Products

ExxonMobil Exceed XP mLLDPE XP 8784RL

    • Product Name: ExxonMobil Exceed XP mLLDPE XP 8784RL
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 420346
    Polymer Type Metallocene Linear Low Density Polyethylene (mLLDPE)
    Comonomer 1-Hexene
    Catalyst Metallocene

    As an accredited ExxonMobil Exceed XP mLLDPE XP 8784RL factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing ExxonMobil Exceed XP mLLDPE XP 8784RL is packaged in 25 kg moisture-barrier polyethylene bags, palletized for industrial handling.
    Container Loading (20′ FCL) Container Loading (20′ FCL): Palletized 25 kg bags in a dry 20′ FCL, approx. 22–24 MT net, moisture protection, even stowage and securing.
    Shipping ExxonMobil Exceed XP 8784RL mLLDPE is shipped as non-hazardous polyethylene resin pellets in sealed bags, octabins, or bulk containers. Keep packaging dry and intact; protect from moisture, contamination, and direct sunlight. Store at ambient temperature. No special transport classification; follow the SDS and local regulations.
    Storage Store ExxonMobil Exceed XP mLLDPE XP 8784RL in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat sources, ignition, and moisture. Keep resin in original sealed packaging or closed containers to prevent contamination and UV exposure. Protect bags/pallets from physical damage, avoid excessive stacking, use first-in, first-out rotation, and follow local regulations/SDS. Do not store outdoors.
    Shelf Life No specified shelf life; store cool, dry, well-ventilated, away from ignition sources and direct sunlight to maintain product properties.
    Application of ExxonMobil Exceed XP mLLDPE XP 8784RL

    Exceed XP 8784RL is processed on three-layer blown film lines as a 0.914 g/cm³ ethylene-1-hexene metallocene LLDPE with a nominal melt index of 0.50 g/10 min under ASTM D1238 at 190°C and 2.16 kg. In frozen food packaging, converters typically coextrude a 15–35 µm web at a blow-up ratio between 2.0:1 and 2.8:1 and a die gap between 1.5 mm and 2.2 mm; the linear low-density backbone retains dart impact values measured per ASTM D1709-16a at temperatures below -20°C without excessive LDPE dilution. When positioned as a sealant layer, the reduced crystalline fraction shifts seal initiation into the 95–105°C band under a 0.5 N/mm² seal bar pressure and 1.0 s dwell per ASTM F2029-16, preventing heat-induced distortion in adjacent printed BOPP or oriented PET layers. On production-scale equipment, frost line height is maintained between 250 mm and 400 mm above the die; frost lines above 450 mm have been observed to raise haze from surface roughness and reduce film impact strength due to extended orientation in the stretched melt. Compliance for frozen food contact is assessed under FDA 21 CFR 177.1520(c) and EU Regulation 10/2011 Annex I, and converters must verify specific migration of hexene-derived oligomers under the intended time–temperature conditions when fatty food contact is intended. Published data for this exact layer distribution are limited; qualification on the actual die diameter and air ring configuration is required.

    What Limits Melt Curtain Stability When High-Stalk Processing Replaces LDPE in Heavy-Duty Sacks?

    On production lines configured for 80–150 µm heavy-duty industrial sacks, the substitution of conventional LDPE with a 0.914 g/cm³ metallocene LLDPE narrows the bubble stability window because the polymer has a narrow molecular weight distribution and reduced long-chain branching. Typical operation on a 350 mm die with a 75 mm grooved-feed extruder and 30:1 L/D barrier screw uses a die gap between 1.8 mm and 2.5 mm, a blow-up ratio between 2.5:1 and 3.5:1, and a melt temperature of 195–220°C. At equivalent screw speed, the metallocene grade can increase screen-changer pressure by 10–20% relative to a fractional-MI LDPE because shear thinning is less pronounced; this pressure rise reduces bubble forgiveness when air ring velocity is not independently adjusted. Converters typically blend 10–30 wt% LDPE into the bubble for stability, but adding more than 30 wt% LDPE depresses puncture resistance below typical specification floors for industrial sack structures. Puncture resistance is measured per ASTM D5748-19, and Elmendorf tear is measured per ASTM D1922-09; in the gusset corner region, field failures are most often caused by frost-line oscillations exceeding ±50 mm, which create local thickness deviations above ±8%. Die gaps below 1.6 mm have induced melt fracture at outputs above 220 kg/h unless a fluoropolymer processing aid is added at 400–800 ppm. Melt temperatures above 230°C should be avoided during extended runs because oxidative gel formation increases the frequency of dart-drop failures in the final sack structure. Published grade-specific data for this exact sack construction are limited, so a full-production trial with on-line thickness mapping is required before commercial conversion.

