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Indian Oil Corporation PP Homopolymer

    • Product Name: Indian Oil Corporation PP Homopolymer
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 655734
    Density 0.91 g/cm³
    Melt Flow Index 11 g/10 min (230°C/2.16 kg)
    Tensile Strength At Yield 35 MPa
    Elongation At Break 12%
    Flexural Modulus 1450 MPa
    Izod Impact Strength 3 kJ/m²
    Heat Deflection Temperature 100 °C
    Vicat Softening Point 150 °C
    Rockwell Hardness R90
    Melting Point 160 °C
    Water Absorption 0.01%

    As an accredited Indian Oil Corporation PP Homopolymer factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Indian Oil Corporation PP Homopolymer is supplied in 25 kg bags, with secure packaging ensuring safe handling and storage.
    Container Loading (20′ FCL) 20′ FCL container loading of Indian Oil Corporation PP homopolymer, safely packed, secured, and stowed for efficient transport.
    Shipping Indian Oil PP Homopolymer is shipped as free-flowing granules in 25 kg bags or 1 MT jumbo bags, containerized for safe transport. The material is non-hazardous, requiring dry, ventilated conditions away from heat and direct sunlight. Proper labeling and handling prevent contamination and maintain polymer quality during delivery.
    Storage Store Indian Oil Corporation PP Homopolymer in a cool, dry, well-ventilated area away from heat, open flames, and direct sunlight. Keep bags on pallets, off the floor, and protect from moisture and mechanical damage. Avoid dust accumulation, static ignition sources, and contamination. Always follow the material safety data sheet and local regulations.
    Shelf Life Shelf life is indefinite when stored in a cool, dry place away from sunlight, heat, and moisture.
    Application of Indian Oil Corporation PP Homopolymer

    Biaxially oriented polypropylene film produced from Indian Oil Corporation PP homopolymer is processed on tenter-frame orientation lines where the cast sheet is quenched on a 20–30°C chill roll to suppress spherulite growth before reheating into the 120–145°C machine direction orientation (MDO) unit. The homopolymer grade suitable for this segment typically shows an MFR of 2.5–4.0 g/10 min under ISO 1133-1:2022 at 230°C/2.16 kg, a low-flow balance that preserves melt strength during transverse stretching. On a single-screw extruder with L/D 30:1 and barrier screw design, melt temperature is maintained at 230–280°C; die gap is set between 1.8 mm and 2.5 mm, with the final cast sheet thickness between 200 µm and 800 µm. In the transverse direction orientation, the sheet is heated to 155–170°C and drawn 8:1 to 10:1, followed by annealing at 165–175°C with 3–7% relaxation to control heat shrinkage; premature cooling below 150°C produces uneven gauge and edge puckering, while residence above 170°C for more than 30 s can oxidise the film surface and reduce corona treatment wettability, which is typically held at 38–48 mN/m for print adhesion. Formulation addition ratios for film grades: slip/antiblock masterbatch 0.8–2.0 wt% to deliver final erucamide concentration 500–1,500 ppm and synthetic silica antiblock 1,000–3,000 ppm; antistatic masterbatch 0.3–0.8 wt%; optional nucleating masterbatch 0.1–0.3 wt% to raise crystallization temperature and reduce haze. For food contact structures, the product must comply with FDA 21 CFR 177.1520 for olefin polymers and EU 10/2011, with overall migration limit 10 mg/dm² in the assigned food simulants. Terminal product types include printed overwrap films for snack packaging, pressure-sensitive label facestock, adhesive tape base film, and metallisable barrier film for laminations.

