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Formosa Plastics HDPE TAISOX 7301

    • Product Name: Formosa Plastics HDPE TAISOX 7301
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 491564
    Density 0.951 g/cm3
    Melt Flow Rate 190 C 2 16 Kg 0.05 g/10 min
    Tensile Strength At Yield 24 MPa
    Tensile Strength At Break 30 MPa
    Elongation At Break >600%
    Flexural Modulus 0.80 GPa
    Notched Izod Impact Strength 0.50 J/cm
    Shore D Hardness 55
    Vicat Softening Point 120°C
    Heat Deflection Temperature 0 45 Mpa 70°C
    Brittleness Temperature -70°C
    Environmental Stress Crack Resistance >1000 h
    Mold Shrinkage 2.0-4.0%
    Melting Point 130°C
    Water Absorption <0.01%
    Thermal Expansion Coefficient 1.2E-4 /°C
    Thermal Conductivity 0.40 W/m·K
    Dielectric Strength 20 kV/mm
    Volume Resistivity >1E16 ohm·cm

    As an accredited Formosa Plastics HDPE TAISOX 7301 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Formosa Plastics HDPE TAISOX 7301 is typically supplied in 25 kg bags or 1,000 kg jumbo bags.
    Container Loading (20′ FCL) 20′ FCL container loaded with Formosa Plastics HDPE TAISOX 7301 in 25 kg bags, palletized and securely stowed for ocean export.
    Shipping Formosa Plastics HDPE TAISOX 7301 is shipped as a non-hazardous polyethylene resin in 25 kg bags or 1,000 kg jumbo bags, palletized and stretch-wrapped. Transport in clean, dry containers by sea or land; keep away from moisture, heat, and direct sunlight. Store under cool, ventilated conditions; no special hazards if handled properly.
    Storage Store Formosa Plastics HDPE TAISOX 7301 in a cool, dry, well-ventilated warehouse away from direct sunlight, heat, sparks, and open flames. Keep original packaging closed to prevent moisture, dust, and contamination. Protect from ultraviolet light and prolonged high temperatures. Stack pallets securely on stable surfaces. Avoid contact with strong oxidizers. Clean spills promptly, as pellets may create slippery conditions.
    Shelf Life Formosa Plastics HDPE TAISOX 7301 has a recommended 12-month shelf life when stored sealed, cool, dry, and away from sunlight.
    Application of Formosa Plastics HDPE TAISOX 7301

    Blown film lines configured for retail carrier bags process Formosa Plastics HDPE TAISOX 7301 as a high-molecular-weight film grade with a nominal melt flow index of 0.30 g/10 min under ASTM D1238 at 190 °C/2.16 kg and a nominal density of 0.951 g/cm³ under ASTM D1505. The extruder profile is set from 170 °C in the feed section to 190 °C in the compression zone, with a melt temperature of 195 °C to 215 °C and a die temperature of 190 °C to 210 °C. A die gap of 1.0 mm to 1.4 mm and a blow-up ratio of 3.0:1 to 4.5:1 maintain bubble geometry on a dual-lip air ring. The frost line height is kept at 5 to 8 die diameters to balance quench rate and gauge uniformity. In a typical carrier-bag formulation, 70 to 80 wt% virgin TAISOX 7301 is blended with 20 to 30 wt% clean post-industrial edge trim. A 10% silica antiblock masterbatch is metered at 1.0 to 2.0 wt%, and a primary hindered phenol antioxidant masterbatch is added at 0.05 to 0.15 wt%. Film gauge is specified between 12 µm and 25 µm. The converted T-shirt bag is sealed on a bottom-seal bag machine at 140 °C to 160 °C with 0.5 s dwell and 0.3 MPa to 0.5 MPa seal pressure. Under FDA 21 CFR 177.1520, the olefin polymer can comply for direct food contact only when the finished film meets extractable limits; for retail bags the route is non-food contact. In Europe, EU 10/2011 compliance applies when the bags are used in bakery or produce applications, and the converter is responsible for overall migration testing. A plant-scale failure mode on lines without internal bubble cooling is bubble instability below 15 µm, which appears as rhythmic gauge bands at the frost line and is corrected by raising air ring pressure rather than increasing melt temperature beyond 215 °C.

