| HS Code | 522540 |
| Density | 1.05 g/cm³ |
| Polymer Type | Acrylonitrile Butadiene Styrene (ABS) |
| Processing Method | Injection Molding |
| Melt Volume Flow Rate 220 C 10 Kg | 12 cm³/10 min |
| Tensile Modulus | 2200 MPa |
| Tensile Strength | 45 MPa |
| Elongation At Break | 20% |
| Charpy Notched Impact Strength 23 C | 15 kJ/m² |
| Vicat Softening Temperature B 50 | 100°C |
| Heat Deflection Temperature 1 8 Mpa | 95°C |
| Molding Shrinkage | 0.4-0.7% |
| Ul 94 Flammability Rating | HB |
| Surface Resistivity | >1E15 ohm |
| Volume Resistivity | >1E15 ohm·cm |
| Water Absorption 24 H | 0.3% |
As an accredited INEOS Styrolution ABS NOVODUR PH-AT factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | INEOS Styrolution ABS NOVODUR PH-AT is packaged in 25 kg moisture-barrier bags, stacked on pallets and stretch-wrapped for safe transport. |
| Container Loading (20′ FCL) | 20′ FCL container loaded with INEOS Styrolution ABS NOVODUR PH-AT in original packaging, evenly distributed, strapped, lashed, and secured for ocean transport. |
| Shipping | Shipping description: **INEOS Styrolution ABS NOVODUR PH-AT**; acrylonitrile-butadiene-styrene (ABS) copolymer, solid pellets; non-hazardous and not classified as dangerous goods for transport; ship in dry, closed packaging/containers, protected from moisture and direct sunlight; no UN number or hazard class required. |
| Storage | Store INEOS Styrolution ABS NOVODUR PH-AT in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and ignition sources. Keep containers tightly closed to protect from moisture, UV radiation, and oxidizing agents. Avoid prolonged storage above 30°C. Use original packaging, prevent dust accumulation, keep away from food and drink, ensure proper labeling, and follow local safety regulations. |
| Shelf Life | Shelf life is typically 24 months when stored dry and cool in original, unopened packaging. |
In automotive cockpit programmes, the substrate for instrument cluster hoods, centre console side covers, and door trim garnish rails is usually injection-moulded from a high-impact ABS rather than a lower-cost polypropylene because the part must reconcile long-term heat ageing under solar load with cold-temperature impact during side-impact trim retention. INEOS Styrolution ABS NOVODUR PH-AT is processed for these components with a melt temperature of 240°C to 260°C and a steel mould temperature of 50°C to 70°C; the published melt volume rate under ISO 1133-1:2022 at 220°C/10 kg is approximately 26 cm³/10 min, which permits filling of ribbed substrates without forcing injection pressures above 120 MPa in thin gate drops. Pre-drying in a desiccant dryer at 80°C for 2–4 h is necessary when the ambient relative humidity exceeds 60%, with residual moisture held below 0.1% because water vapour at the melt front produces splay and weakens knit-line strength at the base of snap-fit towers.
Heat resistance is not specified by HDT alone; dark-coloured dash trim must pass OEM heat-soak cycles at 110°C for 500 h without visible grain washout, unacceptable gloss reduction, or distortion that exceeds 1 mm across a 100 mm span. The Vicat softening temperature of NOVODUR PH-AT under ISO 306/B50 is reported by the manufacturer at approximately 104°C, and the heat deflection temperature under ISO 75-2:2024 method A at 1.8 MPa places the material in the upper range of general-purpose ABS. Components that are painted after moulding should be stress-relieved at 80°C for 1 h before coating; moulded-in stress concentrates at the transition from a thick boss to the nominal wall and can cause solvent-induced cracking when aggressive adhesion promoters are applied.
On production lines, failure modes observed in this application include gate blush when the melt front velocity exceeds 250 mm/s, delamination of multi-cavity hot-runner tips due to thermal imbalance, and flow lines around openings for defroster grilles. Use of a general-purpose screw with 20:1 to 22:1 L/D and a compression ratio of 2.3:1 to 3.0:1 is adequate, provided the screw and barrel are purged; residual acetal or PVC in the plasticating unit accelerates degradation of the butadiene phase and produces brown streaks. The grade is not qualified as a low-emission ABS under VDA 278 unless the specific lot is certified by the supplier; if the cockpit programme requires fogging below 2 mg in VDA 278, additional batch screening is required.
