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Guangdong Huazhuo ABS/PMMA 900BK

    • Product Name: Guangdong Huazhuo ABS/PMMA 900BK
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 585175
    Color Black
    Density 1.08 g/cm³
    Melt Flow Rate 8 g/10 min (230°C/3.8 kg)
    Tensile Strength 45 MPa
    Elongation At Break 20%
    Flexural Strength 70 MPa
    Flexural Modulus 2100 MPa
    Izod Impact Strength 12 kJ/m²
    Rockwell Hardness R105
    Heat Deflection Temperature 85 °C
    Vicat Softening Temperature 95 °C
    Molding Shrinkage 0.4–0.6%
    Surface Gloss 90 GU
    Flammability Rating HB

    As an accredited Guangdong Huazhuo ABS/PMMA 900BK factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Guangdong Huazhuo ABS/PMMA 900BK is typically packed in 25 kg moisture-resistant paper bags, palletized for secure industrial delivery.
    Container Loading (20′ FCL) 20-foot FCL container loaded with Guangdong Huazhuo ABS/PMMA 900BK chemical, securely packed and stowed for ocean freight.
    Shipping Guangdong Huazhuo ABS/PMMA 900BK is shipped as a non-hazardous thermoplastic resin in sealed 25 kg bags or palletized packaging. Keep dry and ventilated, away from moisture, direct sunlight, and heat. No special dangerous-goods classification or transport restrictions are required.
    Storage Store Guangdong Huazhuo ABS/PMMA 900BK in a cool, dry, well-ventilated area, away from direct sunlight, heat, ignition sources, and moisture. Keep original containers tightly sealed and avoid dust or contamination. Stack securely and follow manufacturer guidelines. Avoid contact with strong oxidizers and solvents. Use proper handling to prevent static buildup.
    Shelf Life Guangdong Huazhuo ABS/PMMA 900BK has a typical shelf life of 12 months in unopened original packaging under cool, dry, ventilated storage.
    Application of Guangdong Huazhuo ABS/PMMA 900BK

    Instrument cluster mask rings, center console side inserts, door switch bezels, and steering wheel spoke covers are molded in Guangdong Huazhuo ABS/PMMA 900BK when the cockpit design requires a black, scratch-tolerant decorative surface rather than a structurally loaded component. The alloy is specified for non-impact-critical zones because the PMMA-rich phase raises surface hardness and gloss replication while lowering low-temperature ductility compared with unfilled ABS. Molding operations begin with closed-loop desiccant hopper drying at 80–90 °C for 3–4 h until residual moisture is below 0.05 wt%. Barrel temperatures are profiled from 210 °C in the feed zone to 240–250 °C at the nozzle; excursions above 260 °C induce PMMA degradation, producing splay and a brown shift in the black base. Polished tool surfaces are held between 70 °C and 90 °C with a pressurized-water thermolator to increase replication of SPI A-2 finishing and to reduce visible weld lines around switch apertures. Surface gloss is measured with a 20° geometry under ASTM D523, with polished regions normally reading above 90 GU; pencil hardness under ASTM D3363 falls in the F–2H range for high-gloss formulations of this class. Dimensional stability is validated against OEM thermal cycling schedules that reference ISO 16750-4, typically exposing assembled trim from −40 °C to 90 °C while monitoring stress whitening and snap-fit retention. Sequential valve-gated tools processing 900BK require valve delay settings that prevent melt front dwell times longer than 0.1 s; longer hesitation produces visible flow lines on pedestal transitions. The grade is excluded from airbag covers, knee-bolster substrates, and other high-speed occupant-loading structures because notched impact retention decreases as the PMMA fraction increases.

    ParameterSetpoint windowProcess observation
    Pre-drying80–90 °C for 3–4 hResidual moisture ≤ 0.05 wt%; dryer dew point ≤ -30 °C
    Melt temperatureFeed 210 °C; nozzle 240–250 °CUpper limit 260 °C to protect the PMMA fraction
    Mold surface temperature70–90 °CHigher end used for gloss replication and weld-line strength
    Injection speed80–200 mm/sAvoid direct-gate speeds above 250 mm/s to prevent jetting
    Back pressure3–5 barMaintains homogeneous dispersion of the black masterbatch