    What Limits Downgauging Below 12 µm in High-Speed Bin Liner Conversion?

    Below 12 µm gauge, the dominant constraint in refuse sack conversion is not extruder output but bubble tension loss between the frost line and the collapsing frame. On a line running TAISOX 7301 at 80 kg/h to 120 kg/h through a 90 mm grooved-feed extruder with L/D 30:1, the barrel profile is set from 175 °C in zone 1 to 205 °C at the adapter and die. A die gap of 0.8 mm to 1.0 mm and a blow-up ratio of 3.5:1 to 4.0:1 are used. Because the melt flow index is 0.30 g/10 min, the bubble neck remains stable at frost line heights up to 9 die diameters, but neck flutter appears when the dual-lip air ring is set below 40% of maximum cooling air volume. In a dense refuse sack formulation, 40 to 60 phr TAISOX 7301 is blended with 40 to 60 phr recycled HDPE from post-consumer bottle scrap. A carbon black masterbatch with a 45% carbon black loading is added at 2.0 to 3.0 phr for opacity and ultraviolet screening. The recycled fraction must be dried to 0.02% moisture or less when it originates from a wet granulation line, or splay defects occur at the die lip. For 10 µm film, the target tensile stress at yield under ASTM D882 is at least 20 MPa in the machine direction and 18 MPa in the transverse direction. Tensile elongation at break is typically above 400%. Dart impact under ASTM D1709 Method A is specified above 80 g at 10 µm, and Elmendorf tear strength under ASTM D1922 is not less than 0.12 N in the machine direction. Side-weld bag machines are set at 135 °C to 155 °C, 0.25 MPa to 0.45 MPa, and 0.3 s to 0.6 s dwell. In the European Union, household refuse sacks are classified under EN 13592:2017; the converter carries the classification because the resin producer does not supply finished-sack certificates. The stable operating boundary is reached at 10 µm when recycled content exceeds 60 phr because inconsistent melt flow in post-consumer HDPE widens gauge bands by ±2 µm and increases side-weld pinholes.

    The compliance anchors are not interchangeable across downstream routes, and the following matrix identifies the standard or regulation applied at converter level.

    Application routeCompliance referenceTest methodParameter verified at converter level
    Retail carrier bagFDA 21 CFR 177.1520; EU 10/2011ASTM D1709 Method A; ASTM D1922Dart impact and Elmendorf tear at 20 µm
    Refuse sackEN 13592:2017ASTM D1709 Method A; ASTM D882Burst resistance and gauge classification
    Extrusion-laminated woven sackUN Model Regulations 6.1.5ASTM F88; ASTM F1249Seal strength and moisture vapour transmission rate on finished composite
    Form-fill-seal pouchFDA 21 CFR 177.1520; EU 10/2011ASTM F88; ASTM D882Seal strength and secant modulus
    Drum linerUN Model Regulations 6.1; FDA 21 CFR 177.1520ASTM D1693 Condition BEnvironmental stress crack resistance
    Tissue overwrapFDA 21 CFR 177.1520; EU 10/2011ASTM D1894; ASTM D5748Kinetic coefficient of friction and puncture resistance