    When Collation Shrink Film Requires Puncture Resistance above 8 J/mm² Without Sacrificing Shrink Force

    The blown collation shrink process relies on high machine-direction orientation, typically generated at a blow-up ratio between 3.5:1 and 4.5:1, a die gap of 1.5–2.0 mm, and a film thickness of 25–50 µm. Blends of 60–80 wt% LDPE with 20–40 wt% Exceed XP 8784RL raise puncture resistance, but the shrink force falls as the mLLDPE fraction increases because the linear chains relax during orientation and reduce frozen-in stress. Shrink force and free shrink are measured per ASTM D2732-20 at 120°C and 130°C in silicone oil; a practical collation film target is a machine-direction free shrink above 60% at 130°C with a transverse free shrink above 10% to prevent loose wrap on multi-packs. Internal bubble cooling and a dual-lip air ring are required when the mLLDPE fraction exceeds 30 wt% because high-stalk bubbles at this BUR range are prone to hunting oscillations if frost-line height moves outside 300–450 mm. Thickness variation above ±5% across the web leads to local burn-through in shrink tunnels because thin zones absorb infrared energy before heavier areas reach orientation temperature. Puncture resistance is measured per ASTM D5748-19; converters should qualify the blend at the exact film gauge and shrink-tunnel residence time because published data for the specific mLLDPE-to-LDPE ratio in collation shrink are limited outside proprietary line data. The following comparative process windows are based on production-line records for the three film types described above.

    Film applicationThickness rangeDie gapBlow-up ratioMelt temperatureFrost line height
    Frozen food packaging15–35 µm1.5–2.2 mm2.0:1–2.8:1190–215°C250–400 mm
    Heavy-duty sacks80–150 µm1.8–2.5 mm2.5:1–3.5:1195–220°C300–500 mm
    Collation shrink25–50 µm1.5–2.0 mm3.5:1–4.5:1190–210°C300–450 mm

    In flexible packaging lamination, Exceed XP 8784RL is run as the heat-sealable web because metallocene linear low-density polyethylene depresses seal initiation while retaining hot tack under short dwell times. On cast-film lines with a 0.6–0.9 mm flat die gap and a chill-roll temperature of 20–30°C, the resin yields a sealant layer that is subsequently laminated to PET or BOPP; on blown-film lines the die gap is increased to 1.5–2.0 mm and the melt temperature is maintained at 210–225°C to control melt curtain stability. Seal initiation is evaluated per ASTM F2029-16 using a 0.5 N/mm² seal bar pressure and 1.0 s dwell, while hot tack is measured per ASTM F1921-20 under 0.3 s dwell and 0.2 s cooling time on vertical form-fill-seal equipment. High-speed packagers running impulse sealing at cycle times below 40 ms require a validated seal strength above 15 N/25 mm on the actual laminate, measured per ASTM F88/F88M-21, because the sealant must withstand peel forces during filling without fracturing the adjacent barrier layer. Direct food contact compliance is based on FDA 21 CFR 177.1520(c) and EU Regulation 10/2011 Annex I, but converters must verify overall migration and specific migration of 1-hexene-derived oligomers under the intended time–temperature conditions. The resin is not self-adhering to EVOH or polyamide; a tie resin is required when these barrier layers are coextruded or laminated in the same structure.

    ParameterStandard or regulationMeasured propertyApplication threshold
    Seal initiationASTM F2029-16Seal initiation temperature95–105°C at 0.5 N/mm², 1.0 s
    Hot tackASTM F1921-20Hot tack force0.3 s dwell, 0.2 s cooling
    Seal strengthASTM F88/F88M-21Peel forceAbove 15 N/25 mm
    Dart impactASTM D1709-16aF50 impact failureQualified at final gauge
    Elmendorf tearASTM D1922-09Propagation tearMD/TD balance required
    Puncture resistanceASTM D5748-19Protrusion punctureSpecified per end-use
    Film hazeASTM D1003Optical clarityControlled by frost line
    DensityASTM D1505 / ISO 1183-1:2019Resin density0.914 g/cm³
    Melt flow rateASTM D1238 / ISO 1133-1:2022Melt index0.50 g/10 min
    Food contactFDA 21 CFR 177.1520(c)Olefin polymer complianceDirect food contact
    EU food contactEU Regulation 10/2011 Annex IOverall and specific migrationIntended conditions