    When Thin-Wall Display Bezels Demand Uniform Filling and Low Gloss Variation

    For monitor bezels, laptop lid covers, and television frame strips, the 900BK black alloy is processed in thin-wall tools where nominal wall stock is between 1.2 mm and 1.8 mm. The carbon black pre-color package removes post-mold paint operations, but it also alters infrared absorption during drying; compact dryer setpoints must be verified against actual pellet mass temperature rather than circulating air temperature. Melt is delivered through a velocity-controlled injection unit with screw L/D of 20–24. High injection speed prevents premature freeze-off at the end of fill, but direct-gate speeds above 250 mm/s can produce jetting on visible surfaces. Gate land length is maintained at 0.8–1.2 mm with a gate diameter not less than 0.6 mm for cosmetic front surfaces. Cavity surface temperature is held between 65 °C and 85 °C, and the polished cavity finish is preserved through periodic chromium-plating inspection. Gloss variation is tracked under ASTM D523; a flow-end reading below 85 GU indicates insufficient packing, while readings above 95 GU combined with sink at bosses indicate overpacking. The base 900BK grade carries no inherent antistatic function because the carbon black is a colorant rather than a controlled conductive filler. Where charge dissipation to an operator or card reader is required, surface resistivity must be measured under IEC 61340-2-3, and a conductive primer or post-mold coating is applied only if the test result exceeds the end-product ceiling. Terminal parts include black display bezels, cable-management frames, and rear covers for commercial monitors; flammability evaluation is conducted under UL 94 at end-use thickness.

    Washing machine console subassemblies, refrigerator water-dispenser bezels, and air-conditioner front panels impose repeated contact with dilute cleaners, skin oil, and localized condensation on the black cosmetic surface. ABS/PMMA 900BK is molded at melt temperatures of 230–250 °C and mold temperatures of 70–85 °C to obtain scratch-tolerant gloss without hard coating. The PMMA-rich skin does not remove environmental stress cracking risk, and compatibility is screened by wiped exposure to the intended cleaner under ISO 22088-3, with an applied bending strain of 0.45% for comparative evaluation. Dilute detergent and vinegar solutions at use concentration generally do not produce visible crazing within 24 h at 23 °C, but cleaning concentrates containing more than 5% aromatic hydrocarbon or ketone are excluded because they reduce surface hardness and open micro-cracks at gate bosses. In capacitive-touch control panels, the black alloy is frequently deployed as the cosmetic second shot over a transparent PMMA or polycarbonate light guide; interfacial adhesion at the display window is maintained by controlling the second-shot nozzle temperature at 245–255 °C and by preventing mold release migration from upstream operations. Sink-mark control over rib intersections is checked with a flatness gauge calibrated to 0.05 mm across 100 mm of visible edge. Terminal products include rotary knob rings, LED diffuser frames, and control panel skirts with integrated snap features.

    Medical Enclosure Alkaline Cleaner Resistance and ISO 10993 Verification Limits

    For non-invasive diagnostic carts, bedside monitor housings, and handheld controller shells, 900BK is processed only after the molder confirms that the part geometry does not create recessed seams that retain disinfectant. The grade is applied to black cosmetic areas exposed to hydrogen peroxide or quaternary ammonium compound wiping multiple shifts per day. Under repeated cleaning, PMMA-containing blends retain gloss better than unfilled ABS in mildly alkaline conditions, but the material is not recommended for isopropyl alcohol concentrations above 30% because molded-in strain can develop stress crazing at the PMMA-rich surface. Cleaner compatibility is screened with ASTM D543 and confirmed on finished parts by visual inspection after 50 cleaning cycles according to the device manufacturer protocol. For regulatory submission, cytotoxicity of a geometrically representative sample is evaluated under ISO 10993-5, and skin irritation or sensitization data are generated under ISO 10993-10 and ISO 10993-23 as applicable. The neat 900BK resin does not by itself provide biocompatibility certification for a finished device. If gamma sterilization is required, the PMMA fraction is subject to molecular chain scission and visible yellowing at doses between 25 kGy and 50 kGy; color shift must be quantified before release under ISO 11137-2. The material is restricted to external enclosures and strap-free components without prolonged mucosal or open-wound contact. Molding uses medical-grade tool maintenance, oil-free compressed air, and ultrasonic welding amplitude below 20 µm to avoid energy-director cracking.

