Exxonmobil Hdpe Hd54200

ExxonMobil HDPE HD54200

    • Product Name: ExxonMobil HDPE HD54200
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 258511
    Density 0.954 g/cm³
    Melt Index 0.35 g/10 min (190°C/2.16 kg)
    Tensile Strength At Yield 26 MPa
    Tensile Strength At Break 30 MPa
    Elongation At Yield 9%
    Elongation At Break >600%
    Flexural Modulus 1200 MPa
    Vicat Softening Temperature 127°C
    Melting Point 132°C
    Environmental Stress Crack Resistance Escr 10 Igepal F50 >1000 h
    Shore D Hardness 65
    Notched Izod Impact 80 J/m

    As an accredited ExxonMobil HDPE HD54200 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing ExxonMobil HDPE HD54200 comes in 25 kg polyethylene bags, palletized and stretch-wrapped for secure transport.
    Container Loading (20′ FCL) ExxonMobil HDPE HD54200 is loaded into 20′ FCL containers as 25 kg bags on pallets, securely stowed and moisture-protected for export.
    Shipping ExxonMobil HDPE HD54200 is shipped as non-hazardous polyethylene pellets, typically in 25-kg bags, octabins, or bulk trucks/railcars. Transport in cool, dry, ventilated conditions away from ignition sources and direct sunlight. Keep containers closed, avoid moisture/contamination, and clean spills promptly to prevent slipping. Not regulated for transport.
    Storage Store ExxonMobil HDPE HD54200 in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep containers sealed to prevent moisture, dust, and contamination. Avoid prolonged UV exposure and incompatible oxidizers. Use first-in, first-out stock rotation. Maintain clean, dry floors and pallets; do not stack beyond safe height. Follow manufacturer SDS and local regulations.
    Shelf Life Shelf life is typically 24 months when stored unopened in original packaging, dry, below 50°C, and away from direct sunlight.
    Application of ExxonMobil HDPE HD54200

    In high-cavitation thin-wall injection molding of dairy and delicatessen containers, the combination of a nominal melt flow index of 20 g/10 min (190°C/2.16 kg, ISO 1133-1:2022) and a published density of 0.954 g/cm³ (ASTM D792-20) determines the practical flow-length-to-wall-thickness ratio that can be achieved before short-shot or gate-freeze defects appear. For food-contact articles, HD54200 falls under FDA 21 CFR §177.1520(c) as an olefin polymer, and under EU Regulation (EU) No 10/2011 as amended, with overall migration not exceeding 10 mg/dm² for aqueous, acidic, and low-alcohol food simulants; export-oriented plants frequently additionally test to GB 4806.7-2016. The typical finished-wall formulation is 96–98 wt% virgin HD54200, 2–4 wt% food-contact PE-based white masterbatch containing 55–60 wt% TiO₂, and up to 20 wt% in-house regrind only when the regrind is generated from the same resin and migration testing remains valid for the intended food category. Processing is conducted on high-cavitation injection machines of 8–24 cavities with valve-gated hot runners, clamp force commonly 150–500 tons depending on cavity number, melt temperature 210–240°C, mold temperature 10–30°C, injection speed above 200 mm/s, pack pressure 50–75 MPa, and total cycle time 8–14 s for wall sections of 0.5–0.8 mm. Mold shrinkage is reported in the range 1.5–2.0% parallel and 1.5–2.5% perpendicular to flow, requiring steel-safe tooling adjustments for stackable lids. The main process conflict is thermal degradation at melt temperatures above 250°C, which produces off-odour and gel streaks, while melt temperatures below 210°C reduce flow length and can generate weld-line weakness at the low wall-stiffness end of the part. Terminal articles are dairy spread tubs, delicatessen containers, frozen dessert cups, and take-away food boxes.

    How Does a 20 g/10 min Melt Flow Index Shift Closure Warpage Behavior?

