| HS Code | 821522 |
| Manufacturer | INEOS Styrolution |
| Product Name | ABS NOVODUR HH-112 |
| Polymer Type | ABS |
| Grade | HH-112 |
| Form | Pellets |
| Processing Method | Injection molding |
| Melt Volume Rate Test Condition | 220 °C/10 kg |
| Molding Shrinkage Percent | 0.4-0.7 |
As an accredited INEOS Styrolution ABS NOVODUR HH-112 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | INEOS Styrolution ABS NOVODUR HH-112 is supplied in 25 kg moisture-proof paper bags, palletized for industrial handling and storage. |
| Container Loading (20′ FCL) | INEOS Styrolution ABS NOVODUR HH-112 is loaded into a 20′ FCL container in palletized bags, securely stowed and sealed for export. |
| Shipping | Non-hazardous ABS copolymer pellets (INEOS Styrolution NOVODUR HH-112), supplied in moisture-proof bags or octabins on pallets. Ship by standard road/sea container; keep dry and avoid direct sunlight, moisture, and excessive heat. Not classified as dangerous goods for transport. |
| Storage | Store INEOS Styrolution ABS NOVODUR HH-112 in a cool, dry, well-ventilated area in original, sealed packaging. Protect from moisture, direct sunlight, heat, and ignition sources. Keep away from oxidizing agents and avoid dust generation or package damage. Maintain stable temperatures, separate from incompatible materials, and keep containers closed when not in use. Follow the supplier’s safety data sheet. |
| Shelf Life | Shelf life is approximately 24 months when stored dry, at room temperature, in original unopened packaging, away from moisture and direct sunlight. |
NOVODUR HH-112 is specified for automotive air distribution components where surface temperatures reach 90°C to 100°C during closed-cabin soak cycles. The supplier-reported Vicat softening temperature of 112°C under ISO 306 method B/50 establishes a narrow margin against louver vane warpage. Functional failure begins as a drop in detent torque on horizontal vanes. Male pivot pins lose engagement when the material relaxes. Registers are therefore moulded with pin-to-socket clearances of 0.05 mm to 0.08 mm and are not designed for continuous contact above 95°C. The dominant compliance concern is not flammability but dimensional stability after sequential hot-air and cold-air cycling. Published data for this exact grade under repeated thermal cycling are limited, so production sign-off includes part-level detent torque testing after 500 h at 90°C.
Material preparation includes desiccant drying at 80°C for 2 h to 4 h. Residual moisture is controlled below 0.1% by ISO 15512 Method A. Uncontaminated runner scrap is re-fed at 20 wt% maximum. Higher regrind fractions reduce melt homogeneity and can shift the locally measured Vicat value near the gate seam. The melt is delivered through a general-purpose single-flight screw with L/D between 20:1 and 22:1. Barrel zone temperatures rise from 230°C at the hopper to 250°C at the nozzle. Mould temperature is held at 60°C to 80°C. Holding pressure is 50 MPa to 70 MPa until gate freeze. Vent depth is limited to 0.02 mm to 0.03 mm to avoid flash while releasing volatile fractions from the butadiene phase. Textured surfaces are cut to VDI 27 to VDI 33 to hide flow lines. A mould temperature fluctuation greater than ±5°C is visible as sink mark depth variation on rear mounting bosses.
Regulatory compliance for automotive interior parts includes REACH Annex XVII and RoHS 2011/65/EU Annex II restricted substance screening. Fogging behaviour can be assessed under ISO 6452; published data for this exact grade are limited in open literature. Terminal products are passenger-side dashboard air vent assemblies, rear console climate diffusers, and defroster nozzle grilles. The limiting operational boundary is high-radiation soak behind a closed windshield, not standard cabin airflow velocity.
Electrical enclosure components made from NOVODUR HH-112 are selected when dimensional stability after repeated thermal cycling takes precedence over flame retardancy. Consumer switch frames, socket face plates, and low-current junction box bodies operate at surface temperatures up to 80°C. The primary failure mode is creep of the ABS around brass terminal bosses after 1,000 h of intermittent load, not dielectric breakdown. Heat deflection temperature measured under ISO 75-2/B at 0.45 MPa is used as the comparative value because enclosures are low-stress. The supplier-reported Vicat rating in the region of 112°C provides a thermal margin against softening during short overload events.
