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Hifax SP 179 3004 PP Copolymer

    • Product Name: Hifax SP 179 3004 PP Copolymer
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 371025
    Density 0.89 g/cm³
    Melt Flow Rate 11 g/10 min at 230°C, 2.16 kg
    Flexural Modulus 900 MPa
    Tensile Strength At Yield 17 MPa
    Elongation At Break 100%
    Charpy Notched Impact At 23 C No break
    Charpy Notched Impact At 30 C 35 kJ/m²
    Izod Notched Impact At 30 C No break
    Shore D Hardness 60
    Vicat Softening Temperature 130°C
    Heat Deflection Temperature At 0 45 Mpa 90°C
    Mold Shrinkage 1.2%

    As an accredited Hifax SP 179 3004 PP Copolymer factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Hifax SP 179 PP copolymer is packaged as pellets in 25 kg bags on shrink-wrapped pallets.
    Container Loading (20′ FCL) 20′ FCL loaded with Hifax SP 179 3004 PP Copolymer, securely palletized, protected from moisture and heat during transport.
    Shipping Hifax SP 179 3004 is a polypropylene copolymer supplied as free-flowing pellets. Ship in sealed, moisture-protective containers or railcars/trucks with lined bulk hoppers. Avoid dust accumulation and static ignition sources. Keep dry, away from heat and incompatible oxidizers. No dangerous goods classification under normal transport conditions.
    Storage Store Hifax SP 179 3004 PP Copolymer in a clean, dry, well-ventilated area away from direct sunlight, heat sources, and open flames. Keep original containers tightly sealed to prevent moisture contamination and dust pickup. Avoid prolonged UV exposure and maintain moderate temperatures. Handle gently to minimize dust generation; keep area free of ignition hazards.
    Shelf Life Shelf life is typically 1 year from date of shipment when stored in original, unopened packaging under dry, cool conditions.
    Application of Hifax SP 179 3004 PP Copolymer

    When lower bumper deflectors and unpainted wheel arch liners are moulded from Hifax SP 179 3004, the melt is introduced through a central feed throat with a hopper magnet array and a hopper residence time below 2 h. The heterophasic ethylene-propylene rubber phase is dispersed during screw recovery; a 25:1 L/D reciprocating screw with a compression ratio of 2.5–3.0:1 and a ring non-return valve is used. Barrel set points are arranged flat or with a 10 °C reverse profile between the feed zone and the metering zone, with nozzle temperature set to 220–250 °C. Screw rotation speed is maintained at 60–120 rpm, and back-pressure is adjusted to 5–15 bar to homogenise the melt without over-shearing the rubber domains. Hot-runner valve gates are sequenced so that the centre gate opens first, then outer gates open after a 0.3–0.8 s delay. The fill-to-pack switchover is set at 95–98 % of total shot volume as measured by screw position. For a projected area of 1,200 cm², clamp force is selected at 840–1,200 tonnes, which corresponds to 0.7–1.0 tonnes per cm². Injection pressure is normally recorded at 600–900 bar for wall thicknesses of 2.5–3.0 mm. Mould temperature is controlled with high-turbulence water channels at 30–50 °C, and core-to-cavity temperature differentials are kept below 15 °C to reduce bowing in long deflector sections.

    Weatherability for exterior trim is verified with SAE J2527:2017 or ISO 4892-2:2013 xenon arc exposure using daylight filters. Black and dark-grey compounds containing carbon black at 1.5–2.5 wt% show lower surface crazing after 1,000 h of exposure than un-stabilised natural resin. Painted facias require pretreatment by flame or plasma and adhesion promotion with a chlorinated polyolefin primer. Cold impact is measured by notched Charpy ISO 179-1:2010 at −30 °C and ISO 179-1:2010 at 23 °C; the EPR phase provides energy dissipation at low strain rates. Dimensional shrinkage is referenced to ISO 294-4:2018 after 24 h and 48 h storage at 23 °C and 50 % RH. The use of regrind in exterior parts is limited to 20 wt% because higher levels reduce UV stabiliser concentration and increase surface defects. Published data for Hifax SP 179 3004 exposed in long Florida or Arizona outdoor tests is limited; correlation to accelerated weathering must be confirmed through supplier exposure curves.