    SegmentTest anchorLimitation boundary
    Automotive cockpit trimASTM D523, ASTM D3363, ISO 16750-4Excludes airbag and high-speed load-bearing structures
    Display bezelsUL 94, IEC 61340-2-3No inherent ESD control from colorant carbon black
    Appliance panelsISO 22088-3Excludes cleaning concentrates with aromatic hydrocarbon or ketone
    Medical enclosuresISO 10993-5, ISO 10993-10, ISO 11137-2Gamma sterilization can yellow the PMMA fraction
    POS/ATM fasciaISO 180/1A, IEC 61000-4-2Low-temperature impact is lower than unfilled ABS
    Office imaging coversISO 1133-1, UL 94Standard grade is limited to HB at thin wall

    What Limits Point-of-Sale Bezel Impact Retention at Subzero Temperatures?

    Self-service kiosk bezels, POS terminal covers, and ATM fascia panels are injection molded with 900BK because the black pre-color removes paint-line bottlenecks, but low-temperature impact is the governing design constraint. PMMA increases surface hardness at the expense of ductility; notched Izod measured under ISO 180/1A at −30 °C is typically lower than that of unfilled ABS by a margin that must be confirmed on the supplier certificate of analysis. Sharp gate or snap-fit corners with internal radii below 0.8 mm act as crack initiation sites when point loads are applied to card slots or keypad apertures. Rib-to-wall ratios are kept between 0.4 and 0.6 to reduce shrinkage stress, and ejector pins are positioned away from visible front surfaces. Where electromagnetic shielding is required, electroless nickel or copper-nickel plating on the PMMA-rich surface requires chromic acid etching; published data for plating adhesion on Guangdong Huazhuo ABS/PMMA 900BK is limited, so each plating line must establish its own peel adhesion under ASTM B533. Electrostatic discharge requirements for payment terminals reference IEC 61000-4-2, and the molded black part may require a separate conductive sealing gasket because the base-grade 900BK is not formulated as a static-dissipative compound. Terminal products include fascia frames, side skirts, and cash-acceptor bezels where drop impact at −20 °C and −30 °C is part of field reliability testing.

    Office imaging lanes producing printer front bezels, scanner lid frames, and multifunction device control surrounds allocate the 900BK pre-color to flat cosmetic covers that must remain stable across molded-in bosses and snap features. Lot-to-lot consistency of the black masterbatch is measured by melt flow rate under ISO 1133-1 at 220 °C and 10 kg; a drift of more than 15% from the qualified lot alters filling pressure and changes the sink-mark threshold at rib intersections. Processing temperatures respect the same 250 °C upper limit, with mold temperatures from 60 °C to 80 °C for textured surfaces. For parts containing grained and polished zones in the same cavity, gas entrapment at the step transition is released with vacuum venting below −0.08 MPa to prevent burn marks. Flammability classification for office equipment is commonly assessed under UL 94; standard 900BK without an additional flame-retardant package is generally limited to HB at thicknesses below 1.5 mm. Any V-0 or V-1 requirement must not be assumed and requires a dedicated flame-retardant formulation separate from the standard 900BK grade. Terminal products include black scanner bezels, printer top covers, and control surround panels for document feeders.

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    Certification & Compliance
    More Introduction

    Guangdong Huazhuo ABS/PMMA 900BK is a black-pigmented thermoplastic alloy formulated from acrylonitrile-butadiene-styrene and polymethyl methacrylate. The designation 900BK identifies a black colour concentrate or pre-compounded carbon black masterbatch within the manufacturer’s internal nomenclature; the numeric prefix is not defined by an international standard and should be verified against the lot-specific certificate of analysis. Because the manufacturer does not publish a complete ISO datasheet for this specific grade, the property ranges reported here are drawn from comparable ABS/PMMA alloy specifications and should be used for engineering screening rather than final part qualification. The material is positioned for high-gloss, scratch-resistant moulded components where unpainted black surfaces must survive mechanical loading, moisture exposure, and repetitive cleaning. Unlike general-purpose ABS that depends on a dispersed polybutadiene rubber phase for impact accommodation, ABS/PMMA 900BK relies on the PMMA phase to increase surface hardness and gloss retention while lowering low-temperature ductility relative to pure ABS. The compound must therefore be processed within a narrower thermal window than standard ABS or PC/ABS alloys because PMMA thermally degrades by depolymerisation above approximately 250 °C, while melt viscosity increases rapidly below 210 °C.

