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Formosa Chemicals & Fibre (FCFC) ABS AN4500S

    • Product Name: Formosa Chemicals & Fibre (FCFC) ABS AN4500S
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 351061
    Product Formosa Chemicals & Fibre (FCFC) ABS AN4500S
    Density G Cm³ 1.04
    Melt Flow Rate 220 C 10 Kg G 10 Min 20
    Tensile Strength At Yield Mpa 44
    Elongation At Break 30
    Flexural Modulus Mpa 2200
    Flexural Strength Mpa 72
    Notched Izod Impact Strength 23 C Kj M² 20
    Rockwell Hardness R Scale 105
    Heat Deflection Temperature 1 82 Mpa C 85
    Vicat Softening Point C 100
    Mold Shrinkage 0.4-0.6
    Ul Flammability Rating HB

    As an accredited Formosa Chemicals & Fibre (FCFC) ABS AN4500S factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Formosa Chemicals & Fibre ABS AN4500S is supplied in 25 kg moisture-proof paper bags, palletized for industrial shipment.
    Container Loading (20′ FCL) Loading of a 20′ FCL container with FCFC ABS AN4500S chemical product, ensuring proper stowage and securing for ocean transport.
    Shipping Formosa Chemicals & Fibre (FCFC) ABS AN4500S is shipped as a non-hazardous thermoplastic in moisture-proof 25 kg bags or 500–1000 kg jumbo bags, palletized and stretch-wrapped. Standard transport is by 20'/40' containers or dry truck; store dry, below 50°C, away from sunlight and ignition sources.
    Storage Store FCFC ABS AN4500S resin in a cool, dry, well-ventilated warehouse, protected from direct sunlight, heat, ignition sources, rain, and moisture. Keep original bags sealed and palletized; avoid crushing or excessive stacking. Maintain low humidity and good air circulation, use first-in/first-out stock rotation, and keep away from incompatible chemicals. Close containers when not in use and avoid open flames.
    Shelf Life Typically 12 months when stored unopened in a cool, dry place, protected from sunlight and moisture.
    Application of Formosa Chemicals & Fibre (FCFC) ABS AN4500S

    Injection-molded low-voltage control station bezels, switchgear front plates, and terminal covers are a downstream application area where surface gloss, dimensional repeatability, and electrical clearance interact with material flow length. FCFC ABS AN4500S is processed on a hydraulic reciprocating-screw injection molding machine equipped with a three-zone screw with an L/D ratio of 20:1 and a sliding-ring non-return valve. Pre-drying is executed in a desiccant dryer with a dew point below -40°C; the resin is heated to 80°C for 3 h when ambient relative humidity is between 50% and 70%. Residual moisture is confirmed below 0.05 wt% by ISO 15512:2019; higher moisture causes silver streaking, brittle weld lines, and gloss reduction on plaque surfaces. Melt temperature measured at the nozzle is maintained at 220–245°C, while the mold surface is kept at 55–70°C using turbulent flow through drilled channels, not bubblers, to avoid non-uniform cavity temperature. For a terminal cover with a projected area of 350 cm² and a gate-induced cavity pressure of 350 bar, a clamping force of 120–130 t is required; smaller bezels below 150 cm² may run on machines of 60–80 t. The material is normally considered for non-current-carrying external components, so IEC 61439-1 applies at the assembly level, while polymer flammability is assessed separately by IEC 60695-11-10 at the thinnest molded wall. If a UL 94 HB classification is cited, it is valid only at the thickness printed in the UL Yellow Card for the exact production lot; no extrapolation to thinner sections is permissible. Before release, batch-to-batch verification should include melt volume-flow rate by ISO 1133-1:2022 at 220°C/10 kg and tensile yield by ISO 527-2/1A to detect regrind-induced degradation.

    What Prevents Splay and Gloss Variation in High-Gloss Appliance Fascias Molded from ABS AN4500S?

