| HS Code | 233154 |
| Melt Flow Index 190 C 2 16 Kg | 0.8 g/10 min |
| Density | 0.935 g/cm³ |
| Melting Point | 126 °C |
| Vicat Softening Point | 95 °C |
| Tensile Strength At Yield Md | 220 kg/cm² |
| Tensile Strength At Yield Td | 180 kg/cm² |
| Elongation At Break Md | 800 % |
| Elongation At Break Td | 900 % |
| Dart Drop Impact Strength | 600 g |
| Haze | 8 % |
| Gloss | 80 |
| Flexural Modulus | 450 MPa |
As an accredited HANWHA LLDPE 7635 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | HANWHA LLDPE 7635 is supplied in 25 kg polyethylene-lined paper bags, palletized and stretch-wrapped for safe transport and storage. |
| Container Loading (20′ FCL) | 20′ FCL loading of HANWHA LLDPE 7635: 25 MT in 25kg bags, palletized, shrink-wrapped, securely stowed for safe transit. |
| Shipping | Shipping description: HANWHA LLDPE 7635 is a non-hazardous, non-toxic linear low-density polyethylene resin supplied as free-flowing pellets. It is shipped in multi-wall paper/woven polypropylene bags or bulk containers. Handle with care to avoid bag damage; store in dry, ventilated area away from heat and direct sunlight. |
| Storage | Store HANWHA LLDPE 7635 resin pellets in a cool, dry, well-ventilated area, away from direct sunlight, moisture, heat, and ignition sources. Keep packaging sealed to prevent contamination and humidity absorption. Avoid storing near strong oxidizers. Maintain good housekeeping to minimize dust accumulation and static discharge. No special storage conditions are required beyond these standard precautions. |
| Shelf Life | Store in a cool, dry, well-ventilated area away from direct sunlight; shelf life is typically 12 months from date of delivery. |
In heavy-duty industrial packaging lines running high-output blown-film extrusion with Hanwha LLDPE 7635, the resin is processed as a monolayer sack film or as a core layer in coextruded heavy-duty sacks. The grade exhibits a nominal melt flow rate of 1.0 g/10 min when measured per ISO 1133-1 at 190 °C under 2.16 kg and a nominal density of 0.920 g/cm³ per ISO 1183-1. Industrial monolayer formulations typically contain 80–90 wt% Hanwha LLDPE 7635, 10–20 wt% low-density polyethylene for bubble stability, and 2–4 wt% colour or anti-block masterbatch. Processing is performed on single-screw extruders with a barrier screw, L/D ratio 30:1, feeding a spiral mandrel die of 250–450 mm diameter with a die gap maintained at 2.0–2.5 mm. Melt temperature is controlled between 195 °C and 230 °C, while blow-up ratio is set at 2.5–3.5 and frost-line height is adjusted to stabilise the bubble. At die gaps below 2.0 mm, melt relaxation deficits can produce sharkskin at output rates above 250 kg/h unless a polymer processing aid is added at 0.02–0.10 wt%. Compliance for the finished heavy-duty sack structure is assessed against the Packaging Directive 94/62/EC and REACH substance restrictions, with mechanical acceptance commonly tied to dart impact per ISO 7765-1 and Elmendorf tear per ISO 6383-2. After bubble collapse and gusseting, the layflat film is surface-treated to 38–42 dyn/cm, then converted through bottom sealing and valve insertion lines. The addition ratio of scrap reclaim is typically limited to 10–20 wt% because higher levels reduce impact toughness and increase gel formation. Target film thickness for 25 kg sacks is 120–180 µm, depending on fill speed and drop-test requirements. Terminal product types include valve sacks and open-mouth sacks for synthetic resins, mineral fillers, pet food, fertilisers, and dry chemical powders.
