Products

INEOS Styrolution ABS TERLURAN GP-22

    • Product Name: INEOS Styrolution ABS TERLURAN GP-22
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    VTB
    Specifications
    HS Code 854859
    Density 1.04 g/cm³
    Meltvolumerate 19 cm³/10 min (220 °C/10 kg)
    Moldingshrinkage 0.4-0.7 %
    Tensilemodulus 2100 MPa
    Tensilestressatyield 44 MPa
    Elongationatbreak 20 %
    Charpynotchedimpactstrength 20 kJ/m² (23 °C)
    Hdt B 86 °C
    Vicatsofteningtemperature B50 97 °C
    Ballindentationhardness 95 MPa
    Ul94flammability HB (1.5 mm)

    As an accredited INEOS Styrolution ABS TERLURAN GP-22 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing INEOS Styrolution ABS TERLURAN GP-22 is packaged in 25 kg moisture-resistant paper sacks, palletized for safe industrial storage and handling.
    Container Loading (20′ FCL) 20′ FCL container loaded with INEOS Styrolution ABS TERLURAN GP-22 in 25 kg bags on pallets, securely stowed for ocean transport.
    Shipping INEOS Styrolution ABS TERLURAN GP-22 is shipped as dry thermoplastic pellets in 25 kg bags, octabins, big bags, or bulk silo trucks. It is not classified as dangerous goods for transport. Keep packaging closed, dry, and protected from sunlight and moisture; avoid excessive heat during storage and handling.
    Storage Store INEOS Styrolution ABS TERLURAN GP-22 in a cool, dry, well-ventilated area, away from direct sunlight, heat sources, and ignition risks. Keep in original, closed containers/packaging to prevent moisture, dust, and contamination. Avoid contact with strong oxidizers, acids, and bases. Maintain stable ambient temperature and good housekeeping; use proper grounding to control static where applicable.
    Shelf Life Typically 24 months from production when stored dry in original unopened packaging at ambient temperature, protected from moisture and direct sunlight.
    Application of INEOS Styrolution ABS TERLURAN GP-22

    In cordless handheld vacuum exoskeletons and benchtop appliance top covers, INEOS Styrolution ABS Terluran GP-22 is typically specified as an unfilled, general-purpose injection-molding feedstock with a melt volume-flow rate at 220°C and 10 kg load reported in the supplier’s published datasheet in the 22–24 cm³/10 min range according to ISO 1133-1. The grade’s practical niche on production lines is a balance between thin-wall fill performance in multi-cavity tooling and retained stiffness after demolding. Pre-drying at 80°C in desiccant-bed dryers to a residual moisture of ≤0.10% is required before processing; hydrolysis of the SAN matrix at the melt phase is otherwise observable as silver streaking, surface blush, and intermittent short shots across the cavity array. On a 350–500 tf hydraulic-clamp machine with a L/D 20–24 general-purpose screw and non-return valve, the usable melt-temperature window ranges from 230°C to 260°C, with steel mold temperatures between 35°C and 55°C delivered by water-circulation thermolators. Field variation in gloss on ribbed top covers frequently tracks the uncontrolled recovery stroke and melt-cushion fluctuation rather than the material specification; a cushion of 2–4 mm and a screw-back pressure of 5–10 bar hydraulic are common starting points for eliminating gate blush on directly fed sprue-gated tools. For appliance bodies subject to IEC 60335-1 external-impact clauses, polycarbonate-modified ABS or flame-retarded grades would be substituted only if the housing is partially contacting current-carrying parts; GP-22 in white and high-gloss pigmentation is generally limited to non-fire-enclosure portions of the appliance where glow-wire requirements do not exceed 650°C under IEC 60695-2-11. Regrind addition on these components is controlled at 15–20 wt% maximum when appearance is critical, because repeated heat history lowers the notched Charpy impact in ISO 179-1/1eA testing by 5–15% across regrind generations, a variance that is statistically visible in appliance drop-test protocols.

    What Changes When a High-Gloss ABS Bezel Falls Below 1.2 mm Nominal Wall?

