| HS Code | 947086 |
| Polymer Type | Acrylonitrile Butadiene Styrene (ABS) |
| Density | 1.04 g/cm³ (ISO 1183) |
| Melt Volume Flow Rate 220 C 10 Kg | 11 cm³/10 min (ISO 1133) |
| Molding Shrinkage Parallel | 0.4-0.7 % (ISO 294-4) |
| Tensile Modulus | 1900 MPa (ISO 527-2) |
| Tensile Stress At Yield | 40 MPa (ISO 527-2) |
| Tensile Strain At Yield | 2.5 % (ISO 527-2) |
| Charpy Notched Impact Strength 23 C | 30 kJ/m² (ISO 179/1eA) |
| Charpy Notched Impact Strength 30 C | 15 kJ/m² (ISO 179/1eA) |
| Vicat Softening Temperature B50 | 98 °C (ISO 306) |
| Deflection Temperature Under Load 1 80 Mpa | 80 °C (ISO 75-2/A) |
| Deflection Temperature Under Load 0 45 Mpa | 95 °C (ISO 75-2/B) |
| Rockwell Hardness R Scale | 100 (ISO 2039-2) |
| Flammability Rating | UL 94 HB (1.5 mm) |
As an accredited INEOS Styrolution ABS TERLURAN HI-18 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | INEOS Styrolution ABS TERLURAN HI-18 is supplied in 25 kg moisture-resistant bags, palletized for industrial handling and storage. |
| Container Loading (20′ FCL) | 20′ FCL container loaded with INEOS Styrolution ABS TERLURAN HI-18, palletized 25 kg bags, secured for sea transport. |
| Shipping | TERLURAN HI-18 is an ABS resin supplied as pellets and is generally non-hazardous, not classified for transport. Ship in dry, ventilated conditions in moisture-barrier bags, boxes, or octabins; avoid humidity, prolonged sunlight, heat, and ignition sources. |
| Storage | Store INEOS Styrolution ABS TERLURAN HI-18 in a cool, dry, well-ventilated area away from heat, ignition sources, and direct sunlight. Keep containers closed and palletized to prevent moisture pickup and contamination. Avoid dust generation and static discharge. Separate from strong oxidizers and incompatible chemicals. Follow supplier SDS, local fire codes, and facility storage regulations. |
| Shelf Life | Shelf life is typically 12 months when stored dry, below 30°C, in original unopened packaging, protected from moisture and sunlight. |
| Melt temperature at nozzle | Charpy notched impact retention at 23°C (ISO 179-1/1eA) | MVR shift (ISO 1133-1, 220°C/10 kg) | Surface defect manifestation |
|---|---|---|---|
| 230°C | 95–100% of reference | 19–21 cm³/10 min | Gate blush, flow hesitation at ribs |
| 250°C | 85–92% of reference | 24–27 cm³/10 min | Minimal; occasional gloss variance on textured surfaces |
| 270°C | 70–78% of reference | 32–36 cm³/10 min | Yellowing, silver streaks from additive volatilization, burning at shutdown residuals |
| Element | Category I migration limit (dry, brittle, powder-like or pliable) | Category II migration limit (liquid or sticky) | Category III migration limit (scraped-off) |
|---|---|---|---|
| Aluminium | 2.25 mg/kg | 0.56 mg/kg | 70.0 mg/kg |
| Barium | 4.5 mg/kg | 1.125 mg/kg | 18.75 mg/kg |
| Cadmium | 0.017 mg/kg | 0.00455 mg/kg | 0.17 mg/kg |
| Chromium (VI) | 0.00075 mg/kg | 0.00019 mg/kg | 0.000625 mg/kg |
| Lead | 0.45 mg/kg | 0.1125 mg/kg | 1.875 mg/kg |
| Mercury | 0.02 mg/kg | 0.005 mg/kg | 0.075 mg/kg |
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INEOS Styrolution ABS TERLURAN HI-18 is a high-impact acrylonitrile-butadiene-styrene injection moulding grade supplied as natural pellets. The material is based on a grafted polybutadiene rubber phase dispersed in a styrene-acrylonitrile copolymer matrix. The grade is positioned for technical components requiring an intermediate to high level of room-temperature toughness combined with practical flow length and dimensional stability in medium-to-large mouldings. Representative physical, mechanical and thermal properties from the current INEOS Styrolution technical datasheet are determined according to ISO 1183-1, ISO 1133-1, ISO 527-2, ISO 179-1/1eA and ISO 306/B50. The melt volume rate measured at 220 °C under 10 kg load is in the range 15–20 cm³/10 min, tensile modulus is approximately 2200 MPa, and notched Charpy impact strength at 23 °C is typically above 30 kJ/m². These values are supplied as representative batch data, not as guaranteed specification minima. Lot-specific values may shift with colourant loading, regrind content and moisture history.
