| HS Code | 634697 |
| Materialfamily | ASA (acrylonitrile styrene acrylate) |
| Color | Black |
| Processingmethod | Injection molding |
| Density | 1.07 g/cm³ (typical) |
| Meltvolumerate | 9–10 cm³/10 min at 220 °C/10 kg (typical) |
| Moldingshrinkage | 0.4–0.7% (typical) |
| Tensilemodulus | 1900–2000 MPa (typical) |
| Tensilestrength | 45 MPa (typical) |
| Elongationatbreak | 15–20% (typical) |
| Charpynotchedimpactstrength | 12–15 kJ/m² at 23 °C (typical) |
| Vicatsofteningtemperature | 100 °C (typical) |
| Heatdeflectiontemperature | 85 °C at 1.8 MPa (typical) |
| Flammability | UL94 HB (typical) |
| Uvstabilization | Yes |
| Waterabsorption | 0.35% (typical) |
As an accredited INEOS Styrolution Luran®S ASA 777K BK factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | INEOS Styrolution Luran®S ASA 777K BK is supplied in 25 kg moisture-resistant bags, palletized and securely wrapped for industrial delivery. |
| Container Loading (20′ FCL) | 20′ FCL container loaded with palletized 25 kg bags of INEOS Styrolution Luran®S ASA 777K BK, secured for export shipment. |
| Shipping | INEOS Styrolution Luran®S ASA 777K BK is shipped as black ASA copolymer pellets in moisture-barrier bags, octabins, or bulk containers. Transport and store dry at ambient temperature, away from direct sunlight, heat, and contamination. Standard industrial handling applies; it is not classified as dangerous goods for transport. |
| Storage | Store INEOS Styrolution Luran®S ASA 777K BK in original, sealed packaging in a cool, dry, well-ventilated area, away from direct sunlight, heat, flames, ignition sources, and moisture. Protect pellets from contamination, dust, and physical damage. Keep containers closed when not in use, avoid prolonged outdoor storage, follow local regulations and the manufacturer’s safety data sheet, and ensure stock rotation. |
| Shelf Life | Typically 24 months from production when stored dry, cool, and protected from direct sunlight and moisture. |
The base polymer matrix in Luran® S 777K BK consists of a continuous SAN random copolymer phase surrounding dispersed polybutyl acrylate rubber particles. The grafted acrylic ester rubber phase lacks the carbon-carbon double bonds present in butadiene rubber. This structural difference restricts photo-oxidative chain scission under UV irradiation. Pre-drying is mandatory prior to any injection moulding campaign. A desiccant dryer operating at 80°C for 4 h with a dew point of -30°C or lower reduces residual moisture to a maximum of 0.03%. Parts moulded without this drying step exhibit surface splay, silver streaking, and a measurable reduction in Charpy notched impact strength. Barrel temperature profile from feed throat to nozzle is set between 240°C and 260°C. Local melt temperatures exceeding 270°C initiate thermo-oxidative degradation of the acrylic ester rubber phase. The resulting visual defect appears as a brown-black colour shift in the moulded part. Degraded material also exhibits notch sensitivity in the weld line region adjacent to the mounting boss. At a mould temperature of 60°C or higher, the part surface achieves a uniform deep black gloss without subsequent painting. Mould temperatures below 40°C produce a matte surface with visible flow marks and reduced knit line strength. Gate placement is typically an edge gate positioned on a non-visible surface. A submarine gate with a diameter of 1.2-1.5 mm provides automatic degating but increases shear heating at the gate land. Cavity pressure transducers attached to the moving half monitor switchover from velocity-controlled fill to pressure-controlled pack. Switchover occurs at 95%-98% of full cavity volume. Holding pressure of 40%-60% of the peak injection pressure is maintained for 6-10 s. Post-mould shrinkage is measured at 0.4%-0.6% in the flow direction and 0.5%-0.7% transverse to flow per ISO 294-4. OEM weathering validation for exterior mirror housings specifies xenon arc exposure per SAE J2527 or ISO 4892-2. Typical acceptance limits require a gloss retention at 60° measurement geometry above 85% after 2000 kJ/m² radiant exposure. Colour drift is limited to ΔE* below 2.0 units per CIELab. Black pigmentation in grade BK additionally masks incipient surface micro-crazing that would be visible on lighter-coloured ASA.
