Products

INEOS Styrolution Absolan SAN 2500

    • Product Name: INEOS Styrolution Absolan SAN 2500
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 499622
    Density 1.08 g/cm³
    Melt Flow Rate 20 g/10 min (220°C/10 kg)
    Tensile Modulus 3600 MPa
    Tensile Strength At Yield 70 MPa
    Tensile Elongation At Break 3.5%
    Flexural Modulus 3600 MPa
    Charpy Notched Impact Strength 2 kJ/m²
    Charpy Unnotched Impact Strength 15 kJ/m²
    Vicat Softening Temperature 106°C
    Heat Deflection Temperature At 1 8 Mpa 90°C
    Heat Deflection Temperature At 0 45 Mpa 100°C
    Rockwell Hardness M83
    Water Absorption 0.2%
    Volume Resistivity 1E15 ohm·cm
    Refractive Index 1.57
    Light Transmission 89%
    Haze 1%
    Ul94 Flammability Rating HB

    As an accredited INEOS Styrolution Absolan SAN 2500 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing INEOS Styrolution Absolan SAN 2500 supplied in 25 kg polyethylene bags, palletised and shrink-wrapped for secure storage and transport.
    Container Loading (20′ FCL) INEOS Styrolution Absolan SAN 2500 loaded in clean, dry 20′ FCL; palletized bags secured, evenly distributed, and protected from moisture.
    Shipping INEOS Styrolution Absolan SAN 2500 is shipped as non-hazardous styrene-acrylonitrile copolymer pellets, typically in 25 kg bags or bulk containers. Keep dry, cool, and protected from UV and contamination; avoid prolonged heat. It is not classified as dangerous goods for transport; follow the supplier SDS and local regulations.
    Storage Store INEOS Styrolution Absolan SAN 2500 in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, flames, and strong oxidizers. Keep packages closed to prevent moisture and dust contamination, avoid prolonged UV exposure and high humidity, and follow first-in/first-out stock rotation with appropriate spill containment.
    Shelf Life Shelf life is typically two years when stored in original unopened packaging under dry, cool conditions, away from direct sunlight.
    Application of INEOS Styrolution Absolan SAN 2500

    Moisture in Absolan SAN 2500 feedstock is not visually obvious, but it determines surface-defect density in thin-wall cosmetic-packaging moulding. Desiccant drying at 80°C for 2–4 h to residual moisture of ≤0.05 wt% is required before plasticising; closed-loop hopper air with a dew point below −30°C is used because shop-floor relative humidity above 60% can re-humidify the granulate within 30 min. Multi-cavity tools running mascara outer shells, compact powder trays, and lip-balm outer tubes on 1000 kN toggle presses use a five-zone barrel profile: 190–200°C rear, 210–220°C compression, 220–230°C metering, 225–235°C front, and 230–240°C nozzle. Screw speed is held at 40–60 min⁻¹ and backpressure at 0.8–1.5 MPa to avoid shear-induced yellowing. Mould temperature is kept at 45–60°C with pressurised-water thermolators; raising the tool surface above 70°C increases ejection delay and gas-venting fouling without improving visible finish enough to justify the added cycle time. Filling of 0.6–0.9 mm side walls is completed within 0.5–1.0 s; gate freeze is controlled with pack pressure of 50–70 MPa for 1.5–2.5 s. Opaque colour masterbatch is added at 2–3 wt% of total throughput, and pearlised concentrates above 3.0 wt% in walls below 1.0 mm can promote visible flow-line branching across the cosmetic face. Transparent shells use soluble dyes dosed at 0.02–0.05 wt% and pre-dried with the base resin. Regrind from sprues and runners is tolerated up to 20 wt% when generated through a low-dust granulator with a 4 mm screen and re-dried to the same moisture target; above 20 wt%, a gloss loss greater than 5 GU at 60° may appear as a result of higher-viscosity regrind streams and knit-line visibility. Surface gloss on showroom-visible faces is checked with ASTM D2457-13 at 60°, with values below 70 GU treated as a process deviation. Compliance for cosmetic packaging is managed through REACH Annex XVII entries 51 and 52 for phthalate restrictions, and packaging formulations must not introduce compounds prohibited under Regulation (EC) No 1223/2009.

    What Prevents Stress Whitening at Gate Bosses in Backlit Control Panel Lenses?