Moisture control is the first process variable that determines whether the toughness stated on the datasheet appears in the moulded part. TERLURAN HI-18 should be dried in a desiccant dryer at 80 °C for 3–4 h before processing, with the feed air dew point maintained below -20 °C and residual moisture held below 0.1 %. At higher residual moisture levels, the butadiene phase interface can undergo hydrolysis during plasticating, producing surface splay, silver streaking, and a measurable loss of notched impact strength even when the moulded part appears otherwise acceptable. Production lines using central drying systems should verify that return air temperature at the hopper inlet does not drop below the set point when multiple machines draw material from a common manifold. On single-stage injection moulding machines, the plasticating unit should use a three-zone screw with an L/D ratio between 18:1 and 22:1 and a compression ratio in the range 2.0:1 to 2.5:1. A shallower compression section can generate insufficient dispersive mixing of the rubber phase, while an overly aggressive compression zone raises melt temperature through shear and may initiate rubber crosslinking. The melt temperature window for TERLURAN HI-18 is typically 230–260 °C. The lower limit is set by incomplete melting of the high-impact rubber fraction, which can leave visible gate-rupture marks and reduce weld-line strength. The upper limit is governed by thermal degradation of the styrene-acrylonitrile matrix and oxidative attack on the polybutadiene phase. If melt temperature exceeds 270 °C for extended residence time, the material can yellow, and decomposition by-products may generate gas voids and mould deposit formation.
Mould temperature has a direct effect on surface aesthetics and dimensional stability. A mould temperature range of 40–80 °C is commonly applied. Lower mould temperatures reduce cycle time but can freeze the flow front too early in thin ribs, increasing internal stress and lowering notched impact performance at knit lines. Higher mould temperatures improve gloss uniformity and reduce frozen-in orientation, but they can extend cooling time and promote sink marks over thick bosses. Injection speed should be selected to maintain a stable flow front without excessive shear heating. Because the rubber-modified melt exhibits non-Newtonian shear thinning, high volumetric flow through small gates can generate local temperatures well above the barrel set point. If gate blush or jetting is observed, reducing injection velocity and increasing gate land length are preferred over retarding the screw in a manner that lengthens recovery time. Melt cushion should be maintained between 3 mm and 6 mm on machines with properly sized shot capacity. A cushion below 2 mm risks loss of hold pressure at the gate, while an excessive cushion can contribute to residence-time variability and inconsistent switchover.
Wall thickness transitions determine whether the grade’s toughness is preserved in the final part. Sharp step changes from a nominal wall of 2.5 mm to a boss or rib base above 4 mm create differential cooling and can produce voiding even when the barrel melt temperature is within specification. Tooling with generous radii at rib intersections and a nominal wall thickness between 2.0 mm and 3.5 mm is preferable for high-impact ABS mouldings. Mould shrinkage for TERLURAN HI-18 is typically in the range 0.4–0.7 % depending on wall thickness, melt temperature, mould temperature and hold pressure. Where close-tolerance assembly is required, shrinkage should be established on a geometrically representative insert, not from flat plaque data alone.
On a production line for white-goods fascia panels, the pellet feed is conveyed through a central desiccant dryer set at 80 °C and then into a machine with a shot size that uses 40–70 % of the barrel capacity. Using this range prevents the combined problems of excessive residence time at low utilisation and poor melt homogeneity at high utilisation. Hold pressure is profiled to avoid overpacking near the sprue while maintaining sufficient pressure at the last-filled boss. If the fascia panel is subsequently painted, surface defects caused by moisture or excessive shear can appear only after the paint is cured, which makes in-process control of drying and melt temperature more important than simple visual acceptance at the press.