Hand-held power tool enclosures are structural shells that must withstand 1 m drops onto concrete at −20°C, motor vibration, and screw-boss pull-out forces during service; the controlling resin property is therefore not the room-temperature Charpy value but the low-temperature energy absorption measured with ISO 179-1/1eA on notched specimens. NOVODUR PH-AT is evaluated with a notched Charpy impact of approximately 10 kJ/m² at −30°C; this is sufficient for clamshell housing walls of 2.5–3.0 mm nominal thickness when the design avoids internal radii below 0.5 mm and gates are located away from high-inertia motor mounting points.
Screw bosses in power tool housings are a common fracture initiation site because the self-tapping screw diameter generates hoop stress at the boss root. The recommended boss outer diameter is 2.0–2.5 times the screw nominal diameter, with a wall thickness of 40–60% of the adjacent nominal wall and a height-to-outer-diameter ratio below 3.0:1. The material’s low viscosity allows filling of bosses attached to the outer shell via 1.5 mm ribs without excessive sink; however, packing at 50–70 MPa hydraulic pressure is required to avoid microvoids at the boss base. In destructive pull-out tests performed on production tools, failures are most frequently observed as radial cracks radiating from the boss base, which indicates insufficient melt temperature or premature gate freeze.
The housing halves are joined by ultrasonic welding or self-tapping screws; for ultrasonic welding, a shear joint with interference of 0.2–0.4 mm, weld depth of 1.0–1.5 mm, amplitude of 30–45 µm at 20 kHz, and horn pressure of 0.15–0.25 MPa gives consistent joint strength in ABS. Compliance with IEC 62841-1:2014 is determined on the complete assembled tool; the resin alone does not confer compliance. Because NOVODUR PH-AT is normally listed as UL 94 HB at 1.5 mm, it is not suitable for enclosures where the end-product standard requires a V-0 barrier near uninsulated live parts.
Painted exterior components such as mirror housings, B-pillar covers, and tailgate spoiler side trims are specified on the basis of the complete coating stack after cure, not solely on base resin HDT. The ABS substrate is flame or atmospheric-plasma treated to raise surface energy above 44 mN/m before application of a two-component polyurethane or acrylic clearcoat; an untreated ABS surface often measures below 34 mN/m, causing solvent-borne primers to bead or delaminate. Adhesion is checked with ISO 2409:2020 cross-cut tape tests, and stone-chip resistance is evaluated according to DIN EN ISO 20567-1:2021 with 500 g of chilled cast iron shot at −20°C or with the specific OEM method required by the vehicle platform.
High-gloss painted exteriors require mould surfaces finished to SPI/SPE A2 or better, and mould release agents containing silicone or amine are incompatible because they reduce paint adhesion; ejector pin marks and gate vestiges below 0.15 mm are tolerated only outside Class A sight lines. The mould temperature is held at 70–80°C to reduce frozen-in molecular orientation near the gate and to improve flow-line concealment under low film-build topcoats. If the substrate is painted with a solvent-borne primer, residual stress at the gate region can cause paint popping after oven cure at 80°C for 30 min; stress-relief annealing at 80°C for 1 h prior to coating is therefore applied to components with complex gate regions.
Weathering of unpainted ABS leads to photo-oxidation of the butadiene phase and a rapid loss of surface gloss; therefore all exterior applications must be fully coated or metallized. The grade’s thermal resistance accommodates the short oven cycles used in class A coating lines, but sagging or deformation can occur if fixtures do not support large thin-wall parts above 90°C. Published data for this specific painted configuration is limited; paintability trials on production tools are required because pigment type, filler content, and mould release residue each change the adhesion performance.