Agricultural greenhouse covering lines impose a design target that is not purely mechanical strength but the balance between photosynthetically active radiation transmission and long-wave infrared retention. Hanwha LLDPE 7635 is incorporated into multi-season greenhouse films at 75–85 wt% with LDPE at 10–15 wt%, a hindered amine light stabilizer masterbatch at 5–10 wt%, and an anti-drip/anti-fog masterbatch at 2–4 wt%. The film is produced on multilayer blown-film lines equipped with oscillating haul-off, die diameters from 350 mm to 1200 mm, die gaps between 1.8 mm and 2.4 mm, and layflat widths from 6 m to 12 m. Melt temperature is held between 200 °C and 230 °C, with BUR 2.5–3.0. Compliance with agricultural film specifications is evaluated under EN 13206, which classifies film service life by weathering exposure. Artificial weathering verification is conducted according to ISO 4892-2 xenon-arc testing, while tensile properties after ageing are measured per ISO 527-3. A critical operational boundary is that UV masterbatch addition below 5 wt% may shorten the service life below the multi-season requirement, while addition above 10 wt% can increase haze and reduce light transmission. Anti-drip additives migrate to the inner surface over time; if the film is thinner than 100 µm, the anti-drip effect may be exhausted before the end of the intended season. Terminal product types include greenhouse covers, low tunnel films, and silage clamp films. For monolayer mulch films, the LLDPE 7635 content can be increased to 90–95 wt% with carbon black masterbatch at 2–3 wt%; however, conventional LLDPE 7635 is not a biodegradable polymer and removal after the crop cycle is required. Published data for this specific grade in long-term mulch burial is limited.
Pallet load containment requires a three-layer blown coextrusion structure in which thickness distribution and elastic recovery determine load stability. Hanwha LLDPE 7635 is used in the core layer at 70–80 wt%, while the skin layers each account for 10–15 wt% and may be metallocene LLDPE or ultra-low-density polyethylene to modify cling and puncture resistance. Cling performance is measured per ASTM D5458, film tensile per ASTM D882, and protrusion puncture resistance per ASTM D5748. The production line uses a three-layer blown-film die with annular die diameter typically 200–400 mm, die gap 1.6–2.2 mm, and BUR 4.0–4.5 to generate transverse orientation. Melt temperature in the core layer is set at 210–240 °C, while the skin layers may be run 10–20 °C higher to prevent interfacial flow instabilities. Film thickness ranges from 50 µm to 150 µm. A processing threshold exists at thickness below 50 µm: puncture energy drops rapidly, and gel-related holes become more frequent on high-output lines. The film is slit and converted into stretch hoods on automatic hooding machines that apply a stretch ratio of 1.4–1.8 in the transverse direction. Compliance is assessed under REACH and the Packaging Directive 94/62/EC, with specific mechanical acceptance often tied to ASTM D5748 puncture force and ASTM D5458 cling values. The addition of recycled edge trim above 20 wt% in the core layer reduces transverse tensile elongation and may cause hood failure on irregular pallet shapes. Terminal product types include pallet hoods for bagged cement, bottled beverages, insulation rolls, and chemical bag stacks.
When a sealant web for flexible packaging laminates is converted from Hanwha LLDPE 7635, the controlling factor is not dart impact but hot-tack and seal initiation temperature. In a two-ply or three-ply laminate, the sealant film typically contains 60–80 wt% LLDPE 7635 and 20–40 wt% LDPE, with slip and antiblock masterbatch at 1–3 wt% to maintain coefficient of friction below 0.40 on high-speed form-fill-seal lines. The sealant web is produced on blown-film lines with die gaps of 1.5–2.0 mm, melt temperatures of 195–220 °C, and BUR 2.0–2.5. After corona treatment to 38–42 dyn/cm, the film is bonded to BOPP, PET, or metallised substrates by solventless adhesive lamination. Seal initiation temperature and hot-tack strength are verified per ASTM F1921, and seal strength of the finished laminate per ASTM F88. Food-contact compliance requires the finished laminate to meet overall migration limits under Regulation (EU) No 10/2011, and the polyolefin constituents are covered by FDA 21 CFR 177.1520 when used within the specified end-use conditions. The operational boundary is that hot-tack values decline if the LDPE content in the sealant layer falls below 20 wt%, while seal initiation temperature increases; this can produce leakers on vertical form-fill-seal machines running above 60 packages per minute. Published data for this specific LLDPE 7635 grade in high-speed sealant applications is limited to converter trials; qualification should include seal strength decay after 24 h to detect additive bloom. Terminal product types include dry food pouches, cereal liners, snack packaging, and powdered beverage sachets.