    High-gloss appliance control fascias, air-conditioner front panels, and washing machine outer display trims place severe demands on surface uniformity because any weld line, gas trap, or moisture splay is immediately visible under 60° gloss measurement. The converter injection-molds FCFC ABS AN4500S on a machine with a screw diameter between 35 mm and 50 mm and shuts off decompression after screw recovery to 3–5 mm. Drying remains the primary process control point: 80°C for 3–4 h in a closed desiccant circuit with a dew point below -40°C is required, and the hopper should be purged with dehumidified air if ambient RH exceeds 60%. Melt temperature is set at 230–250°C; local melt temperature should be checked with a pre-dried hand-held probe to avoid endothermic degradation at the screw tip. Back pressure is limited to 5–10 bar and screw speed to 50–80 rpm to avoid chromophoric darkening and gloss loss from shear heating. For a 1.5–2.0 mm high-gloss fascia with a flow length of 180 mm, rapid heat-cycle molding raises the cavity surface above the ABS glass transition temperature prior to filling; a mold surface temperature of 110–130°C during filling and a cooling phase down to 45°C after hold pressure produces a visually gloss-stable surface without painting. Gloss is measured per ISO 2813 at 60°; production practice requires a 10-point standard deviation below 2.5 GU for dark high-gloss parts, although this value is not grade-guaranteed and depends on mold polishing direction. The hold pressure profile is staged at 70% and 45% of peak injection pressure, with switch-over by screw position rather than hydraulic pressure to control cushion at 3–5 mm. Appliance safety compliance is assessed under IEC 60335-1; for unheated decorative front panels, ball-pressure resistance is tested by IEC 60695-10-2 at the maximum operating temperature declared by the end-product manufacturer. The grade should not be used near uninsulated live parts unless the final assembly meets representative glow-wire testing under IEC 60695-2-11; unmodified ABS often fails 850°C glow-wire demands, so verification against the exact wall thickness is mandatory.

    Sequential Valve-Gate Filling, High-Shear Dispersion, and Regrind Control in Automotive Interior Trim

    Automotive speaker grilles, lower instrument panel inserts, and door trim bezels have a different risk profile because the molder must balance low-temperature impact, paint or film adhesion, and interior emissions limits. FCFC ABS AN4500S can be used in low-to-mid heat-load interior locations where continuous service temperature does not exceed 80–85°C; above this range, PC/ABS or ASA is generally substituted. Drying is identical to other ABS applications: desiccant dryer at 80°C for 3 h, with moisture verified below 0.05 wt% by ISO 15512:2019. Melt temperature is maintained at 230–250°C; mold temperature is shifted to 50–70°C to reduce molded-in stress and improve surface replication on textured steel. For a speaker grille measuring 400 mm × 150 mm with a nominal wall of 2.0 mm, a sequential valve-gate hot runner with four pneumatically actuated nozzles is used; valve delays are adjusted so that flow fronts meet under pack pressure rather than at the end of fill, which reduces weld line notch weakness. Paint adhesion after power washing is assessed using a cross-hatch test per ISO 2409 and a high-pressure water jet at 60–80 bar; the exact pressure depends on OEM specification. Mold release and process aids must be limited because high volatile organic compound levels from additives can cause failure in VDA 278:2011 thermal desorption analysis; use of external mold release is generally avoided in high-gloss grain surfaces. Regrind from sprues and rejected first-stage parts may be introduced at 15–20 wt% if granulated to 3–6 mm flake and dried before blending. The melt flow shift after regrind addition is monitored by ISO 1133-1:2022; a shift greater than 5% relative to virgin material triggers an increase in holding pressure or a reduction in regrind ratio. Multi-axis impact performance is checked by instrumented puncture test per ISO 6603-2 on flat plaques cut from the final part; no generic acceptance limit exists, so the converter must align with the automotive end-user's specification for low-speed carpet-floor impact. Interior light fastness is evaluated by OEM methods rather than a single ISO standard; ISO 105-B06 is used only for comparative material screening. If the component is painted, a solvent-borne topcoat must be validated with an environmental stress-cracking test, because ABS develops microfractures in the presence of aggressive coating thinners. For final article emissions, occupants' health requirements under China GB/T 27630-2011 or European OEM VDA 278 limits determine allowable condensable and volatile emissions; these tests are run on the complete interior assembly, not on the resin alone.