    Thin-Wall Injection Molding of Dairy Cups and Container Lids

    Thin-wall injection molding of Indian Oil Corporation PP homopolymer uses high-flow grades with MFR values between 35 g/10 min and 70 g/10 min under ISO 1133-1:2022; the high flow is not merely a convenience but compensates for the frozen skin layer that reduces effective flow channel thickness to 50–70% of nominal wall during filling of 0.4–1.2 mm part sections. Barrel temperature profile is maintained from 210°C at the feed zone to 245°C at the nozzle; melt temperature above 250°C induces detectable chain scission with lower viscosity, increased flash at the parting line, and odour development, while below 200°C the pressure demand in the hot runner and thin ribs rises beyond 1,600 bar and short shots appear. Production-scale machines typically use a screw L/D 20:1–24:1 and compression ratio 2.5:1, with injection pressure between 1,000 bar and 1,600 bar; clamp force requirement is approximated at 3–5 t/cm² of projected part area. Mold temperature is controlled at 10–30°C for fast skin layer formation, but must remain above the dew point when relative humidity exceeds 60% RH; although the homopolymer is not hydrolytically sensitive, surface moisture on pellets causes splay in this process. Shrinkage measured according to ASTM D955-14 falls in the 1.5–2.2% range; holding pressure must be maintained until gate freeze, otherwise sink marks appear at the intersection of ribs and nominal wall. Addition ratios: neat IOCL PP homopolymer is modified with acid-neutralizing masterbatch at 0.05–0.15 wt% and color masterbatch at 1–3 wt%; nucleating agent is added at 0.10–0.25 wt% to increase crystallization temperature and reduce cooling time, while dosages above 0.30 wt% reduce surface gloss. Food-grade parts must demonstrate that the final additive system complies with FDA 21 CFR 177.1520 and EU 10/2011, including specific migration of the nucleating agent under the plastics material regulation. Terminal product types include dairy cups, delicatessen containers, tamper-evident lids, dip tubs, ice cream container bodies, and thin-wall living-hinge boxes.

    On woven sack tape extrusion lines, the first observable process conflict is the draw ratio window: a draw ratio of 1:5 produces tape with insufficient tensile strength for stable circular loom weft insertion, while a draw ratio above 1:7 induces edge fibrillation and loom breakage. Indian Oil Corporation PP homopolymer tape grades with an MFR of 3–6 g/10 min under ISO 1133-1:2022 are extruded at 220–260°C through a slit die and quenched in a water bath at 25–40°C to retain amorphous orientation before hot-air stretching at 120–160°C. The quenched cast film is slit to 2–4 mm widths then oriented in a hot-air tunnel; annealing immediately after orientation at 5–10°C below the stretching temperature is required to control heat shrinkage to 5–8% when measured in boiling water for 15 min. Addition ratios for export woven sacks: 0.3–0.8 wt% HALS UV stabilizer masterbatch, 1–4 wt% pigment masterbatch, and 2–8 wt% calcium carbonate only where low-cost non-food bags are specified; food-contact packaging should avoid calcium carbonate loadings above 5 wt% because surface roughness increases bacterial retention and reduces heat-sealed seam strength. Industry compliance includes ISO 21898:2004 for flexible intermediate bulk containers when the woven fabric is cut and sewn, REACH EC 1907/2006 Annex XVII for UV stabilizer and pigment substances, and FDA 21 CFR 177.1520 or EU 10/2011 when the bag is intended for indirect food contact in dry cereal or sugar packaging. Terminal products include cement bags, fertilizer sacks, grain packaging, onion sacks, and FIBC body fabric.

    Downstream segmentRepresentative addition ratioCritical process thresholdReference standard
    BOPP film0.8–2.0 wt% slip/antiblock masterbatchTD draw 8:1–10:1; annealing 165–175°CISO 1133-1:2022
    Thin-wall injection molding0.10–0.25 wt% nucleating agentMelt temperature 210–245°C; mold 10–30°CASTM D955-14
    Raffia/woven sack0.3–0.8 wt% HALS UV masterbatchDraw ratio 1:5–1:7; hot-air 120–160°CISO 21898:2004
    Thermoforming0.1–0.25 wt% nucleating agentSheet surface 160–175°C; draw ratio ≤1.5:1FDA 21 CFR 177.1520
    Strap extrusion0.1–0.3 wt% hindered phenolic antioxidantDraw ratio 1:8–1:9; hot rolls 110–150°CASTM D4675-14a
    Spunbond nonwovens0.05–0.2 wt% peroxide masterbatchCalender 145–160°C; bond area 15–25%ISO 9073-3:2023

    What Limits Plug-Assist Wall Thickness Uniformity in Polypropylene Sheet Thermoforming?

    Homopolymer sheet manufactured from Indian Oil Corporation PP homopolymer is extruded through a flat die into a three-roll polishing stack with roll temperatures set at 70–100°C; the sheet is then reheated to 160–175°C surface temperature before forming in a plug-assist vacuum or pressure former. The central limitation is the narrow sag temperature window: homopolymer sheets below 155°C exhibit insufficient extensibility and create thick rim sections, while above 175°C the melt strength is insufficient to hold the sheet against gravity, causing fold lines and non-uniform sidewall thickness. For draw ratios up to 1.5:1, a plug assist constructed from syntactic foam or acetal homopolymer is used; the plug travel profile must be delayed by 0.2–0.5 s after sheet sag initiates, otherwise the material freezes against the plug and transfers plug marks to the finished part. Addition ratios in thermoforming compounds: 0.1–0.25 wt% nucleating agent, 1–3 wt% color masterbatch, and 0.2–0.5 wt% antistatic masterbatch where dust-free bakery trays are required; the nucleating agent raises crystallization temperature by 5–8°C, reducing cycle time but also lowering hot-melt draw depth if added above 0.30 wt%. Compliance for thermoformed food-contact articles requires FDA 21 CFR 177.1520, EU 10/2011 overall migration limit 10 mg/dm², and low-temperature impact must be verified under ISO 179-1:2023 because homopolymer loses impact strength rapidly below 0°C; thermoformed homopolymer trays are therefore confined to ambient or chilled distribution unless an impact modifier is used. Terminal product types include bakery trays, seedling trays, clamshell deli containers, opaque dairy cup bases, and produce punnet bases.