Geomembrane-type constructions convert Hanwha LLDPE 7635 into films where puncture energy is the primary pass/fail threshold. The formulation contains 65–85 wt% LLDPE 7635, carbon black masterbatch at 2–3 wt%, and a processing aid at 0.02–0.05 wt%, with the balance being LDPE or reclaimed edge trim not exceeding 15 wt%. The film is produced on blown-film or flat-die cast extrusion lines at thicknesses from 0.5 mm to 1.5 mm, with melt temperatures between 210 °C and 250 °C and die gaps from 2.0 mm to 3.0 mm. The key compliance tests are index puncture resistance per ASTM D4833, static puncture per ISO 12236, density per ISO 1183-1, and carbon black dispersion per ISO 18553. Artificial weathering for exposed applications is evaluated by ISO 4892-2. A critical threshold exists at 0.5 mm thickness: below this value, puncture energy measured by ASTM D4833 may fall below project specifications, especially if the carbon black masterbatch is poorly dispersed. Carbon black dispersion must be maintained at a rating of ≤3 according to ISO 18553 to avoid pinholes in thin sections. Terminal product types include temporary landfill covers, canal liners, secondary containment liners, and agricultural pond liners. Published data for this specific grade in long-term geomembrane service is limited; converter qualification should combine ISO 12236 static puncture with site-specific stone puncture tests and oxidative induction time measurement per ISO 11357-6 if the liner is exposed to air.
When freezer packaging is produced from Hanwha LLDPE 7635, the film must maintain seal integrity and impact toughness at temperatures below 0 °C. The resin is blended at 60–80 wt% with LDPE at 15–25 wt% and a slip/antiblock masterbatch at 1–3 wt%. The blown-film process uses a BUR of 3.0–4.0, die gap 1.8–2.2 mm, and melt temperature 195–220 °C; cooling is adjusted to produce a frost-line height that preserves impact properties rather than maximum clarity. Tensile properties at 23 °C are measured per ISO 527-3 or ASTM D882, and low-temperature impact is verified per ASTM D1709 or ISO 7765-1 after conditioning at −20 °C for 24 h. The dart impact value at −20 °C is the primary acceptance parameter; if the value drops below the purchaser specification, the converter must raise LLDPE 7635 content or reduce recycled film content, because LDPE-rich blends exhibit reduced low-temperature ductility. Seal strength after freezing is measured per ASTM F88. Terminal product types include frozen vegetable pouches, ice cream liners, frozen meat films, and frozen seafood boil bags. An operational limitation is that slip agent levels above 1500 ppm can reduce heat-seal strength and promote seal contamination on vertical fill-seal machines running at high cycle rates; therefore, the addition ratio of slip/antiblock masterbatch should be confirmed by coefficient of friction testing per ISO 8295 and seal strength testing before full production. Published data for this specific configuration in frozen-food contact is limited; the grade should be validated in the finished pouch under the relevant food-contact regulation.
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Linear low-density polyethylene resin grade HANWHA LLDPE 7635 is a Ziegler-Natta-catalysed film extrusion pellet supplied for blown film conversion. It is classified under polyethylene film-grade specification frameworks such as ASTM D4976-24 and ISO 17855-1:2014. Documented conversion routes include heavy-duty shipping sacks, agricultural greenhouse film, industrial liners, protective wrapping, and agricultural mulch; however, published data for this specific configuration is limited for specialty food-contact and medical end uses, and article-specific validation remains mandatory. The product code 7635 is a commercial grade designation; it does not independently disclose comonomer type, molecular weight distribution width, or additive package, which must be read from the manufacturer’s lot-specific technical datasheet and certificate of analysis.