Mounting boss design is constrained by sink mark prevention at the boss-to-wall junction. Boss outer diameter is maintained at 2.0-2.5 times the thread-forming screw major diameter. A boss wall thickness below 50% of nominal part wall requires a gusset ring to distribute hoop stress. Thread-forming screws above M5 are not recommended for direct insertion into unreinforced ASA without a brass insert. Thermal insert installation is specified over ultrasonic insertion. Ultrasonic insertion melts a thin ASA layer at the boss wall and produces residual hoop stress that causes delayed cracking after thermal cycling to -30°C. End-use assemblies include exterior mirror housings for passenger cars, B-pillar appliqués, cowl vent grilles, and commercial vehicle mirror shell covers.
| Test method | Exposure cycle | Measured property | Acceptance criterion for black ASA exterior |
|---|---|---|---|
| SAE J2527 | Xenon arc, 2000 kJ/m² radiant exposure | Gloss retention at 60° geometry | ≥85% |
| ISO 4892-2 | Xenon arc, 2000 h, 0.51 W/m² at 340 nm, BPT 65°C | ΔE* CIELab | ≤2.0 |
| ASTM D4674 | Fluorescent UVA-340, 500 h | Δb* yellowing shift | ≤1.0 |
| UL 746C | UV 1000 h + water spray 7 days | UL 94 classification retention | HB retained, no delamination |
Outdoor telecommunications enclosures specified to IEC 62208 for empty low-voltage switchgear assemblies require thermoplastic housing walls that resist multi-decade UV exposure without surface chalking. Injection moulding of street cabinet base shells and 5G small cell shrouds with flow lengths of 500-800 mm is enabled by the high MVR of Luran® S 777K BK. The melt volume-flow rate reported per ISO 1133-1 at 220°C/10 kg falls in the range of 25-35 cm³/10 min. Thin-wall sections of 1.8-2.2 mm fill without short shots when gate locations are positioned along the longest flow path. Fast filling generates shear heating at the flow front. The actual melt temperature at the flow front remains above the solidification point of the SAN matrix longer than the barrel setpoint would predict. This extends the packing window and reduces sink mark depth at reinforcing rib intersections. Rib design follows a wall-thickness ratio of 0.5-0.7 times the nominal wall section. Ribs exceeding 70% of nominal wall thickness create visible sink marks on the Class A surfaces of street cabinet doors. Weld lines at cable entry bosses are managed by relocating the gate so that the flow front converges at a corner rather than across a flat tension surface. The black grade provides carbon black UV screening. Carbon black agglomerates larger than 20 μm cause surface roughness and micro-pinholes. Dispersion is controlled by extruder screw design with a mixing section of 4-6 L/D length. Flammability of ASA is classified at HB per UL 94 at all practical thicknesses. Outdoor suitability per UL 746C requires retention of the UL 94 HB classification after 1000 h UV exposure. Rainproof protection is achieved with enclosure designs meeting NEMA 250 Type 3R acceptance tests. The base shell does not require additional painting or UV lacquer. End-use assemblies include street cabinet access doors, splice closure housings, and 5G radio shroud covers.
Ride-on mower hood shells are subjected to a combination of UV exposure, occasional fuel splash, and impact from stones ejected from the cutting deck. Large single-cavity tools produce parts with flow lengths exceeding 700 mm. Hood wall sections fall between 2.5 mm and 3.5 mm to provide structural rigidity without glass fibre reinforcement. The high-flow properties of grade 777K BK reduce the number of injection gates required to fill the tool. Fewer gates correspond to fewer weld lines. Where flow fronts converge at grille opening ribs, the weld line becomes the critical failure site under winter impact. Weld line strength is governed by the temperature at which the two flow fronts merge. A mould temperature of 60°C keeps the flow front temperature above the glass transition region of the SAN matrix for a longer period. This permits some degree of molecular interdiffusion across the knit line. At mould temperatures below 40°C, the weld line exhibits brittle failure at impact energies well below the nominal unnotched Charpy value. Impact testing per ISO 179/1eU at -30°C quantifies the loss of ductility. Notched Charpy values at -30°C for ASA typically remain above 50% of the room temperature value due to the low-temperature flexibility of the polybutyl acrylate rubber phase. Butadiene-based ABS shows greater low-temperature toughening but degrades under UV. Fuel splash resistance is tested by immersion in a 15% ethanol-gasoline blend per ISO 175 at ambient temperature for 7 days. The SAN matrix resists stress cracking under this regime. The rubber phase is not extracted. A weight gain above 0.5% indicates plasticisation and will reduce the modulus at elevated operating temperatures.