    A reduction in nominal wall below 1.2 mm on display bezels and laptop keyboard decks shifts the limiting variable from thermal degradation to shear-induced free-jetting at the gate. At melt temperatures below 240°C, the unfilled melt can still fill a 1.0 mm wall at flow length-to-thickness ratios above 120:1, but only if injection velocity is profiled to maintain a constant melt-front velocity of 200–350 mm/s at the transducer. The pressure drop across a side-gated 8-cavity bezel tool frequently reaches 800–1,100 bar effective cavity pressure, requiring hydraulic system capability near the upper end for a 280 tf press. Packing time should be set by gate-seal time determined on the molding machine by weight-curve flattening; typical gate-seal values for a tunnel-gated bezel with 0.8 mm gate land are 3–6 s. Material variance is governed by ISO 294-3 for melt viscosity stability and ISO 1133-1 for lot-to-lot flow tracking. For electro-static discharge control in electronics assembly, the base GP-22 is not an inherently dissipative polymer; surface resistivity is in the insulating range above 10¹² Ω/sq under IEC 62631-3-2, so any claim of ESD-safe bezels requires an external antistatic coating or filled compound, not the base grade. If cosmetically sensitive high-gloss black covers are molded, the feed system should avoid hot-runner stagnation zones above 230°C; brown streaking from dead spots becomes visible after 20–30 min residence time. Use of a reverse-taper cold sprue with a 3–4° taper and positive sprue break improves color-change recovery on 80–120 s cycles. Post-industrial regrind for black bezels is limited to 10–15 wt% because higher levels reduce the 60° gloss reading measured under ISO 2813 and increase the probability of pigment specking in mirror-finish cavities.

    Under cabin heat-soak conditions approaching 90°C surface temperature on black trim panels, unfilled ABS GP-22 is specified for non-structural carriers such as air-vent louvre support frames, speaker grille backs, and center console side rails that are mechanically fastened rather than welded to polypropylene substrates. The grade’s Vicat softening temperature of ~96°C under ISO 306/B50 creates a narrow upper boundary for ribbed snap hooks under constant load; creep rupture on an undercut hook of 1.0 mm engagement can occur within hours if the cantilever is deflected beyond 0.8% outer-fibre strain at 80°C. Injection temperatures at the lower edge of the window, 220–235°C, are preferred for interior parts because lower residual thermal stress reduces post-molding breakage in solvent-containing assembly cleaners. The melt is predried to ≤0.08% moisture because the thinner 1.5–2.0 mm rib roots are more sensitive to moisture-driven delamination along weld lines than thick appliance panels. For automotive interior air quality, the component supplier should measure volatile organic compound desorption according to VDA 278:2011 on a painted and unpainted PP/ABS combination; published data for terpolymer-grade general-purpose ABS GP-22 specifically is limited in public databases, so release values must be verified on the actual tooled part and paint stack. Tight-tolerance datum features on the carrier are machined after sampling with 0.3–0.5 mm allowance because mold shrinkage in ISO 294-4 ranges between 0.4% and 0.7% and is anisotropic along flow direction. Regrind of glass-fiber-reinforced PP from the same assembly must be kept out of the ABS waste stream; as little as 0.5 wt% contamination is visible as surface inclusions and can initiate notch failure in ISO 179-1/1eU tests. Clean post-industrial regrind from non-appearance carriers can be re-added at up to 20 wt% if the incoming flake is dried to the same residual moisture limit as virgin pellets.