    When Orientation Ratios Exceed 1:9 in Polypropylene Strap Extrusion

    Oriented polypropylene strap is produced by extruding Indian Oil Corporation PP homopolymer at 220–260°C into a water quench bath at 20–40°C, followed by slitting and hot roll orientation at 110–150°C. The draw ratio is the primary control variable: a ratio of 1:8 to 1:9 yields strap with enough transverse toughness to survive pallet strapping, while exceeding 1:9 creates high longitudinal fibrillation and drops elongation at break below the 10–15% typically required for retaining load under shifting. The process is run with a two-stage drawing configuration, where the first stage is 60% of total draw and the second stage completes the orientation; this staging prevents excessive heat generation at the draw point and reduces filament splitting. Addition ratios: 0.1–0.3 wt% hindered phenolic antioxidant, 0.3–0.6 wt% HALS UV stabilizer, and 1–3 wt% pigment masterbatch; calcium carbonate is not used because its concentration above 1 wt% reduces tensile strength and initiates splitting at the embossing station. Compliance includes ASTM D4675-14a for selection of flat strapping materials, REACH EC 1907/2006 Annex XVII for heavy-metal pigments, and ISO 527-1:2019 tensile property testing. Terminal product types include machine-grade strapping for corrugated boxes, hand-tool strapping for export bundling, and printed palletizing straps for logistics hubs.

    Calender Bonding Temperature Control in Spunbond Nonwoven Lines

    Spunbond nonwoven lines using Indian Oil Corporation PP homopolymer run melt temperatures between 220°C and 250°C, with spinneret hole density and quench air set to produce filaments of 1.5–2.5 denier before deposition on a moving conveyor. Calender bonding is the critical step: smooth and engraved roll temperatures must be maintained between 145°C and 160°C; below 140°C bond spot integrity is insufficient and the fabric delaminates under ISO 9073-3 tensile loading, while above 160°C the fabric becomes glossy and stiff because the bond area expands beyond the designed 15–25% emboss pattern. The homopolymer used for nonwovens typically has an MFR of 25–45 g/10 min under ISO 1133-1:2022; if a lower-MFR grade is converted, controlled vis-breaking is performed with peroxide masterbatch at 0.05–0.2 wt%, but dosages above 0.3 wt% lead to uncontrolled molecular weight loss, melt drip at the spinneret, and a measurable increase in fabric pinholes. Addition ratios also include 0.2–0.5 wt% antioxidant and, for geotextile or outdoor covers, 0.4–1.0 wt% HALS UV stabilizer. Industry compliance includes ISO 9073-1:2023 for mass per unit area, ISO 9073-3:2023 for tensile strength, REACH EC 1907/2006, and OEKO-TEX Standard 100 class product requirements where the nonwoven contacts skin. Published commercial data for Indian Oil Corporation homopolymer grades on multi-beam spunbond lines is limited; line trials are required to correlate rheology modifiers with bond roll temperature because fiber formation is affected by the grade’s peroxide residue and antioxidant package. Terminal product types include hygiene topsheets, medical isolation gown coverstock, geotextile separation layers, automotive headliner backing, and furniture fabric backing.

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    Certification & Compliance
    More Introduction

    Indian Oil Corporation Limited markets its propylene homopolymer range under the Propel trade name. A representative injection-moulding and extrusion grade, Propel H030SG, is supplied for rigid packaging, housewares, raffia tape, and general-purpose moulded articles. The homopolymer designation indicates that no intentional ethylene comonomer is introduced; therefore, the matrix develops a higher crystalline fraction and a sharper tensile yield point than random copolymers or impact copolymers. Propel H030SG is listed with a nominal melt mass-flow rate of 3.0 g/10 min at 230 °C and 2.16 kg when determined to ISO 1133-1:2022. Converters should confirm lot-specific certificate-of-analysis values because additive loading affects flow, ash, and colour. Published data for the specific IOCL grade under every downstream machine configuration is limited.