    Closure molding platforms running 32- to 64-cavity tools with cold-runner or hot-runner systems document that HD54200’s flow window influences ovality and continuous-thread engagement in screw caps for non-carbonated products. Warpage in HDPE closures is governed by differential shrinkage between the thread area and the shell top panel; the grade’s melt-flow index of 20 g/10 min (ASTM D1238-23, 190°C/2.16 kg) requires pack-pressure profiling between 55 and 85 MPa and mold temperatures of 8–15°C to maintain roundness within ±0.15 mm on a 28 mm closure. FDA compliance under 21 CFR §177.1520 applies for aqueous and dry food contact; EU 10/2011 migration limits apply for dairy closures, and torque-retention testing according to ASTM D2063 is used for continuous-thread closures. Formulation for the shell is typically 98–99 wt% HD54200 with 1–2 wt% of a PE-based slip masterbatch containing 5% erucamide to reduce coefficient of friction and application torque; if a liner is required, an EVA or elastomer-modified PE liner is injection-molded or heat-inserted at 5–10 wt% of total closure weight. Downstream production uses high-speed injection machines with accumulator assist, clamp force 150–350 tons, injection velocity 80–150 mm/s, and cycle times of 5–8 s for 1.0–1.5 mm nominal wall. Gate-stringing and cold-slug formation appear at nozzle temperatures above 230°C, while lower melt temperatures reduce flow into the tamper-evident band and can cause incomplete thread filling; hot-tip thermal control within ±1°C per nozzle is required. Terminal finished products are screw closures for still water, dairy beverages, personal-care bottles, and nutritional container caps with tamper-evident bands.

    Comparative production parameters reported across three typical HD54200 application regimes
    Application regimeWall thickness bandMelt temperatureMold temperatureInjection speedPack pressureCycle time
    Thin-wall food packaging0.5–0.8 mm210–240°C10–30°C>200 mm/s50–75 MPa8–14 s
    Closures1.0–1.5 mm200–230°C8–15°C80–150 mm/s55–85 MPa5–8 s
    Pails and medical shells2.0–3.5 mm210–250°C15–35°C60–120 mm/s55–80 MPa25–45 s

    For open-head 20-L pail molding, HD54200 is processed neat or with 3–5 wt% color masterbatch; load-bearing pails requiring drop impact at -18°C are occasionally blended with 10–15 wt% butene-based LLDPE at the expense of top-load retention. The resin’s density of 0.954 g/cm³ contributes to stiffness and top-load capacity, while the melt flow index of 20 g/10 min shortens fill time compared with lower-MFI blow-molding grades. Compliance for food-ingredient pails is under FDA 21 CFR §177.1520 and EU 10/2011 overall migration of 10 mg/dm²; industrial chemical pails follow UN 1H2 open-head plastics drum requirements under 49 CFR §178.509 for hazardous-material packaging when tested at 40°C and -18°C drop conditions. Injection molding is performed on single-face machines with clamp force between 800 and 1,250 tons, shot capacity 15–25 kg, melt temperature 220–250°C, mold temperature 15–25°C, pack pressure 55–75 MPa, holding time 12–20 s, and total cycle time 30–45 s for 2.0–3.5 mm nominal wall thickness. Top-load capacity is measured on a constant-speed compression tester; industry acceptance values for 20-L open-head pails typically exceed 250 kg at 10 mm/min. Drop testing according to ASTM D5276 is commonly specified. Failed pails typically show stress-cracking at mold-parting line knurls when mold temperature is below 15°C or when sharp transitions exceed 0.5 mm radius. Terminal articles are 20-L open-head industrial pails, 5-gallon food-ingredient containers, and 10-L paint pails with wire-bail handles.

    Sharps Container Shells and ISO 23907-1 Puncture-Resistance Constraints

    Sharps container shells molded from HD54200 combine a hard, shatter-resistant wall with high flow for nestable stack molds. The relevant compliance framework for single-use sharps containers is ISO 23907-1, which specifies puncture resistance, deformation, and stability tests; additionally, medical waste container colors and markings may be governed by regional regulations, and the base resin may be tested under ASTM D256-23 for notched Izod impact and ASTM D790-17 for flexural modulus. Formulation typically uses 100 wt% virgin HD54200 with 2 wt% red or yellow PE masterbatch; post-consumer regrind is generally excluded because autoclave and chemical exposure histories cannot be fully validated. Production is thick-wall injection molding, 2.0–3.5 mm nominal wall, melt temperature 210–240°C, mold temperature 20–35°C, pack pressure 60–80 MPa, total cycle 25–40 s; two-plate molds with 2–8 cavities are typical because deep draws require adequate ejection area. In-mold stress accumulation at gate regions is a documented failure mode when fill velocity exceeds 120 mm/s; stress-cracking around the lid underload can be reduced by keeping sprue gate diameters between 2.0 and 2.5 mm and by maintaining melt temperature above 210°C. Terminal finished product types include single-use sharps disposal containers, biohazard specimen transport shells, and wall-mount pharmaceutical waste containers.