Decorative chrome-plated ABS parts such as radiator grille surrounds, boot lid trim, and wheel cover accents are not selected on notched impact alone; the microstructure of the moulded surface controls whether chromic–sulfuric etching can anchor the electroless deposit. The industrial etch bath is maintained at 380–400 g/L chromium trioxide, 200–400 g/L sulfuric acid, and 60–70°C, with immersion times of 5–15 min; the oxidizing solution attacks the butadiene-rich domains and leaves sub-micron cavities that retain palladium-tin catalyst after neutralization and reduction. Operating limits are critical: trivalent chromium above 25 g/L reduces etch rate, and dissolved ABS fines require continuous filtration to avoid non-uniform pit density.
After activation, the deposition sequence is normally electroless nickel at 0.2–0.5 µm, bright acid copper at 20–30 µm, bright nickel at 10–15 µm, and decorative chromium at 0.3–0.5 µm; the copper layer absorbs thermal stress, while the nickel provides leveling and the chromium provides surface hardness. Thermal cycling adhesion is assessed under ISO 4525:2003 conditions, typically 30 min at 85°C followed by 30 min at −30°C, with no blistering or peeling allowed on visible surfaces. For NOVODUR PH-AT, published electroplated adhesion data for this specific configuration is limited; the grade’s high heat resistance reduces distortion during the heated etch and plating baths, but part geometry, gate location, and mould temperature still alter the etch pit density.
Electroplating-grade ABS parts are moulded with slower injection velocities than standard cosmetic parts because high shear freezes orientation that resists uniform etching. Mould temperatures are usually set at 60–80°C, and gates are moved to non-critical areas or fan gates are used to minimise visible flow fronts. A major processing incompatibility is silicone-containing mould release; even traces cause skip plating and blistering and cannot be removed by acid etch. Chromium plating on ABS is not suitable for service above 80°C continuous because the metal-polymer thermal expansion mismatch can initiate microcracking at the interface.
A battery-powered diagnostic device enclosure is not a homogeneous mechanical design problem; it combines snap-fit closures, LCD window frames, and printed circuit board standoffs that must survive repeated opening and accidental side impacts without cracking at the screw boss roots. The material is processed at a melt temperature of 230–250°C and a mould temperature of 40–60°C for wall sections down to 1.8 mm; flow length-to-wall-thickness ratios are maintained below 120:1 to avoid short shots at the last-fill snap arms. Pre-drying at 80°C for 2–3 h is mandatory because wet pellets generate splay and reduce knit-line strength at the junction between wall and snap features.
Snap-fit retention in ABS requires strain at the flexural hinge to remain below approximately 0.8% for repeated assembly; higher strain leads to stress whitening and eventual fracture. The notched impact performance of PH-AT allows snap arms with a thickness of 1.0–1.2 mm and a deflection of 0.5 mm for typical battery-cover latches; however, living hinges should not be designed in ABS because the butadiene phase has limited flexural fatigue resistance. For enclosures with internal metal housings or connectors, creep-aged ABS at 60°C can lose 30–40% of its initial assembly force; published long-term relaxation data for this specific grade at elevated temperature is limited.
Flammability classification is performed to IEC 60695-11-10, and PH-AT is typically rated UL 94 HB at 1.5 mm; the enclosure can be used only for battery-powered or low-power peripheral devices where the end-product standard does not require a V-0 barrier. Electrostatic discharge control requires a conductive coating or ionizer because natural ABS has a surface resistivity near 10^14 Ω/sq under IEC 61340-2-3 and cannot dissipate static charges from moving belts or connectors. If the housing is painted with a solvent-based EMI shield, the same solvent-stress limitations as exterior paint apply at boss roots and weld lines.
Household appliance fascia moulding requires dimensional stability after contact with warm detergent solutions, not simply short-term HDT. The finished part is normally tested with the ball pressure method under IEC 60695-10-2:2021 at 75°C or 125°C depending on the insulation separation requirement; an ABS with Vicat B50 near 104°C under ISO 306/B50 passes the 75°C condition but may require post-mould annealing at 80°C for 1 h to meet the higher temperature condition if sink marks and frozen-in stress are present. Components such as washing machine control panel carriers, vacuum cleaner wheel housings, and refrigerator end caps are moulded on 800–1,600 t presses with hot runner valve gates; the grade’s melt volume rate supports filling of 1.5 mm ribs without overpacking adjacent thick bosses, but cavity-to-cavity flow balance must be maintained within 5% fill time to avoid warpage.