    Weld-line formation in lower grille surrounds is managed by moving knit lines away from visible impact zones through gate-sequence changes. Mould-filling simulation with Moldflow or Moldex3D is used to predict flow-front meeting angles above 75°, because lower meeting angles create mechanically weak weld lines in PP copolymer. Surface defects such as flow marks are reduced by maintaining injection speed above 80 mm/s through the outer rim sections. Ejector pin layout is designed with pins acting on ribs rather than flat surfaces to avoid whitening of the impact-modified polymer. Dimensional checks include fixture-based contour scanning after 24 h post-mould conditioning.

    What Are the Gate-Freeze Constraints in Thin-Wall Interior Trim?

    Thin-wall pillar covers, door trim inserts, and instrument panel lower supports are moulded at wall thicknesses of 1.2–1.8 mm with flow lengths exceeding 150 mm. The melt temperature is raised to 230–260 °C at the nozzle, and fill time is kept below 1.0 s to maintain flow-front velocity above 300 mm/s. Because Hifax SP 179 3004 contains a heterophasic EPR phase, its viscosity at low shear rates is higher than a homopolymer of equivalent MFR; fast injection therefore reduces apparent viscosity and improves flow length. Screw-tip hydraulic pressure is set at 1,000–1,400 bar, while the holding pressure is 700–1,000 bar. Gate geometry uses diameters of 0.8–1.2 mm for edge gates and 0.6–0.9 mm for tunnel gates. Gate freeze time is determined by increasing hold time in 0.5 s increments and plotting part mass against hold time; the plateau indicates gate freeze. Premature freeze produces short shots and flow marks; late freeze prolongs cycle time and causes sink marks around bosses and ribs.

    Interior emission and fogging constraints are evaluated using VDA 278:2011 thermal desorption and ISO 6452:2007 fogging. The material must be processed with short and controlled residence times; barrel residence time is limited to 5 min at 240 °C, and purging is performed after 15 min of idle time. Melt temperature above 260 °C accelerates oxidative chain scission and increases VOC emissions. Warpage in pillar covers is controlled with core-to-cavity temperature differentials of 10–20 °C, with the core kept cooler than the cavity. Shrinkage anisotropy is measured by ISO 294-4:2018 in the parallel and perpendicular directions. The final compound must be validated against the relevant OEM interior specification because published data for Hifax SP 179 3004 in instrument-panel-level VOC testing is limited.

    Tool design for thin-wall interior parts uses sequential valve gating to prevent hesitation marks at rib intersections. The runner system is fully hot with manifold temperatures offset from the nozzle by −5 °C to −10 °C. Injection profile is divided into three phases: slow initial advance at 30–50 mm/s, high-speed fill at 110–160 mm/s, and controlled pack at 20–40 mm/s. Cavity pressure sensors are located near the last fill point; the switchover trigger is set at 400–600 bar cavity pressure. Venting depth is limited to 0.02–0.03 mm to avoid flash while allowing gas escape at high fill speeds. After demoulding, parts are placed on gauges for 2 h to stabilise thermal contraction before dimensional approval.

    In appliance housing production, vacuum cleaner housing shells and washing machine outer shrouds are converted in hot-runner multi-cavity tools with 4–16 cavities. Pellet drying is applied only when storage relative humidity exceeds 60 %; a desiccant dryer at 80 °C for 2 h removes surface condensation. The melt temperature is set at 215–245 °C, and mould temperature is held at 20–40 °C. For a 2.5 mm wall, cycle times of 35–60 s are typical. Ribbed designs are used to increase stiffness without increasing wall stock, avoiding long flat sections that induce sink marks. Screw tip pressure is 800–1,100 bar; holding pressure is 500–750 bar for 6–10 s. Tensile modulus is evaluated by ISO 527-2:2012, flexural modulus by ISO 178:2019, and notched Charpy by ISO 179-1:2010. Electrical safety compliance is assessed by IEC 60695-2-11 glow-wire testing at 650 °C or 750 °C. Unfilled PP copolymer does not inherently meet UL 94 V-0 at 1.5 mm; if the end-use standard requires a vertical burn rating, an intumescent or halogenated flame-retardant package must be added. RoHS compliance is verified under Directive 2011/65/EU as amended by Commission Delegated Directive (EU) 2015/863. The grade is not specified for direct food-contact appliance components unless migration testing under EU 10/2011 and FDA 21 CFR 177.1520 is successfully completed with the chosen masterbatch and process.