    What Drying and Melt-Temperature Constraints Apply to ABS/PMMA 900BK Before Compounding or Moulding?

    The resin should be dried in a desiccant dryer with a dew point not higher than -40 °C at 80 °C for 3 h to 4 h, targeting residual moisture below 0.02% by weight. Moisture levels above 0.05% hydrolyse the PMMA ester groups during plastication and produce splay, silver streaks, and molecular weight reduction. Conditioned at 23 °C and 50% RH, the alloy can reach equilibrium moisture absorption of 0.3% to 0.5% when evaluated according to ISO 62:2008. Drying hopper residence time at 80 °C should not exceed 6 h to avoid yellowing of the PMMA phase. For injection moulding, a general-purpose screw with 20:1 to 24:1 L/D and compression ratio of 2.0:1 to 2.5:1 is acceptable if the screw provides sufficient dispersive mixing. For compounding, a 40:1 L/D co-rotating twin-screw extruder is typical because it limits thermal history while dispersing carbon black. Barrel temperatures are usually set between 210 °C and 240 °C, with the nozzle held at 230 °C to 250 °C. Melt temperature measured at the nozzle should not exceed 250 °C, and total residence time at melt temperature should be kept below 5 min. When hot runner manifolds are used, independent zone control with setpoint deviation limited to ±2 °C reduces the risk of dead-zone carbon black accumulation.

    Rheological Signature and Screw Design Requirements in High-Gloss Moulding

    Melt volume-flow rate tested under ISO 1133-1:2022 at 220 °C with 10 kg is expected to fall between 10 cm³/10 min and 20 cm³/10 min for an ABS/PMMA blend of this viscosity class; the exact value must be confirmed because black pigment increases viscosity slightly and shifts batch-to-batch flow properties. The forward pressure at the nozzle during injection should be 80 MPa to 120 MPa, with screw back pressure maintained between 0.5 MPa and 1.0 MPa to stabilise melt cushion without overshear. Hold pressure is typically 50% to 70% of injection pressure for 3 s to 6 s, although gate geometry and part thickness control the required packing time. Mould temperature should be held between 60 °C and 80 °C. Temperatures below 50 °C reduce gloss and increase flow marks, while temperatures above 80 °C extend cycle time and may cause part sticking in the PMMA-rich surface layer. High injection speed is preferred to prevent premature freeze-off, but excessive speed creates jetting and black specks from shear-induced degradation. Fan gates or tab gates are preferable to pin gates smaller than 1.0 mm because small gates freeze off before adequate packing, producing sink marks and dimensional variability. On production-scale injection moulding machines, the shot volume should not exceed 80% of the barrel capacity for thermally sensitive black ABS/PMMA compounds.

    Mechanical screening values for black ABS/PMMA alloys are sensitive to carbon black dispersion, moulded skin orientation, and weld-line placement. Test specimens should be prepared under controlled conditions following ISO 294-1:2017, and the results below are typical ranges for comparable ABS/PMMA grades rather than lot-specific values for Guangdong Huazhuo ABS/PMMA 900BK.

    PropertyTest methodABS/PMMA 900BK typical rangeGeneral-purpose ABS typical range
    DensityISO 1183-1:20191.06–1.10 g/cm³1.04–1.06 g/cm³
    Melt volume-flow rateISO 1133-1:202210–20 cm³/10 min15–30 cm³/10 min
    Tensile yield stressISO 527-2:201245–55 MPa40–50 MPa
    Tensile elongation at yieldISO 527-2:20123–5%2–4%
    Flexural modulusISO 178:20192200–2800 MPa2000–2500 MPa
    Notched Izod impact at 23 °CISO 180:20238–12 kJ/m²20–30 kJ/m²
    Notched Izod impact at -30 °CISO 180:20233–5 kJ/m²8–12 kJ/m²
    Vicat softening temperatureISO 306:202295–105 °C95–105 °C
    Heat deflection temperatureISO 75-2:202080–90 °C80–95 °C
    Water absorption 24 hISO 62:20080.3–0.5%0.2–0.4%

    Compared with PC/ABS, ABS/PMMA 900BK uses PMMA rather than polycarbonate as the stiffening and gloss-enhancing phase. PC/ABS grades generally retain higher multiaxial impact at low temperature and higher heat distortion, but they require higher melt temperatures and are more likely to show surface defects when moulded with high carbon black loadings. ABS/PMMA 900BK is selected when the application prioritises surface hardness, colour depth, and scratch resistance over extreme ductility. Compared with unmodified PMMA, the ABS phase improves melt toughness and part ejection while sacrificing optical clarity and outdoor weatherfastness. Published data for this specific configuration is limited, so direct substitution should be confirmed by part-level impact testing under the intended service temperature range.