Chemical resistance is process- and stress-dependent; PH-AT withstands repeated exposure to dilute nonionic and anionic detergents but not ketone-containing cleaners, esters, or concentrated aromatic hydrocarbons. Contact with undiluted citrus-based degreasers is a known stress-cracking risk in ABS and should be evaluated with ISO 22088-3:2021 bent-strip tests before field use. Dimensional stability after warm detergent exposure is measured as linear change under ISO 175:2010 and is typically below 0.5% for short-term immersion at 60°C; continuous use above this temperature in water contact is not recommended.
For high-gloss cosmetic surfaces, mould temperature is set at 60–80°C and the tool is maintained without silicone release agents; for textured surfaces, a lower mould temperature near 40°C reduces gloss variation but increases moulded-in stress and should be paired with reduced hold pressure. A major processing boundary is residence time: at melt temperatures above 250°C, total residence time in the barrel should not exceed 5 min, and shutdown procedures should include purging with a general-purpose ABS or acrylic to avoid butadiene phase degradation. The grade is not intended for direct food contact or potable water contact without a separate food-contact certification from the supplier under EU 10/2011 or FDA 21 CFR 177.1020.
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INEOS Styrolution ABS NOVODUR PH-AT is an unfilled acrylonitrile-butadiene-styrene copolymer supplied as pellets for injection molding and is principally specified for electroplated components that must withstand elevated service temperatures. The grade belongs to the Novodur family and differs from high-flow general-purpose ABS formulations by a narrower polybutadiene rubber particle-size distribution and a styrene-acrylonitrile matrix tuned for controlled chromic acid etching. Producer documentation lists the melt volume-flow rate under ISO 1133-1:2022 at 220°C/10 kg within the range of 18–25 cm³/10 min, with density under ISO 1183-1:2019 near 1.04 g/cm³. Exact lot values are controlled by the manufacturer’s certificate of analysis rather than by nominal literature values.
Incoming material acceptance commonly includes moisture analysis, melt volume-flow rate trending, and Vicat softening temperature verification under ISO 306:2013, method B50. The grade is not a direct drop-in replacement for lower-heat ABS if tooling is designed for very high-flow grades. When PH-AT is substituted into an existing tool, gate geometry and packing pressure must be revalidated because melt-flow length and gate-seal behavior are likely to differ. Raw material batches should be stored in sealed containers at 15–30°C; opened containers should be consumed from dry-air hopper systems after immediate transfer.
Drying is the first boundary condition. Moisture must be reduced below 0.10% before plastication. Desiccant drying at 80°C for 2–4 h is the standard starting condition, but residence time must be extended when granules have been stored at relative humidity above 60% or when regrind content is introduced. Regrind for electroplating parts should be restricted to 20–30% maximum of mixed material, and only from hot-runner purgings or sprues that have not contacted mold-release sprays. Excessive moisture or contaminated regrind produces splay, silver streaks, and subsurface porosity that becomes visible after electroplating as blisters or skip plating.
Plastication is normally performed with a three-zone screw having an L/D ratio of 20:1–24:1 and a compression ratio of 2.0:1–2.5:1. Barrel zones are typically profiled from 220°C near the feed throat to 245°C at the nozzle, with the actual melt temperature confirmed by hand probe and held below 250°C. Residence time above 240°C should not exceed 5 min; longer dwell thermally oxidizes the polybutadiene phase and generates brown streaking, styrene monomer odor, and reduced etch uniformity. On production lines with hot-runner systems, the hot-runner manifold should be controlled in zones no higher than 245°C, and stagnant drops must be purged after color changes or shutdowns.
Mold temperature control exerts a larger influence on electroplating performance than is typical for unpainted ABS. The mold surface should be held at 50–70°C using positive-temperature-control units with a maximum variation of ±2°C across the cavity. Lower mold temperatures increase frozen-in molecular orientation and residual stress near the surface, causing non-uniform oxidation during chromic acid etching. High-gloss plating tools require polished cavities with surface roughness below 0.05 µm Ra; textured surfaces are generally avoided because etch depth and electroless deposition are difficult to control on rough topography.
