| HS Code | 547086 |
| Polymer Type | Isotactic Polypropylene Homopolymer |
| Melt Flow Rate 230 C 2 16 Kg | 12 g/10 min |
| Density | 0.90 g/cm³ |
| Tensile Strength At Yield | 34 MPa |
| Elongation At Break | 10% |
| Flexural Modulus | 1500 MPa |
| Notched Izod Impact 23 C | 25 J/m |
| Rockwell Hardness | R-100 |
| Heat Deflection Temperature 0 45 Mpa | 100 °C |
| Vicat Softening Temperature | 155 °C |
| Melting Temperature | 160 °C |
As an accredited ExxonMobil PP Homopolymer PP4052E1 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | ExxonMobil PP Homopolymer PP4052E1 is supplied as pellets in 25 kg bags, 1,000 kg boxes, or bulk quantities. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL): 20-foot full container of ExxonMobil PP Homopolymer PP4052E1, loaded with palletized bags, secured for safe transport. |
| Shipping | ExxonMobil PP Homopolymer PP4052E1 ships as free-flowing pellets in sealed bags or bulk hoppers. Use clean, dry containers to prevent contamination and moisture absorption. Store away from direct sunlight, heat, and ignition sources. Keep packaging intact during transport. Ensure proper ventilation and follow safe handling procedures to avoid static discharge and dust accumulation. |
| Storage | Store ExxonMobil PP Homopolymer PP4052E1 in a clean, dry, well-ventilated area, away from direct sunlight, heat, and ignition sources. Keep pellets in sealed original packaging to prevent moisture pickup and contamination. Maintain moderate temperatures and avoid outdoor exposure or prolonged storage near oxidizing materials. Handle with care to prevent dust accumulation. |
| Shelf Life | Shelf life is indefinite when stored in original, unopened packaging in a cool, dry place away from sunlight. |
In hygiene-grade spunbond nonwoven production, PP4052E1 is metered as the dominant feedstock at 92–98 wt%, with the balance supplied by a TiO₂-based color masterbatch at 2–4 wt% and a process aid/antistat masterbatch at 0.5–1.0 wt% when static discharge, fiber-to-fiber friction, or color uniformity specifications require it. The homopolymer is characterized by a nominal melt flow rate of 38 g/10 min under ISO 1133-1:2022 at 230°C/2.16 kg, placing the melt inside the drawability window required for slot-jet attenuation without excessive filament breaks. Pre-drying at 80°C for 2–4 h is enforced when silo relative humidity exceeds 60%; residual moisture above 0.1% produces surface splay and draw resonance on production-scale spunbond beams. Compliance for skin-contact hygiene nonwovens is documented through a REACH SVHC declaration confirming candidate list substances below 0.1% wt/wt, and, where converter specifications require, OEKO-TEX Standard 100 product class I certification; physical test methods follow ISO 9073-1 for basis weight and ASTM D5035 for strip tensile. The production line is configured with a single-screw extruder at 30:1 L/D, barrel zones from 200°C to 230°C, adapter and melt pipe at 230–240°C, and a spinneret with hole diameters of 0.35–0.60 mm and hole density of 2,500–4,000 holes/m. Die melt temperature is held at 235–245°C; residence time above 250°C is limited to below 15 min to avoid thermo-oxidative chain scission that presents as filament breaks and die drool. Quench air at 12–20°C and 0.5–1.5 m/s solidifies the filaments, which are then attenuated in a slot jet at 3–6 kPa and bonded on a heated calender at 145–155°C with nip pressures of 60–100 N/mm. The resulting spunbond fabric ranges from 8 g/m² to 40 g/m² and is converted into diaper topsheets, adult incontinence topsheet coverstocks, feminine hygiene top and back sheet textile components, and leg cuff laminate substrates.
The SMS configuration places PP4052E1 exclusively in the two outer spunbond beams, because meltblown attenuation demands melt flow rates above 800 g/10 min, whereas PP4052E1 at 38 g/10 min would deliver insufficient drawability and would require melt temperatures exceeding 280°C to lower viscosity, inducing oxidative gel formation. In the spunbond beams, the formulation is maintained at 96–100 wt% PP4052E1, with the remaining 0–4 wt% comprised of a fluoropolymer-free processing aid masterbatch used only when line speed exceeds 300 m/min to reduce die lip deposition. Medical conformance is established by EN 13795-1:2019 for surgical drapes and gowns, AAMI PB70:2012 for liquid barrier classification, ISO 10993-5:2009 for cytotoxicity, and ISO 10993-10:2021 for skin sensitization under Regulation (EU) 2017/745 where the nonwoven constitutes a medical device component. The spunbond beams run at the same 235–245°C die temperature as hygiene lines, but bonding is shifted to the lower end at 140–150°C to preserve bulk and maintain hydrostatic head after lamination with the meltblown layer; fabric basis weight is typically 25–60 g/m². Terminal products include SMS surgical gowns, surgical drapes, isolation gowns, scrub suit overlays, and sterilization wrap.