    When a 20 g/10 min HDPE Grade Moves into Stackable Household Storage and Transit Cases

    Where thin-wall housewares and stackable transit cases require a balance between impact resistance and fast cycle times, HD54200 is processed at melt temperatures between 200°C and 230°C and mold temperatures of 20–35°C. General-product compliance is typically documented under REACH Annex XVII restrictions and EU SVHC absence declarations; for toys or childcare articles, EN 71-3:2019+A1:2021 migration of elements and US CPSC lead and phthalate limits may apply when the article is marketed to children, though HD54200 itself does not contain phthalates. Formulation uses 95–100 wt% HD54200, with 2–5 wt% color masterbatch and occasional addition of 10–20 wt% butene or octene LLDPE for hinge flex in latch-type totes. Injection molding occurs on 250–600 ton machines with 1–4 cavities, wall thickness 0.8–2.0 mm, injection speed 60–150 mm/s, pack pressure 40–65 MPa, and cycle time 18–30 s. Published data for HD54200 living-hinge endurance is limited; stress whitening can occur after repeated flexing, so hinged latches often use a separate PP insert. Terminal products are stackable storage totes, garment hangers, tool boxes, and reusable transit cases.

    Extractables Testing Sets the Upper Melt-Temperature Limit at 230°C

    Because toy and recreational articles demand both impact toughness and a controlled toxicological profile, HD54200 is used in injection-molded children’s toys and outdoor playset components where the article is not a living-hinge design. Toy-specific compliance under EN 71-3:2019+A1:2021 migration of eight elements and ASTM F963-23 soluble heavy-metal limits must be verified on the final pigmented part because some masterbatches contribute barium or zinc; physical mechanical testing includes ASTM D638-14 tensile and ASTM D256-23 Izod. Formulation generally uses 98–100 wt% HD54200 and 2–4 wt% colour masterbatch; no impact modifier is needed for wall thickness above 2.0 mm, but thin-walled play panels below 1.0 mm may incorporate 10–15 wt% octene LLDPE to resist corner cracking. Processing is performed at melt temperature 190–230°C, mold temperature 15–30°C, injection speed 40–100 mm/s, and pack pressure 40–60 MPa, with total cycle 15–25 s. The primary limitation is odour and extractables generation at melt temperatures above 230°C, so processors cap hot-runner manifold temperatures accordingly. Terminal products include toy building blocks, outdoor sand and water play molds, and rigid recreational accessories.

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    Certification & Compliance
    More Introduction
    ExxonMobil HDPE HD54200 is a high-density polyethylene blow molding grade supplied as pelletized resin for extrusion blow molding of rigid containers and industrial packaging. The nominal density is 0.954 g/cm³ when determined in accordance with ISO 1183-1:2019. The melt flow rate is 0.20 g/10 min at 190 °C/2.16 kg using ISO 1133-1:2022, and the high-load melt index is 20 g/10 min at 190 °C/21.6 kg under the same standard. These rheological values place HD54200 in the high-molecular-weight HDPE envelope intended for accumulator-head and shuttle blow molding, not for thin-wall injection molding or cast film extrusion. The ratio of high-load melt index to standard melt flow rate is approximately 100, indicating a broad molecular weight distribution and pronounced shear thinning during extrusion. The resin is supplied with a standard processing antioxidant package and acid scavenger. It does not contain slip or anti-block additives of the type used in blown film grades. This additive position reduces the risk of plate-out in blow molding heads and allows end-use additives such as color concentrates, UV stabilizers, or antistatic masterbatches to be introduced at the feed throat without antagonistic interactions. The base polyethylene is a copolymer; the density of 0.954 g/cm³ is deliberately below the 0.960 g/cm³ threshold of highly stiff HDPE injection molding grades, preserving environmental stress crack resistance at the expense of a small reduction in flexural modulus.

    Where Does HD54200 Sit Within the Density and Flow Range of Polyethylene Blow Molding Grades?