Formulation uses titanium dioxide masterbatch at 2 wt% to 4 wt% for white and grey indoor housing bodies. Carbon black masterbatch is compounded at 0.2 wt% to 0.5 wt% for UV screening in semi-outdoor service. Regrind is permitted up to 15 wt% when generated from hot-sprue scrap that has been passed through a magnetic separator. The presence of ferrous contamination from regranulators produces black specks on visible surfaces. Melt is prepared in a hot-runner manifold at 250°C to 260°C. Residence time is limited to 12 min to prevent yellowing and volatile generation. Injection pressure at transfer is maintained between 80 MPa and 100 MPa; pressures above this range induce jetting around inserted brass terminals.
Flammability classification remains HB under UL 94 for the unmodified grade. No V-0 rating is claimed. End-product standards such as IEC 60695-2-11 determine glow wire requirements at specific thicknesses. Terminal products include wall-mounted socket cover plates, modular switch frames, DIN rail breaker housings, and low-current adaptor backshells. The material is not specified for high-current switchgear or continuous loaded busbar enclosures because thermal ageing at terminal points can exceed the practical ABS service ceiling.
| Standard or regulation | Relevant attribute | Application limit |
|---|---|---|
| IEC 60695-2-11 | glow wire endurance of enclosure material | end-product specified temperature |
| UL 94 | horizontal burning classification | HB at tested thickness |
| ISO 75-2/B | heat deflection under low load | continuous low-stress temperature selection |
| RoHS 2011/65/EU Annex II | restricted substance screening | maximum concentration values per annex |
| REACH Annex XVII | substance restriction | articles placed on EU market |
Control panel back housings in front-load washing machines and tumble dryer lint filter frames are moulded from this grade for coplanarity after intermittent warm-air exposure. The key dimensional risk is warpage of the rectangular frame following steam cleaning cycles. Critical mounting bosses are held to positional tolerance of ±0.05 mm using DIN 16901 general tolerance levels. Mould cooling layout is more important than material selection for this requirement. A preheated core at 65°C is used to balance differential shrinkage between the thick boss area and the thin surrounding web. Fill time is 1.8 s to 2.4 s for part mass up to 120 g to prevent hesitation lines at the last filling point.
Material ratio is typically 2:1 virgin to closed-loop sprue regrind. Drying is stricter than for unpigmented ABS because residual moisture above 0.08% produces splay on the textured control panel face. The moisture limit is measured by ISO 15512 Method A. External release is a neutral silicone-free mist. Internal mould release agents are avoided because they reduce adhesion of adhesive labels and tactile topcoats applied after moulding. Compliance is assessed under EN 60335-1 as an end-product standard. The polymer component is screened under REACH and RoHS 2011/65/EU. Continuous contact with strong alkaline cleaning solutions at elevated temperature may cause stress cracking around threaded metal inserts; design must keep hoop stress below the applied strain threshold.
Terminal products are front-load washing machine control panel carriers, dryer lint filter frames, and door kick panel retainers. The application is constrained to ambient water and warm air. The material is not placed in direct contact with uninsulated heater elements where continuous temperature exceeds the Vicat-related limit.
Thin-wall AC adapter housings are manufactured from NOVODUR HH-112 when wall stock is reduced to 1.4 mm and a high-gloss exterior is required. The melt viscosity of high-heat ABS is more temperature dependent than general-purpose ABS, so fill speed must be high and hold time short. Screw recovery is set between 80 rpm and 120 rpm on a 40 mm general-purpose screw. Back pressure of 0.5 MPa to 1.0 MPa stabilizes melt density without excessive shear heating. Decompression after recovery is limited to 3 mm to 5 mm; excessive suck-back draws air into the melt and creates surface splay. Nozzle temperature is maintained at 245°C to 255°C. Mold temperature is kept at 65°C to 75°C for gloss consistency. Short-shot parts are not sorted visually before assembly because gate blush on the inner surface is allowed.
Material preparation includes a desiccant dryer with dew point below -20°C and hopper holding time of 2 h to 3 h at 80°C. Regrind from thin-wall runners is limited to 10 wt% because thin-wall regrind granules have lower bulk density and may cause feed-bridging. No internal lubricant is required. If external release is used, it is applied as a micro-fine neutral silicone mist only on the core side. Printed surfaces require corona or plasma pre-treatment because untreated surface energy is below 38 mN/m. Pad print adhesion is checked by cross-cut test ISO 2409, with ink removal below 5% after 24 h room-temperature recovery. Compliance for finished adaptors is evaluated under IEC 62368-1. The polymer contributes to mechanical enclosure strength but not to insulation coordination. The unmodified grade remains HB under UL 94; therefore live parts require insulated barriers or separators.