When PP4052E1 is directed into automotive interior spunbond lines, the feedstock is set at 92–98 wt% resin, with 2–5 wt% of a UV/HALS masterbatch and 0–2 wt% of a color concentrate depending on whether the fabric is exposed or covered. The conformance boundary is governed by FMVSS 302 and ISO 3795 for horizontal burn rate, VDA 277 for total VOC emissions, VDA 278 for VOC/SVOC desorption, and IATF 16949 production process control. Published converter data specific to PP4052E1 in this exact route is limited; the above values represent standard PP homopolymer spunbond practice and should be verified on the target line. The spunbond line uses a single-screw extruder at 230–250°C melt temperature, a spinneret hole density of 2,500–4,000 holes/m, slot-jet attenuation at 3–6 kPa, and calender bonding at 140–155°C with nip pressures of 50–90 N/mm. Fabric mass produced from PP4052E1 in this segment ranges from 60 g/m² to 250 g/m²; the spunbond is subsequently laminated with a polyurethane foam or polyester scrim in a second operation when acoustic or structural stiffness is required. Terminal products include headliner facing layers, trunk side trim, parcel shelf scrims, door panel backings, and wheel arch liners.
PP4052E1 is introduced into extrusion coating lines at 70–90 wt% in blends with either low-density polyethylene at 10–30 wt% or a propylene-ethylene random copolymer at 10–25 wt%, the latter selected when the finished laminate must remain polyolefin-monolithic for mechanical recycling streams. Compliance is anchored to FDA 21 CFR 177.1520(c) for olefin polymers when the coated woven fabric is intended as food-contact bulk packaging, and to EU Regulation (EU) 10/2011 with an overall migration limit of 10 mg/dm²; where industrial bulk bags do not contact food, the applicable boundary is a certified REACH conformity declaration and ISO 9001 batch traceability. The extrusion coating process runs a single-screw extruder with 28:1 L/D, barrel temperatures of 200–270°C, die temperature 260–290°C, air gap 100–200 mm, and chill roll temperature 15–25°C. The woven PP substrate is corona-treated to 38–42 dyne/cm immediately before coating to raise adhesion; coating weight is maintained between 15 g/m² and 50 g/m² at line speeds of 100–300 m/min. Terminal products include FIBC bulk bags, woven fertilizer sacks, onion and citrus mesh bag coatings, tarpaulin laminates, and carpet secondary backing.
Under high-speed HVAC filter media conversion, PP4052E1 is used to produce a calendered spunbond support layer at 93–97 wt%, with 3–7 wt% of a masterbatch containing hindered amine light stabilizer and antistat when the layer is specified for electrostatic discharge-sensitive cleanrooms. The support layer is not the active filtration phase, so conformance is governed by ISO 9073-1 for basis weight, ISO 9237 for air permeability at 100 Pa, EN 13501-1 for fire classification when installed in building HVAC, and UL 900 for air filter flammability. The spunbond process uses the same beam layout as hygiene lines but with calender pressure reduced to 40–60 N/mm and bonding temperature held at 145–155°C to retain air permeability in the 1,500–3,500 L/m²/s range. Filament diameter is maintained between 15 µm and 25 µm, and fabric basis weight is held at 15–30 g/m² to avoid excessive pressure drop while stabilizing pleated media. Terminal products include pleated panel filter support layers, pocket filter scrims, cassette filter support mats, and cleanroom wiping substrates.
PP4052E1 is delivered to high-speed continuous filament lines at 95–98 wt%, with 2–5 wt% of a UV-stabilized masterbatch based on hindered amine light stabilizers and carbon black or titanium dioxide depending on exposure class. Outdoor-use compliance is referenced to ISO 13431 for tensile creep and ISO 10319 for wide-width tensile of geotextiles, while agrotextile conformance draws on REACH Annex XVII for restricted substances and ISO 4892-2:2013 for weathering after xenon-arc exposure. The continuous filament process operates with a single-screw extruder and melt temperature of 235–250°C, spinneret hole counts from 1,000–2,000, quench air at 15–25°C, and spinning speeds of 1,500–2,500 m/min. Drawn filaments at 3.0:1–4.5:1 draw ratio are laid into a web and either needlepunched or thermally bonded; geotextile fabric mass ranges from 80 g/m² to 400 g/m². Because converter data specific to PP4052E1 in continuous filament geotextile spinning is limited, the stated ranges derive from PP homopolymer fiber practice and require production-scale confirmation. Terminal products include nonwoven geotextiles for separation layers, drainage filters, erosion control blankets, greenhouse shading webs, and vineyard ground covers.