    Tandem extrusion lamination lines for woven polypropylene fertiliser sacks use TAISOX 7301 as the moisture-barrier coating. The extrusion lamination line uses a 90 mm single-screw extruder with a barrier mixing section and L/D 28:1. Barrel temperatures rise from 200 °C in the feed zone to 290 °C at the front zone, and the T-die is held at 270 °C to 290 °C. The air gap between die exit and chill roll nip is 150 mm to 200 mm, and the chill roll is set at 15 °C to 25 °C. Coating thickness is 15 µm to 30 µm over 50 g/m² to 70 g/m² woven PP substrate. The substrate is corona-treated to at least 40 dyn/cm. When the sack is destined for hygroscopic fertiliser under high humidity, an 8 to 12 µm LDPE or EMA tie layer is inserted between substrate and HDPE coating. The tie layer reduces delamination in drop testing of filled 50 kg sacks. The coated side is re-treated to 38 to 42 dyn/cm before rotogravure printing. Seal strength measured under ASTM F88 on a 25 µm coating typically exceeds 30 N/25 mm when the sealer is set at 145 °C and 0.5 s dwell. For dangerous goods packaging, the composite sack may be qualified under UN Model Regulations 6.1.5 for solid hazardous materials in Packing Group II or III if the complete package passes the 1.2 m drop test and stacking test; the film coating alone is not the certified component. Moisture vapour transmission rate under ASTM F1249 at 38 °C and 90% RH must be measured by the converter because published data for this exact composite configuration is limited. Edge neck-in is controlled by keeping the die-to-nip distance below 200 mm and melt temperature above 280 °C, but raising melt temperature above 300 °C can initiate gel formation from degraded antioxidant packages and should be avoided.

    Dowel-Stiff HDPE as the Middle Layer in Three-Layer Form-Fill-Seal Film

    In coextruded form-fill-seal films for dry food pouches, TAISOX 7301 is processed as a stiffness core in an ABA structure where the outer layers are LDPE or LLDPE sealants. The HDPE core layer is set at 20% to 40% of total film thickness, and final film gauge is 60 µm to 100 µm. On a three-layer blown film line with extruder diameters of 50 mm, 65 mm, and 50 mm, the core extruder is operated at 185 °C to 210 °C, while the seal-layer extruders are held at 160 °C to 180 °C. A die gap of 1.2 mm is selected to accommodate the higher viscosity of the HDPE core, and the blow-up ratio is kept at 2.0:1 to 2.5:1 to favour transverse stiffness without destabilising the bubble. The core layer contains 100 phr TAISOX 7301 plus 0.1 to 0.2 phr of a phosphite stabiliser masterbatch. No antiblock is added to the core because slip and antiblock additives are carried in the sealant at 1.0 to 1.5 wt%. The finished film is tested for tensile modulus under ASTM D882, with the HDPE core raising the 1% secant modulus above 450 MPa depending on layer ratio. Heat seal initiation temperature is controlled by the LDPE sealant; seal strength of 15 N/25 mm is typically achieved at 125 °C with 0.5 s dwell under ASTM F88. For food contact compliance, the HDPE component must satisfy FDA 21 CFR 177.1520, and the multilayer structure must meet EU 10/2011 overall migration limits. Specific migration testing for the core is not required when the sealant layer acts as a functional barrier under the intended filling temperature and time, but the converter must document that barrier function. Terminal pouches are run on vertical form-fill-seal machines at 40 to 80 pouches per minute. A limitation occurs when the core layer exceeds 40% because the film becomes too stiff for the forming collar and develops longitudinal fold memory lines that crack open after creasing.

    When 200-L Drum Liners Face Environmental Stress Crack Resistance and Chemical Contact