    When EN 71-3 Migration Limits Are Applied to Pigmented GP-22 Compounds

    Compounding of GP-22 with cadmium-free masterbatches for toy wheel hubs, construction-block frames, and ride-on vehicle body panels shifts the certification burden to the molder because the base pellet alone does not carry a toy-grade certificate. Under EN 71-3:2019+A1:2021, the migration limits for chromium(VI), lead, cadmium, and tin in the 0.07 M hydrochloric acid leachate vary by material category; ABS parts fall into Category I or II depending on whether the toy component is ingested or accessible. The molder should request masterbatch declarations covering REACH Annex XVII entries 51 and 52 for phthalate plasticizers, even though the GP-22 matrix is not intentionally plasticized, because let-down ratios of 2–4 wt% may introduce carrier resins containing DBP, DIBP, BBP, or DEHP above the combined 0.1 wt% threshold. Molded parts should be post-processed without gate trimming on edges accessible to a child unless a tumbler with 2–4 mm ceramic media is used to blunt sharp vestiges. The processing window for thick toy body panels with 2.5–4.0 mm wall is wider than for electronics, but sink marks on ribbed underbodies must be controlled by gas counter-pressure or by replacing solid ribs with dual thin ribs. A hydraulic pack pressure of 40–60 bar for 8–12 s on a 350 tf press is sufficient to consolidate the core; higher pack pressure transmits internal stress to the gate areas, creating white stress rings when the toy is dropped under EN 71-1 mechanical abuse tests. Because GP-22 is unfilled, sharp corners below 0.5 mm radius should be radiused to 0.5–1.0 mm to avoid notch-sensitive breakage. Field records from multi-cavity toy production indicate yellowing during hot-runner residence above 240°C is a batch-to-batch color-control issue; CIELAB b* values can shift by +0.6 to +1.2 after 45 min of hold time, requiring purging discipline during shift changes. Toy molders often limit regrind to 10 wt% or below despite the material’s ability to accept more, because impact retention after multiple heat histories becomes the controlling variable in edge-loaded boss areas.

    Application segmentStandard designationTest or clauseTypical requirement
    Small appliance housingsIEC 60335-1, IEC 60695-2-11Glow-wire ignition on external enclosureNon-fire-enclosure portions only; verify 650°C class
    Consumer electronics bezels2011/65/EU RoHS Annex II, EN IEC 63000Restricted substances screeningCd 0.01 wt%, Pb 0.1 wt%
    Automotive interior carriersVDA 278:2011VOC and FOG desorptionOEM-specific; public universal limit not defined
    Children’s toys and ride-on componentsEN 71-3:2019+A1:2021, REACH Annex XVIIElement migration and phthalate restrictionCategory I/II substance limits; phthalates combined 0.1 wt%
    Power tool housingsISO 179-1/1eANotched Charpy at 23°CMaterial comparison 20–25 kJ/m²; part-level drop test required
    Office equipment chassisIEC 60068-2-6Vibration and particulate auditPart-specific limit based on optical inspection

    Cordless drill motor housing halves and reciprocating-saw front boots are molded from GP-22 when the tool’s drop-test requirement is not driven by cold-impact below 0°C, as the grade’s ductile-to-brittle transition moves toward −10°C to −20°C depending on geometry and molded-in stress. Housing halves with 1.8–2.5 mm wall are pre-dried to ≤0.10% moisture and gated with a fan or tab gate at the motor-bearing boss to orient the melt front away from the weak weld line at the top of the handle. Field failures in corded orbital sander clamshells most often initiate at the screw-boss weld or at the snap-fit latch when melt temperature is below 230°C; a minimum melt temperature of 240°C at the nozzle improves knit-line strength in ISO 179-1/1eA notched Charpy by up to 15–20% relative to cold molding. For impact-sensitive areas, a 0.5–1.0 mm radius at the housing split line and a uniform wall transition of 1:2 are specified to avoid the notch effect around the motor flange. The material registers a notched Charpy impact of 20–25 kJ/m² at 23°C in supplier data when tested per ISO 179-1/1eA, but that value is specimen-dependent and cannot be used as a direct part-drop predictor without instrumented drop testing on the tooled housing. Overmolding with a TPU soft-grip in a two-shot or insert process requires the GP-22 first-shot surface to be maintained above 80°C at the bond interface, otherwise the TPU bond strength falls below practical peel resistance; surface contamination from mold-release spray must be zero in this zone. Use of internal air blow-off and venting gaps of 0.02–0.05 mm along the split line prevents gas burns at the end of fill, especially when the tool is run at cycle times below 45 s. Post-industrial regrind from sprues and runners is limited to 10–20 wt%, with tight incoming flake control because contamination from nylon snap rings or acetal dust causes visible delamination streaks in dark-colored tool shells.