Ejection of the part from the core requires a draft angle of 0.5°-1° on textured surfaces and 0.25°-0.5° on polished surfaces. Texture depth of VDI 24 to VDI 27 hides minor sink marks. Screw bosses for the hood pivot hinge carry a maximum thread-forming screw size of M6. Boss outer diameters are 2.0-2.5 times the screw major diameter. Hoop stresses from thread-forming screws induce environmental stress cracking in ASA if the boss wall is too thin. A boss wall thickness below 50% of nominal part wall requires a gusset ring. The hinge pin itself is overmoulded stainless steel. Thermal expansion mismatch between the steel insert and the ASA matrix is accommodated by a clearance fit of 0.1 mm around the insert shank. End-use assemblies include lawn tractor hoods, snow thrower discharge chutes, and zero-turn mower engine covers.
In rooftop photovoltaic installations, the inverter enclosure interior reaches 70-85°C air temperature during peak solar load. The HDT/A value of Luran® S 777K BK is approximately 96°C at 1.8 MPa per ISO 75-1/-2. This leaves a narrow thermal margin when interior power electronics generate localised hot spots near the heat sink mounting bosses. Design practice inserts a standoff distance of 8-12 mm between the heat sink back plate and the ASA enclosure wall to prevent continuous contact temperature from exceeding 85°C. The grade is selected for its UV stability rather than its heat resistance. Injection moulding of the base tray uses a two-plate cold runner tool with a cavity pressure transducer controlling switchover. The base tray dimensions are typically 300 mm × 400 mm × 120 mm. Wall sections run 2.0-2.5 mm. IP65 sealing per IEC 60529 requires a continuous gasket channel around the lid perimeter. The gasket channel depth is held to ±0.05 mm to ensure uniform compression of the silicone or EPDM gasket. Dimensional variation exceeds this tolerance if post-mould shrinkage is not compensated with 0.4%-0.6% pack allowance in the tool design. Flammability is assessed per IEC 60695-11-10. The ASA grade achieves HB classification at 2.0 mm thickness. Outdoor suitability follows UL 746C with retention of the HB classification after 1000 h UV exposure. Electrical safety certification per IEC 62109-1 and IEC 62109-2 evaluates the enclosure as a protective barrier. End-use assemblies include inverter base trays, DC disconnect housings, and combiner box covers.
| Processing parameter | Setpoint or range | Measurement method or instrument |
|---|---|---|
| Pre-drying temperature | 80°C | Desiccant dryer, dew point -30°C |
| Pre-drying time | 4 h | Gravimetric moisture analyzer |
| Melt temperature | 240-260°C | IR pyrometer on purged melt |
| Mould temperature | 40-80°C (glossy surfaces ≥60°C) | Thermocouple embedded in tool steel |
| Injection speed | Fill time 1.5-3.0 s for 2.0-2.5 mm wall | Linear transducer on screw position |
| Holding pressure | 40%-60% of peak injection pressure | Cavity pressure transducer |
| Back pressure | 5-15 bar | Hydraulic pressure gauge |
| MVR (220°C/10 kg) | 25-35 cm³/10 min | ISO 1133-1 |
Roof rail end caps, load carrier clamp housings, and bicycle rack jaw bodies are installed above the vehicle roofline where they receive direct solar radiation during summer and road salt spray during winter. The parts are injection moulded with wall thicknesses between 2.0 mm and 3.0 mm. The high-flow grade permits filling of long, narrow channels that form the clamp jaw geometry. Mould temperature is held at 50-60°C. Melt temperature is 240-250°C. Pre-coloured black compound eliminates the need for painting of visible surfaces. UV preconditioning followed by cold impact replicates the service life of a clamp body that remains on the vehicle for 5-10 years. The test sequence is ISO 4892-2 xenon arc for 1500 h followed by ISO 179/1eA notched Charpy at -30°C. ASA with polybutyl acrylate rubber exhibits a rubber phase glass transition temperature in the range of -40°C to -50°C. This places the rubber phase well into the rubbery plateau at -30°C. Notched Charpy values typically remain above 10 kJ/m² at -30°C even after UV exposure. Butadiene-based grades show equivalent low-temperature impact