    When a 200-L drum liner must endure stack pressure and aggressive chemical contact, environmental stress crack resistance becomes the controlling property. For 200-L steel drum and fibre drum liners, the film is extruded as a lay-flat tube with wall thickness from 80 µm to 120 µm and a circumference matched to the drum interior. TAISOX 7301 is used because its molecular weight, indicated by the 0.30 g/10 min melt flow index under ASTM D1238, provides higher environmental stress crack resistance than low-density film grades under ASTM D1693 Condition B in 10% Igepal CO-630 at 50 °C. The blown film line is configured with a 70 mm extruder, a die gap of 1.5 mm to 2.0 mm, and a blow-up ratio of 1.8:1 to 2.5:1 to produce a large tube diameter. Melt temperatures are held at 180 °C to 200 °C to limit oxidative degradation during long runs. The formulation includes 100 phr TAISOX 7301, 0.3 to 0.5 phr of a hindered amine light stabiliser system when liners are stored outdoors, and 0.05 to 0.10 phr of a process stabiliser. For pharmaceutical or food adjunct liners, the converter specifies FDA 21 CFR 177.1520 and maintains batch traceability to the resin certificate of analysis under ISO 9001. For chemical drum liners carrying liquid hazardous goods, the finished packaging is qualified under UN Model Regulations 6.1 as a combination package. The drum liner itself is not an independent UN package unless tested as an inner receptacle with its own closure. Melt fracture at the die lip occurs when melt temperature drops below 175 °C or when the die land length is shorter than 10 mm; the resulting shark-skin bands reduce flex-crack pinhole resistance under ASTM D1693 and are corrected by raising die temperature to 195 °C or increasing die gap. On a 1.2 m circumference tube, gauge uniformity of ±5% is attainable at 60 kg/h; below 45 kg/h the bubble loses internal pressure and produces port lines at the collapsing frame.

    Tissue Overwrap Lines Run Faster With Higher Slip Additive Loadings

    High-speed tissue overwrap lines place the coefficient of friction after slip migration ahead of film tensile strength. TAISOX 7301 is extruded into 15 µm to 25 µm monolayer film on a line with L/D 25:1, a die gap of 1.0 mm, and a blow-up ratio of 4.0:1 to 5.0:1. Melt temperature is held at 190 °C to 210 °C. The formulation adds 0.5 to 1.0 wt% of a 5% erucamide slip masterbatch and 0.5 to 1.0 wt% of a 10% silica antiblock masterbatch. The targeted kinetic coefficient of friction is below 0.25 under ASTM D1894. Slip migration continues for up to 72 h after extrusion; in-line rewinding before complete migration produces wrinkling on the flow-wrapper. Flow-wrap machines run at 60 to 120 packs per minute, and the film is corona-treated to 38 to 40 dyn/cm on the print side before flexographic marking with water-based inks. Under FDA 21 CFR 177.1520 and EU 10/2011, the converter must ensure the slip and antiblock masterbatches do not introduce substances outside the positive list when tissue products are sold into food-adjacent markets. Blocking of film rolls after warehouse storage above 35 °C is reduced by specifying a coefficient of friction no higher than 0.20 after 48 h and by keeping winder tension below 30 N/m. Puncture resistance under ASTM D5748 prevents protrusion puncture on automatic case packers.

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    Certification & Compliance
    More Introduction

    Formosa Plastics HDPE TAISOX 7301 is a high-density polyethylene injection-moulding grade supplied in pellet form. The nominal melt mass-flow rate is 20 g/10 min at 190°C under a 2.16 kg load when tested to ISO 1133-1:2022 or ASTM D1238-23. The density at 23°C is reported as 0.954 g/cm³ using ASTM D1505-18. The grade is intended for thin-wall injection moulding at nominal wall thicknesses between 0.6 mm and 2.0 mm, including food containers, dairy tubs, overcaps, housewares, and thin-walled pails. The high melt flow and unimodal molecular weight distribution lower filling pressure in multi-cavity tools, but they also reduce environmental stress crack resistance relative to medium-flow or low-flow HDPE grades. Converters must evaluate that trade-off against the service environment and applied load. Published spiral-flow data for this exact formulation is limited; flow simulation with supplier-viscosity models is recommended for hot-runner layouts.

    How Does Melt Rheology and Molecular Architecture Affect Mould Filling?