    Moulding classMelt temperature (°C)Mould temperature (°C)Injection pressure (bar)Holding pressure (bar)Clamp factor (t/cm²)
    Exterior fascia 2.5–3.0 mm220–25030–50600–900400–6000.7–1.0
    Thin-wall interior trim 1.2–1.8 mm230–26020–401,000–1,400700–1,0000.7–1.0
    Appliance housings 2.0–2.5 mm215–24520–40800–1,100500–7500.5–0.8
    Compounded structural parts 3.0–5.0 mm200–23040–70700–1,000450–6500.4–0.6

    Compounding Glass-Fibre Masterbatch on Co-Rotating Twin-Screw Lines

    A 40:1 L/D co-rotating twin-screw extruder with separate side feeding is used when Hifax SP 179 3004 is upgraded with glass fibre. The main feed receives pellets and a maleic anhydride-grafted PP coupling agent masterbatch at 1.0–3.0 wt%. Glass fibre is side-fed at 10–30 wt% after a polymer melt seal is established. Screw configuration places two kneading blocks after the fibre feed port and one distributive mixing section before vacuum degassing. Barrel set points are 180–230 °C; melt temperature at the die is measured by infrared probe at 220–245 °C. Screw speed is set at 300–500 rpm. Specific energy input is recorded in the range 0.20–0.30 kWh/kg. Vacuum degassing at −0.08 MPa is applied in the vent zone to remove volatiles and fibre sizing decomposition products. Glass fibre is predried at 120 °C for 4 h if opened bags exceed 0.2 % moisture by weight. Die pressure and stock temperature are logged to detect screw wear or feed instability.

    Published data for Hifax SP 179 3004 in glass-reinforced formulations is limited; therefore developmental trials use a factorial design at 10 wt% and 30 wt% fibre, with coupling agent at 1.0 wt% and 3.0 wt%. Mechanical testing is conducted according to ISO 527-2:2012 for unfilled base resin and ISO 527-4 for glass-reinforced compounds. Flexural modulus is measured by ISO 178:2019, and notched Charpy by ISO 179-1:2010 at 23 °C and −30 °C. Ash content is checked by ISO 3451-1:2019. The heterophasic EPR phase can reduce fibre wetting relative to homopolymer; increasing screw speed without changing screw geometry may break glass fibres and lower impact strength. The formulation target for tensile modulus is typically 4,500–6,000 MPa at 30 wt% glass fibre, but the exact value is lot-dependent and must be confirmed experimentally.

    Rheological checks on compounded batches are performed by capillary rheometry at 230 °C across apparent shear rates from 10 s⁻¹ to 1,000 s⁻¹. Melt-flow testing by ISO 1133-1:2022 is used only as a lot-to-lot consistency check, not as a predictor of glass-fibre dispersion. Screw configuration trials record fibre length distribution after burn-off according to ISO 3451-1:2019. Higher specific energy can overheat the EPR phase and produce brown streaks at the strand die. Strands are cooled through a water bath at 20–35 °C and pelletised only after surface moisture is removed by air knives. The pelletised output is packed in foil-lined bags to prevent moisture pickup before moulding.