    The unfilled homopolymer is a rigid, semicrystalline polypropylene. Its density is usually reported between 0.90 g/cm³ and 0.91 g/cm³ under ISO 1183-1:2019. The matrix is dominated by α-phase crystallites unless a β-nucleating package is compounded. The absence of ethylene comonomer raises flexural modulus and heat deflection temperature but reduces optical clarity and low-temperature impact. This positions Propel H030SG as a general-purpose PP-H rather than a high-clarity or subzero-toughness material. The selection logic is therefore based on a stiffness-versus-impact trade-off, not on a single universal property profile.

    What Structural and Thermal Parameters Separate PP Homopolymer from Random Copolymer and Impact Copolymer Grades?

    The principal structural variable is comonomer content. Random copolymers usually incorporate 1–4 wt% ethylene, which interferes with chain regularity and lowers the crystallisation onset. This reduces flexural modulus and improves transparency. Impact copolymers contain a dispersed ethylene-propylene rubber phase in a polypropylene matrix; notched Charpy impact at 23 °C rises from roughly 2–5 kJ/m² for PP-H to 10 kJ/m² or higher in impact grades when tested to ISO 179-1:2010. The trade-off is a reduction in stiffness and a coarser phase-separated morphology that can affect surface gloss. A homopolymer such as H030SG is therefore selected when the functional requirement is dimensional stability under load, creep resistance, and lower tendency to smear during machining; it is not selected for deep-freeze packages or thin-wall transparent containers.

    Class-typical property envelope for unfilled PP-H, PP random copolymer, and PP impact copolymer
    Property PP Homopolymer PP Random Copolymer PP Impact Copolymer Test method
    Density 0.90–0.91 g/cm³ 0.89–0.91 g/cm³ 0.89–0.91 g/cm³ ISO 1183-1:2019
    Flexural modulus 1400–1800 MPa 800–1300 MPa 1000–1600 MPa ISO 178:2019
    Tensile yield stress 30–38 MPa 20–30 MPa 22–32 MPa ISO 527-2:2012
    Notched Charpy impact at 23 °C 2–5 kJ/m² 5–15 kJ/m² 10–60 kJ/m² ISO 179-1:2010
    Heat deflection temperature at 0.45 MPa 95–115 °C 75–95 °C 80–105 °C ISO 75-2:2013
    Optical character translucent to opaque transparent to translucent opaque

    The homopolymer’s higher crystallinity also raises tensile yield stress above that of many random copolymers. For unfilled PP-H, tensile yield stress is generally reported between 30 MPa and 38 MPa at 50 mm/min under ISO 527-2:2012. The corresponding flexural modulus usually falls between 1400 MPa and 1800 MPa under ISO 178:2019. These values support thin-walled injection moulded articles that require wall-stiffness retention without mineral filler. At 0 °C, notched impact strength drops sharply; published data for the specific Propel H030SG impact transition is limited, but the class behaviour is well established.

    Processing Boundaries, Screw Recovery, and Melt-Temperature Ceilings in PP-H Conversion

    On a single-screw extruder with 20:1 to 30:1 L/D used for raffia tape or monofilament, the barrel profile is generally set between 200 °C and 240 °C, with the die zone near 230 °C. For reciprocating-screw injection moulding, a 20:1 to 24:1 L/D screw with a 2.5:1 to 3:1 compression ratio and a non-return valve is suitable. Where masterbatch or β-nucleating agent is compounded, a co-rotating twin-screw extruder with 40:1 L/D and vacuum devolatilisation is typical; melt temperature at the die is maintained below 240 °C. Melt temperatures should not exceed 270 °C; above that ceiling, chain scission may dominate over molecular weight preservation and the melt flow rate increases during processing. The processing window for unfilled PP-H is wider than for ethylene-containing random copolymer because there is no ethylene segment to accelerate thermo-oxidative degradation, yet residence time must still be controlled. Back pressure in injection moulding can be held at 5–15 bar; excessive back pressure increases melt temperature and may produce yellowing in natural grades.

    Polypropylene homopolymer does not hydrolyse, so drying is not mandatory in low-humidity warehouses. However, surface moisture from storage above 60% relative humidity or from wet regrind can generate splay marks. Desiccant drying at 80 °C for 2–4 h is a standard corrective measure. Crystallisation temperature is typically 105–125 °C under ISO 11357-3:2018. Mould temperature is normally held between 20 °C and 50 °C; higher mould temperatures up to 80 °C increase crystallinity and flexural modulus but lengthen cycle time. Unfilled PP-H exhibits mould shrinkage of about 1.0–2.0% when measured to ISO 294-4:2018; the difference between flow-direction and transverse-direction shrinkage is a frequent cause of warp in flat parts.