Terminal products include USB-C charger housings, plug-in AC adaptor shells, and compact travel power supplies. High-gloss surfaces are polished, not textured, because thin-wall flow lines on textured finishes are more visible. This application is sensitive to moisture; a desiccant-bed dryer alarm is set to stop production if dew point rises above -20°C.
Instrument panel lower retainers and centre console support brackets are load-bearing components under screw-clamp assembly. The controlling failure is not heat distortion alone but creep after repeated clip insertion. The grade is chosen for a supplier-reported Vicat B/50 of 112°C under ISO 306, but clip retention also depends on flexural modulus and notched impact. Components with snap hooks and screw bosses require balanced gating. A sequential valve gate system with 6 nozzles is used on a press with clamp force from 3,500 kN to 6,000 kN. Melt temperature at the nozzle is held between 240°C and 270°C. The lower boundary is set by incomplete filling of ribs below 1.0 mm. The upper boundary is set by butadiene-phase degradation at extended residence. The practical nozzle-temperature band is narrower than standard ABS because the grade consumes more shear heating to fill long flow paths. A fluctuation of ±5°C in mould temperature changes post-mould shrinkage on the mounting face enough to alter flatness.
Material preparation requires pre-drying at 80°C for 3 h to 4 h and residual moisture below 0.1% by ISO 15512. Regrind is permitted at 20 wt% from pre-sorted runner systems only. Dust contamination is held below 0.05 wt% because piano-black visual surfaces reveal dust pips immediately. The process uses holding pressure of 60 MPa to 80 MPa for 6 s to 10 s, followed by gate freeze. Screw cushion is controlled to 2 mm to 4 mm to minimize pressure loss in the check ring. Production stops are defined by screw-condition monitoring rather than timer because check-ring wear introduces melt-pressure loss and short shots. Regrind concentration, melt residence, and nozzle temperature are charted together because their combined effect governs impact retention after thermal ageing.
Compliance is assessed under REACH Annex XVII and RoHS 2011/65/EU. Performance is verified by part-level testing because published multi-axial impact data for this exact configuration are limited. Terminal products are lower instrument panel retainer brackets, centre console side rails, gear selector surround supports, and defroster duct clips. The material is not specified for exposed A-surface instrument panels; painted or grained skins are used where appearance and low gloss requirements exceed the base ABS capability.
LED driver enclosures and emergency lighting battery trays are specified in this grade when continuous internal ambient temperature reaches 85°C under enclosed luminaire conditions. The main risk is not luminous output loss but screw-terminal creep and vent-slot dimensional change after 10,000 h of cyclic operation. The material is selected if the end product does not require V-0 flammability. Heat is transferred from wound components and switching devices through the polymer shell. The supplier-reported Vicat value of 112°C under ISO 306 B/50 leaves a narrow but acceptable margin. Designers limit internal hotspot contact to stand-offs and metal inserts, not continuous polymer surface contact. Vent slots are placed away from internal heat-generating components to prevent local softening.
Formulation does not include flame retardants because adding them would lower flowability and reduce the Vicat margin. A UV-stabilized masterbatch at 1 wt% is compounded for models exposed to indirect sunlight at exterior luminaire heads. Drying is at 80°C for 2 h to 4 h, with moisture below 0.1%. Processing uses a melt temperature of 250°C and mould temperature of 70°C. Weld lines around knockouts are a concern; the mould is laid out with one sub-gate per depression to prevent trapped gas. Injection speed is profiled from 40 mm/s to 80 mm/s to avoid jetting through thin vent slots. Screw back pressure is 0.5 MPa to 1.0 MPa.
End-product compliance is determined under IEC 61347-1 for lamp controlgear. The unmodified grade is classified HB under UL 94; V-0 approval is not claimed. Restricted substance compliance uses RoHS 2011/65/EU Annex II and REACH SVHC screening. Terminal products are linear troffer LED driver enclosures, emergency lighting battery trays, fluorescent ballast end caps, and lighting junction box shells. The material is excluded from applications where the enclosure must withstand a glowing wire test above its end-product specified temperature because softening begins before ignition and can alter creepage distances.