For disposable protective apparel, PP4052E1 outer layers are run at 96–100 wt% resin with 0–4 wt% antistat masterbatch, and the fabric is typically not paired with a meltblown barrier unless the garment is specified for liquid-tight protection. Conformance is established under Regulation (EU) 2016/425 for personal protective equipment, EN 13982-1:2004 for Type 5 particulate protection, and EN 13034:2005+A1:2009 for Type 6 light chemical spray protection, with garment seam strength verified by EN ISO 13935-1. The spunbond process uses a melt temperature of 235–245°C, calender bonding at 140–155°C, and fabric basis weight of 40–70 g/m². Garment assembly is performed by ultrasonic or heat-sealed seams rather than needle stitching when particle barrier is specified. Terminal products include Type 5/6 coveralls, bouffant caps, shoe covers, sleeve protectors, and non-surgical isolation garments.
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ExxonMobil PP Homopolymer PP4052E1 is a high-isotacticity polypropylene engineered for thin-wall injection moulding applications where rapid crystallisation, elevated stiffness, and consistent mould release are simultaneous requirements. Its nominal melt mass-flow rate of 45 g/10 min (230 °C, 2.16 kg; ASTM D1238) positions it in the high-flow homopolymer segment, delivering spiral flow lengths exceeding 800 mm in a 1.5 mm channel at 100 MPa injection pressure, which enables cavity filling in multi-drop hot-runner systems with wall stocks below 0.40 mm. The grade is supplied in a controlled-rheology, non-nucleated form, yielding a narrow molecular weight distribution that reduces shear sensitivity during high-speed filling while preserving break-away torque in dispensing closures.
Unlike a 25 g/10 min homopolymer such as ExxonMobil PP4042E1, PP4052E1 exhibits a steeper solidification plateau in the pressure-volume-temperature (pvT) diagram, which translates to machine-direction shrinkage values nearer to 1.5 % under unrestricted cooling (measured per ISO 294-4 on 60×60×2 mm plaques). Transverse shrinkage typically runs 0.2 – 0.4 percentage points higher, creating a predictable anisotropy that tooling engineers leverage when sizing gate inserts for rectangular containers. Haze, determined on 1 mm injection-moulded plaques according to ASTM D1003, falls in the range 8 – 12 %, which is low enough for translucent dairy tubs yet not equivalent to clarified random copolymer grades. The absence of an external nucleating agent means spherulite size remains dependent on mould temperature: a surface temperature of 50 °C produces fine crystalline domains with a gloss (60°) above 85 GU, whereas 10 °C moulds force quench-induced amorphous layers that elevate shrinkage variation across the part footprint by as much as 0.3 %.
ExxonMobil PP4052E1 complies with FDA 21 CFR 177.1520(c) 1.1a for food contact, EU Regulation 10/2011 (specific migration limits satisfied up to 70 °C for aqueous simulants), and the heavy-metal restrictions of EU Directive 94/62/EC. The homopolymer backbone contains no intentionally added phthalates, organotin stabilizers, or slip agents, making it a candidate for applications requiring low migratory risk, including pharmaceutical secondary packaging and beverage-can overcap liners. Pre-drying is not mandatory when the product is stored under ≤ 60 % relative humidity; if surface moisture exceeds 0.05 wt%, a drying regime of 80 °C for 2 – 4 h in a desiccant hopper dryer with a dew point of −40 °C restores process consistency.
Melt temperature in thin-wall processing must balance flow-path extension against oxidative chain scission. Laboratory thermo-oxidative testing via ASTM D3895 (OIT at 200 °C) indicates an induction time exceeding 30 min in the as-supplied stabilised form, yet prolonged residence at 260 °C reduces intrinsic viscosity by more than 0.05 dL/g within 8 min, shifting spiral flow length by 5 – 7 % and causing yellowing measured as ΔYI > 1.5 (ASTM E313). Therefore, converter sites running accumulators or extended hot-runner residence times are advised to maintain melt front temperatures at 230 – 250 °C and to keep shot weight above 40 % of barrel capacity, as shot-to-shot stagnation promotes unacceptably wide melt-viscosity drift when the barrel L/D exceeds 24:1.