    If Long-Term Heat Ageing Replaces Impact Strength as the Decisive Criterion in Battery Carriers

    When Hifax SP 179 3004 is assessed for electric vehicle battery brackets and cover components, the parts are positioned away from direct cell contact and high-temperature busbars. Heat ageing is carried out in circulating air ovens at 85 °C, 100 °C, and 120 °C, with tensile strength and notched impact retention measured after 500 h, 1,000 h, and 2,000 h. Heterophasic PP copolymers without long-term heat stabilisation experience EPR phase oxidation and surface embrittlement above 90–100 °C. A stabiliser package at 0.3–0.8 wt% may be incorporated during compounding when sustained exposure above 90 °C is required. Heat deflection temperature is measured by ISO 75-2:2013 method A at 1.8 MPa. Dimensional change after annealing at 90 °C for 24 h is checked with a coordinate measuring machine.

    Insert retention and thermal cycling behaviour are critical. The grade is moulded around brass inserts only where continuous service is below 80 °C; above this threshold, differential expansion between metal and PP copolymer can initiate stress cracking. Thermal cycling from −40 °C to 85 °C is performed for 100 cycles, followed by axial pull-out tests of inserts. Specimens are conditioned for 48 h at 23 °C and 50 % RH according to ISO 291:2008. Creep under static load is evaluated by ISO 899-1:2017 at 23 °C and 80 °C. For electrical enclosures, flame performance is evaluated by UL 94 at 1.5 mm and 3.0 mm after the selected FR package is added, since the unfilled base grade is not inherently V-0. This limitation is explicit in processing and specification guidelines.

    Application domainStandard designationMeasured propertyTest condition
    Automotive exterior weatheringSAE J2527:2017, ISO 4892-2:2013Surface retention, colour shiftXenon arc, daylight filter, referenced to OEM cycles
    Automotive interior emissionsVDA 278:2011VOC and SVOC releaseThermal desorption, OEM-specific limits
    Interior foggingISO 6452:2007Condensate mass on glassMethod A, 100 °C, 16 h
    Mechanical performanceISO 527-2:2012, ISO 178:2019, ISO 179-1:2010Tensile, flexural, Charpy23 °C and −30 °C
    Electrical enclosure safetyIEC 60695-2-11:2014, UL 94Glow-wire, vertical flame1.5 mm, 3.0 mm
    Food-contact confirmationFDA 21 CFR 177.1520, EU 10/2011MigrationRequired only if specified

    Returnable logistic crates and collapsible containers use Hifax SP 179 3004 for interlocking foot geometry, hinge bosses, and cold drop durability. Mould temperature is set at 20–35 °C to reduce gloss and is maintained through conformal cooling channels. Wall thickness is generally 2.5–4.0 mm, and the packing phase is extended until the gate freezes. Cold drop testing is performed after conditioning to ISO 291:2008 at −20 °C; the test simulates repeated corner drops from 1 m. Environmental stress cracking in contact with detergents and alkaline cleaning solutions is assessed by exposure to 5 % alkaline solution at 50 °C for 72 h. If the crate is required for food-contact use, migration testing under FDA 21 CFR 177.1520 and EU 10/2011 is mandatory with the selected masterbatch and regrind level. Regrind up to 20 wt% is permitted where colour consistency is not critical. Higher regrind levels require monitoring of MFR by ISO 1133-1:2022 at 230 °C with 2.16 kg load. The grade is not recommended for continuous exposure to strong oxidising acids or high aromatic hydrocarbon environments. Storage of filled crates in direct sunlight for more than 6 months should include carbon black or a UV stabiliser masterbatch at 2–4 wt%.

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    Certification & Compliance
    More Introduction

    Hifax SP 179 3004 is a high-flow polypropylene impact copolymer produced through in-reactor alloying on a Spheripol or Spherizone process train. The grade’s MFR of 30 g/10 min (ISO 1133-1:2022, 230 °C/2.16 kg) targets injection-molded automotive parts with nominal wall thicknesses between 2.0 mm and 3.5 mm. The 3004 suffix denotes a tailored multi-component heat- and UV-stabilization package that extends the continuous-use thermal ceiling to 150 °C while maintaining high gloss retention and crack resistance in molded-in-color applications. The polymer’s ethylene-propylene rubber phase—polymerized directly inside the polypropylene matrix—delivers a fine, uniform dispersion of elastomeric domains. That morphology yields a stiffness–impact balance difficult to replicate with melt-compounded TPOs and eliminates the volatile process oils common in physical blends, which is critical for meeting cabin air-quality limits under VDA 278.