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INEOS Styrolution ABS NOVODUR HH-112 is an unfilled acrylonitrile-butadiene-styrene moulding compound classified under ISO 2580-1:2002 as an impact-modified styrene-acrylonitrile copolymer. The grade designation HH-112 corresponds to a Vicat softening temperature B/50 of 112 °C when measured under ISO 306 with a 50 N load and a 50 K/h heating rate. This value places the material above standard general-purpose ABS grades commonly supplied with Vicat B/50 values between 94 °C and 98 °C. Published datasheet values for HH-112 include a density of 1.05 g/cm³ (ISO 1183-1), melt volume-flow rate of 6 cm³/10 min at 220 °C and 10 kg (ISO 1133-1:2022), tensile modulus of approximately 2 600 MPa (ISO 527-2), tensile yield stress near 54 MPa (ISO 527-2), and Charpy notched impact strength of 19 kJ/m² at 23 °C (ISO 179-1/1eA). The material is intended for injection moulded components such as automotive interior trim, electrical enclosures, sanitary fittings, and small appliance housings requiring intermittent heat resistance without mineral filler or glass fibre reinforcement.
High-heat ABS attains an elevated Vicat and heat deflection temperature by shifting the SAN matrix glass transition upward and by controlling the grafted polybutadiene particle size distribution so that impact energy absorption is maintained without a large drop in melt flow. In HH-112, the reported Vicat B/50 of 112 °C is accompanied by a heat deflection temperature of approximately 105 °C under a 1.8 MPa flexural load (ISO 75-2/A). A standard unfilled ABS with a Vicat B/50 of 97 °C typically shows an HDT/A near 87–90 °C. The difference becomes significant in electrically heated enclosures and automotive cockpit components in which short-term temperature excursions above 95 °C can create visible deformation or loss of snap-fit retention. HH-112 remains an amorphous ABS rather than a creep-resistant engineering polymer such as polycarbonate or PBT; continuous load-bearing service should therefore be restricted to temperatures below the Vicat value, commonly 85–95 °C depending on stress and exposure duration.
| Property | Test method | Indicative value |
|---|---|---|
| Density | ISO 1183-1 | 1.05 g/cm³ |
| Melt volume-flow rate | ISO 1133-1:2022 at 220 °C/10 kg | 6 cm³/10 min |
| Tensile modulus | ISO 527-2 | 2 600 MPa |
| Tensile yield stress | ISO 527-2 | 54 MPa |
| Charpy notched impact, 23 °C | ISO 179-1/1eA | 19 kJ/m² |
| Vicat softening temperature B/50 | ISO 306 | 112 °C |
| Heat deflection temperature A, 1.8 MPa | ISO 75-2/A | 105 °C |
| Flammability rating | UL 94 | HB at 1.5 mm |
In production-scale injection moulding cells equipped with a general-purpose 20:1 or 22:1 L/D screw, the grade is processed at a melt temperature of 240 °C to 280 °C, with a preferred setting of 260 °C when screw recovery time and colour stability are balanced. Tool temperature is maintained at 60–80 °C for high-gloss surfaces and dimensional repeatability; raising the tool to 90 °C is used to improve weld-line strength and reduce orientation-induced residual stress. Holding pressure between 600 bar and 1 200 bar is typical for direct-gated parts, while back pressure of 5–15 bar improves melt homogenisation without excessive shear heating. Screw peripheral speed should not exceed 0.15 m/s when the screw is not fed by an external melt pump, because the high SAN glass transition increases viscous dissipation and can generate surface defects from local overheating.
Typical failure modes observed in moulding trials include gate blush, jetting in sections below 1.5 mm, and gloss loss when tool temperature is below 50 °C. Jetting is mitigated by reducing injection velocity to 100–200 mm/s and increasing the gate diameter to 1.0–1.5 mm. Gate blush is controlled with a two-stage fill profile in which the initial fill velocity is 30–50 % of machine maximum until gate freeze-off is partially established. Weld lines in HH-112 retain approximately 50–70 % of base Charpy notched impact when tool temperature is above 80 °C; below 60 °C, weld-line impact retention can fall below 40 % because the polybutadiene phase does not interpenetrate across the melt front. Gate placement should direct weld lines away from snap-fit and boss regions.
Post-industrial regrind from sprues and runners may be incorporated up to 20 wt% for appearance parts and up to 30 wt% for non-appearance parts if the regrind is dry, free of fines below 0.5 mm, and has undergone no more than 2 heat histories. Above 50 wt% regrind, melt-flow stability declines and the risk of black specks from degraded polybutadiene particles increases; such high regrind levels are not recommended for thin-wall or high-gloss moulded components.