Injection speed and hold pressure must be determined by flow simulation and gate-seal experiments. Fill speed is typically set high enough to avoid premature solidification of the flow front but low enough to avoid jetting at gates and weld-line venting. Hold pressure is normally 50–70% of the peak injection pressure and must be maintained past gate freeze. Weld lines in plated parts are critical because they can etch preferentially, and peel strength there may drop below 1.0 N/mm if the weld line is poorly packed. For large radiator grilles or wheel covers, sequential valve-gate control and cavity pressure sensors are preferred to maintain a stable flow-front velocity and uniform packing across sections from 2.0–3.0 mm nominal wall thickness.
Capillary rheometry under ISO 11443:2014 at 240°C typically shows shear-thinning behavior, but melt volume-flow rate alone is insufficient for predicting filling pressure in hot-runner tools. Mold-filling simulations should include measured shear-viscosity curves and pressure-volume-temperature data rather than a single flow number. Cold-runner systems should avoid undersized sprues; sprue and runner diameters below 4 mm can freeze prematurely if melt temperature is at the lower end. For a part with projected area of 0.40 m² and peak cavity pressure of 35 MPa, the theoretical clamp force demand is 14,000 kN; a machine with 16,000 kN clamp force leaves only 12.5% margin. Clamp tonnage should not be reduced below calculated demand when processing PH-AT because flash can alter surface tension and plate uniformity.
When the molded substrate enters the electroplating line, the surface preparation sequence rather than the raw ABS datasheet determines final metal adhesion. The typical sequence for platable ABS begins with an alkaline cleaner, followed by a chromic-sulfuric acid etch at 60–68°C for 5–15 min. The etch selectively oxidizes polybutadiene domains to create submicron pits that anchor electroless metal. PH-AT is formulated so that the rubber-phase particle density and distribution produce etch topography with sufficient mechanical keying without excessive surface erosion. A high-flow general-purpose ABS with the same melt volume-flow rate may not provide the same etch uniformity because its rubber phase is optimized for impact dissipation rather than controlled oxidation.
After etching, the part is neutralized to remove hexavalent chromium residues, activated with a palladium-tin colloid, and coated with electroless nickel or copper. Electrolytic copper, nickel, and chromium are then deposited to the required OEM thickness. Adhesion is verified by peel testing according to ASTM B533 or an equivalent OEM method. Many automotive decorative-plating specifications require initial peel strength above 1.0 N/mm, with no blistering or loss after thermal cycling. Published comparative data for PH-AT across all bath chemistries is limited; adhesion values are influenced by molding parameters, gate location, mold temperature, and bath age more heavily than by the base resin alone.
Mold release agents and silicone-containing external lubricants must be excluded from the process because they contaminate the etch and activation baths and produce skip plating. The same restriction applies to maintenance sprays, hydraulic oil leaks near clamp units, and zinc stearate-based purging compounds. If a purging compound is required, the supplier should confirm that the purge is free of migrating metallic soaps. In addition, part design for plating should avoid sharp edges with radii below 0.5 mm; high current-density regions at edges can produce non-uniform metal thickness and adhesion loss after thermal cycling.
Post-plating quality evaluation includes thermocycling per OEM schedules, often comprising repeated cycles between -30°C and 80°C with water immersion, followed by cross-hatch, peel, and microscopic inspection. Blisters in the plated layer are typically traced to gas entrapment at weld lines, not to poor metal adhesion; the corrective action is to increase packing and mold temperature or to move the gate. Failure analysis on production-scale lines shows that variations in peel strength across the same part correlate with molded-in stress, which can be mapped by annealing the unplated part above 80°C for 1 h and observing distortion.