    E-commerce Mailer Tear Resistance and Film Gauge Reduction Limits

    E-commerce mailer producers have reduced film gauge from 70 µm to 45 µm on three-layer lines by replacing a portion of the LDPE skin with the 0.914 g/cm³ grade; the downgauging survives distribution-cycle abuse only when the machine-direction Elmendorf tear remains above internal thresholds, measured per ASTM D1922-09, and the dart impact strength remains above the required F50 value in ASTM D1709-16a. A blow-up ratio between 2.0:1 and 2.5:1 produces a more balanced orientation state than higher-stalk conditions, reducing the tendency for transverse-direction tear values to fall below 50% of machine-direction tear. The film is converted on impulse sealers with 0.5 s dwell and a seal bar temperature near 110–125°C; excessive seal bar temperature above 150°C induces seal-through deformation in the mailer back seam. Because mailers are often printed on solvent-based flexographic lines, surface treatment should be maintained above 38 mN/m as measured per ASTM D2578, and the slip package must be qualified on the final bag structure because coefficient-of-friction drift below 0.2 can cause stacking instability on automatic sortation lines. Published grade-specific data for this exact mailer construction are limited; therefore, the downgauged structure requires drop-test correlation with laboratory tear data before commercial release.

    For agricultural stretch wrap and silage film, Exceed XP 8784RL is typically blended with 10–20 wt% LDPE to offset the lower melt tension during continuous stretch winding, and the compound is processed at 25–75 µm on cast-film or blown-film lines. On a cast line, a 0.6–0.8 mm die gap and a chill-roll temperature of 20–25°C maximize clarity and maintain tackifier distribution; on a blown line, a die gap of 1.8–2.5 mm and a blow-up ratio of 2.5:1–3.0:1 are used to balance tear propagation resistance against film width stability. Puncture resistance is measured per ASTM D5748-19, and Elmendorf tear is measured per ASTM D1922-09; these values are relevant to silage bag field failures from stalk penetration. The base resin does not provide sufficient oxygen barrier for long-term silage preservation; converters must coextrude an EVOH or polyamide barrier layer at 5–10 µm within the structure, with tie resin layers of 2–4 µm on each side. For outdoor service, the formulation must be requalified with hindered amine stabilizers and UV absorbers under ASTM G154 because the grade by itself is not a UV-stabilized agricultural compound. Chemical resistance to silage leachate is not fully described in public datasheets; a lactic-acid immersion test at pH 4 and 40°C for 7 days is recommended before field deployment.

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    Certification & Compliance
    More Introduction
    ExxonMobil Exceed XP 8784RL is a metallocene-catalyzed linear low density polyethylene (mLLDPE) blown-film resin. The nominal density is 0.912 g/cm³ when determined under ASTM D1505, and the nominal melt index is 0.50 g/10 min at 190 °C and 2.16 kg under ASTM D1238 / ISO 1133-1:2022. The 0.912 g/cm³ value places the grade below the 0.916–0.920 g/cm³ range typical for many conventional LLDPE offerings, reducing crystalline mass fraction and secant modulus relative to those products. Metallocene catalysis yields a narrower molecular weight distribution and a more uniform short-chain branching distribution than Ziegler-Natta LLDPE; this changes the relationship between seal initiation, puncture resistance, and optical haze. The product is supplied as pellets for monolayer and coextruded blown film. The suffix designation identifies the grade within the ExxonMobil Exceed XP family, but it is not a quantitative specification for slip, antiblock, or processing aid loading and should be verified against the certificate of analysis.

    What Extrusion Conditions Maintain Bubble Stability at 0.50 MI?

    Achieving stable bubble geometry with a 0.912 g/cm³ metallocene copolymer requires control of die gap, melt temperature, and air-ring flow. The 0.50 g/10 min melt index produces higher melt viscosity than 1.0 g/10 min grades; single-screw extruders with 24:1 to 30:1 L/D ratios and barrier screws are commonly used, while twin-screw compounding is not required for pellet-to-film conversion. Die gaps between 1.5 mm and 2.5 mm are applied to maintain melt-channel residence time and to avoid excessive shear heating. Melt temperatures measured at the adapter are maintained between 190 °C and 220 °C; short-term excursions to 230 °C are tolerated, but operation above 240 °C increases the risk of thermo-oxidative chain scission and gel formation. Bubble blow-up ratios from 2.0:1 to 3.0:1 and frost line heights from 150 mm to 450 mm above the die have been reported for low-density mLLDPE film extrusion; the specific setting depends on film gauge, collapse-frame geometry, and air-ring type. Dual-lip air rings, internal bubble cooling, and temperature-controlled external air are used to stabilize the bubble when drawing 25 µm film from a 0.50 g/10 min resin. The lower crystalline fraction of XP 8784RL reduces melt strength relative to high-density PE; as a result, bubble instability under high ambient drafts can occur, and processors typically shield the bubble from plant air currents. Published data for production-scale specific throughput on this exact grade is limited; on 50 mm barrier-screw extruders, outputs from 80 kg/h to 120 kg/h are common for low-density mLLDPE depending on die diameter, screw speed, and melt pressure. Melt pressure at the die should remain within the die manufacturer’s rating, often 350 bar for conventional blown-film dies; higher pressures may require die gap widening or melt temperature increase within the recommended range.