ABS absorbs atmospheric moisture primarily through the polybutadiene phase. At 23 °C and 50 % RH, equilibrium moisture is near 0.2 wt%. If HH-112 is plastified without drying, dissolved moisture flashes to steam at the nozzle and produces splay, silver streaking, and a degradation of notched impact due to hydrolysis of the SAN phase and microvoiding around rubber particles. Pre-drying in a dehumidified air dryer at 80 °C for 2–4 h reduces residual moisture to below 0.05 wt%. When ambient relative humidity exceeds 60 %, the holding time should be extended to 4 h at 80 °C before the first shot. Hopper residence after drying should not exceed 4 h unless dry-air purge is maintained. In hot-runner tools, manifold temperatures between 240 °C and 270 °C are acceptable; melt residence above 5 min at 270 °C increases thermo-oxidative gel formation and can create black specks in natural or coloured grades.
The drying system should deliver air with a dew point below -20 °C and sufficient airflow of 0.1 m³/h per kg/h of material throughput. Desiccant-bed dryers with regeneration are preferred over simple hot-air ovens because hot-air ovens do not reduce absolute humidity efficiently. The material should be dried in shallow trays or hopper dryers with a bed depth not exceeding 50 cm to ensure uniform moisture removal.
The amorphous SAN matrix provides resistance to dilute aqueous acids, alkalis, aliphatic hydrocarbons, and many household cleaning agents. Ketones, esters, chlorinated solvents, and aromatic hydrocarbons plasticize or dissolve the matrix; exposure to these solvents under moulded-in stress can cause environmental stress cracking. Components that require contact with isopropanol or ethanol should be annealed at 80 °C for 1 h or moulded with a tool temperature above 70 °C to lower surface residual stress. Additive packages containing amine-based heat stabilisers, certain phosphate flame retardants, or transition-metal salts should be evaluated before compounding with HH-112 because they can migrate into the polybutadiene phase and alter its oxidation stability.
The high Vicat temperature supports paint-bake cycles of 100–110 °C for 30 min without dimensional change, but adhesion to solvent-borne coatings requires surface activation to a surface energy above 40 mN/m. Corona or plasma treatment is preferred, and silicone-based mould release agents are incompatible because they depress surface energy and produce paint delamination. Vacuum metallization is possible after a UV-curable base coat; the moulded surface must be free of moisture and volatile residues, requiring drying and immediate processing after moulding.
| Framework | Applicability |
|---|---|
| ISO 2580-1:2002 | Base designation for ABS moulding and extrusion materials |
| UL 94 HB | Unfilled high-heat ABS commonly rated HB at 1.5 mm; final thickness and colour affect the rating |
| RoHS Directive 2011/65/EU | Restricted heavy metal and flame retardant limits: 0.1 wt% for lead, mercury, hexavalent chromium, PBB, PBDE; 0.01 wt% for cadmium |
| REACH Regulation (EC) No 1907/2006 | SVHC disclosure required for substances above 0.1 wt% in the article; no SVHC is routinely declared in the standard ABS datasheet |
| EU 10/2011 | Food-contact suitability is subject to overall migration testing below 10 mg/dm² on the finished article; the pellet is not food-contact certified per se |
Because HH-112 is an unfilled resin, compliance is partly grade-dependent and partly dependent on colour concentrates, mould release agents, and assembly components used in final articles. No pellet-level certification should be substituted for finished-article migration, ignition, or compatibility testing under the end-use standard.
Automotive interior components such as instrument cluster housings, HVAC vents, and map pockets are moulded at wall thicknesses of 2.5–3.0 mm and subjected to solar-loaded cabin air temperatures that can exceed 95 °C. Under these conditions, HH-112 resists short-term creep and sag more effectively than standard ABS; however, unpainted ABS is not suitable for exterior weathering because ultraviolet radiation degrades the polybutadiene phase and reduces impact strength. Interior parts are therefore painted, covered, or compounded with UV-stabilised colour masterbatch when exposed to direct sunlight.
Electrical enclosures exposed to internal heat from relays, transformers, or power semiconductors benefit from the material’s HDT/A of 105 °C. The tracking resistance of unfilled ABS is generally below CTI 600 under IEC 60112; published data for HH-112 under all specific creepage and clearance testing configurations is limited. HH-112 should not be selected for primary insulation in high-voltage applications unless the complete device is verified under the relevant electrical safety standard.
HH-112 is not a direct replacement for PC/ABS blends in low-temperature impact or load-bearing applications, nor for PPO/PPE blends in continuous high-heat exposure above 105 °C. The grade is selected when short-term thermal stability, unfilled density, resistance to typical cleaning agents, and injection moulding processability are required in the same component.