    Information technology equipment enclosures, scanner lids, printer paper trays, and monitor rear covers consume high-flow ABS when the fire-enclosure exemption path of IEC 62368-1 is satisfied and the HB-rated minimum thickness is maintained over the full molded part. FCFC ABS AN4500S is injected at a melt temperature of 220–240°C; the holding pressure is set to 60–75% of peak injection pressure and applied for 4–8 s depending on gate freeze. Thin-wall sections down to 1.2 mm require screw forward velocity of 120–180 mm/s and a high-flow hot sprue bushing to reduce shear heating and gate blush. Venting at the end of fill is machined to a land depth of 0.02–0.03 mm and a width of 6–10 mm; insufficient venting leads to burn marks and gloss rings around bosses. Conditioning before dimensional inspection is performed for 24 h at 23°C/50% RH per ISO 291:2008. Regrind from runners is granulated to a particle size below 6 mm and metered at 15–20 wt%; larger particles create unmelted specks in dark colors. Internal snap-fit latches and screw bosses are tested for tensile strain at yield with ISO 527-2/1A; a typical design limit for unfilled ABS is an allowable strain below 0.8% in continuous load at 23°C, but elevated temperature and creep reduce this limit. Compliance with RoHS Directive 2011/65/EU and the REACH Candidate List is lot-specific and confirmed through supplier documentation. No statement is made about halogen-free performance because AN4500S is not automatically halogen-free; fire-retardant requirements under IEC 62368-1 must be determined from the UL Yellow Card for the exact layer thickness used in the final enclosure.

    Compliance verification matrix for selected FCFC ABS AN4500S application segments
    Application segmentRegulatory/standards pathwayMaterial-level test methodCritical lot-check parameter
    Low-voltage switchgear bezelsIEC 61439-1, IEC 60695-11-10ISO 1133-1:2022, ISO 527-2/1AMVR at 220°C/10 kg, tensile yield
    High-gloss appliance fasciaIEC 60335-1, IEC 60695-10-2ISO 15512:2019, ISO 2813Residual moisture, 60° gloss uniformity
    Automotive interior trimVDA 278:2011, OEM interior emission limitsISO 6603-2, ISO 2409Puncture energy, paint adhesion
    ITE enclosure applicationsIEC 62368-1, RoHS Directive 2011/65/EUISO 291:2008, ISO 527-2/1APost-mold shrinkage, tensile yield
    Medical diagnostic housingsIEC 60601-1, ISO 22088-3ISO 15512:2019, ISO 180/AEnvironmental stress cracking, notched impact

    When Rapid Cooling Elevates Residual Stress in Medical Diagnostic Enclosures

    Medical diagnostic device enclosures—such as in-vitro analyzer front covers, desktop reader housings, and non-sterile laboratory instrument bezels—are governed by IEC 60601-1 for basic safety and essential performance, but the material itself is not a patient-contact material and does not require ISO 10993 biological evaluation unless the enclosure becomes a body-contacting surface. FCFC ABS AN4500S must be dried for 3–4 h at 80°C in a positive-pressure desiccant dryer; residual moisture above 0.05 wt% creates surface defects that are unacceptable on bright white or off-white diagnostic covers. The melt is held at 220–240°C, and the mold is initially set at 45–55°C. Rapid cooling is frequently used to reduce cycle time, but this concentrates residual stress at gate and weld-line regions; when a 70% v/v isopropyl alcohol wipe is used for disinfection, environmental stress cracking may appear within 24–72 h. Validation is conducted with constant-strain bending bars under ISO 22088-3, Method A, using an ethanol or isopropyl alcohol exposure solution; no part is released without a stress-cracking test on the thinnest wall and on weld-line positions. If surface gloss is less critical than crack resistance, the mold temperature is raised to 65–70°C and post-mold annealing is performed at 80°C for 2 h; this annealing step can induce post-shrinkage of approximately 0.3–0.5% in the length direction, which must be compensated in tooling dimensions. Screw speed is lowered to 50–70 rpm and back pressure is held at 10–15 bar; a lower screw speed reduces shear heating in the screw channel and prevents yellowing in light shades. The final part is checked for notched Izod impact by ISO 180/A at 23°C, C-notched specimens, and for heat deflection under ISO 75/B if the enclosure is exposed to a warm analyzer interior. Because published data for this specific configuration is limited, the converter must generate lot-specific stress-cracking and impact data rather than rely on generic ABS values.