    At 190°C and 2.16 kg, the 20 g/10 min MFR value classifies the material as a high-flow HDPE. Capillary rheometry in the shear-rate range of 100 s⁻¹ to 1,000 s⁻¹ shows shear-thinning behaviour that is exploited during thin-wall filling. The viscosity at 100 s⁻¹ is lower than that of an 8 g/10 min injection grade, although exact values depend on lot molecular-weight distribution. On production-scale hydraulic injection moulding machines of 100–150 tonne clamp force, the lower melt viscosity commonly reduces peak injection pressure by 10–20% compared with medium-flow HDPE grades at equal wall section. The molecular architecture is linear and unimodal; it does not possess the long-chain branching associated with certain LLDPE grades. Consequently, melt strength is low, and nozzle drool can occur when melt temperatures exceed 240°C. The 0.954 g/cm³ density contributes stiffness but also increases solidification shrinkage, which must be compensated in tooling design and packing profiles.

    Processing on production-scale injection moulding lines uses a general-purpose polyolefin screw with 20:1 to 24:1 L/D ratio and a compression ratio of 2.5:1 to 3.0:1. Barrel settings from feed throat to nozzle are typically 180°C to 230°C; melt temperature measured by air shot should remain between 200°C and 240°C. Mould temperature is set between 10°C and 40°C. Low mould temperature reduces cooling time but increases frozen-in orientation and dimensional variation; mould temperatures near 40°C improve surface gloss and reduce anisotropic shrinkage at the cost of longer cycle time. For thin-wall containers of 0.7 mm nominal wall thickness, injection pressure commonly falls between 700 bar and 900 bar, with hold pressure at 60–80% of peak pressure until gate freeze. Screw speed is held between 50 min⁻¹ and 100 min⁻¹; back pressure is 0.5–1.5 MPa. A stable melt cushion of 3–5 mm is maintained. Drying is not usually required, but storage above 60% relative humidity or surface condensation on pellets warrants 80°C for 2 h in a desiccant hopper to prevent splay failures on the moulding line.

    Mechanical Property Benchmarks for Thin-Wall Packaging

    Typical property ranges reported for injection-moulded plaques conditioned at 23°C and 50% relative humidity for 40 h in accordance with ISO 291:2008 are shown below. The values should be read as class-representative for high-flow HDPE injection grades rather than guaranteed lot-specific results; the current supplier certificate of analysis governs final acceptance. Colour masterbatch and regrind content can shift mechanical properties significantly.

    PropertyTest methodTypical value or range
    Melt mass-flow rate (190°C, 2.16 kg)ISO 1133-1:2022 / ASTM D1238-2320 g/10 min
    Density (23°C)ASTM D1505-180.953–0.955 g/cm³
    Tensile yield stressISO 527-2:201223–27 MPa
    Tensile elongation at yieldISO 527-2:20127–10%
    Flexural modulusASTM D790-17800–1,000 MPa
    Notched Izod impact at 23°CASTM D256-2320–40 J/m
    Vicat softening point, 10 NASTM D1525-17122–126°C
    Heat deflection temperature at 0.45 MPaASTM D648-1870–80°C
    Mould shrinkage, flow directionASTM D955-081.5–2.5%

    The flexural modulus and density support stacking stiffness in thin-wall containers, while the notched Izod values restrict the material to ambient-temperature packaging rather than impact-critical industrial parts. Post-mould shrinkage may increase after 7 days because of secondary crystallisation; dimensional inspection should therefore be delayed or conditioned according to the applicable part standard.

    When Thin-Wall Part Geometry Raises Flow-Length-to-Wall-Thickness Ratios Above 120:1

    Design of thin-wall packaging with flow-length-to-wall-thickness ratios above 120:1 imposes a narrower processing window than conventional HDPE. At 0.6 mm nominal wall, the high MFR delays flow-front freeze-off, but gate geometry becomes critical. Valve-gated hot tips with gate diameters of 0.6–1.0 mm are common; edge gates below 0.8 mm freeze before packing and produce post-fill sink marks. In such geometries, melt temperature is maintained in the upper range of 220°C to 240°C. Excursions above 250°C are avoided because oxidative chain scission increases MFR and reduces molecular weight, which can lower drop-impact performance. Mould temperature is deliberately kept at 10–20°C for rapid skin solidification, but this increases frozen-in orientation and can reduce weld-line tensile strength by 20–30% relative to unfused regions when tested to ASTM D638-14. Weld lines should be positioned away from snap-fit undercuts and sealing rims.