    Backlit fascia lenses for washing-machine and dishwasher control panels produced from Absolan SAN 2500 require a low-haze optical path, but the dominant production rejection is stress whitening around the gate when the lens is snapped into a painted frame. The lens is injection moulded with wall thickness of 2.0–2.5 mm, an edge fan gate width of 8–10 mm, and gate depth of 1.0–1.2 mm. Nozzle melt temperature is held at 230–245°C, and tool surface temperature is maintained at 60–80°C to allow molecular orientation to relax before solidification. Packing pressure is profiled as 60 MPa for 2 s, followed by 30 MPa for 4 s, and then screw decompression is applied to prevent nozzle drool. To reduce residual stress before printing and clip assembly, the lenses are annealed at 70°C for 2 h in forced-air ovens and cooled at 0.5°C min⁻¹ until the part core reaches 40°C; faster cooling can leave a bow above 0.2 mm across a 200 mm face. Detergent compatibility is screened by immersion in 5 wt% sodium carbonate solution at 40°C for 96 h according to ISO 175:2010, followed by apparent crazing assessment under polarised light. The operating boundary is explicit: undiluted alkaline detergent reservoirs must not contact the SAN lens directly because the styrene-acrylonitrile matrix has limited hydrolytic stability at pH above 10. For electronic appliance integration, the final assembly is evaluated under IEC 60335-1; flammability classification is not inherited from the natural resin and must be verified at final thickness under IEC 60695-11-10, where many natural SAN compounds achieve HB but not V-2. Optical transmission through the light-guide area is checked with ISO 13468-2; total transmittance above 85% at 2 mm is typical only when the melt cushion is controlled to 3–5 mm, because a small cushion can leave unmelted material that lowers clarity in the gate region. Terminal articles include backlit control-panel lenses, cycle-selector surrounds, and transparent cover windows for appliance user interfaces.

    Food Contact Wall-Section Balance in Blender Jar Bodies and Processor Bowls

    Blender jar bodies and food-processor work bowls are produced from Absolan SAN 2500 with wall sections between 2.5 mm and 4.0 mm to withstand clamping loads from blade assemblies and occasional drops at 5°C. The melt at the nozzle is set to 240–250°C, and the tool surface is maintained at 70–80°C to reduce visible sink over the threaded neck area. Cooling time in these thick-wall tools is the controlling cycle variable and often exceeds 20–30 s; early ejection creates a soft thread that later deforms under assembly torque above 2 N·m. The screw should have a compression ratio between 2.0:1 and 2.5:1 with an L/D of 20:1–22:1; higher compression can push melt temperature beyond the narrow thermal window and shift the mass tone toward yellow. Food-contact conformity of the finished article is assessed under Commission Regulation (EU) No 10/2011 for overall migration and specific migration of acrylonitrile; compliance declarations must be issued after testing of the moulded item, not the pellet. In production, moulder set points are 200°C, 215°C, 230°C, 240°C, and 245°C from hopper to nozzle. Hold pressure of 80–100 MPa for 4–6 s is needed to keep the thick base flat; insufficient hold pressure raises the risk of a concave bowl bottom beyond 0.8 mm over a 150 mm diameter. Chemical resistance of the bowl to food oils is checked by immersion in refined vegetable oil at 23°C for 24 h per ISO 175:2010; dimensional change is measured after a 24 h recovery period and must remain below the sealing-face warp tolerance. The terminal component is intended for top-rack dishwasher exposure, but steam sterilisation or continuous service above 85°C is outside the suitable operating window for unmodified SAN because the part can soften and lose thread engagement. Processors should also exclude knife-edge gates and sharp thread roots below 0.5 mm radius, because these act as stress concentrators when the filled bowl is dropped onto hard flooring.

    Transparent doors and inspection windows for laboratory diagnostic instruments such as gel imagers and automated analysers use Absolan SAN 2500 when optical clarity and resistance to alcohol-based cleaning agents are both required. Moulding of these flat panels involves wall thickness from 2.0 mm to 3.0 mm, a central sprue or valve gate, and an open tool surface polished to SPI/SPE A-2 finish. Nozzle melt temperature is held at 230–245°C, with tool temperature at 60–75°C; the packing phase is 50–70 MPa for 3–5 s to prevent sink around hinge bosses for service access. Cleaning-agent resistance is evaluated by wiping with 70% ethanol and 70% isopropanol for 500 cycles under 1 kg load, followed by inspection for crazing; controlled test data can be generated with ISO 175:2010 immersion screens or constant-strain environmental stress-cracking evaluation under ISO 22088-3:2006. Published data for this specific grade under repeated wipe loading is limited, so production qualification should include a pilot-run stain and craze audit using the actual cleaning formulation. The housing does not require ISO 10993 biocompatibility evaluation when classified as a non-patient-contacting surface, but the instrument manufacturer must demonstrate electrical and mechanical safety under IEC 61010-1. Flame retardance is not claimed from the natural resin; any requirement for UL 94 V-class must be confirmed on the final assembly. Since laboratory instruments may be sanitised with quaternary ammonium compounds, the operating boundary includes avoiding continuous contact with concentrated quaternary ammonium solutions because these can accelerate environmental stress cracking in transparent styrenic copolymers at low strain levels. Terminal components are analyser inspection windows, transparent service doors, and lens covers for diagnostic imaging systems.