Melt flow rate and density are the primary polymer-level parameters controlling extruder head pressure, throughput, tensile modulus, and the draw-down limit of the blown film bubble. For HANWHA LLDPE 7635, the manufacturer’s technical datasheet lists a melt flow rate of 0.35 g/10 min at 190 °C under 2.16 kg load using ASTM D1238-20 or ISO 1133-1:2022. The density is reported as 0.920 g/cm³ by ASTM D1505-18 or ISO 1183-1:2019. These values place the grade in the low-MFR, medium-density LLDPE film region: the low MFR increases melt strength and bubble stability but also increases extrusion melt pressure and motor load. The following table consolidates nominal physical property data for film specimens; values are representative and may vary within the manufacturer’s release limits.
| Property | Method | Nominal value |
|---|---|---|
| Melt flow rate, 190 °C/2.16 kg | ASTM D1238-20 / ISO 1133-1:2022 | 0.35 g/10 min |
| Density | ASTM D1505-18 / ISO 1183-1:2019 | 0.920 g/cm³ |
| Melting peak temperature | ASTM D3418-21 | 121 °C |
| Tensile strength at yield, MD/TD | ASTM D638-14 | 11.0 MPa / 10.5 MPa |
| Tensile strength at break, MD/TD | ASTM D638-14 | 42.0 MPa / 38.0 MPa |
| Elongation at break, MD/TD | ASTM D638-14 | 720% / 850% |
| Dart impact, F50 | ASTM D1709-15a | 650 g |
| Elmendorf tear, MD/TD | ASTM D1922-15 | 250 g / 350 g |
The mechanical values in the table are generated on 25 µm blown film using standard conditions; production-line films often show lower dart impact and tear values when the gauge distribution widens or when frost-line height is not separately optimised after the resin change.
Production-scale blown film extrusion of a 0.35 g/10 min LLDPE requires equipment configured for high melt pressure and controlled shear heating. On a 65 mm grooved-feed extruder with a 30:1 L/D barrier screw feeding a 250 mm mono-layer die, the grade has been processed at die melt temperatures of 185 °C to 205 °C; the exact set point depends on screw speed, back pressure, and gauge control. A die gap of 1.5 mm to 2.5 mm is used to balance output against film toughness. The blow-up ratio is normally maintained between 2.0:1 and 3.0:1, with a frost-line height between 5 and 8 die diameters. Reducing the die gap below 1.2 mm is not recommended for this viscosity class because the increased die land shear can initiate melt fracture and oxidation-induced die-lip deposit; the resulting film surface shows sharkskin and reduces dart impact by concentrating stress at surface irregularities.
The low melt flow rate also means that melt temperature control is more sensitive to screw speed than in higher-MFR film grades. On a line equipped with a melt pump and internal bubble cooling, the melt pump suction pressure should be monitored to maintain 8 MPa to 12 MPa before filtration; a screen pack of 40/60/80 mesh is used to remove gel particles while limiting pressure drop. Filter pack pressure buildup during extended runs is a batch-to-batch variance marker for LLDPE film extrusion and can indicate contamination before visible gel counts increase on the film surface.
Thermally driven crosslinking and chain scission in Ziegler-Natta LLDPE become process-relevant when melt temperature exceeds 230 °C for more than 10 min residence time. Dead spots in the adapter or screen changer can generate oxidised gel particles that pass through the die and appear as fisheyes; the oxidation induction time is governed by the stabiliser package and is not a fixed resin property. The apparent shear viscosity of LLDPE in the 180–220 °C range follows an Arrhenius temperature dependence with an activation energy reported in the literature between 25 kJ/mol and 35 kJ/mol; this means that small barrel-temperature changes of 5 °C to 10 °C can materially alter melt pressure and bubble stability.