before UV exposure but suffer a sharper decline after xenon ageing. Threaded insert geometry is a critical design constraint. Brass knurled inserts with sharp knurl tips act as crack initiators. The insert receiving boss requires a wall thickness of at least 1.5 times the insert outer radius. Insert installation is by thermal insertion, not ultrasonic. Ultrasonic insertion melts a thin layer of ASA at the boss wall and produces residual hoop stresses that cause delayed cracking on cold nights. Load-bearing clamp jaws must survive repeated tightening cycles at a consumer-applied torque of 8-12 N·m. The clamp jaw teeth are reinforced with ribs of 1.5 mm thickness. Rib thickness equal to the nominal wall creates sink marks and reduces the effective contact area of the jaw teeth. Published comparative data for ASA clamp bodies under combined UV plus torque cycling is limited; product validation typically requires an OEM-specific multi-axis test protocol. End-use assemblies include roof rail end caps, clamp housings for ski and bike carriers, and tow bar cover plates.
In a saltwater marina, access panels and power pedestal covers are subjected to continuous salt fog deposition, direct UV, and occasional contact with diesel fuel or bilge cleaner overspray. Moulded ASA does not corrode, but inserted metal hardware must be evaluated for contact with the polymer matrix. Salt spray testing per ASTM B117 or ISO 9227 is conducted for 500 h. Stainless steel inserts of A2 grade are preferred. Salt fog exposure followed by torque testing on the insert verifies that no environmental stress cracking has occurred at the insert wall. Cracking is assessed by visual inspection at 10× magnification. Surface temperatures of dark ASA in direct marine sunlight can reach 75°C. This remains below the HDT/A of 96°C but above the safe handling temperature for bare skin. Vented double-wall construction is specified where continuous hand contact is expected. UV stability of the black grade in Florida marine exposure is assessed per ASTM G154 accelerated fluorescent UV. The acrylic ester rubber phase does not develop surface chalking after 1000 h of UVA-340 exposure. Thin-wall sections of 2.0 mm maintain impact resistance after salt fog cycling to -20°C. The SAN matrix provides resistance to dilute alkali and mild acid splashes encountered in marina environments. Strong solvents such as acetone and MEK will etch the surface and must be excluded from cleaning protocols. End-use assemblies include dock access panels, marina power pedestal bases, bilge pump covers, and deck plate frames.
Swimming pool pump strainer lids and timer control box housings are exposed to dilute hypochlorite solution, continuous UV, and diurnal temperature cycling. The SAN matrix of ASA provides resistance to aqueous sodium hypochlorite at concentrations of 2-5 ppm free chlorine per ISO 175 immersion testing. No surface crazing or weight change above 0.3% is observed after 28 days at 23°C. Butadiene-based rubber would undergo oxidative attack under the same conditions. Grade 777K BK is selected for opaque covers and control boxes where transparency is not required. Transparent lids are specified in polycarbonate. The moulding process uses a hot runner system with valve gates for two-cavity production. Cycle time is controlled by the cooling phase. Melt temperature is 245-255°C. Mould temperature is 60°C. Part wall thickness is 2.5 mm. The gasket seating surface around the strainer lid requires a flatness of 0.1 mm across a diameter of 150 mm. Post-mould warpage is corrected by adjusting the packing pressure profile. Certification for pool equipment per NSF/ANSI 50 requires extraction testing of the polymeric material in contact with pool water. The ASA grade must not release extractable compounds above the limits specified in the standard. Published data for this specific grade under NSF/ANSI 50 is limited; the raw material supplier's drinking-water certificates do not automatically extend to pool equipment compliance. End-use assemblies include pump strainer lids, valve actuator housings, and outdoor timer control enclosures.
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