    When laser printer paper feed windows are specified in Absolan SAN 2500 instead of acrylic

    Laser printer exit-tray windows and paper-path inspection covers are flat parts with flow lengths up to 150 mm and wall thickness between 1.8 mm and 2.5 mm. In this configuration, the melt at the nozzle is held at 230–240°C, and the tool surface is set at 55–65°C. Because the flow length-to-thickness ratio can exceed 80:1, filling speed is profiled with an initial injection velocity of 30 mm/s, ramping to 70 mm/s over the first 0.5 s, and then dropping to 15 mm/s at the end of fill to avoid gas traps at the final flow front. Pack pressure of 55–65 MPa is maintained for 2–3 s. The main production defect in this part family is flow-front hesitation around paper-guide ribs; if the rib thickness is below 0.8 mm, the flow front splits and recombines as a visible weld line across the transparent window. Rib-to-wall ratio is therefore kept at 0.6–0.7, and gate placement is moved to the centre of the long edge to equalise fill distance. Office equipment compliance is governed by RoHS Directive 2011/65/EU and, where applicable, REACH Annex XVII. Because unmodified SAN has high surface resistivity, static dust attraction on paper feed windows can occur; an external antistatic coating or ionised air rinsing is used instead of high-load antistatic masterbatch, which would lower transmission by 2–3% at 2 mm measured with ISO 13468-2. The terminal components are paper-path inspection covers, document feeder input trays, and scanner glass support frames. Acrylic replacement is justified when the part requires higher methanol resistance or lower water absorption than acrylic in the same cleanroom paper-handling environment.

    Rigid handle shells for powered toothbrushes are produced from Absolan SAN 2500 as a transparent or opacified substrate that is later overmoulded with a thermoplastic elastomer. The substrate is moulded in four-cavity tools with a wall thickness of 2.0–2.5 mm, nozzle melt temperature of 230–245°C, tool temperature of 50–65°C, and a hold pressure of 60–75 MPa for 2–4 s. Weld lines are avoided by moving the gate to the closed end of the handle and using a cold runner diameter of 6 mm to maintain a uniform melt front across the battery compartment. Dimensional control is critical around the sealing groove: out-of-roundness must remain below 0.1 mm on a 20 mm diameter thread shoulder to pass water immersion testing under IEC 60529 IPX7 conditions in the final device. The injection moulding process uses a cushion of 3–5 mm and screw decompression of 3–6 mm to prevent drool into the nozzle during ejection. Toothpaste and saliva contact is limited to external surfaces, so the material is not positioned as a food-contact or long-term skin-contact component; biocompatibility testing under ISO 10993-1 is the responsibility of the device manufacturer when the shell design leaves SAN surfaces in direct skin contact. Chemical resistance testing with ISO 175:2010 for 24 h in 0.5% sodium lauryl sulfate solution at 35°C is used as a conservative screen for toothpaste-surfactant exposure. The operating boundary is the resonance frequency in sonic toothbrushes; repeated flexural loading at 200–300 Hz can induce fatigue cracking at sharp corners below a radius of 0.5 mm, so rib roots are specified with a minimum radius of 0.8 mm and are located away from the sealing groove. Terminal articles are rigid handle substrates used in two-shot sonic toothbrush manufacturing.

    Downstream segmentNominal wall thicknessNozzle melt temperatureTool surface temperatureHold pressurePrimary defect controlled
    Cosmetic packaging shells0.6–0.9 mm230–240°C45–60°C50–70 MPaSplay and flow-line visibility
    Appliance control panel lenses2.0–2.5 mm230–245°C60–80°C60 MPa, 2 s; 30 MPa, 4 sGate-region stress whitening
    Blender jar bodies2.5–4.0 mm240–250°C70–80°C80–100 MPaSink and thread deformation
    Laboratory instrument windows2.0–3.0 mm230–245°C60–75°C50–70 MPaHinge-boss sink and cleaning-agent crazing
    Printer paper feed windows1.8–2.5 mm230–240°C55–65°C55–65 MPaRib-zone weld lines
    Powered toothbrush handle shells2.0–2.5 mm230–245°C50–65°C60–75 MPaSealing-groove out-of-roundness
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    Certification & Compliance
    More Introduction