    Raffia tape operations select homopolymer because the oriented tape can be drawn to ratios between 1:5 and 1:8, with the exact ratio set by line speed, water-bath temperature, and annealing rolls. Tensile properties of oriented film or tape are commonly measured to ISO 527-3:2018 or ASTM D882-18. For injection-moulded buckets, rigid closures, and appliance components, the flexural modulus of unfilled PP-H permits down-gauging relative to random copolymer at equal stiffness. The limitation appears when the part must survive impact at 0 °C or below; notched Charpy values fall below 2–3 kJ/m², making elastomer-modified or impact copolymer grades necessary for freezer or cold-chain service. Published data for the specific IOCL grade in oriented-tape lines with water-bath temperatures below 35 °C is limited.

    Compliance With Food-Contact, RoHS, and Packaging Logistics Standards Is Grade-Specific

    Grade-specific compliance declarations should be requested from Indian Oil Corporation Limited. Unfilled polypropylene homopolymer can be formulated for food-contact use under FDA 21 CFR 177.1520, which covers olefin polymers, subject to end-use extraction tests. In the European Union, migration testing is governed by Regulation (EU) No 10/2011 and subsequent amendments; the specific migration limit for total migration and for individual additives must be established on the finished article. Under Directive 2011/65/EU (RoHS), neat PP-H can be formulated without intentionally added lead, mercury, cadmium, hexavalent chromium, PBB, or PBDE; pigmented masterbatches or processing aids may alter that status. Flame performance of neat PP-H is typically HB under UL 94; flame-retardant versions require separate classification.

    Compliance matrix for unfilled polypropylene homopolymer
    Requirement Reference Basis for unfilled PP-H Converter verification
    United States food-contact olefin polymer FDA 21 CFR 177.1520 Applicable when formulated with permitted additives End-use extraction or migration testing
    European food-contact plastics Regulation (EU) No 10/2011 Compliance depends on additive package and article surface-to-volume ratio Specific migration testing on finished article
    RoHS restricted substances Directive 2011/65/EU Neat PP-H can be formulated without intentionally added restricted metals or flame retardants Verify pigment masterbatch and processing aids
    Flammability classification UL 94 Neat PP-H is typically HB; flame-retardant grades require separate formulation Test on final part thickness
    Accelerated weathering reference ASTM D4329-13 Only stabilised formulations should be exposed to outdoor service Correlate accelerated data with actual outdoor weathering

    Neat PP-H is oxidative-degradation limited in outdoor service. Without ultraviolet stabilisation, surface embrittlement and gloss loss occur under solar exposure; carbon black at 2–3 wt% or a hindered amine light stabiliser package is common for durable outdoor articles. The material is not recommended for sustained contact with strong oxidising acids, chlorinated solvents at elevated temperature, or high aromatic hydrocarbons unless specific permeability and stress-cracking evaluations are completed. Published data for the specific Propel H030SG at extended outdoor exposure is limited; therefore, ultraviolet service life must be confirmed by actual weathering or accelerated tests such as ASTM D4329-13.

    When Sustained Stiffness Above 100 °C Outweighs Low-Temperature Ductility

    PP-H is selected for hot-fill closures, under-hood covers, and appliance housings because unfilled heat deflection temperature under 0.45 MPa commonly falls between 95 °C and 115 °C when tested to ISO 75-2:2013. The same crystalline structure that supplies this heat resistance reduces notched impact at -20 °C; typical class behaviour falls below 2 kJ/m². The alternative impact copolymer offers crack-propagation resistance and better hinge performance but lower modulus and lower heat deflection temperature. Random copolymer offers transparency for clear containers but sacrifices stiffness and hot-fill capability. The homopolymer’s differentiation is therefore narrow: it is specified when the product must hold a load at elevated temperature, resist creep, and provide a stable moulding window without ethylene comonomer. For low-temperature ductility or clarity, Indian Oil Corporation’s copolymer grades or compounded formulations are more appropriate.

    Comparative evaluation against other domestic PP-H materials should use identical test specimens prepared to ISO 19069-2:2016 and tested for melt flow rate, tensile yield stress, flexural modulus, and notched Charpy impact. Ranking based on datasheet values without normalized plaque preparation can be misleading because mould temperature, injection speed, and hold pressure affect crystallinity and shrinkage. The most reliable differentiation is obtained through documented production-scale moulding trials using the converter’s own tooling and cycle time.

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