    The product is differentiated from standard injection molding HDPE by its low standard melt flow rate and from very high-molecular-weight film grades by its moderate high-load melt index. An injection molding grade with a melt flow rate above 20 g/10 min flows readily into thin walls but lacks the melt strength required to support a parison during extrusion blow molding. A film grade with a high-load melt index below 5 g/10 min may generate excessive backpressure in a blow molding extruder and may not exhibit the parison diameter swell needed for container pinch-off zones. HD54200 is therefore positioned where die swell is sufficient for container wall formation but melt pressure at the die remains within conventional machine limits. The following nominal property values are used in production specification reviews and are not maximum or minimum lot-release values unless separately agreed. The values are typical for the grade family and are expressed under the standard conditions shown.
    Table 1 — Nominal physical and mechanical properties of ExxonMobil HDPE HD54200
    PropertyTest standardNominal value
    Density at 23 °CISO 1183-1:20190.954 g/cm³
    Melt flow rate at 190 °C/2.16 kgISO 1133-1:20220.20 g/10 min
    High-load melt index at 190 °C/21.6 kgISO 1133-1:202220 g/10 min
    Tensile stress at yieldISO 527-2:2012, type 1BA specimen, 50 mm/min26 MPa
    Tensile elongation at breakISO 527-2:2012>600%
    Flexural modulusISO 178:20191100 MPa
    Environmental stress crack resistance, 100% Igepal CO-630, F50ASTM D1693-21, condition A>50 h
    Vicat softening temperature, A120ISO 306:2022127 °C
    Shore D hardness, 15 sISO 868:200364
    Charpy notched impact strength at 23 °CISO 179-1:201022 kJ/m²
    Lot-to-lot variation in the 0.20 g/10 min melt flow rate is typically controlled within ±0.03 g/10 min for blow molding operations; wider variation increases the risk of parison sag or insufficient wall distribution. The 0.954 g/cm³ density is typically controlled within ±0.002 g/cm³. These ranges are production controls observed in polymer manufacturing and are not ASTM or ISO specification limits.

    Rheological Boundaries in Extrusion Blow Molding

    On a shuttle blow molding machine equipped with an 80 mm grooved-feed extruder and a 24:1 length-to-diameter screw, HD54200 is processed in the melt temperature window of 180 °C to 205 °C. The lower bound is set by melt homogenization and surface finish; below 180 °C, the viscosity is high enough to produce melt fracture at the die lip and poor weld-line strength in the container handle. The upper bound is set by oxidative degradation; above 205 °C, the residence time in the accumulator head can lead to odor formation and yellowing. The die head temperature is held between 190 °C and 205 °C. Mold temperature is maintained between 10 °C and 40 °C, with lower temperatures favoring shorter cycle times and higher temperatures favoring lower residual stress. At the die entrance, accumulator-head machines processing HD54200 often operate with hydraulic pressures of 18 MPa to 25 MPa depending on screw speed and die gap. The parison swell is reported in field trials as approximately 45% to 60% at a 190 °C melt temperature and a 3 mm die gap; published data for this specific configuration is limited to proprietary mold trial records. Blow pressure is set at 0.6 MPa to 0.9 MPa. Lower blow pressure may produce incomplete detail in molded-in threads and handle pinch-off, while higher pressure can increase flash and mold parting-line stress. Pre-drying is generally not required for HD54200 when the pellets are stored in closed silos or dry warehouses. If surface condensation occurs from storage below dew point, the resin should be dried at 80 °C for 2 h using a desiccant dryer with a dew point of -40 °C or lower. Vent ports on the extruder should be kept clear; moisture levels above 0.02 wt% at feed can cause melt-phase hydrolysis of process stabilizers and surface splay.

    When the Container Geometry Requires Cyclic Loading and Chemical Resistance at Low Wall Thickness