    INEOS Styrolution Absolan SAN 2500 is a high-flow styrene-acrylonitrile copolymer supplied as a pelletized injection-moulding grade. The amorphous backbone places it within the INEOS Styrolution styrenics portfolio, where the acrylonitrile comonomer raises the softening temperature and chemical resistance relative to general-purpose polystyrene while retaining melt processability on conventional single-screw plasticating equipment. Published provisional data for the grade are associated with ISO 1133-1:2022 melt volume-flow rate measurements performed at 220 °C under a 10 kg mass, with a nominal value of approximately 25 cm³/10 min. Density is reported at 1.08 g/cm³ according to ISO 1183-1. Because the polymer is amorphous, moulding shrinkage is governed primarily by mould restraint, gate configuration, hold pressure, and packing time; the linear moulding shrinkage range is published as 0.4 % to 0.7 % under ISO 294-4.

    Mechanical property values are generated from injection-moulded test specimens under standard laboratory conditions. Tensile modulus is reported at 3800 MPa and tensile stress at yield at 75 MPa under ISO 527-2. Flexural modulus is typically quoted in the range of 3700 MPa to 3900 MPa by ISO 178. Notched Charpy impact strength at 23 °C is low and reflects the absence of a discrete elastomeric phase; a nominal value of 2.5 kJ/m² is obtained under ISO 179/1eA. Vicat softening temperature, reported as VST/B/50 under ISO 306, is 106 °C, and heat deflection temperature at 1.8 MPa is 98 °C under ISO 75-2. These values are single-point data from standard specimens and are not design allowables for load-bearing parts.

    ParameterNominal valueTest standard
    Melt volume-flow rate, 220 °C/10 kg25 cm³/10 minISO 1133-1:2022
    Density1.08 g/cm³ISO 1183-1
    Tensile modulus3800 MPaISO 527-2
    Tensile stress at yield75 MPaISO 527-2
    Charpy notched impact strength, 23 °C2.5 kJ/m²ISO 179/1eA
    Vicat softening temperature, VST/B/50106 °CISO 306
    Heat deflection temperature, 1.8 MPa98 °CISO 75-2

    What limits the use of a 25 cm³/10 min SAN grade in thick-section mouldings?

    The high melt volume-flow rate of Absolan SAN 2500 reduces injection time in multi-cavity tools, but it also lowers melt strength and narrows the processing window for thick-section parts. In mouldings with wall stock above 3 mm, low melt strength can produce flow marks, jetting, and inconsistent packing if the injection velocity is not profiled. The grade is therefore suited to thin-wall housewares, closures, personal-care components, and appliance panels where flow length-to-wall-thickness ratios are high. Production experience on toggle-clamp injection machines of 600 kN to 1200 kN clamping force indicates that filling a 0.8 mm to 1.2 mm wall two-cavity hot-runner tool at 240 °C melt temperature and 50 °C mould temperature requires a hold-pressure increase from 60 MPa to 90 MPa to prevent sink marks near the gate. Short shots are observed when back pressure is below 5 MPa because the melt cushion is not homogenized before transfer.

    For thick-wall components such as appliance handles, a lower-flow grade with higher melt strength is preferred. With Absolan SAN 2500, extended hold pressure can compensate for packing shrinkage, but the narrow freeze-off window makes the process sensitive to gate size. Gates below 1.0 mm diameter can freeze before the packing phase is complete, leaving voids or dimensional drift across a production run. The material is not suitable for continuous profile extrusion or high-draw blow moulding because the melt does not sustain the required parison stability.

    Injection Moulding Parameters, Shear Limits, and Hot-Runner Boundary Conditions

    Pellet drying is required under standard injection-moulding conditions. The grade is shipped in sealed packaging, but storage in an unheated warehouse above 60 % relative humidity can raise surface moisture to levels that cause silvering and gate splay. Pre-drying in a desiccant dryer with a drying-air dew point at or below −20 °C for 2 h to 4 h at 80 °C is recommended before processing. Dried pellets should be consumed within 30 min to 60 min if the hopper dryer is not fitted with a closed-loop dry-air circuit. The melt-temperature envelope is 220 °C to 260 °C at the nozzle. At barrel temperatures above 250 °C, residence time should be limited to 5 min to 8 min; prolonged exposure accelerates yellowing and shifts melt viscosity. A general-purpose screw with low to medium compression ratio and L/D ratio of 18 to 22 is adequate for the material. High-compression screws increase shear heating and can generate local melt temperatures above the set zone temperatures.