The following values are representative of unfilled electroplating ABS of the PH-AT product class and should not be used as lot-specific specification limits. Table 1 consolidates typical property ranges reported in producer technical literature for electroplating ABS and compares them with the broad envelope for high-flow general-purpose ABS injection-molding grades.
| Parameter | Test method | Unit | PH-AT typical range | General-purpose ABS typical range |
|---|---|---|---|---|
| Density | ISO 1183-1:2019 | g/cm³ | 1.04–1.05 | 1.03–1.05 |
| Melt volume-flow rate | ISO 1133-1:2022 at 220°C/10 kg | cm³/10 min | 18–25 | 25–40 |
| Tensile yield stress | ISO 527-2:2012 | MPa | 42–46 | 38–45 |
| Tensile modulus | ISO 527-2:2012 | MPa | 2200–2500 | 1900–2400 |
| Flexural modulus | ISO 178:2019 | MPa | 2200–2500 | 1900–2400 |
| Charpy notched impact, 23°C | ISO 179-1eA:2010 | kJ/m² | 20–26 | 18–30 |
| Vicat softening temperature, B50 | ISO 306:2013 | °C | 98–103 | 94–99 |
| HDT A, 1.8 MPa | ISO 75-2:2013 | °C | 94–98 | 88–95 |
The principal differentiation is not higher tensile strength but etch uniformity and thermal stability under service load. The moderate melt flow of PH-AT is intentional; it reduces jetting and molecular orientation compared with high-flow ABS. For parts where flow length dominates and electroplating is not required, a high-flow ABS may be selected. For electroplated exterior trim with heat soak requirements, PH-AT is selected when etch uniformity and thermal resistance govern the specification.
Mold shrinkage of the unfilled grade is typically 0.4–0.7% in the flow direction and 0.5–0.8% transverse to flow, depending on wall thickness and mold temperature. Dimensions critical after plating should be measured on molded substrates, because electroplating adds 20–50 µm of metal thickness depending on the specification. Flammability of unfilled ABS is generally classified as HB under IEC 60695-11-10:2013 and UL 94; no V-series rating is claimed for PH-AT in this document. Ultraviolet exposure can degrade ABS; electroplated metal layers provide complete opacity, but unpainted or partially plated regions require UV stabilization if exterior weathering is specified.
Compared with PC/ABS blends, PH-AT processes at lower melt temperatures, does not require drying at 100–110°C, and provides better direct electroplating adhesion without primer layers. However, PC/ABS offers greater notched impact at sub-zero temperatures and higher heat deflection. Compared with PMMA/ABS blends, PH-AT has lower surface pencil hardness but higher melt ductility and less tendency to stress-crack in heated plating baths.
Chemical compatibility is a constraint after plating as well as during processing. The ABS matrix of PH-AT should not be combined with low-molecular-weight ester lubricants that can be extracted by alkaline cleaner solutions or saponified in heated acid baths. Migration kinetics of extractable species are relevant because released additives can poison palladium-tin activation baths. If a custom color compound is produced, the converter must verify that the selected masterbatch carrier and pigments do not alter etch density or release extractable species into the plating bath. Use of producer-approved purging compounds and mold-release chemistries is a condition for maintaining predictable bath life.
Incompatibility with ketones, chlorinated solvents, and aromatic hydrocarbons is common to ABS. Cleaners used before plating should be tested; solvent wiping with methyl ethyl ketone or toluene prior to plating is not recommended because it can stress-crack the surface. If adhesive bonding is used for subassemblies, one-component cyanoacrylates may be acceptable, while solvent-based adhesives with high aromatic content should be screened.
Regulatory documentation for the raw material is typically based on REACH EC 1907/2006 and RoHS 2011/65/EU as amended by (EU) 2015/863. The supplier should provide a material declaration for the unfilled grade, but final article compliance depends on pigments, additives, and metal layers applied by downstream operations. No direct food-contact claim is established for PH-AT in this document; if the plated article is used in repeated food-contact applications, the finished article must be separately evaluated under applicable migration limits, including 21 CFR 177.1020 for ABS where relevant. Automotive end uses may also require compliance with OEM limits for odour, fogging, and total volatile organic compounds under methods such as VDA 270 and ISO 12219-1:2021, but the base ABS grade alone cannot guarantee final part-level emissions.
No statement in this technical introduction replaces the producer’s latest safety data sheet, processing guide, or certificate of analysis. Process limits listed here are general for unfilled electroplating ABS; a particular production tool and plating line may require narrower ranges based on part mass, wall thickness, and bath automation.