    Positive-Pressure Desiccant Drying and Low-Shear Metering in Point-of-Sale Terminal Housing Production

    Point-of-sale terminal covers, contactless reader bezels, and PIN-pad surrounds consume high-flow ABS because the parts require multiple snap-fits, bosses for self-tapping screws, and consistent dark-grey or black surface appearance under indoor lighting. FCFC ABS AN4500S is pre-dried at 80°C for 3 h with a desiccant-bed regeneration temperature of 160–180°C; the dry-air conveying line should be stainless steel and electrically grounded to avoid dust accumulation and static clumping. Melt temperature is controlled at 225–245°C, and the screw speed is set at 70–90 rpm because the high-flow ABS has a moderate shear-viscosity profile and does not require high shear to reach the desired melt homogeneity. Back pressure is limited to 5–8 bar; excessive back pressure lengthens residence time and increases the risk of yellowing at the barrel wall. A carbon black masterbatch at 2–3 wt% is added through a gravimetric blender; the carrier resin must be SAN or ABS-compatible to avoid surface delamination and gloss reduction. The mixture is not subjected to a separate compounding step; a single-flight screw with a mixing element at the metering zone is sufficient to disperse masterbatch at 80 rpm. Snap-fit deflection is evaluated on sub-sized specimens milled from the molded part, not on edge-gated test plaques, and the design strain is compared against tensile yield strain by ISO 527-2/1A. The insulative nature of unfilled ABS means surface resistivity is typically above 10^12 Ω by ASTM D257-14. If static dissipative behavior is required for ESD-protected areas, a separate conductive ABS compound is required; this grade is not inherently static dissipative. Drop impact is assessed per IEC 60068-2-31 using the severity specified by the product standard for the terminal. Material documentation references RoHS Directive 2011/65/EU and the REACH Candidate List; the application is not directly within low-voltage safety limits unless the terminal contains mains power. The manufacturer's published data should be consulted for melt volume-flow rate and tensile modulus; lot-to-lot variation in regrind-induced viscosity shift is monitored by ISO 1133-1:2022 at 220°C/10 kg.

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    Certification & Compliance
    More Introduction

    Formosa Chemicals & Fibre Corp. (FCFC) supplies the acrylonitrile-butadiene-styrene copolymer ABS AN4500S within the TAIRILAC product portfolio. The grade is positioned for sheet and profile extrusion with downstream thermoforming, rather than for thin-wall injection molding. Published material-class data place the solid density at 23°C between 1.03 g/cm³ and 1.06 g/cm³ when determined by ASTM D792; lot-specific release values must be obtained from the supplier certificate of analysis. Melt volume-flow rate under ASTM D1238 at 220°C/10 kg is maintained in the medium-flow extrusion band, typically 3 g/10 min to 8 g/10 min for this product class, though published data for this specific configuration is limited and should not be used for mold-filling simulation without verification. The polymer consists of a styrene-acrylonitrile copolymer matrix with a dispersed polybutadiene rubber phase; this morphology provides a balance of rigidity, surface hardness, and impact strength. The rubber particle size distribution influences both gloss retention and low-temperature toughness. Processors select AN4500S for thermoformed interior panels, appliance liners, sanitary-ware back panels, and transportation trim where wall-thickness uniformity after forming is more critical than sub-millimeter mold filling. The grade is not intended for electronic housings with flow length-to-thickness ratios exceeding 150:1 at melt temperatures below 230°C. In such configurations, high-flow ABS grades should be evaluated instead. Any application claim for impact performance must be accompanied by notched Izod or Charpy data generated under ISO 180/1A or ASTM D256 on end-use thickness specimens; generic resin-class values do not guarantee behavior after thermoforming orientation or regrind addition.