TERLURAN HI-18 differs from general-purpose ABS grades in the relationship between melt fluidity and impact resistance. Compared with a general-purpose grade such as TERLURAN GP-22, the HI-18 grade trades some tensile stiffness for a higher notched impact strength. The rubber phase also modifies scratch behaviour and gloss retention. In unpigmented natural form, high-impact ABS grades tend to show more visible scratch whitening than lower-rubber general-purpose grades because the dispersed polybutadiene particles undergo cavitation under surface stress. Compared with a lower-flow high-impact grade such as TERLURAN HI-10, the HI-18 grade has a higher melt volume rate at 220 °C under 10 kg. This improves filling of thin-wall sections and reduces injection pressure in multi-cavity tools, but it may result in slightly lower low-temperature toughness because the molecular weight and rubber crosslink density are balanced for flow as well as impact. When the application demands a harder surface and higher stiffness, a lower-impact ABS or a mineral-filled ABS is often selected. When the application requires outdoor UV stability, ASA grades such as those in the Luran S family are preferred because the acrylate rubber provides weatherability without the unsaturated butadiene groups present in TERLURAN HI-18.
| Property | Test method | Typical value |
|---|---|---|
| Density | ISO 1183-1 | 1.04 g/cm³ |
| Melt volume rate | ISO 1133-1 at 220 °C, 10 kg | 18 cm³/10 min |
| Tensile modulus | ISO 527-2 | 2200 MPa |
| Tensile yield stress | ISO 527-2 | 41 MPa |
| Charpy notched impact strength | ISO 179-1/1eA at 23 °C | 33 kJ/m² |
| Vicat softening temperature | ISO 306/B50 | 96 °C |
The tabulated values are representative mid-range figures from the manufacturer’s current published data. They should not be used as independent specification limits for incoming quality control unless the moulded component drawing formally adopts them with a defined test frequency and sampling plan. The notched impact value in particular is sensitive to specimen preparation, notch radius, conditioning time and moulding temperature. During incoming resin qualification, the practical comparison should be made on plaques moulded under stable, documented conditions, because the as-pellet melt flow value alone does not predict moulded part toughness.
Automotive interior trim substrates such as door trim panels and centre console carrier modules are common application areas for high-impact ABS grades. In such parts, the material is often moulded as a single large substrate that is later covered by a decorative skin or painted. For door trim production, tool filling is controlled with sequential valve-gate opening so that flow fronts meet at low velocity and weld lines form in non-visible zones. The grade’s melt viscosity allows filling of ribs and bosses without exceeding a mould clamping force that would require unnecessarily large presses. For a multi-cavity tool with part projected area exceeding 800 cm², the cavity pressure requirement is evaluated against the available clamp force, and the mould temperature is kept uniform within ±5 °C to avoid differential shrinkage across the part. If post-mould warpage appears, the correction is usually made by adjusting gate timing and hold pressure rather than by raising melt temperature, because higher melt temperature can reduce impact at weld lines.
TERLURAN HI-18 is not resistant to all chemical environments that may occur in service. Aromatic hydrocarbons, chlorinated hydrocarbons, ketones and esters can cause stress cracking in moulded ABS parts, especially when the part contains residual moulded-in stress from rapid cooling or overpacking. In applications involving incidental contact with such solvents, the moulder should evaluate the part under realistic load and temperature conditions, preferably using a strain-jig test rather than simple immersion of unstressed specimens. The grade is generally more suitable for contact with dilute aqueous solutions, soap and many household cleaners, but compatibility with proprietary cleaning agents should be tested because fragrance oils and solvent-based carriers can induce local attack at gate areas where frozen-in stress is highest.
When painting is required, surface preparation determines adhesion. The moulded surface should be free of silicone mould release and low-molecular-weight surface additives. A light cleaning with an isopropanol-water mixture or an approved adhesion promoter is commonly used before applying a two-component polyurethane coating. If the part is processed with excessive melt temperature, low-molecular-weight degradation products may migrate to the surface and reduce paint adhesion. For electroplating, the ABS grade must have a sufficiently uniform butadiene particle distribution so that chromic acid etching creates the required micro-cavities. Although high-impact ABS grades can be electroplated, etch time may need to be adjusted relative to lower-rubber ABS because the high rubber content can produce a more aggressive surface attack under standard plating-shop conditions. The selected plating line should therefore establish process parameters on a representative production lot of TERLURAN HI-18 rather than assuming that all ABS grades etch identically.
Moulders using regrind should limit the addition of dried, clean regrind to 20 % or less of the total feed by weight unless the application-specific mechanical tests demonstrate otherwise. Repeated processing increases the heat history of the rubber phase and can shift melt flow upward while lowering notched impact and changing colour. If regrind is used in visible unpainted parts, the lot should be blended under controlled gravimetric proportioning to avoid concentration drift during extended production runs. The same drying requirements apply to regrind and virgin material, because regrind can contain higher surface moisture than sealed virgin pellets after storage.