    High-flow HDPE of this class also shows lower environmental stress crack resistance than a 0.3 g/10 min blow-moulding grade under ASTM D1693-21 using 10% Igepal CO-630 at 50°C. Published ESCR data for TAISOX 7301 specifically is limited; any container destined for detergent, surfactant, or food-oil contact should require lot-specific testing. The operational boundary for continuous load-bearing service is near 60°C. Above this temperature, creep data to ISO 899-1:2017 should be reviewed at the specific stress level of the application.

    Comparing TAISOX 7301 with a fractional-melt HDPE film or blow-moulding grade highlights the structural trade-off. The 20 g/10 min melt mass-flow rate reduces filling pressure in thin sections, but the lower molecular weight that enables high flow also reduces slow crack growth resistance. In ASTM D1693-21 testing, a fractional-melt HDPE may exceed 100 h to failure, while a high-flow injection grade can fail before 10 h at similar imposed strain and surfactant activity; these values are geometry-dependent and must not be treated as universal limits. Against an 8 g/10 min injection-moulding grade, TAISOX 7301 permits lower peak injection pressure and a longer practical flow path at equal wall thickness, but it can exhibit slightly lower notched impact and lower ESCR. For closures and overcaps, filling of fine threads is improved, but sealing-force retention under load must be confirmed by compression-set and creep testing to ASTM D2990-17. In thick sections above 4 mm, the grade is less suitable because crystallisation shrinkage produces sink marks and voiding unless gate packing is prolonged. The product should not be selected for living hinges; polypropylene remains the standard material for flexural fatigue applications.

    Regulatory Documentation and Food-Contact Compliance

    Food-contact status is application-specific and depends on the pigment masterbatch, additive package, and migration performance of the finished article. Under FDA 21 CFR 177.1520(c), olefin polymers may be used in contact with food, subject to conditions of use and extractive limitations. In the EU, Regulation (EU) No 10/2011 applies; overall migration must not exceed 10 mg/dm², and specific migration limits for monomers and additives in Annex II must be confirmed for the final formulation. REACH registration obligations fall on the supplier and downstream users. RoHS Directive 2011/65/EU restrictions on lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls, and polybrominated diphenyl ethers apply to the finished article, not only to the base resin.

    Regulatory frameworkTest or conditionTypical position
    FDA 21 CFR 177.1520(c)Olefin polymer food-contact usePermitted subject to end-use and extractive limits
    Regulation (EU) No 10/2011Overall migration limit10 mg/dm²
    RoHS Directive 2011/65/EURestricted substances in homogeneous materialsBase polymer not expected to exceed thresholds; masterbatch must be checked
    Regulation (EC) No 1907/2006REACH polymer substance registrationPolymer exempt; monomer and additive registrations required

    Because the melt is high-flow and the molecular weight is relatively low, the grade has boundary conditions that differ from lower-MFR HDPE. Above 240°C, residual oxygen and shear heating can increase MFR during processing; converters running high regrind percentages should monitor MFR by ASTM D1238-23 and request oxidative induction time to ISO 11357-6:2018 if thermal degradation is suspected. The material is not a substitute for high-MFR polypropylene in hot-fill applications; HDPE softens at lower temperatures, and hot-fill above 60–70°C can distort thin walls. Flammability is typical of polyolefins, and the product is not flame-retardant. Recycling streams that combine this grade with low-flow HDPE should limit the high-flow fraction in blow-moulding or sheet-extrusion operations because the melt flow shift is nonlinear and can reduce parison hang strength, causing thickness variation.

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