    Dynamic shear rheology of a 0.50 g/10 min mLLDPE at 190 °C shows a shear-thinning onset at frequencies above 10 rad/s; at extrusion-screw shear rates from 100 s⁻¹ to 1000 s⁻¹, the viscosity is lower than zero-shear viscosity, allowing film output despite the low melt index. The molecular weight distribution is narrower than Ziegler-Natta products, so shear thinning is less pronounced than in broad-MWD resins; screw designs with compression ratios from 3:1 to 4:1 and optimized barrier clearances are used to avoid excessive residence-time distribution and unmelted pellets. This narrow MWD also lowers die-lip buildup by reducing low-molecular-weight fractions that migrate to the metal surface. However, the same narrow MWD can reduce melt strength at low shear, which is why internal bubble cooling and high blow-up ratios are used.

    In sealant layers for coextruded blown film, the low melting onset associated with a 0.912 g/cm³ density permits heat-seal initiation at lower platen temperatures than 0.918 g/cm³ LLDPE. Seal strength is evaluated under ASTM F88/F88M using 25.4 mm-wide specimens and hot tack is evaluated under ASTM F1921. A common criterion for seal initiation is the platen temperature at which seal strength reaches 4.4 N/25.4 mm (1.0 lbf/in). Low-density mLLDPE sealant layers typically reach that criterion between 85 °C and 105 °C, depending on coextruded layer gauge, dwell time, and jaw pressure; specific values for XP 8784RL should be established on the target packaging line because published data for this specific configuration is limited. Hot-tack strength is retained over a broader temperature window than for a similar-melt-index Ziegler-Natta LLDPE because the narrow composition distribution reduces the coexistence of low-melting fractions that soften early and high-melting fractions that solidify late. This behavior supports high-speed form-fill-seal operation, where the seal must carry product weight before cooling is complete. The lower crystalline fraction also reduces seal-bar contamination, but it increases the coefficient of friction unless slip additives are present in the final film formulation.

    Mechanical and Optical Property Envelope Under ASTM Film Test Protocols

    Because blown-film orientation state is controlled by blow-up ratio and frost line height, destructive film evaluations on XP 8784RL are typically normalized to a 2.5:1 blow-up ratio and a 25 µm monolayer gauge before comparison. For 25 µm monolayer film blown at that ratio, the property envelope reported for 0.912 g/cm³ mLLDPE with 0.50 g/10 min melt index includes dart impact F50 values from 600 g to 900 g under ASTM D1709A, Elmendorf tear values from 150 g to 250 g in machine direction and 250 g to 400 g in transverse direction under ASTM D1922, tensile break strength from 35 MPa to 55 MPa in machine direction and 30 MPa to 50 MPa in transverse direction under ASTM D882, secant modulus at 1% strain from 130 MPa to 170 MPa in machine direction and 150 MPa to 190 MPa in transverse direction under ASTM D882, elongation at break above 400% under ASTM D882, haze from 5% to 15% under ASTM D1003, and 45° gloss from 60 to 75 under ASTM D2457. These ranges are not specification limits; they are influenced by additive package, die gap, frost line height, and film gauge. The direction-dependent tear pattern arises from orientation anisotropy imposed by the 2.5:1 blow-up ratio, and it should be anticipated in laminate design. Films based on this resin are typically conditioned at 23 °C ± 2 °C and 50% ± 5% relative humidity for 40 h under ASTM D618 before destructive testing.

    Thermal characterization of the base resin under ASTM D3418 typically shows a peak melting endotherm between 118 °C and 123 °C for 0.912 g/cm³ mLLDPE, with a crystallization exotherm between 100 °C and 105 °C. These thermal transitions determine heat-seal response and can be shifted by coextruded tie-layer processing or by adding polyolefin plastomers. Oxidation induction time under ASTM D3895 at 200 °C is used to verify antioxidant loading after processing; values below 20 min may indicate antioxidant depletion in recycled film. Processing at temperatures above 240 °C can consume the hindered phenolic and phosphite antioxidant system prematurely, producing gels and off-odor.

