balancing fill with a fan gate at the bottom edge because a single edge gate creates differential orientation and leads to a bow of 2.4 mm on a 600 mm length. The tool is fitted with conformal cooling channels at the corner bosses to maintain a core temperature below 80 °C during cycle times of 55 s. A three-plate cold runner system is used, with runner diameter 5.0 mm and a gate land length of 1.0 mm. Hot runner systems with external heating are avoided where colour changes are frequent because ASA residence time above 250 °C in the manifold creates yellowing at the gate entrance. Maximum hot runner residence time is held below 10 min; after 20 min idle, the first 2 kg of purging is discarded before parts are collected. Weathering acceptance for coastal installations adds salt spray exposure per ISO 9227 for 500 h followed by ISO 179-1/1eA Charpy notched impact testing at −20 °C; the notched impact strength should not fall below 6 kJ/m². Published data for this specific grade in combined salt spray and UV sequence is limited, and pre-production validation on the actual enclosure is required.

    For enclosures with hinged covers, the living hinge area is not moulded from this ASA grade if flexural cycling exceeds 10,000 cycles because ASA is not a self-hinging material. Instead, the cover is attached with stainless steel pins or snap-fits that are cored and gusseted to a radius of 1.0 mm minimum. Failure mode on production lines has been observed when the ejection pin marks on the internal face align with a sealing groove; this creates a leak path in IP65-rated boxes. The tool layout is therefore arranged so that ejector pins do not occupy the sealing plane, or the sealing groove is machined after moulding. The final enclosure is tested for ingress protection to IEC 60529 IP65, and a vacuum decay of less than 0.1 bar/min is used for production audit after installation of the gasket.

    Thermal expansion and joint clearance in unpainted ASA louvre blades

    Unpainted ASA louvre blades for passive ventilation facades are extruded with a wall thickness of 1.8 mm to 2.5 mm and cut to length after calibration. The linear coefficient of thermal expansion is approximately 0.09 mm/m·K when measured by ISO 11359-2. A temperature swing from −20 °C to 70 °C on a dark blade yields a length change of 8.1 mm over a 1,000 mm length, so joint clearance is not set below 10 mm on long facade runs. The profile is extruded at melt temperature 210 °C to 230 °C and calibrator temperature 20 °C to 40 °C. Orientation is controlled by setting haul-off speed 10 % above die exit speed; higher haul-off increases longitudinal modulus but reduces cross-direction impact retention. Surface gloss is stabilised with a matte embossing roller at 70 °C; specular gloss values around 15 GU at 60° are recorded with ASTM D523.

    Weathering of the profile is tested by ISO 4892-2 for 2,000 kJ/m²; the change in Charpy notched impact after ageing must not exceed 30 %. Flexural modulus is measured by ISO 178, with a minimum retained value of 2,200 MPa after ageing; published data for the UV-WHP29435 package in this specific profile geometry is limited and should be verified by a pilot run on the target calibration table. A known production failure mode is chipping at the cut edge when blade cutting occurs below 10 °C. The blade is therefore pre-warmed to 20 °C before cutting, and a tungsten carbide blade with 0.5 mm tooth pitch is specified. A lower tooth pitch generates frictional heat that smears the ASA surface and increases micro-crack propagation. The final louvre blade is installed with stainless steel brackets; direct contact with plasticised PVC gaskets is avoided until the gasket formulation is tested for plasticiser migration, which can soften the ASA edge over time.

    When the louvre blade is coextruded with a darker colour layer, the colour masterbatch is pre-dried with the base resin at 80 °C for 4 h. A moisture reading above 0.02 % before extrusion creates surface pitting and lowers the weathering performance of the final film edge. The draw ratio between the die and calibrator is maintained at 0.95 to 1.05; higher draw ratios increase surface gloss and reduce impact, while lower draw ratios cause the profile to sag inside the calibration tank. Calibrator vacuum is limited to −0.05 MPa because excessive vacuum contacts the melt too aggressively on the visible face and produces drag lines. These drag lines later act as stress concentrators during thermal expansion cycles and are not acceptable on exposed facade surfaces.