    Ultrasonic Welding Joint Design and Cosmetic Reject Rates on GP-22 Office-Equipment Housings

    Ultrasonic welding of GP-22 to itself in printer paper-path frames is governed less by the polymer’s thermal properties than by joint configuration; a shear joint with 0.25–0.40 mm interference and a 60°–90° energy director angle produces tensile weld factors in the range of 0.7–0.9 of the parent ABS strength when tested under ISO 527-2 at 23°C. The process window narrows if the joint contains a textured cosmetic surface adjacent to the horn contact area; high amplitude above 30 µm or weld pressure above 2 bar is frequently linked to visible stress whitening on the outside of the housing, raising the cosmetic reject rate on matte black office-machine panels. Use of a 20 kHz titanium horn with a 1.5–2.0 s weld time and 0.5–0.8 s hold time is a conservative starting condition for a 2.0 mm wall joint, but the relation between weld depth and joint strength is not linear; beyond the energy-director collapse depth, additional energy simply melts the wall and can reduce the joint efficiency. Adhesive bonding with solvent-weld formulations based on methyl ethyl ketone or methylene chloride is not recommended for GP-22 because the grade’s butadiene-rich rubber phase can undergo stress-crazing at residual mold-stress concentrations around bosses and sharp internal corners; if solvent welding is unavoidable, the part must be annealed at 70°C for 2 h before application and the joint should be tested for environmental stress-cracking resistance under ISO 22088-3 bent-strip conditions. For laser-marked office equipment fascia, the base grade can be marked with a 1064 nm fiber laser at 20–30 W output and a 4–6 kHz pulse frequency to produce a high-contrast foamed mark, but color-dependent behavior means inventory of a single laser parameter set across multiple pigments is not valid; white and light-gray grades may require higher energy density or additive masterbatches. Regrind content is not permitted on laser-marked fascia if color drift and froth consistency are critical; if used in hidden paper-path frames, clean runner regrind is held at ≤10 wt% to maintain weld reproducibility. The critical cleanliness test for printer chassis is particulate shedding after vibration testing under IEC 60068-2-6; unfilled GP-22 generates few particulate contaminants compared with filled grades, but machined snap features and masked-off areas must be deburred because loose ABS dust is visible to automated optical inspection at 50 µm resolution.

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    Certification & Compliance
    More Introduction

    INEOS Styrolution ABS TERLURAN GP-22 is a general-purpose acrylonitrile-butadiene-styrene injection-moulding compound. The grade is supplied as natural or pre-coloured cylindrical pellets and is classified under ISO 2580-2 as an ABS injection-moulding material. Its nominal melt volume-flow rate under ISO 1133-1:2022 at 220 °C/10 kg is approximately 22 cm³/10 min, placing it in the medium-flow band of the Terluran ABS portfolio. Density under ISO 1183-1:2019 is approximately 1.04 g/cm³. Typical end-use sectors include electrical appliance housings, power-tool casings, sanitary fittings, automotive interior trim, and consumer packaging components. The material is not flame-retardant and is not pre-stabilised for long-term outdoor UV exposure unless a UV-stabilised colour masterbatch or black formulation is specified. Parts moulded from GP-22 are generally specified for wall thicknesses between 1.5 mm and 4.0 mm, where a combination of processable melt viscosity, moderate ambient-temperature impact strength, and rigidity is required.

    The grade differs from high-flow GP-35 and high-impact HI-10 principally through the rubber-phase volume and molecular weight modification that control melt flow and notched impact response. GP-22 does not provide the lowest melt viscosity in the Terluran injection-moulding range, nor does it provide the highest impact resistance. Its selection is therefore governed by tooling conditions in which GP-35 may require excessively high melt temperatures to avoid short shots, or where HI-10 may be unnecessarily expensive and difficult to fill in thin-wall areas. The transition from GP-35 to GP-22 in identical multi-cavity tooling is normally associated with a measurable increase in injection pressure because of lower MVR, but also with improved Charpy notched impact strength under ISO 179-1/1eA. The trade-off is not linear and is best assessed using injection-moulding simulation data based on manufacturer viscosity curves.

    Does GP-22 retain sufficient notched impact resistance at sub-zero service temperatures when replacing HI-10 in appliance housings?