    HD54200 is used in monolayer containers for household detergents, agricultural chemical packs, industrial liquids, and automotive fluids where wall thickness is reduced to control weight but the container must withstand top-load compression, drop impact, and environmental stress cracking. The density of 0.954 g/cm³ provides sufficient flexural modulus for top-load stability; container design rather than resin modulus is the dominant factor in vertical load resistance because stress is distributed through the sidewall profile and base geometry. The environmental stress crack resistance measured under ASTM D1693-21 condition A is a relative indicator of performance in contact with surfactants and agrochemical formulations. The F50 value above 50 h in 100% Igepal CO-630 distinguishes HD54200 from lower-molecular-weight HDPE blow molding grades that may fail below 20 h under identical conditions. The difference is partly due to comonomer distribution and molecular weight; resins with higher density and narrower molecular weight distribution develop higher molded-in stress and lower tie-molecule concentration at the same cooling rate. Published data for this specific configuration is limited, but the controlled density of HD54200 is below the 0.958 g/cm³ level at which environmental stress crack resistance in HDPE often declines steeply. The resin is not classified as a high-temperature service material. Continuous service above 60 °C in the presence of aggressive organic surfactants should be avoided unless container testing under the actual chemical formulation demonstrates acceptable stress crack resistance. HDPE containers exposed to aromatic hydrocarbons, chlorinated solvents, or strong oxidizing acids can swell, lose mechanical strength, or undergo environmental stress cracking if molded-in stress is high.

    Compliance Matrix and Conditions for Regulated Use

    The base olefin polymer is a high-density polyethylene produced from ethylene and a higher alpha-olefin comonomer. Regulatory applicability depends on the complete article, including colorants, masterbatches, and processing aids added downstream.
    Table 2 — Regulatory assessment framework for HD54200 in typical containers
    Regulation or standardReferenceCondition or limitation
    U.S. food contactFDA 21 CFR 177.1520High-density polyethylene olefin polymers may be used as articles or components of articles intended for food contact; specific migration and additive authorization must be confirmed for the final formulation.
    European food contactEU No 10/2011, overall migration via EN 1186-1Compliance is assessed on the final article; migration limit is 10 mg/dm² for plastic articles.
    REACHEC 1907/2006, Article 2(9)Polymers are exempt from registration, but ethylene and hexene monomers must meet registration requirements in the supply chain.
    RoHSDirective 2011/65/EU, IEC 62321 seriesApplicable only to electrical and electronic equipment; unmodified HDPE does not contain lead, cadmium, mercury, hexavalent chromium, PBB, or PBDE above the restricted thresholds.
    Chemical resistance classificationISO 22088-1 or ASTM D543-21HD54200 should be tested in the actual packaged liquid; no universal chemical resistance certificate can replace immersion testing under stress.

    Known Operational Boundaries and Incompatibilities

    HD54200 is not formulated for injection molding. The low standard melt flow rate of 0.20 g/10 min and high viscosity at shear rates below 100 s⁻¹ produce excessive pressure drop in thin-wall molds. Injection molding of this resin can result in short shots, high gate stresses, and weld lines with reduced impact strength. For thin-wall closures or caps, a high-flow HDPE or polypropylene grade is preferred. The resin is not recommended for film extrusion. Blown film lines with narrow die gaps below 1 mm experience high die pressure and melt fracture; the grade does not contain the polymer processing aids required for low-extrusion-pressure film operations. Cast film use is also not supported because the high molecular weight limits drawdown and inhibits gauge uniformity. In blow molding, the melt temperature should not remain above 205 °C for more than 10 min in accumulator heads. Prolonged high-temperature residence promotes chain scission and crosslinking reactions that shift melt viscosity and can produce gel particles. If gels appear on the container surface, the first corrective action is to lower head temperature and reduce screw speed, not to add processing aid. The standard grade is not UV-stabilized. Outdoor storage of containers made from HD54200 above 6 months in direct sunlight may result in surface embrittlement and loss of impact strength due to photo-oxidation. For outdoor service, a hindered amine stabilizer or carbon black masterbatch is added at the blow molding machine; the addition level is typically 2 wt% to 3 wt%, but the specific masterbatch recommendation depends on the final wall thickness and exposure latitude. The resin is not compatible with all chemical formulations. Strong oxidizing acids at elevated temperature, aromatic hydrocarbons, and halogenated solvents are outside the recommended service envelope. Prolonged contact with some nonionic surfactants at concentrations above 10 wt% can accelerate environmental stress cracking; container qualification should include ASTM D1693-21 testing after exposure to the actual liquid at the intended storage temperature. HD54200 differs from a high-stiffness HDPE injection molding grade by having a lower density, lower melt flow rate, and higher environmental stress crack resistance. It differs from a very high-molecular-weight HDPE film grade by having a higher high-load melt index and lower melt pressure in blow molding dies. These differences govern its position in the polyethylene family.
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