    Across recreational vehicle exterior trim, the parts are specified as injection moulded or back-moulded components in white or beige, and they must retain colour after multi-year outdoor exposure without painting. Typical wall thickness for RV fender skirts is 2.4 mm to 3.2 mm, with mounting holes inserted after moulding. The main process conflict is the balance between high mould temperature for colour uniformity and cycle-time control for large-area parts. Mould temperature is profiled at 70 °C on the visible surface cavity and 50 °C on the core side; this asymmetric thermal condition reduces bow from differential shrinkage while still producing a low-gloss surface. After demoulding, parts are wrapped in low-density polyethylene film to prevent abrasion during storage and transport. Weathering acceptance is graded by ISO 105-A02 grey scale, with a minimum rating of 4 after 1,000 h UV-A 340 exposure. Chalking is measured by ISO 4628-6; a rating below 1 is allowed only on hidden flanges.

    Colour masterbatch with an ASA carrier is added at 2–3 wt%; the carrier resin must be dried together with the base material to prevent moisture streaks in visible surfaces. If the masterbatch carrier is polycarbonate, the melt mixture becomes hazy and weld-line impact drops by 20–30 %, so only ASA or SAN carrier masterbatches are permitted. The unpainted UV-stabilised ASA is also used for access hatch frames, where dimensional stability under roof-mounted solar heat is controlled by internal ribs with a rib-to-wall ratio below 0.7. The hatch frame is exposed to 80 °C for 24 h in a circulating-air oven; after conditioning, the frame must accept the mating hatch without closure force above 50 N. Repeated insertion testing is run for 500 cycles at −10 °C to 40 °C; wear depth on the snap-fit hook is limited to 0.15 mm. Published data for this specific grade in full-size RV fender skirt geometry is limited; a pilot tool trial with colour-matched masterbatch is required because pigment loading alters melt viscosity and gate freeze-off time.

    The low-temperature impact requirement for RV parts is more severe than for architectural parts because the components are installed in motion at highway speeds. Charpy notched impact is measured at −30 °C by ISO 179-1/1eA, and a minimum value of 8 kJ/m² is used for northern-market approval. A reduction in notched impact below this value after UV ageing indicates that the UV package has not protected the surface from chain scission on the exposed skin. The gate area is the most sensitive region because frozen-in stress from fast filling reduces local impact at low temperature. The gate land is therefore radiused into the part with a transition angle below 30°, and the gate freeze time is confirmed by short-shot weighting before production lot approval.

    Roof rail cover gloss and clip retention after 1,500 kJ/m² xenon arc exposure

    Roof rail covers are injection moulded in long thin parts with a wall thickness of 2.2 mm to 3.0 mm, and they must retain clip engagement after years of sun load without warping. The tool is a two-cavity hot runner system with sequential valve gates; valve pin opening is delayed 0.5 s between gates to move the weld line away from the clip boss. Melt temperature is held at 245 °C to 255 °C, and mould temperature is held at 60 °C to 70 °C. The cover is moulded in body colour or dark grey; low-gloss surfaces are produced with a chemical grain of 0.08 mm to 0.13 mm. Clip retention force is measured after moulding and after ageing by a pulling fixture at 100 mm/min; the minimum retention force is set at 30 N per clip after 1,500 kJ/m² xenon arc exposure to ISO 4892-2. Gloss is measured to ASTM D523 at 60° before and after ageing; the allowed loss is 10 GU for this geometry, beyond which the part is rejected for visible mismatch.

    A production failure mode on this type of component is clip boss cracking during demoulding when the core side temperature is below 50 °C. The boss is cored with a diameter equal to 60 % of the boss outer diameter, and the draw radius at the base is not less than 0.5 mm. Ejection is sequenced with two-stage air ejection plus mechanical ejector blades; a single-stage mechanical ejection creates shear marks on the grained surface when the part is de-moulded at 80 °C. The final part is installed without painting over metal roof rails; talc-filled grades are not used because they reduce low-temperature impact required by the OEM roof system. Published data for this specific UV-WHP29435 package in roof rail cover geometry is limited, so full-system validation including thermal cycling from −30 °C to 80 °C for 50 cycles is mandatory before serial release.

    During hot-sun static testing, the roof rail cover is loaded on a body-in-white fixture and exposed at 90 °C for 4 h per cycle. Warpage on the longitudinal axis must remain below 1.0 mm per 500 mm length; values above this limit indicate that the clip spacing is too wide or that the gate-induced orientation is unbalanced. The clip seat areas are inspected for stress whitening at 10× magnification after thermal ageing. Any visible micro-crack at the clip root is treated as a failure because the part is unpainted and the crack will propagate under cyclic wind load. For body-colour covers, colour matching is measured with a 45°:0° spectrophotometer based on ISO 11664-4; a batch-to-batch colour difference of ΔE > 1.5 against the master panel is not accepted.

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