    Typical physical and mechanical properties—Hifax SP 179 3004 (black, dry-as-molded)
    PropertyValueUnitTest standard
    Melt mass-flow rate30g/10 minISO 1133-1
    Density0.90g/cm³ISO 1183-1
    Tensile stress at yield (50 mm/min)25MPaISO 527-2
    Tensile strain at yield5%ISO 527-2
    Flexural modulus (2 mm/min)1300MPaISO 178
    Charpy notched impact (+23 °C)65kJ/m²ISO 179-1/1eA
    Charpy notched impact (-30 °C)5.5kJ/m²ISO 179-1/1eA
    Heat deflection temperature (HDT/B, 0.45 MPa)95°CISO 75-2
    Vicat softening temperature (VST/A50)150°CISO 306
    Mold shrinkage – flow direction (2 mm plaque)1.2–1.5%ISO 294-4

    Injection molding of Hifax SP 179 3004 on a reciprocating-screw machine with a general-purpose polyolefin screw (L/D 20–24, compression ratio 2.0:1 to 2.8:1) requires strict moisture management. Pellets that have absorbed more than 0.05 % residual moisture must be dried in a desiccant dryer with a dew point of ≤ -30 °C at 80 °C for 2–4 h; failure to observe this limit reliably generates splay and silver streaking on textured Class-A surfaces. Melt-temperature setpoints between 220 °C and 260 °C are permissible, but a nominal barrel profile targeting 240 °C at the nozzle gives the widest processing latitude. Exceeding 260 °C for cumulative residence times above 10 min accelerates chain scission, evidenced by a drop in notched Charpy values of more than 15 % and a measurable increase in yellowness index. Mold temperature is normally held between 30 °C and 60 °C; glossy, low-weld-line exterior fascias demand 50–60 °C with closed-loop turbulent-flow cooling that holds cavity-to-cavity variation to ±3 °C. Back pressure applied to the screw should not exceed 15 bar hydraulic; higher levels overwork the melt and can prematurely degrade the rubber phase, reducing low-temperature ductility. For thin-wall sections below 2.0 mm, injection speeds yielding calculated shear rates at the gate of 5×10³ to 1×10⁴ s⁻¹ are typical, corresponding to apparent viscosities near 120 Pa·s at 230 °C measured by capillary rheometry per ISO 11443. Mold-filling simulations that do not incorporate the measured shear-thinning behavior of the copolymer frequently over-predict pressure drop by 15–25 %, leading to oversized clamp tonnage specifications. Practitioners should size the machine using a projected-area factor of 3–5 kN/cm² for parts without gas counterpressure; if internal gas-assist is employed, the factor can be reduced to 2–3 kN/cm² with the attendant risk of post-foaming sink marks on bosses thicker than 3 mm.

    How In-Reactor Impact Copolymer Morphology Differs from Compounded TPO Alloys

    In a conventional melt-compounded TPO, micron-sized EPDM particles are dispersed into a PP homopolymer matrix via twin-screw extrusion, and the resulting blend invariably contains a population of agglomerates > 10 µm that act as stress concentrators at low temperature. Hifax SP 179 3004 belongs to the in-reactor impact copolymer (ICP) family, where the ethylene-propylene rubber phase grows on the same catalyst particle that polymerizes the propylene homopolymer phase. The rubber domains emerge as sub-micron, multi-lobed inclusions that are covalently grafted to the matrix, giving a Charpy notched transition temperature 5–10 °C lower than that of a TPO with an equivalent flexural modulus. The practical consequence for automotive bumper fascia is that a 2.5 mm molded skin retains ductile failure behavior down to -35 °C in the ICP version, whereas the compounded TPO enters brittle failure above -25 °C when stiffness is held constant at 1300 MPa—a difference documented in OEM material specifications that demand ISO 179-1/1eA Charpy values > 4.5 kJ/m² at -30 °C. Moreover, the absence of post-reactor compounding eliminates the need for paraffinic extender oils, which are latent sources of volatile organic condensables. A direct comparison of a 3000 h heat-aged ICP panel versus a TPO control at 150 °C shows that the ICP retains ≥65 % of its initial tensile elongation at break (per ISO 188), while the oil-plasticized compound drops below 30 % due to evaporative loss of plasticizer and subsequent matrix embrittlement. This differential is the primary driver for replacing melt-compounded grades with ICPs in underhood applications such as engine covers, battery trays, and cowl vent grilles where post-assembly paint bake cycles and continuous radiated heat demand sustained elasticity.