    Published representative data for GP-22 under ISO 179-1/1eA list Charpy notched impact strength of approximately 17 kJ/m² at 23 °C and approximately 8 kJ/m² at −30 °C. High-impact Terluran HI-10 is reported at approximately 28 kJ/m² at 23 °C and approximately 10 kJ/m² at −30 °C under the same test configuration. The lower rubber content of GP-22 therefore produces a stiffer tensile response but reduced low-temperature ductility. For refrigerator trim, freezer frames, or outdoor equipment handles that may be impacted below 0 °C, the controlling design value is not the ambient notched Charpy figure but the −30 °C result combined with part thickness and residual moulded-in stress. GP-22 is not equivalent to HI-10 under those conditions. If the loading mode is dominated by high-speed puncture rather than notch propagation, instrumented puncture testing under ISO 6603-2 should be performed before substitution is accepted. Published data for GP-22 in that specific high-speed puncture configuration is limited, and end-users should require lot-specific validation from the resin supplier.

    Table 2: Nominal portfolio differences for Terluran injection-moulding grades
    Grade Nominal MVR (ISO 1133-1:2022, 220 °C/10 kg) Charpy notched impact strength (ISO 179-1/1eA, 23 °C) Tensile modulus (ISO 527-1/-2)
    GP-22 22 cm³/10 min 17 kJ/m² 2300 MPa
    GP-35 35 cm³/10 min 13 kJ/m² 2300 MPa
    HI-10 10 cm³/10 min 28 kJ/m² 2000 MPa

    The values in Table 2 are representative lot averages taken from published manufacturer data and are not guaranteed specification limits. They define the distinguishing portfolio position of GP-22: a medium-flow grade with higher impact strength than GP-35 but lower impact strength than HI-10, while retaining a tensile modulus equivalent to or higher than both grades. In applications where the tool has restricted runner diameters or long flow paths, GP-22 is selected over HI-10 because its lower melt viscosity reduces pressure drop. In applications where impact is not the primary mechanical requirement but weld-line integrity matters, GP-22 is selected over GP-35 because the higher molecular weight component reduces notch sensitivity at knit-line regions.

    Mechanical and thermal property profile for natural GP-22 injection-moulded test specimens

    The following property set represents the typical short-term mechanical and thermal response of injection-moulded GP-22 test plaques. Values are dependent on mould temperature, gate size, and melt temperature; end-users should evaluate parts under the actual moulding conditions specified for production.

    Table 1: Representative property data for INEOS Styrolution TERLURAN GP-22
    Property Test method Unit Representative value
    Density ISO 1183-1:2019 g/cm³ 1.04
    Melt volume-flow rate ISO 1133-1:2022, 220 °C/10 kg cm³/10 min 22
    Tensile modulus ISO 527-1/-2 MPa 2300
    Tensile stress at yield ISO 527-1/-2 MPa 45
    Tensile strain at yield ISO 527-1/-2 % 2.6
    Flexural modulus ISO 178 MPa 2200
    Flexural strength ISO 178 MPa 65
    Charpy notched impact strength, 23 °C ISO 179-1/1eA kJ/m² 17
    Charpy notched impact strength, −30 °C ISO 179-1/1eA kJ/m² 8
    Vicat softening temperature VST/B/50 ISO 306 °C 95
    Heat distortion temperature HDT/A, 1.8 MPa ISO 75-2 °C 94
    Coefficient of linear thermal expansion, parallel ISO 11359-2 × 10⁻⁶ K⁻¹ 90
    Mould shrinkage ISO 294-4 % 0.4–0.7
    Water absorption, 23 °C, 50% RH ISO 62 % 0.25
    Ball indentation hardness ISO 2039-1 MPa 95

    In the as-moulded condition, the combination of Vicat softening temperature at 95 °C under ISO 306 and heat distortion temperature at 94 °C under ISO 75-2 limits continuous service temperature in load-bearing applications. The coefficient of linear thermal expansion of approximately 90 × 10⁻⁶ K⁻¹ means that assembled components with metallic inserts or rigid mating parts require expansion clearance when operating temperature differences exceed 30 °C. Mould shrinkage between 0.4% and 0.7% under ISO 294-4 must be corrected for cavity-to-cavity variation and gate location. In parts with wall thicknesses above 3.0 mm, the higher thickness section can produce sink marks and dimensional variation beyond 0.05 mm, requiring gas counter-pressure or foaming processing if tight ISO 2768 classifications are specified.