Where the manufacturer’s documentation identifies a higher alpha-olefin comonomer, the differentiation against C4-butene LLDPE grades of similar density and melt flow rate is most consistently observed in low-temperature dart impact and tear propagation resistance. The higher tie-molecule concentration in higher alpha-olefin LLDPE permits more energy absorption before puncture, shifting film failure from brittle puncture to ductile stretching. A converter replacing a butene-based LLDPE with LLDPE 7635 must re-optimise blow-up ratio and frost-line height after the change; shear rheology and melt elasticity are not identical, and an unchanged parameter set can erase the expected toughness gain. Comparative quality-control measurements should be made on identical gauge film using ASTM D1709-15a for dart impact, ASTM D1922-15 for Elmendorf tear, and ASTM D1003-21 for haze.
The grade is not a metallocene-catalysed resin. Its molecular weight distribution is broader than that of metallocene-catalysed LLDPE of equivalent density, which generally improves bubble stability and shear thinning but increases haze and lowers gloss. The broader distribution also means that the onset of melt fracture occurs at lower shear rate than with metallocene grades; therefore, copying a metallocene-grade die gap and die land geometry directly is not valid. Compared with low-density polyethylene film grades of similar density, LLDPE 7635 provides higher elongation and tear propagation resistance but lower melt strength at a given melt temperature; compared with high-density polyethylene film grades, it exhibits lower tensile modulus and higher water vapour transmission rate, as expected from the density difference.
Food-contact status for polyolefin film grades is commonly evaluated under US FDA 21 CFR 177.1520(c) for olefin polymers. The specific status of HANWHA LLDPE 7635 must be confirmed against the manufacturer’s food-contact statement and the finished article’s end-use conditions; generic polymer compliance is not sufficient for overall migration certification. Under EU food-contact legislation, compliance is evaluated against EU Regulation (EU) No 10/2011, with overall migration measured according to EN 1186-1:2002 and specific migration according to the applicable EN 13130-1:2004 methods. The regulatory matrix below summarises the verification framework applicable to polyolefin packaging and E&E components.
| Regulation/standard | Scope | Verification method |
|---|---|---|
| US FDA 21 CFR 177.1520(c) | Olefin polymers for food contact | Extraction and end-use testing under §177.1520(d) conditions |
| EU Regulation (EU) No 10/2011 | Plastic food-contact materials and articles | Overall migration via EN 1186-1:2002; specific migration via EN 13130-1:2004 |
| REACH Regulation (EC) No 1907/2006 | SVHC screening and communication | Article 33 notification at 0.1 wt% SVHC threshold |
| RoHS Directive 2011/65/EU | Hazardous substance restrictions in E&E | Screening via IEC 62321-3-1:2013 XRF methods |
REACH SVHC screening and RoHS restrictions are article-level obligations that depend on the full formulation, including masterbatches and printing inks, not solely on the base resin. If the final article contains a substance of very high concern above the 0.1 wt% threshold, REACH Article 33 communication duties apply even when the base resin itself is below the threshold.
At normal warehouse humidity levels, storage of the resin does not require drying; however, condensation on pellet surfaces at relative humidity above 60% can introduce surface moisture into the extruder feed throat and should be prevented by allowing the material to reach processing area temperature before opening the packaging. Extended hold-up at melt temperatures above 230 °C increases crosslinking and gel-particle generation in Ziegler-Natta LLDPE, particularly in extruders with dead spots. The resin should not be blended with amine-containing antifog or antistatic concentrates unless the masterbatch supplier has confirmed compatibility with the antioxidant package; amine migration can shift the film seal initiation temperature and affect coupon-level migration results under EN 1186-1:2002. A purge sequence from a metallocene LLDPE or HDPE product should maintain barrel temperatures in the range of 170 °C to 210 °C and avoid abrupt drops in screw speed that can leave stagnant resin at the adapter.