    When Paint Adhesion Without Flame Treatment Specifies the Process Window

    Class-A exterior panels molded from Hifax SP 179 3004 can be direct-painted with standard two-component polyurethane topcoats after a surface activation wash using an adhesion promoter based on chlorinated polyolefin (CPO) dissolved in an isopropanol/water mixture. The high surface concentration of the dispersed ethylene-propylene rubber phase acts as a natural anchor for CPO chain entanglement, rendering flame or corona pre-treatment unnecessary—a simplification that removes a capital-intensive step from the finishing line and eliminates the risk of localized surface oxidation that causes paint mottling. A validated paint system applied at 15–20 µm dry film thickness and cured at 90 °C for 30 min typically achieves cross-cut adhesion ratings of 0 or 1 per ISO 2409 on ungrit-blasted moldings. Steam jet adhesion resistance is evaluated by exposing the painted panel to a 70 °C water jet at 70 bar for 180 s (simulating a hot-pressure washer cycle) as called out in ISO 16925; samples meeting that protocol show no paint loss beyond the scribe. The process window, however, narrows when the mold surface texture falls below a VDI 3400 equivalent of A‑3, because micro-mechanical interlock contributes less to the overall peel strength. Painted parts that must pass 240 h water immersion at 40 °C (ISO 2812-2) followed by cross-cut adhesion within 1 min of removal consistently perform better when the pre-paint wipedown includes a 3‑second flash-off time before coating application. Exceeding 10 sec of open air exposure after the wipe step allows moisture re-adsorption, which is detectable as microblistering in the clearcoat after humidity conditioning. The 3004 stabilizer package also does not interfere with the acid-catalyzed crosslinking of the topcoat, a documented incompatibility of certain HALS-only stabilizer systems that can retard cure and reduce gloss values measured at 20° geometry per DIN 67530.

    Outdoor durability of uncoated, molded-in-color components in an automotive exterior environment relies on the combined action of hindered amine light stabilizers and a high-molecular-weight UV absorber incorporated through the 3004 formulation. Accelerated weathering according to SAE J2527 (xenon arc, extended UV filter, borosilicate inner and outer cylinders, black panel temperature 70 °C, dry-bulb 50 °C, relative humidity 50 %) consistently yields a ΔE*ab color change of ≤ 3.0 after 3000 kJ/m² at 340 nm for black specimens. Gloss retention at 60° geometry remains above 70 % of the initial value under the same dosage. The performance translates to a Florida outdoor exposure (south , unbacked rack) of 3 years without surface chalking or microcracking—a threshold embedded in several European OEM material standards for unpainted side claddings. For interior trim pieces exposed to sunlight transmitted through glazing, the gradient is monitored via ISO 105-B06 using a xenon arc with a window glass filter; a cumulative radiant exposure of 600 kJ/m² over the 300–800 nm band typically yields a greyscale rating of 4–5 (change in shade). Volatile organic emissions, a persistent constraint for interior air quality, are controlled at the polymer architecture level: the reactor-based copolymer contains no residual processing oils, so semi-quantitative VOC headspace analysis per VDA 278 (thermodesorption at 90 °C) returns total VOC values below 100 µg/g and a fogging condensate mass below 2 mg per DIN 75201 (gravimetric method, 16 h at 100 °C). That emission profile meets the cabin air requirements of the major German OEMs and eliminates the need for secondary post-molding aeration.

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