    When melt pressure and gate-freeze constraints govern thin-wall processing

    Before melt processing, GP-22 granulate requires drying in a desiccant dryer at 80 °C for 2–4 h. Residual moisture above 0.10 wt%, measured by ISO 15512, causes hydrolysis of the rubber phase during melt processing and produces surface splay, silver streaks, and a loss of Charpy notched impact strength in the finished part. The dryer should achieve a dew point of −20 °C or lower. In installations with open conveyors or long hopper residence times at relative humidity above 60%, drying must be extended to 4 h and the material should be conveyed under dry air or nitrogen.

    Barrel temperature settings for a general-purpose three-zone screw with L/D ratio between 19:1 and 22:1 are typically 200–220 °C in the feed zone, 220–240 °C in the compression zone, and 230–250 °C in the metering zone. Nozzle temperature is held at 235–250 °C. Melt temperature measured by a pyrometer should not exceed 250 °C. At melt temperatures above 250 °C or residence times exceeding 5 min, the polybutadiene phase can oxidise and coagulate, producing yellowing and a reduction in notched impact strength of more than 20%. Screw recovery time should be shorter than the part cooling time; if recovery time exceeds cooling time, screw speed of 60–120 rpm is usually increased, but this increases shear heating in the melt pool and may produce localised melt temperatures above the barrel set point.

    Mould temperature control is specified between 40 °C and 80 °C. Lower mould temperatures reduce cycle time but increase residual stress and reduce weld-line strength. Higher mould temperatures above 80 °C improve knit-line appearance and surface gloss but can cause dimensional distortion in deep-draw parts and may extend cycle time beyond economically acceptable limits. Injection pressure is typically 70–120 MPa, with holding pressure 50–80% of peak injection pressure. The holding pressure must be maintained until gate freeze-off; gate diameter for edge or submarine gates at wall thicknesses between 2.0 mm and 3.0 mm is generally 0.8–1.2 mm. Gate land length should not exceed 1.0 mm to avoid premature gate freeze.

    A shut-off nozzle is recommended because GP-22 is a free-flowing ABS and can exhibit nozzle drool at melt temperatures above 240 °C. When hot-runner systems are used, needle shut-off gates reduce drool and provide positive gate sealing. Imbalanced multi-cavity runner layouts produce cavity-to-cavity weight variation above 1.5% with GP-22 because the lower melt flow compared with GP-35 increases sensitivity to shear-induced temperature differences in the runner. Flow simulation using viscosity data from the manufacturer should be used when flow length exceeds 120:1 relative to wall thickness.

    Regulatory compliance and chemical incompatibility boundaries

    Standard GP-22 is supplied to comply with Directive 2011/65/EU RoHS Annex II restrictions for lead, cadmium, mercury, hexavalent chromium, polybrominated biphenyls, and polybrominated diphenyl ethers; compliance is by supplier declaration. Under REACH Regulation (EC) No 1907/2006, standard GP-22 is supplied without intentional addition of substances of very high concern above the communication threshold of 0.1% w/w per Article 33; however, regulation changes and regional subsets require confirmation from the manufacturer for the specific lot and colour formulation. Food-contact status for GP-22 is grade-specific and article-specific. Natural GP-22 does not automatically comply with all migration limits under EU Regulation (EU) No 10/2011, and the final article must be tested for overall migration and specific migration of monomers and additives. US food-contact status must be confirmed under the applicable sections of 21 CFR for acrylonitrile copolymer resins; article-specific migration testing is required because processing conditions can alter residual monomer levels.

    GP-22 is not resistant to ketones, esters, aromatic hydrocarbons, chlorinated solvents, or concentrated oxidising acids. Moulded parts with high residual stress can develop environmental stress cracking when exposed to these chemicals, even at low surface concentration. Resistance to methanol, ethanol, and dilute acids is moderate but depends on injection-induced stress and service temperature. Continuous immersion in hot water above 60 °C is not recommended because hydrolysis of the acrylonitrile component can reduce molecular weight and impact strength over extended contact. The grade is also not intended for direct UV weathering without protection; unstabilised natural parts exposed outdoors can fail by surface chalking and embrittlement within 12–24 months depending on latitude and radiation dose. If outdoor use is specified, black formulations with carbon black loadings above 1.5 wt% or UV-stabilised custom masterbatches are required, and the selected colourant package must not contain amine-based additives that can accelerate oxidative degradation of the polybutadiene phase during melt processing.

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