    Process parameterSet point or rangeEquipment condition
    Pre-drying temperature80 °Cdesiccant dryer, dew point ≤ −20 °C
    Pre-drying time2 h to 4 hvirgin pellets, closed hopper
    Melt temperature220 °C to 260 °Cinjection moulding, general-purpose screw
    Mould temperature40 °C to 60 °Ccontrolled water circuit
    Back pressure5 MPa to 10 MPahydraulic or electric screw recovery
    Maximum residence time5 min to 8 minbarrel at ≤ 250 °C

    Hot-runner systems with externally heated manifolds are preferred because of the narrow thermal control window. Internally heated torpedo systems can overheat rejected polymer at the gate, especially during colour changes or after short interruptions. In manifold systems, the hot-runner manifold should be set to maintain the melt at 240 °C to 250 °C, and the nozzle tips should be individually trimmed to prevent drool. Gate blush and surface streaking have been traced to excessive tip temperature rather than to melt moisture when the material is dried correctly.

    Typical application fields reported for the grade include cosmetic packaging, stationery barrels, transparent appliance covers, non-invasive medical device components, and thin-wall containers. In cosmetics packaging, the combination of high flow and low notched impact is acceptable for simple clamshell closures and compact bases; impact loading must be managed through wall thickness and external rib design. The polymer is not intended to replace polycarbonate or transparent impact-modified polymers in glazing or safety-critical covers. In stationery barrels, the high stiffness reduces flexing during writing; however, the low elongation at break means snap-fit assembly should use a generous lead-in angle and should not exceed 1.5 % outer-fibre strain.

    When Absolan SAN 2500 is substituted for general-purpose ABS in a rigid, transparent application

    Compared with general-purpose ABS, Absolan SAN 2500 contains no butadiene impact-modifier phase. The absence of butadiene provides higher transparency but reduces notched impact from the typical ABS range of 15 kJ/m² to 35 kJ/m² to the low single-digit range. This difference changes joint design. Snap-fits and ultrasonically welded bosses on an ABS part may need to be modified to lower insertion forces and to increase the radius at the base of cantilever hooks. The SAN component also has a higher elastic modulus than many general-purpose ABS grades; wall sections can sometimes be reduced if the loading is flexural, but the brittle failure mode prevents the use of thin film hinges or high-strain closures.

    Against general-purpose polystyrene, Absolan SAN 2500 has superior resistance to many oils, greases, and household cleaners. The acrylonitrile comonomer raises resistance to environmental stress cracking, but not to the level of a polycarbonate or an amorphous polyester. It is resistant to aliphatic solvents and aqueous detergent solutions, but prolonged contact with ketones, esters, or aromatic hydrocarbons can cause swelling, haze, or stress cracking. Published data for specific solvent combinations is limited; a wet patch test and stress-crazing evaluation under the intended service load should be performed before replacing polystyrene in a food-contact or cosmetic container.

    Regulatory Benchmarks and Incompatibility Boundaries

    For direct food-contact applications, compliance is governed by regional regulations. The grade may be supplied with a statement of compliance to European Commission Regulation (EU) No 10/2011 as amended, provided the final article is assessed for overall migration and specific migration of acrylonitrile. In the United States, food-contact status must be confirmed against 21 CFR 177.1040 for styrene-acrylonitrile copolymers, depending on use condition and contact type. No food-contact status should be inferred from the polymer name alone. Under European chemical management, REACH registration duties apply to the polymer as a whole. RoHS Directive 2011/65/EU thresholds for lead, mercury, cadmium, hexavalent chromium, PBB, and PBDE require a production lot test, not a type-based assumption.

    Material incompatibility with certain release additives is documented for styrene-acrylonitrile matrices. External lubricants based on low-molecular-weight amides and some metallic stearates can create haze or deposit on cavity surfaces over multi-day runs. Processing with colour concentrates containing unknown carriers at addition levels above 3 % can shift the flow curve and invalidate the published melt viscosity. For static-dissipative or filled compounds, mould wear and gate erosion are controlled by filler hardness; hard ceramic fillers may reduce tool life on unhardened tool steel. The polymer is not resistant to strong alkaline media at elevated temperature, and continuous contact with brake fluid, some plasticizers, or chlorinated solvents can produce softening and loss of dimensional stability.

    Because published data for this specific configuration is limited in application areas requiring prolonged outdoor exposure, the material should not be specified for UV-stabilized automotive exterior parts without additional weather testing. Where long-term light exposure is expected, a UV-stabilized or ASA-grade product from the same portfolio should be evaluated. In applications requiring repeated steam sterilization above 121 °C, the grade is unsuitable because the heat deflection temperature and Vicat softening point are below the autoclave hold temperature.

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