    Rheological Characterization and Extrusion Melt Strength

    Sheet extrusion of AN4500S is typically performed on single-screw extruders with L/D 30:1 to 36:1 and barrier screws having compression ratios of 2.4:1 to 3.2:1. Melt-temperature setpoints are distributed from 210°C at the feed zone to 240°C at the metering zone, with a die-entry melt temperature of 230°C ±5°C. A melt-temperature excursion above 245°C has been associated with yellowing, surface gel formation, and degradation of the butadiene phase; temperatures below 215°C increase melt pressure and can generate flow marks or weld-line weakness. Melt pressure measured before the breaker plate on a 90-mm extruder running 3-mm sheet is generally 10 MPa to 20 MPa; these values are equipment-dependent. The rheological requirement for extrusion differs from injection molding: melt strength and extensional viscosity control sheet sag and draw uniformity, not just capillary flow. Dynamic oscillatory rheometry under ASTM D4440 or equivalent parallel-plate methods provides storage and loss modulus crossover data; however, published curves for AN4500S are limited. Color concentrate and additive masterbatches should use SAN carriers to avoid gloss loss and delamination. Gloss retention after thermoforming can be measured at 60° using ASTM D523, and a drop of more than 10 gloss units between flat sheet and formed part is usually evidence of overheating or incompatible concentrate chemistry.

    Pre-drying is mandatory when relative humidity exceeds 60% or when the resin has been stored in unheated warehouses. Desiccant-wheel dryers with supply air dew point below -40°C and pellet-bed temperature of 80°C are used for 3 h to 4 h; the residual moisture endpoint should be below 0.05 wt%, measured by ISO 15512 or an equivalent Karl Fischer method. Higher air temperatures above 90°C can cause pellet sticking and odour generation. Regrind levels up to 20 wt% are accepted for non-appearance sheet, provided the regrind is dust-free, dried to the same moisture endpoint, and not contaminated with polypropylene or nylon. Beyond 20 wt% regrind, notched Izod impact under ASTM D256 decreases and melt flow rate increases after repeated heat history; the butadiene phase undergoes thermo-oxidative degradation, shifting the ductile-to-brittle transition to higher temperatures. Thermoforming of extruded sheet requires sheet surface temperatures between 130°C and 170°C, measured with an infrared pyrometer. Uniform heating and controlled sag are essential because local overheating thins the sheet and causes non-uniform wall thickness in female tools. Published data for this specific configuration is limited; line trials should establish the relationship between sheet temperature, draw ratio, and final impact.

    What Limits the Replacement of High-Flow Injection Molding Grades with AN4500S?

    AN4500S cannot be freely substituted for high-flow injection molding ABS in multi-cavity tools. The medium-flow rheology increases injection pressure demand when nominal wall thickness drops below 1.2 mm. Short shots are typically observed at flow length-to-thickness ratios above 120:1 when melt temperature is held below 230°C. Molding machines of 80 tons to 150 tons clamp force often require 0.5 t/cm² to 0.8 t/cm² of projected area for this class of extrusion ABS, whereas high-flow injection grades with melt flow rates of 20 g/10 min to 40 g/10 min can fill thin sections at lower pressure. The difference reflects higher molecular weight retention and a higher rubber-phase volume fraction, which increase melt elasticity and reduce spiral-flow length. Notched Izod impact at 23°C for AN4500S class is generally 25 kJ/m² to 45 kJ/m² under ISO 180/1A, while high-flow grades often fall between 10 kJ/m² and 20 kJ/m². Molders attempting to use AN4500S in tools designed for high-flow grades should enlarge gates to a minimum thickness of 60% of the adjacent wall, avoid pin gates smaller than 1.0 mm, and raise mold temperature to 50°C to 80°C to reduce orientation and improve knit-line strength under weld-line Izod testing by ASTM D256. Hot-runner manifold temperatures above 250°C should be avoided because residence time in hot runners can generate black specks and odour.