    When ABS/PMMA 900BK Replaces Painted ABS in Automotive Interior Trim

    Painting ABS automotive interior components can be eliminated when ABS/PMMA 900BK is used because the alloy provides a high-gloss black surface with improved mar resistance. In instrument panel bezels, air vent rings, steering wheel trim, and centre console elements, moulded-in black gloss eliminates post-mould painting in selected low-wear areas. Compared with painted ABS, the advantage is reduced volatile organic compound emissions and fewer manufacturing steps. Compared with unpainted ABS, the alloy shows higher surface hardness, typically F to H pencil hardness under ASTM D3363-20. Gloss retention under dry abrasion is process-dependent and must be correlated using a standardised scratch tip; no single international standard covers all automotive interior scratch modes. At -30 °C, notched Izod impact falls to approximately 3 kJ/m² to 5 kJ/m² in comparable alloys, so components must avoid sharp corners and heavy snap-fit deflection. Outdoor exposure is not implied unless a UV stabiliser package is specified, because the butadiene phase in ABS embrittles under sunlight and pigmented PMMA does not fully protect the rubber phase.

    Electronic enclosures and appliance fascias represent a second use category. The black-pigmented alloy supports moulded-in logos, grille slats, vacuum cleaner wands, headphone shells, and control panel surrounds where surface aesthetics and scratch resistance are critical. For these applications, the melt must be processed without excessive shear because carbon black loading can lower weld-line tensile strength by 20% to 30% relative to unfilled ABS when weld lines are formed by direct impingement. Gate locations should therefore be set using mould-filling simulation to move weld lines away from structural bosses and snap-fit anchors. Regrind content should not exceed 20% unless the moulder validates impact retention and surface appearance, because repeated thermal cycling degrades the PMMA phase and shifts the melt-flow rate by 2–3 cm³/10 min in production lots.

    Compliance verification for Guangdong Huazhuo ABS/PMMA 900BK should be obtained from the manufacturer or the compounder for each production lot. The following checklist lists the relevant standard designations and required verification data.

    Regulatory areaStandard or directiveScope for ABS/PMMA 900BKRequired verification
    Restriction of hazardous substancesEU RoHS Directive 2011/65/EU Annex II including EU 2015/863Black-pigmented alloy may contain carbon black; heavy metals and phthalates must be below maximum concentration valuesSupplier certificate of compliance per lot
    Chemical registrationREACH Regulation (EC) No 1907/2006Substances of very high concern declared by manufacturerArticle 33 communication if SVHC exceeds 0.1%
    Polymer markingISO 11469:2016Marking as >ABS+PMMA<Mould cavity or label
    Density testISO 1183-1:2019Quality control for material consistencyLaboratory balance per method A or B
    Specimen preparationISO 294-1:2017Injection moulding of test specimensControlled mould temperature and documented cycle

    Failure Modes Observed on Production Lines Originate from Inadequate Venting and Overshear

    Splay and silver streaks on moulded black surfaces are most frequently traced to residual moisture above 0.05% or barrel residence times longer than 5 min. In production, this defect appears as elongated streaks radiating from the gate and is confirmed by drying the material to below 0.02% moisture and reducing screw recovery speed. Black specks are often caused by carbon black agglomerates released from dead zones in hot runner manifolds or screw decompression settings above 5 mm. To prevent this, decompression should be limited to 3 mm to 5 mm, and the hot runner should be purged after any colour change from natural to black. Gloss variation across large surfaces is controlled by mould temperature uniformity. Mould cooling circuits should maintain a temperature differential of no more than ±3 °C across the cavity surface. Vent grooves on the parting line should be cut to 0.02 mm to 0.03 mm depth to prevent gas burn; deeper vents cause flash on low-viscosity ABS/PMMA melts. Weld-line weakness is an inherent limitation of pigmented ABS/PMMA and becomes unacceptable when the gate layout places a weld line across a load-bearing snap-fit. In those cases, a second gate or sequential valve gate control is required to relocate the weld line to a non-structural cosmetic area.

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