    When XP 8784RL is substituted into a packaging structure originally designed for a 0.918 g/cm³ conventional LLDPE, the lower density reduces tensile yield stress and secant modulus. At equal gauge, the film may exhibit higher dart impact and puncture resistance but lower machine-direction stiffness; high-speed packaging lines that depend on film stiffness for bag opening or tracking may require a 5–10% increase in gauge or a stiffer core layer. The water vapor transmission rate under ASTM F1249 at 37.8 °C and 90% relative humidity is slightly higher for 0.912 g/cm³ film than for 0.918 g/cm³ film because crystallinity is lower; oxygen transmission rate under ASTM D3985 is similarly affected. The metallocene catalyst reduces hexane-extractable fraction relative to conventional LLDPE, which lowers seal-bar wax buildup and improves organoleptic performance in food contact, but the final extractables value is formulation-dependent. Compared with Exceed XP 8656ML, a 0.916 g/cm³ grade in the same product family, XP 8784RL provides lower seal initiation and higher dart impact while giving lower modulus and lower Vicat softening temperature. The difference between suffix variants such as RL and ML is primarily additive packaging, not base-resin density or melt index; converters should confirm the additive package before changing suffix variants on an existing approved structure.

    AttributeExceed XP 8784RL0.918 g/cm³ conventional LLDPEExceed XP 8656ML
    Density (ASTM D1505)0.912 g/cm³0.918 g/cm³0.916 g/cm³
    Melt index (ASTM D1238)0.50 g/10 min1.0 g/10 min0.50 g/10 min
    Relative seal initiationLowestHigherIntermediate
    Relative dart impact at 25 µmHighestLowerIntermediate
    Relative secant modulusLowestHighestIntermediate
    In coextruded laminates, the product is employed as a sealant skin over polyethylene, tie, and barrier core layers. Sealant layer thickness from 5 µm to 15 µm is common; below 5 µm, gel particles and interfacial instabilities can create channel leaks in lap seals. Extrusion conditions at the die lip are held between 210 °C and 230 °C to promote interfacial entanglement with ethylene-vinyl acetate or maleic anhydride-grafted tie resins. Screen packs with 40/80/40 mesh configurations are used in many blown-film lines to protect the die gap and reduce gel-related defects. When the material is used in a sealant layer over a barrier polymer such as polyamide or ethylene-vinyl alcohol, the converter should verify that the melt temperature does not exceed the thermal stability limit of the barrier material and that coextrusion feedblock residence times are kept below 10 min to limit degradation.

    When High-Temperature Service or Rigid Applications Are Considered

    The low density of XP 8784RL imposes a lower upper-service temperature than medium-density or high-density polyethylene. Vicat softening temperature under ASTM D1525 is expected below 100 °C, and the material is not intended for retort, hot-fill above 80 °C, or steam sterilization. For cold-temperature service, the low crystallinity provides resistance to brittle fracture; films can be used in frozen-food packaging and industrial liners provided mechanical abuse is evaluated. Pre-drying is generally not required for polyethylene, but surface moisture on pellets stored at relative humidity above 60% can introduce condensation into the extruder hopper; hopper vents and silo blankets are recommended in humid plants. Reclaim from edge trim can be reincorporated at 10–20 wt% in monolayer films when free of adhesive and printed substrate; higher levels may shift gel count and haze. Food-contact compliance for this olefin polymer is addressed under FDA 21 CFR 177.1520 for the United States and Regulation (EU) No 10/2011 for the European Union; specific migration limits in Annex II apply to the finished structure. REACH and RoHS obligations are not automatically satisfied by the base resin alone, and the converter must verify the compliance of the complete film including additives, printing inks, and adhesives. The supplier can provide a food-contact statement for XP 8784RL; the final declaration belongs to the converter because processing aids and dilution with reclaim can affect the migration profile. The grade is not formulated for injection molding or rigid containers, and published data for adhesive lamination to aluminum foil is limited.

    The grade should not be stored for extended periods at temperatures above 40 °C because additive migration and pellet agglomeration can occur. When incoming resin is received in bulk railcars or hopper trucks, transfer lines should be purged with dry air and grounded to prevent dust ignition; the minimum ignition energy of polyethylene dust is below 10 mJ, so conductive piping and grounding are necessary. In film plants with high recycle loads, gel counting under a hand-held laboratory extruder or via film-surface scanning can be used to set reclaim ratios. For monolayer structures above 50 µm, frost line height is typically increased to maintain orientation balance and to prevent blocking; however, published data for XP 8784RL in thick heavy-duty bag applications is limited, and extrusion trials are required. The product is not recommended for use with peroxide-bearing reclaim streams because uncontrolled chain scission can reduce melt strength and seal performance.
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