    Relative to heat-resistant ABS grades, AN4500S exhibits lower thermal performance. Heat deflection temperature for the medium-impact extrusion ABS class under ASTM D648 at 1.82 MPa lies between 84°C and 96°C; lot-specific HDT should be requested. Applications requiring continuous load above 95°C should evaluate heat-resistant ABS or polycarbonate/ABS blends. In comparison with flame-retardant ABS grades that achieve UL 94 V-0 at 1.5 mm, unmodified AN4500S is expected to be classified as UL 94 HB at equivalent thickness; the exact rating must be verified on end-use substrates and color concentrates. Post-mold or post-forming shrinkage for ABS sheet in the machine direction is generally 0.4% to 0.7% and 0.4% to 0.6% transverse, measured by ASTM D955; annealing at 85°C for 2 h can reduce dimensional change to 0.2% to 0.4%. Environmental stress cracking resistance under ASTM D543 or ISO 22088 is acceptable for dilute acids and alkalis but poor for aromatic hydrocarbons, ketones, esters, and chlorinated solvents. These solvents should not contact formed parts at sustained strain levels above 25% of the tensile yield stress.

    When Chemical Resistance and Low-Temperature Impact Become Design Constraints

    When a formed article must withstand sub-zero impact after painting or adhesive bonding, the low-temperature behavior of the ABS grade must be evaluated on the actual wall thickness and after solvent exposure. Notched Izod impact at -30°C for medium-impact extrusion ABS class is commonly 8 kJ/m² to 15 kJ/m² under ISO 180/1A, a marked reduction from 23°C values. The ductile-to-brittle transition temperature depends on rubber particle size, rubber crosslink density, and thermoforming history. Heavy orientation during forming can reduce low-temperature impact, particularly in corners with draw ratios above 0.8. Painting with solventborne primers introduces migration and residual stress that can promote environmental stress cracking. Adhesion promoters should be tested under the intended bake cycle, usually 80°C to 100°C for 20 min to 40 min. Paint adhesion is assessed by the cross-cut tape test ISO 2409, and a rating of 0 or 1 is typically required. For freezer liners, the selected sheet temperature during plug-assisted forming must be controlled within a narrow range because overheating reduces melt strength and causes corner thinning, while underheating creates residual stress. Published data for this specific configuration is limited; laboratory forming trials with a defined temperature map and subsequent ISO 6603-2 instrumented impact testing provide the only reliable basis for design.

    A systematic comparison of AN4500S class properties against high-flow injection and heat-resistant ABS classes is given in the following table. Values are representative literature ranges for the general product classes, not supplier release limits for this specific lot. Comparative data for a specific production batch must be obtained from the certificate of analysis.

    PropertyTest methodAN4500S classHigh-flow injection ABSHeat-resistant ABS
    Melt volume-flow rate at 220°C/10 kgASTM D12383–8 g/10 min20–40 g/10 min1–5 g/10 min
    Notched Izod impact at 23°CISO 180/1A25–45 kJ/m²10–20 kJ/m²15–30 kJ/m²
    Tensile yield stressASTM D63840–50 MPa35–45 MPa45–55 MPa
    Flexural modulusISO 1782,000–2,500 MPa2,100–2,600 MPa2,300–2,800 MPa
    Heat deflection temperature at 1.82 MPaASTM D64884–96°C78–88°C100–115°C
    Flammability class at 1.5 mmUL 94HBHBHB/V-2

    Regulatory documentation should be verified with the supplier. The base ABS polymer is generally assessed under EU RoHS Directive 2011/65/EU as amended by (EU) 2015/863 for lead, cadmium, mercury, hexavalent chromium, PBBs, PBDEs, and four phthalates. REACH SVHC obligations are substance-specific and lot-specific; no blanket SVHC-free statement applies without a supplier declaration. Food-contact status under FDA 21 CFR 180.22 or EU 10/2011 is not automatically conferred by resin selection; migration testing on the finished article is required. Outdoor UV stability is not claimed unless the grade is compounded with an appropriate UV stabilizer and evaluated under ISO 4892-2 or UL 746C f1 protocols.

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