Mould temperature settings between 15 °C and 60 °C are practical for PP4052E1, but demoulding stiffness becomes marginal below 10 °C, where the heat deflection temperature under 0.455 MPa (ISO 75-2/B) of 95 °C cannot compensate for a glassy skin that develops tensile surface stresses exceeding 12 MPa. Ejection forces measured on a 200 kN toggle-clamp machine with a 4-cavity closure mould rise by approximately 30 % when mould temperature drops from 30 °C to 10 °C, mandating draft angles of at least 1.5° on deep-draw features to prevent stress whitening.
A production-scale failure mode documented on a 48-cavity hot-runner system with valve-gate drops concerned intermittent stringing at gate vestige due to incomplete viscous pinch-off. The resolution involved raising nozzle temperature by 5 °C (from 230 °C to 235 °C) while reducing valve-pin holding pressure from 7 MPa to 5 MPa, which restored clean break-off. This illustrates the process sensitivity window of approximately ±5 °C at the nozzle tip when running PP4052E1 at maximum flow rates.
| PP4052E1 (homopolymer, high flow) | PP4042E1 (homopolymer, medium flow) | PP7032E1 (impact copolymer, medium flow) | Test method | |
|---|---|---|---|---|
| Melt flow rate (230 °C, 2.16 kg) | 45 g/10 min | 25 g/10 min | 35 g/10 min | ASTM D1238 / ISO 1133-1 |
| Tensile strength at yield | 35 MPa | 37 MPa | 28 MPa | ASTM D638 (Type I, 50 mm/min) |
| Flexural modulus | 1500 MPa | 1550 MPa | 1150 MPa | ASTM D790 (1.3 mm/min) |
| Notched Izod impact (23 °C) | 25 J/m | 22 J/m | 120 J/m | ASTM D256 |
| Heat deflection temperature (0.455 MPa) | 95 °C | 98 °C | 85 °C | ASTM D648 |
| Density | 0.90 g/cm³ | 0.90 g/cm³ | 0.90 g/cm³ | ASTM D792 |
Values represent typical data from injection-moulded specimens and may vary by production lot. Download current product specifications before engineering design.
When PP4052E1 replaces an impact copolymer in a snap-cap closure with a living hinge, the increase in flexural modulus by approximately 30 % enhances strip torque, but notch sensitivity rises. Under a standard capping test per ASTM D2063, closures moulded with PP4052E1 achieve a removal torque of 1.8 – 2.2 N·m after 24 h of conditioning at 23 °C and 50 % relative humidity, compared to 1.5 – 1.8 N·m for PP7032E1. However, after 500 hinge flex cycles at −10 °C, crack initiation at the hinge root is observed in PP4052E1, whereas the copolymer withstands 2000+ cycles before failure. This delineates the application boundary: PP4052E1 suits one-time tamper-evident flip-top caps; repeated-use hinges require a copolymer like PP7032E1.
In single-piece dispensing fitments with integrally moulded spring elements, the creep modulus of PP4052E1 at 60 °C (ISO 899-1, 1000 h) registers around 700 MPa, which sustains sealing force over shelf-life when closure preload is designed not to exceed 0.5 % strain. Published data for long-term creep beyond 5000 h in fatty-food simulants is limited; laboratory migration tests with olive oil (40 °C, 10 days) show no swelling beyond 1.5 % mass uptake, indicating acceptable dimensional stability for short-term food packaging.
Cold-seal adhesive bonding on PP4052E1 lids requires corona discharge treatment at a line speed of 30 m/min to raise surface energy above 48 dyn/cm (measured per ASTM D2578). Untreated homopolymer surfaces exhibit wetting tension below 30 dyn/cm, leading to peel strengths below 0.5 N/15 mm (ASTM F88). After in-line corona at 4 kW output, peel strength climbs to 3.5 – 4.2 N/15 mm, matching the 3 N/15 mm minimum specified for dairy tub seals. The higher crystallinity of PP4052E1 relative to random copolymers intensifies rate of corona decay: drop in wetting tension by 10 – 15 dyn/cm within 72 h of treatment is typical when stored at 30 °C, necessitating just-in-time treatment or the use of a top-coated sealant film.
In overcap stacking tests, the top-load resistance at yield of PP4052E1 reaches 350 N on a 63 mm diameter skirt (crosshead speed 12.5 mm/min, ASTM D2659), surpassing the 250 N threshold demanded by beverage distribution logistics. The failure mode under excessive top load is vertical cracking at gate point, not buckling, confirming the influence of flow-induced molecular orientation aligned radially outward from the centre gate.